Design criteria in PCM wall thermal storage

Performance criteria for a wall with an enclosed phase-change material (PCM) are discussed. Qualitative conclusions about how best to choose the PCM are derived and illustrated by means of computer simulations. Material properties dominating the heat-transfer process are identified and relations between them are determined.     

An analysis of a packed bed latent heat thermal energy storage system using PCM capsules: Numerical investigation

This paper is aimed at analyzing the behavior of a packed bed latent heat thermal energy storage system. The packed bed is composed of spherical capsules filled with paraffin wax as PCM usable with a solar water heating system. The model developed in this study uses the fundamental equations similar to those of Schumann, except that the phase change phenomena of PCM inside the capsules are analyzed by using enthalpy method. The equations are numerically solved, and the results obtained are used for the thermal performance analysis of both charging and discharging processes. The effects of the inlet heat transfer fluid temperature (Stefan number), mass flow rate and phase change temperature range on the thermal performance of the capsules of various radii have been investigated. The results indicate that for the proper modeling of performance of the system the phase change temperature range of the PCM must be accurately known, and should be taken into account.     

An organic PCM storage system with adjustable melting temperature

A proper storage temperature is an important criterion for selecting a phase change material (PCM) for a passive solar heating application. Here we describe a novel procedure to produce a mixture of carboxylic acids with a melting temperature adjustable to the climate specific requirements. The approach is based on the ideal solution model and differential scanning calorimetry (DSC). The applicability of the method is demonstrated and it is also applied to a PCM wall design. The accuracy of the theoretical model is ±2°C in the temperature range of 20°–30°C and even a ±0.5°C accuracy can be obtained by the experimental procedure.     

Numerical analysis on the thermal behavior of high temperature latent heat thermal energy storage system

High temperature latent heat thermal energy storage technology is a promising option for future cost reduction in parabolic trough or tower power plant. However, low thermal conductivity of phase-change material (PCM) is the major shortage of latent heat thermal energy storage. This paper proposed a new thermal energy storage system (TESS) that metal foam and fins were used to enhance the effective conductivity of PCM. Three-dimensional physical model was established for representative element extracted from TESS. Considering the natural convection in the liquid part of PCM, volume-averaged mass and momentum equations were employed with the Brinkman–Forchheimer extension to Darcy law to simulate the porous resistance. A local thermal equilibrium model was developed to obtain temperature field. The governing equations were solved with finite-volume approach and enthalpy method was employed to account for phase change. The model was firstly validated against low temperature experiments from the literature and then used to predict the charging and discharging behavior of the present TESS. The position of solid/liquid interface was explored and the effects of design parameters, including that of metal foam pore density and porosity, configuration of fin and Rayleigh number, on melting and solidifying rate and energy stored in each time step were revealed and discussed. The results indicate that metal foam and fins can effectively improve the heat transfer performance for thermal storage system and decrease charging and discharging time.     

Numerical simulation of geothermal-PVT hybrid system with PCM storage tank

As the increase in greenhouse emissions, climate changes, and other irreversible repercussions stems from environmentally destructive energies such as fossil fuels, exploiting solar and geothermal energy as unlimited clean sources of energy in the renewable energy technologies can survive the planet earth, which is facing a catastrophe on a global scale. The main purpose of this research is to study Techno analysis of the combined ground source heat pump (GSHP) and photovoltaic thermal collectors (PVTs) with a “phase-change material” (PCM) storage tank to fulfill the energy demands of a residential building. In the first step of this study, in order to model the heat pump behavior in multi-usage operation modes (heating and cooling), a numerical transient simulation of a water-to-water GSHP, which includes a vertical U-type ground source heat exchanger (GSHX) and a variable speed drive (VSD) compressor, was conducted by developing a numerical code in Engineering Equation Solver software. To study the thermodynamic aspect of the hybrid system in terms of exergy and energy, a transient numerical simulation was accomplished using the TRNSYS program. Also, the impact of effective characteristics of ingredients such as areas of PVT panels and the volume of the storage tank of PCMs on the performance of the hybrid system are investigated. On top of that, the two types of the GSHP-PVT-PCMs and GSHP-PV from the energy and exergy points of view are compared. The obtained results demonstrate that the irreversibility of the solar modules of the GSHP-PVT-PCMs is 6.6% lower than that of the GSHP-PV. Furthermore, the calculation of the annual required load of the building for these two kinds of hybrid systems shows that the use of collectors in this combined system has reduced the total load of the building by 6.5%. The use of collectors in the GSHP-PVT-PCM gives rise to a difference in the value of solar factor (SF) of this system by 1.4% more than the one for the hybrid system without thermal collectors.     

Numerical investigation of free-cooling system using plate type PCM storage

Free cooling night ventilation is the process of storing the coolness in the night time and releasing this coolness in hot day time. In this paper, a numerical study was carried out to simulate and to find out the optimum design for plate type storage filled with phase change material (PCM) which is used in night ventilation systems. The effect of different parameters such as thickness of PCM-plates, inlet air temperature and air mass flow rates on melting front, cooling power, outlet temperature and thermal performance of heat exchanger was studied. The results showed that cooling power can be increased by increasing the mass flow rate. Also, the thickness of the plates in the storage device plays an important role in the thermal performance of the unit and has a linear relation with the melting process duration of PCM for considered configuration.     

Numerical analysis of melting with constant heat flux heating in a thermal energy storage system

Melting in a finite slab with a second kind boundary condition is studied numerically in order to simulate the charging process of a thermal energy storage system. A dimensionless model is given, from which it is concluded that the main factors that influence the melting process are the dimensionless heating flux, the modified Stefan number, the relative thermal diffusivity and the relative thermal conductivity. The influence of preheating or solid subcooling is studied. It is found that though preheating does not have very important effects on the melting time, it does influence the interface marching velocity significantly. The melt fraction and the melting time are calculated extensively for various dimensionless numbers. The numerical results show that the ratio of the thermal conductivity of the solid to that of the liquid has little effect on the melting time, and the time for finishing melting can be expressed as a function of the dimensionless heating flux, the modified Stefan number and the relative thermal diffusivity, and the possible function form is suggested.     

Numerical analysis of natural convection for a porous rectangular enclosure with sinusoidally varying temperature profile on the bottom wall

Numerical investigations of steady natural convection flow through a fluid-saturated porous medium in a rectangular enclosure with a sinusoidal varying temperature profile on the bottom wall were conducted. All the walls of the enclosure are insulated except the bottom wall which is partially heated and cooled. The governing equations were written under the assumption of Darcy-law and then solved numerically using finite difference method. The problem is analyzed for different values of the Rayleigh number Ra in the range 10 ≤ Ra ≤ 1000, aspect ratio parameter AR in the range 0.25 ≤ AR ≤1.0 and amplitude λ of the sinusoidal temperature function in the range 0.25 ≤ λ ≤ 1.0. It was found that heat transfer increases with increasing of amplitude λ and decreases with increasing aspect ratio AR. Multiple cells were observed in the cavity for all values of the parameters considered.     

Numerical analysis of a cool-thermal storage system with a thermal conductivity enhancer operating under a freezing condition

Enhancing the cooling process of water in a cool-thermal storage system is investigated in this paper. The system is utilized to cool air during on-peak power consumption hours to save energy. The system consists of parallel plates filled with water and triangular corrugated fins. A finite element model for the system is used to predict the cooling time of water for different water's initial temperatures, and also to study the effect of fins design on the cooling process. The result indicates that the aspect ratio of the triangular fin has a significant effect the cooling process of water, and cooling rate increases for the aspect ratio greater or less than 0.75. Temperature contours, average water temperature, and Nusselt number are presented for the cooling process.     

Thermal performance of PCM thermal storage unit for a roof integrated solar heating system

The thermal performance of a phase change thermal storage unit is analysed and discussed. The storage unit is a component of a roof integrated solar heating system being developed for space heating of a home. The unit consists of several layers of phase change material (PCM) slabs with a melting temperature of 29 °C. Warm air delivered by a roof integrated collector is passed through the spaces between the PCM layers to charge the storage unit. The stored heat is utilised to heat ambient air before being admitted to a living space. The study is based on both experimental results and a theoretical two dimensional mathematical model of the PCM employed to analyse the transient thermal behaviour of the storage unit during the charge and discharge periods. The analysis takes into account the effects of sensible heat which exists when the initial temperature of the PCM is well below or above the melting point during melting or freezing. The significance of natural convection occurring inside the PCM on the heat transfer rate during melting which was previously suspected as the cause of faster melting process in one of the experiments is discussed. The results are compared with a previous analysis based on a one dimensional model which neglected the effect of sensible heat. A comparison with experimental results for a specific geometry is also made.     

Melting of PCM in a thermal energy storage unit: Numerical investigation and effect of nanoparticle enhancement

The present paper describes the analysis of the melting process in a single vertical shell‐and‐tube latent heat thermal energy storage (LHTES), unit and it is directed at understanding the thermal performance of the system. The study is realized using a computational fluid‐dynamic (CFD) model that takes into account of the phase‐change phenomenon by means of the enthalpy method. Fluid flow is fully resolved in the liquid phase‐change material (PCM) in order to elucidate the role of natural convection. The unsteady evolution of the melting front and the velocity and temperature fields is detailed. Temperature profiles are analyzed and compared with experimental data available in the literature. Other relevant quantities are also monitored, including energy stored and heat flux exchanged between PCM and HTF. The results demonstrate that natural convection within PCM and inlet HTF temperature significantly affects the phase‐change process. Thermal enhancement through the dispersion of highly conductive nanoparticles in the base PCM is considered in the second part of the paper. Thermal behavior of the LHTES unit charged with nano‐enhanced PCM is numerically analyzed and compared with the original system configuration. Due to increase of thermal conductivity, augmented thermal performance is observed: melting time is reduced of 15% when nano‐enhanced PCM with particle volume fraction of 4% is adopted. Similar improvements of the heat transfer rate are also detected. Copyright © 2012 John Wiley & Sons, Ltd.     

Optimising PCM thermal storage systems for maximum energy storage effectiveness

A new performance parameter for PCM thermal storage systems, the energy storage effectiveness, is defined. This parameter can be used to optimise the design of any PCM thermal storage system to maximise the use of the thermal storage media. The paper presents results of a parametric study using an experimentally validated numerical model for PCM encapsulated in plates. The results are used to calculate the energy storage effectiveness which is ultimately used to optimise the useful energy that can be stored in the PCM thermal storage system. The energy storage effectiveness is also used to compare the useable storage capacity of the PCM relative to a sensible energy storage system.     

Numerical analysis of the discharging performance of a solar energy storage tank containing PCM modules

采用数值模拟软件FLUENT对含有相变储能模块的储热水箱(下文简称为相变储能水箱)和不含相变储能模块的普通水箱(直接进水)的释能工况进行数值模拟,并将模拟结果进行了对比.数值模拟结果表明水箱加入相变储能模块后,一方面相变储能模块的堆积起到了散流作用,减缓了进口水流造成的扰动;另一方面冷水进入水箱中通过相变储能模块缝隙时,相变储能模块对冷水有一定的加热作用.加入相变储能模块后,改善了释能过程的水箱内热分层效果,提高了储热水箱的释热总量.在流量为5 L/min时,相变储能水箱的释能效率比普通水箱的释能效率高7%,但是随着流量的增大,相变储能水箱的释能效率逐渐降低.     

Numerical modeling of aquifer thermal energy storage system

The performance of the ATES (aquifer thermal energy storage) system primarily depends on the thermal interference between warm and cold thermal energy stored in an aquifer. Additionally the thermal interference is mainly affected by the borehole distance, the hydraulic conductivity, and the pumping/injection rate. Thermo-hydraulic modeling was performed to identify the thermal interference by three parameters and to estimate the system performance change by the thermal interference. Modeling results indicate that the thermal interference grows as the borehole distance decreases, as the hydraulic conductivity increases, and as the pumping/injection rate increases. The system performance analysis indicates that if η (the ratio of the length of the thermal front to the distance between two boreholes) is lower than unity, the system performance is not significantly affected, but if η is equal to unity, the system performance falls up to ∼22%. Long term modeling for a factory in Anseong was conducted to test the applicability of the ATES system. When the pumping/injection rate is 100 m³/day, system performances during the summer and winter after 3 years of operation are estimated to be ∼125 kW and ∼110 kW, respectively. Therefore, 100 m³/day of the pumping/injection rate satisfies the energy requirements (∼70 kW) for the factory.     

Experimental and computational evolution of a shell and tube heat exchanger as a PCM thermal storage system

A combined experimental and numerical study has been designed to study thermal behavior and heat transfer characteristics of Paraffin RT50 as a phase change material (PCM) during constrained melting and solidification processes inside a shell and tube heat exchanger. A series of experiments are conducted to investigate the effects of increasing the inlet temperature of the heat transfer fluid (HTF) on the charging and discharging processes of the PCM. The computations are based on an iterative, finite-volume numerical procedure that incorporates a single-domain enthalpy formulation for simulation of the phase change phenomenon. The molten front at various times of process has been studied through a numerical simulation. The experimental results show that by increasing the inlet HTF temperature from T_H = 70 °C to 75 and 80 °C, theoretical efficiency in charging and discharging processes rises from 81.1% to 88.4% and from 79.7% to 81.4% respectively.     

Experimental research on thermal characteristics of PCM thermal energy storage units

To explore thermal management integration in electric vehicles (EVs), a phase change materials (PCMs) thermal energy storage unit using flat tubes and corrugated fins is designed. The investigation focuses on the thermal characteristics of the PCM unit, such as the temperature variation, heat capacity, and heat transfer time, etc. Meanwhile, the heat storage and release process will be influenced by different inlet temperature, liquid flow rate, melting point of the PCM, and the combination order of the units. Under the same inlet temperature and flow rate condition, the PCM unit with higher melting point enters the latent heat storage stage slowly and enters the phase change melting release stage quickly. Furthermore, the heat storage and release rates increase with increasing liquid flow rates, but the effects are diminishing in the middle and later periods. The multiple PCM units with different melting temperatures are cascaded to help recycle low-grade heat energy with different temperature classes and exhibit well heat storage and release rates.     

Numerical simulation of a multi-layer latent heat thermal energy storage system

A computational model for the prediction of the thermal behaviour of a compact multi-layer latent heat storage unit is presented. The model is based on the conservation equations of energy for the phase change material (PCM) and the heat transfer fluid (HTF). Electrical heat sources embedded inside the PCM are used for heat storage (melting) while the flow of an HTF is employed for heat recovery (solidification). Parametric studies are performed to assess the effect of various design parameters and operating conditions on the thermal behaviour of the unit. Results indicate that the average output heat load during the recovery period is strongly dependent on the minimum operating temperature, on the thermal diffusivity of the liquid phase, on the thickness of the PCM layer and on the HTF inlet mass flowrate and temperature. It is, on the other hand, nearly independent of the wall thermal diffusivity and thickness and of the maximum operating temperature. Correlations are proposed for the total energy stored and the output heat load as a function of the design parameters and the operating conditions. © 1998 John Wiley & Sons, Ltd.     

Encapsulation of PCM in ceramic thermal energy storage materials

以红柱石为主要原料,采用原位生成堇青石技术制备高温性能优良的红柱石蜂窝陶瓷储热材料.再利用特制的封装剂将相变材料(PCM)封装在部分蜂窝陶瓷孔中,制备储热密度大的显热-潜热高温复合储热材料.采用SEM,EPMA,TG-DTA等测试方法对封装剂与陶瓷基体的结合性,PCM与陶瓷基体的适应性及复合储热材料的储热密度进行研究.结果表明红柱石蜂窝陶瓷能安全地封装PCM,封装质量分数为20%的K₂SO₄后的储热密度为987.70 kJ/kg(0~1080 ℃),封装质量分数为16%的NaCl复合储热密度为796.40 kJ/kg(0~810 ℃).制备的复合储热材料具有较高的储热密度,能实现高温储热.     

Numerical analysis and evaluation of an open-type thermal storage system using composite sorbents

A family of composite sorbents has been acknowledged as promising thermal storage materials for low grade thermal energy storage owing to its high specific storage capacity and low regenerating temperature. This paper reports a simplified numerical model aiming to determine the dynamic characteristics of the composite sorbents and evaluate the specific capacity and COP of the open-type thermal energy storage system. The computational results were validated with the experimental measurements carried out on an open-type thermal energy storage set-up filled with composite sorbents. By using the simplified numerical model, the dynamic characteristics of the composite sorbents in the thermal energy storage process were determined. The effects of the composite sorbents and the operating parameters on thermal energy storage system performance were also evaluated.