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1.
Underground Hydrogen Storage (UHS) has received significant attention over the past few years as hydrogen seems well-suited for adjusting seasonal energy gaps.We present an integrated reservoir-well model for “Viking A″ the depleted gas field in the North Sea, as a potential site for UHS. Our findings show that utilizing the integrated model results in more reasonable predictions as the gas composition changes over time. Sensitivity analyses show that the lighter the cushion gas, the more production can be obtained. However, the purity of the produced hydrogen will be affected to some extent, which can be enhanced by increasing the fill-up period and the injection rate. The results also show that even though hydrogen diffuses into the reservoir and mixes up with the native fluids (mainly methane), the impact of hydrogen diffusion is marginal. All these factors will potentially influence the project's economics.  相似文献   

2.
Hydrogen storage can help achieve climate change and reduce greenhouse gas emissions. This paper presents a first assessment of the suitability of northeastern Italy for underground hydrogen storage (UHS). The study focuses on the analysis of publicly available well data, which allowed identifying geological formations potentially suitable for UHS. The most promising area, known as the “Treviso Area” consists of both saline aquifers and depleted gas fields. One of the key petrophysical properties, i.e. porosity, was calculated for each of the five wells revealing conditions potentially suitable for UHS by applying empirical formulas to geophysical log data. For the two depleted gas fields, a hydrogen injection simulation was also performed. This work is a pioneer study and lays the foundation for hopeful further analyses, which could help implement the recently launched “North Adriatic Hydrogen Valley” initiative.  相似文献   

3.
Underground Hydrogen Storage (UHS) is an emerging large-scale energy storage technology. Researchers are investigating its feasibility and performance, including its injectivity, productivity, and storage capacity through numerical simulations. However, several ad-hoc relative permeability and capillary pressure functions have been used in the literature, with no direct link to the underlying physics of the hydrogen storage and production process. Recent relative permeability measurements for the hydrogen-brine system show very low hydrogen relative permeability and strong liquid phase hysteresis, very different to what has been observed for other fluid systems for the same rock type. This raises the concern as to what extend the existing studies in the literature are able to reliably quantify the feasibility of the potential storage projects. In this study, we investigate how experimentally measured hydrogen-brine relative permeability hysteresis affects the performance of UHS projects through numerical reservoir simulations. Relative permeability data measured during a hydrogen-water core-flooding experiment within ADMIRE project is used to design a relative permeability hysteresis model. Next, numerical simulation for a UHS project in a generic braided-fluvial water-gas reservoir is performed using this hysteresis model. A performance assessment is carried out for several UHS scenarios with different drainage relative permeability curves, hysteresis model coefficients, and injection/production rates. Our results show that both gas and liquid relative permeability hysteresis play an important role in UHS irrespective of injection/production rate. Ignoring gas hysteresis may cause up to 338% of uncertainty on cumulative hydrogen production, as it has negative effects on injectivity and productivity due to the resulting limited variation range of gas saturation and pressure during cyclic operations. In contrast, hysteresis in the liquid phase relative permeability resolves this issue to some extent by improving the displacement of the liquid phase. Finally, implementing relative permeability curves from other fluid systems during UHS performance assessment will cause uncertainty in terms of gas saturation and up to 141% underestimation on cumulative hydrogen production. These observations illustrate the importance of using relative permeability curves characteristic of hydrogen-brine system for assessing the UHS performances.  相似文献   

4.
With the expected increase in the use of hydrogen as an energy carrier, large-scale underground storage sites will be needed. Unlike underground natural gas storage (UGS), many aspects on the performance of underground hydrogen storage (UHS) are not well understood, as there is currently no UHS in use for energy supply. Here we present the results of a detailed comparative performance study of UGS and UHS, based on an inflow/outflow nodal analysis. Three UGS sites in depleted gas fields and one in a salt cavern cluster in the Netherlands are used as case studies. The results show that although hydrogen can be withdrawn/injected at higher rates than natural gas, this can be limited by technical constraints. It also indicates that wider ranges of working pressures are required to increase the storage capacity and flow performance of an UHS site to compensate for the lower energy density of hydrogen.  相似文献   

5.
Underground hydrogen storage (UHS) in depleted hydrocarbon reservoirs is a prospective choice to store enormous volumes of hydrogen (H2). However, these subsurface formations must be able not only to store H2 in an effective and secure manner, but also to produce the required volumes of H2 upon demand. This paper first reviews the critical parameters to be considered for geological analysis and reservoir engineering evaluation of UHS. The formation depth, the interactions of rock-brine-H2, the caprock (seal) and well integrity are the most prominent parameters as far as UHS is concerned. In respect of these critical parameters, tentative H2 storage is screened from the existing gas storage fields in the Niigata prefecture of Japan, and it was revealed that the Sekihara gas field is a suitable candidate for UHS with a storage capacity of 2.06 × 108 m3 and a depth of 1000 m. Then, a series of numerical simulations utilizing CMG software was conducted to find out the extent to which critical parameters alter H2 storage capacity. The results demonstrated that this field, with a recovery factor of 82.7% in the sixth cycle of production is a prospective site for H2 storage.  相似文献   

6.
The underground hydrogen storage (UHS) capacities of shut down oil and gas (O&G) fields along the Norwegian continental shelf (NCS) are evaluated based on the publicly available geological and hydrocarbon production data. Thermodynamic equilibrium and geochemical models are used to describe contamination of hydrogen, loss of hydrogen and changes in the mineralogy. The contamination spectrum of black oil fields and retrograde gas fields are remarkably similar. Geochemical models suggest limited reactive mineral phases and meter-scale hydrogen diffusion into the caprock. However, geochemical reactions between residual oil, reservoir brine, host rock and hydrogen are not yet studied in detail. For 23 shut down O&G fields, a theoretical maximum UHS capacity of ca. 642 TWh is estimated. We conclude with Frigg, Nordost Frigg, and Odin as the best-suited shut down fields for UHS, having a maximum UHS capacity of ca. 414 TWh. The estimates require verification by site-specific dynamic reservoir models.  相似文献   

7.
Hydrogen is regarded as one of the most important energy sources for the future. Safe, large-scale storage of hydrogen contributes to the commercial development of the hydrogen industry. Use of bedded salt caverns for natural gas storage in China provides a new option for underground hydrogen storage (UHS). In this study, the physical properties of multicomponent gases in UHS and salt rock are reviewed and discussed, along with the flow of hydrogen in the surrounding salt rock. Mathematical models of the two-phase multicomponent flow of the gas–brine system in the UHS were established. A numerical model of a simplified elliptical salt cavern was built to simulate the migration of the gas–brine system in the UHS. The hydrogen tightness of the UHS was evaluated through simulation with different storage strategies, salt rock and interlayer permeabilities, and gas components. The results indicate that: (1) Cyclic injection and withdrawal facilitate hydrogen leakage, which is accelerated by increasing the frequency. (2) The huff-n-puff of hydrogen gas in the injection and withdrawal cycles forces the gas into pore space and enhances the relative permeability of the gas phase. The migration of hydrogen and brine weakens the hydrogen tightness. Brine saturation is an important index for evaluating the hydrogen tightness of UHS. (3) The leakage rate of UHS increases with an increase in the permeability of the salt rock and interlayer and the total thickness of the interlayers. The average permeability Kwa weighted by the thickness of layers for the bedded salt formation is proposed to integrate three variables to facilitate field application of the simulation results. The critical Kwa is less than 3.02 × 10−17 m2 if the recommended annual hydrogen leakage rate is less than 1%. (4) The difference between hydrogen and other gas species is another important factor in the leakage rate and should be considered. This study provides theoretical guidance for evaluating the feasibility of UHS in salt caverns and site selection in China.  相似文献   

8.
Underground hydrogen storage is considered an option for large-scale green hydrogen storage. Among different geological storage types, depleted oil/gas fields and saline aquifers stand out. In these cases, hydrogen will be prevented from leaking back to the surface by a tight caprock seal. It is therefore essential to understand hydrogen interactions with shale-type caprocks. To this end, natural pure montmorillonite clay was exposed to hydrogen gas at different pressures (0–50 bar) and temperatures (77, 195, 303 K) to acquire data on its adsorption capacity related to UHS and caprock saturation. Montmorillonite was chosen because of its large specific surface area enabling quantification of the adsorption process. Hydrogen adsorption was successfully fitted with a Langmuir isotherm model and yielded small partition coefficients indicating that hydrogen does not preferentially adsorb to the clay surface. Adsorption on montmorillonite goes back to weak physisorption as inferred from minor negative changes in the enthalpy of reaction (−790 J/mol), derived from an Excel Solver approach to the van't Hoff equation. Based on own as well as literature values, adsorption capacities, which were originally reported as mol/kg or wt%, are recast as hydrogen volume adsorbed per specific surface area (μL/m2). The acquired range is surprisingly narrow, with values ranging from 3 to 6 μL/m2, and indicates the normalised volume of hydrogen that can be expected to remain in the shale-type caprock after injected hydrogen migrated upwards through the porous reservoir. This ‘residual’ caprock saturation with hydrogen can be further restrained by considering the geothermal gradient and its effect on the molar volume of hydrogen. The experimental results presented here recommend injecting hydrogen deeper rather than shallower as pressure and temperature work in favour of increased storage volumes and decreased hydrogen loss through clay adsorption in the caprock.  相似文献   

9.
Increased emissions of greenhouse gasses into the atmosphere has adversely been contributing to global warming as a result of burning fossil fuels. Therefore, the energy sectors have been looking into renewable sources such as wind, solar, and hydro energy to make electricity. However, the strongly fluctuating nature of electricity from such energy sources requires a bulk energy storage system to store the excess energy as a buffer and to fulfill the demand constantly. Underground storage is a proven way to store a huge amount of energy (electricity) after converting it into hydrogen as it has higher energy content per unit mass than other gases such as methane and natural gas. This paper reviews the technical aspects and feasibility of the underground storage of hydrogen into depleted hydrocarbon reservoirs, aquifers, and manmade underground cavity (caverns). Mechanisms of underground hydrogen storage (UHS) followed by numerous phenomena such as hydrodynamics, geochemical, physiochemical, bio-chemical, or microbial reactions have been deliberated. Modeling studies have also been incorporated in the literature to assess the feasibility of the process that are also reviewed in this paper. Worldwide ongoing lab study, field study together with potential storage sites have been reported as well. Technical challenges along with proper remedial techniques and economic viability have been briefly discussed. Finally, this paper delivers some feasible strategies for the underground hydrogen storage process, which would be helpful for future research and development of UHS.  相似文献   

10.
As hydrogen provides a high heating value with the least environmental impact, it can be considered as an energy carrier pioneer in following the global zero-carbon policies. Then, since storing hydrogen in large quantities can also be a valuable technique for alleviating energy shortages due to energy consumption fluctuations, underground hydrogen storage (UHS) is being explored further in today's world. To the best of our knowledge, the role of fracture on underground hydrogen storage performance has not comprehensively been evaluated. For the first time, in this study, the effects of fracture on hydrogen storage and production were investigated in a naturally fractured gas reservoir in the Middle East using a numerical simulation. Then, to determine whether the fracture was able to accelerate hydrogen production, UHS was evaluated under various conditions, including the fracture system, condensate presence, Initial hydrogen injection stage, cushion gas type, hydrogen storage commence time and different injection/production cycle duration. The results of this study proves that although a huge amount of hydrogen is invaded into the matrix during hydrogen injection, the fracture accelerates hydrogen production, resulting in higher hydrogen recovery and purity, which indicates fractures are suitable media for hydrogen storage. However, it should be noted that the purity of hydrogen produced from naturally fractured reservoirs (NFR) decreases more rapidly than a conventional one during a single cycle due to the higher mixing of gases in the fracture. In the case of the initial stage of hydrogen injection, fractures are not found to be attractive as storage media. Therefore, it is necessary to analyze the fracture effects as a storage media under various situations and stages. In addition, alternative gas injection revealed that nitrogen injection into cushion gas resulted in the highest hydrogen production in the entire porous media, whereas methane injection led to the highest hydrogen recovery in the fracture media. Also, the rapid injection/production cycle duration improved hydrogen recovery, indicating that the required time for high hydrogen invasion into the matrix is not provided during hydrogen injection.  相似文献   

11.
Hydrogen stored on a large scale in porous rocks helps alleviate the main drawbacks of intermittent renewable energy generation and will play a significant role as a fuel substitute to limit global warming. This study discusses the injection, storage and production of hydrogen in an open saline aquifer anticline using industry standard reservoir engineering software, and investigates the role of cushion gas, one of the main cost uncertainties of hydrogen storage in porous media.The results show that one well can inject and reproduce enough hydrogen in a saline aquifer anticline to cover 25% of the annual hydrogen energy required to decarbonise the domestic heating of East Anglia (UK). Cushion gas plays an important role and its injection in saline aquifers is dominated by brine displacement and accompanied by high pressures. The required ratio of cushion gas to working gas depends strongly on geological parameters including reservoir depth, the shape of the trap, and reservoir permeability, which are investigated in this study. Generally, deeper reservoirs with high permeability are favoured. The study shows that the volume of cushion gas directly determines the working gas injection and production performance. It is concluded that a thorough investigation into the cushion gas requirement, taking into account cushion gas costs as well as the cost-benefit of cushion gas in place, should be an integral part of a hydrogen storage development plan in saline aquifers.  相似文献   

12.
Hydrogen is an integral component of the current energy transition roadmap to decarbonize the economy and create an environmentally-sustainable future. However, surface storage options (e.g., tanks) do not provide the required capacity or durability to deploy a regional or nationwide hydrogen economy. In this study, we have analyzed the techno-economic feasibility of the geologic storage of hydrogen in depleted gas reservoirs, salt caverns, and saline aquifers in the Intermountain-West (I-WEST) region. We have identified the most favorable candidate sites for hydrogen storage and estimated the volumetric storage capacity. Our results show that the geologic storage of hydrogen can provide at least 72% of total energy consumption of the I-WEST region in 2020. We also calculated the capital and levelized costs of each storage option. We found that a depleted gas reservoir is the most cost-effective candidate among the three geologic storage options. Interestingly, the cushion gas type plays a significant role in the storage cost when we consider hydrogen storage in saline aquifers. The levelized costs of hydrogen storage in depleted gas reservoirs, salt caverns, and saline aquifers with large-scale storage capacity are approximately $1.15, $2.50, and $3.27 per kg of H2, respectively. This work provides essential guidance for the geologic hydrogen storage in the I-WEST region.  相似文献   

13.
With the rising potential of underground hydrogen storage (UHS) in depleted oil and gas reservoirs or deep saline aquifers, questions remain regarding changes to geological units due to interaction with injected hydrogen. Of particular importance is the integrity of potential caprocks/seals with respect to UHS. The results of this study show significant dissolution of calcite fossil fragments in claystone caprock proxies that were treated with a combination of hydrogen and 10 wt% NaCl brine. This is the first time it has been experimentally observed in claystones. The purpose of this short communication is to document the initial results that indicate the potential alteration of caprocks with injected hydrogen, and to further highlight the need for hydrogen-specific studies of caprocks in areas proposed for UHS.  相似文献   

14.
Hydrogen has attracted attention worldwide with its favourable inherent properties to contribute towards a carbon-free green energy future. Australia aims to make hydrogen as its next major export component to economize the growing global demand for hydrogen. Cost-effective and safe large-scale hydrogen storage in subsurface geology can assist Australia in meeting the projected domestic and export targets. This article discusses the available subsurface storage options in detail by first presenting the projected demand for hydrogen storage. Australia has many subsurface formations, such as depleted gas fields, salt caverns, aquifers, coal seams and abandoned underground mines, which can contribute to underground hydrogen storage. The article presents basin-wide geological information on the storage structures, the technical challenges, and the factors to consider during site selection. With the experience and knowledge Australia has in utilizing depleted reservoirs for gas storage and carbon capture and sequestration, Australia can benefit from the depleted gas reservoirs in developing hydrogen energy infrastructure. The lack of experience and knowledge associated with other geostructures favours the utilization of underground gas storage sites for the storage of hydrogen during the initial stages of the shift towards hydrogen energy. The article also provides future directions to address the identified important knowledge gaps to utilize the subsurface geology for hydrogen storage successfully.  相似文献   

15.
Underground hydrogen storage (UHS) appears to be an important means as a large-scale and long-term energy storage solution. A primary concern of UHS is the in-situ geochemical reactions-induced hydrogen loss. In this context, we performed geochemical modelling to examine the hydrogen loss associated with hydrogen dissolution and fluid-rock interactions using PHREEQC (Version 3) as a function of temperature and pressure. We also performed geochemical modelling with kinetics to investigate the potential hydrogen loss in two commercial gas storage reservoirs (Tubridgi and Mondarra) in Western Australia against the reservoir mineralogy, fluid properties, depth and temperature.Our results show that increasing pressure and temperature only slightly increases hydrogen solubility in brines without minerals. Increasing salinity slightly decreases the solubility of hydrogen in brines. The saturated hydrogen aqueous solution almost does not react with silicate and clay minerals, which is favorable for underground hydrogen storage in quartz-rich sandstone reservoirs. However, unlike silicate and clay minerals, carbonates like calcite triggers up to 9.5% hydrogen loss due to calcite dissolution induced hydrogen dissociation process. Kinetic simulations show that Tubridgi only leads to 0.72% of hydrogen loss, and Mondarra causes 2.76% of hydrogen loss as a result of reservoir calcite dissolution and hydrogen dissociation in brines in 30-year time. Nearly over 87% of calcite cement from Mondarra may be dissolved in 30-year, suggesting potential risks associated with wellbore stability. In conclusion, geochemical reactions-induced hydrogen loss would be minor for UHS in porous media, and we argue that deep calcite-free reservoirs together with calcite-free caprocks would be preferable for underground hydrogen storage.  相似文献   

16.
Hydrogen usage and storage may contribute to reducing greenhouse gas emissions by decarbonising heating and transport and by offering significant energy storage to balance variable renewable energy supply. Underground storage of hydrogen is established in underground salt caverns, but these have restricted geographical locations within the UK and cannot deliver the required capacity. Hydrogen storage in porous geological formations has significant potential to deliver both the capacity and local positioning. This study investigates the potential for storage of hydrogen in porous subsurface media in Scotland. We introduce for the first time the concept of the hydrogen storage play. A geological combination including reservoir, seal and trap that provides the optimum hydrogen storage reservoir conditions that will be potential targets for future pilot, and commercial, hydrogen storage projects. We investigate three conceptual hydrogen storage plays in the Midland Valley of Scotland, an area chosen primarily because it contains the most extensive onshore sedimentary deposits in Scotland, with the added benefit of being close to potential consumers in the cities of Glasgow and Edinburgh. The formations assessed are of Devonian and Carboniferous age. The Devonian storage play offers vast storage capacity but its validity is uncertain due to due to a lack of geological data. The two Carboniferous plays have less capacity but the abundant data produced by the hydrocarbon industry makes our suitability assessment of these plays relatively certain. We conclude that the Carboniferous age sedimentary deposits of the D'Arcy-Cousland Anticline and the Balgonie Anticline close to Edinburgh will make suitable hydrogen storage sites and are ideal for an early hydrogen storage research project.  相似文献   

17.
Subsurface hydrogen storage in depleted hydrocarbon reservoirs and saline formations is a potential option for storing hydrogen at large scales. These subsurface formations need to store sufficient hydrogen efficiently and securely, and the hydrogen must be withdrawn in adequate quantities on demand. In this study, we investigate the reservoir, geological, and operational controls that enable large-scale hydrogen storage and maximize hydrogen injection and withdrawal from depleted natural gas reservoirs. Hydrogen injection, storage, and withdrawal scenarios were computed using a reservoir simulator. Sensitivity analyses exposed the crucial parameters to achieve the goal of optimum storage and withdrawal of hydrogen. We determined that reservoirs with smaller pressures at the start of storage operations are suitable for hydrogen storage if wellhead pressure constraints permit. Steeply dipping reservoirs enable better hydrogen withdrawal if the reservoirs have good permeability (greater than 100 mD) and the injection/withdrawal well is placed updip within the reservoir. Permeable reservoirs and reservoirs with sufficient thickness increase hydrogen withdrawal rates. These findings and the results of the sensitivity analyses are used to propose site selection criteria for underground storage of hydrogen in depleted gas reservoirs.  相似文献   

18.
The underground hydrogen storage (UHS) in depleted hydrocarbon reservoirs, aquifers, and saline caverns is regarded as a vital component of hydrogen economy value-chains, meant to tackle carbon emissions and global warming. The caprock integrity and storage capacity of the carbonate formations can be altered by the reaction between the injected hydrogen and the calcite/dolomite minerals during UHS. However, experimental investigations of hydrogen-calcite/dolomite reactions at underground storage temperature are rarely reported in literature. Thus, we conducted X-ray computed micro-tomography (μCT) scans of limestone and dolomite cores before and after pressurization with hydrogen for 75 days at 700 psi and 75 °C. For the first time, a significant calcite expansion was observed and led to reduction in storage capacity (i.e., effective porosity) by 47%. However, the storage capacity of the dolomite rock slightly increased (~6%) because the grain expansion effects canceled out the dissolution effects. The study suggests that reduction in storage capacity of carbonate formation due to hydrogen reactivity with calcite is possible during UHS in carbonate formations. Thus, hydrogen reactivity with carbonate minerals should be evaluated to de-risk hydrogen storage projects in carbonate formations.  相似文献   

19.
Hydrogen is produced on a large scale by a wide variety of processes starting with feedstocks like natural gas, crude oil products to coal as well as water-using processes like steam reforming, partial oxidation, coal gasification, metal-water processes and electrolysis. Hydrogen is also recovered from various gas streams especially in refineries.Depending on the basic energy scenarios to be used, steam reforming natural gas will remain the major hydrogen source from today till tomorrow, i.e. the turn of the century. Coal gasification will significantly increase in its share for hydrogen production. This will be achieved via newly developed coal gasification processes.The development of thermochemical hydrogen production technology as well as biological hydrogen production technologies will progress, but their widespread application remains to be seen in the next century.  相似文献   

20.
    目的   文章研究规模化氢能供应链的经济性,未来十年,氢能作为战略能源将会重构社会的能源结构,并影响未来社会能源总成本。预测大规模氢能时代的制氢、储氢、输氢、分销、应用的成本,和市场化的趋势有着重要的意义。氢气由于高储运成本,用途、品质的多样性,氢气市场存在分层结构。分析氢能与常规能源的可比价格,提出原油当量价格(POE)的概念,预测未来氢能价格的合理区间。解决供应链问题是获得低成本氢能的关键,由此提出干线门站模式,解决绿氢的资源分布与长距离输送氢能的问题。    方法   利用平准化氢气成本(LCOH)分析模型,测算大型光伏制氢管道输氢LCOH,分析大规模可再生能源制氢输氢的经济性。利用氢能供应链的储、输、卸六个象限成本公式,分析气氢、液氢、固氢、有机氢、管道氢等不同储运技术,短距离氢储运成本,分析门站后输氢的场景和成本,预测短距离输氢的成本趋势。    结果   研究表明:我国有丰富的绿氢资源,随着投资下降,预计大规模绿氢管道输送的城市门站LCOH将低于2.0 RMB/Nm3,将成为未来主要的氢源。当前,氢储运技术气氢、液氢、甲醇、合成氨、有机氢、固氢、管道氢,随着规模的增加实现远距离输送。在现有的技术下,城市门站到终端的输送,氢短距输送(<100 km)测算成本都在1.2 RMB/Nm3以下,由此评估的氢能供应链的总成本,干线门站模式下氢能最终到达终端的价格约为3.2 RMB/Nm3,当量价格POE与汽油价格接近,考虑燃料电池的能效因素,氢能汽车在4.0 RMB/Nm3的氢价下,具有比汽油车更低的百公里燃料费用。    结论   因此,氢能作为战略能源,在无补贴的情况下实现中国氢能源的绿氢替代,在技术经济上是可行的。  相似文献   

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