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1.
The objective of this work is to investigate numerically the turbulent non‐premixed hydrogen (H2) and hydrogen–hydrocarbon flames in a small burner. Numerical studies using Fluent code were carried out for air‐staged and non‐staged cases. The effects of fuel composition from pure hydrogen to natural gas (100%H2, 70%H2+30%CH4, 10%H2+90%CH4, and 100%CH4) were also investigated. The predictions are validated and compared against the experimental results previously obtained and results from the literature. Turbulent diffusion flames are investigated numerically using a finite volume method for the solution of the conservation equations and reaction equations governing the problem. Although, three different turbulence models were tested, the standard kε model was used for the modelling of the turbulence phenomena in the burner. The temperature and major pollutant concentrations (CO and NOx) distributions are in good agreement with the existing experimental results. Air staging causes rich and lean combustion regions thus lower NOx emissions through the combustor exit. Blending hydrogen with methane causes considerable reduction in temperature levels and thus NO emissions. Increasing the mixture ratio from stoichiometric to leaner mixtures also decreases the temperature and thus NO emissions. Hydrogen may be considered a good alternative fuel for burners, as its use reduces the emission of pollutants, and as it is a renewable synthetic fuel. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

2.
Although many detailed chemical reaction mechanisms, skeletal mechanisms and reduced mechanisms are available in the literature to modeling the natural gas, they are computational expensive, required high power computing especially for three dimensional complex geometries with intense meshes. For example, though the DRM19 reduced mechanism does not include NO and NO2 species, it includes 19 species and 84 reactions. On the other hand, Eddy Dissipation combustion model in which the overall rate of reaction is mainly controlled by turbulent mixing can be utilized as a practical approach for fast burning and fast reaction fuels such as natural gas. Unlike fossil fuels, hydrogen is a renewable energy and quite clean in terms of carbon monoxide and carbon dioxide emissions. However, numerical and experimental studies on hydrogen combustion in burners are very restricted. In this study, the combustion of natural gas in an industrial low swirl burner–boiler system has been experimentally investigated. The results obtained from the experimental setup have been utilized as boundary conditions for CFD simulations. With the use of Eddy Dissipation method, methane-air-2-step reaction mechanism is used for modeling of natural gas as methane gas and the reaction mechanism has been modified for natural gas considering the natural gas properties to reveal the similarities and differences of both fuels in modeling. In addition, the combustion performances of natural gas with the use of full and periodic models, which are geometric models of the burner–boiler pair, are compared. Moreover, in order to reveal the effect of the hydrogen-enriched natural gas and pure hydrogen on the performance of low swirl burner–boiler considering the combustion emissions, four various gas contents (thermal load ratio: 75%NG + 25%H2, 50%NG + 50%H2, 25%NG + 75%H2, 100%H2) at the same thermal load have been investigated. The turbulent flames of the industrial low swirl burner have been studied numerically using ANSYS Fluent 16.0 for the solution of governing equations. The results obtained in this study show that with the utilizing Eddy Dissipation method, natural gas can be modeled as methane gas with well-known methane-air-2step reaction mechanism or as natural gas with modified methane-air-2step reaction mechanism with approximate results. Additionally, the use of periodic boundary condition, which enables studying with 1/4 of geometric model, gives satisfactory results with less number of meshes when compared to the full model. Furthermore, in the case of using hydrogen-enriched natural gas or pure hydrogen instead of natural gas as the fuel, the combustion emissions of the burner–boiler such as CO and CO2 are remarkably decreasing compared to the natural gas. However, the NOx emissions are significantly increasing especially due to thermal NO.  相似文献   

3.
Pollutant emissions are one of the major problems for the World. In this regard, researchers focus on the studies on emission reduction. Hydrogen is an alternative solution for this problem. Hydrogen produces only water as a result of combustion with oxygen. Therefore, this study examines the combustion stability and emissions of a high hydrogen content fuel mixture. The fuel mixture containing 45% H2 by volume was supported with 5% CH4 in order to provide stable combustion. In addition, in order to reduce the instabilities caused by the high laminar burning rate of hydrogen, it was diluted with 50% CO2 which equal volume with the fuel mixture. After the fuel mixture containing 45% H2 - 5% CH4 - 50% CO2 was burned with air containing 21% O2, enrichment was applied at the rates of 24% and 27% O2. The flame that contains different oxygen ratios was acoustically forced through the speakers around the combustion chamber. The stability data, dynamic pressure, and light intensity fluctuation of the flame were recorded under different acoustic resonance frequencies (110 Hz, 190 Hz, 260 Hz). In this way, the oxygen enrichment performance and flame characteristics of hydrogen in a premixed burner, which is promising in zero-emission studies, were investigated. As a result, when the combustion condition of 21% O2 and 24% O2 ratios are compared, the instability increased slightly from 801 Pa to 887 Pa, respectively. However, at 27% O2, the flame could not perform a stable combustion under acoustic enforcement. The flame flashbacked with a dynamic pressure fluctuation of 1577 Pa under an acoustic frequency of 110 Hz. In addition, it was observed that CO emissions have decreased with the increase in oxygen enrichment rate. CO emission measured at 1080 ppm at 21% O2 decreased to 542 ppm and 276 ppm respectively at 24% and 27% oxygen enrichment levels. While NOx emission was measured at 10 ppm in the case of combustion with air, it was observed that decreased to 4 ppm at the rate of 27% O2.  相似文献   

4.
This paper presents an experimental study of mild flameless combustion regime applied to methane/hydrogen mixtures in a laboratory-scale pilot furnace with or without air preheating. Results show that mild flameless combustion regime is achieved from pure methane to pure hydrogen whatever the CH4/H2 proportion. The main reaction zone remains lifted from the burner exit, in the mixing layer of fuel and air jets ensuring a large dilution correlated to low NOx emissions whereas CO2 concentrations obviously decrease with hydrogen proportion. A decrease of NOx emissions is measured for larger quantity of hydrogen due mainly to the decrease of prompt NO formation. Without air preheating, a slight increase of the excess air ratio is required to control CO emissions. For pure hydrogen fuel without air preheating, mild flameless combustion regime leads to operating conditions close to a "zero emission furnace", with ultra-low NOx emissions and without any carbonated species emissions.  相似文献   

5.
With the increasing need to reduce greenhouse gas emission and adopt sustainability in combustion systems, injection of renewable gases into the pipeline natural gas is of great interest. Due to high specific energy density and various potential sources, hydrogen is a competitive energy carrier and a promising gaseous fuel to replace natural gas in the future. To test the end use impact of hydrogen injection into the natural gas pipeline infrastructure, the present study has been carried out to evaluate the fuel interchangeability between hydrogen and natural gas in a residential commercial oven burner. Various combustion performance characteristics were evaluated, including flashback limits, ignition performance, flame characteristics, combustion noise, burner temperature and emissions (NO, NO2, N2O, CO, UHC, NH3). Primary air entrainment process was also investigated. Several correlations for predicting air entrainment were compared and evaluated for accuracy based on the measured fuel/air concentration results in the burner. The results indicate that 25% (by volume) hydrogen can be added to natural gas without significant impacts. Above this amount, flashback in the burner tube is the limiting factor. Hydrogen addition has minimal impact on NOX emission while expectedly decreasing CO emissions. As the amount of hydrogen increases in the fuel, the ability of the fuel to entrain primary air decreases.  相似文献   

6.
Formic acid (FA) is a potential hydrogen energy carrier and low-carbon fuel by reversing the decomposition products, CO2 and H2, back to restore FA without additional carbon release. However, FA-air mixtures feature high ignition energy and low flame speed; hence stabilizing FA-air flames in combustion devices is challenging. This study experimentally investigates the flame stability and emission of swirl flames fueled with pre-vaporized formic acid-methane blends over a wide range of formic acid fuel fractions. Results show that by using a swirl combustor, the premixed formic acid-methane-air flames could be stabilized over a wide range of FA fuel fractions, Reynolds numbers, and swirl numbers. The addition of formic acid increases the equivalence ratios at which the flashback and lean blowout occur. When Reynolds number increases, the equivalence ratio at the flashback limit increases, but that decreases at the lean blowout limit. Increasing the swirl number has a non-monotonic effect on stability limits variation because increasing the swirl number changes the axial velocity on the centerline of the burner throat non-monotonically. In addition, emission characteristics were investigated using a gas analyzer. The CO and NO concentrations were below 20 ppm for all tested conditions, which is comparable to that seen with traditional hydrocarbon fuels, which is in favor of future practical applications with formic acid.  相似文献   

7.
Combustion characteristics of natural gas – hydrogen hybrid fuel were investigated experimentally in a free jet turbulent diffusion flame flowing into a slow co-flowing air stream. Experiments were carried out at a constant jet exit Reynolds number of 4000 and with a wide range of NG–H2 mixture concentrations, varied from 100%NG to 50%NG-50% H2 by volume. The effect of hydrogen addition on flame stability, flame length, flame structure, exhaust species concentration and pollutant emissions was conducted. Results showed that, hydrogen addition sustains a progressive improvement in flame stability and reduction in flame length, especially for relatively high hydrogen concentrations. Hydrogen-enriched flames found to have a higher combustion temperatures and reactivity than natural gas flame. Also, it was found that hydrogen addition to natural gas is an ineffective strategy for NO and CO reduction in the studied range, while a significant reduction in the %CO2 molar concentration by about 30% was achieved.  相似文献   

8.
The role of hydrogen addition on the structure of the Moderate or Intense Low oxygen Dilution (MILD) combustion regime is examined using a combination of experimental techniques and laminar flame calculations. Laser diagnostic imaging is used to simultaneously reveal the in situ distribution of the hydroxyl radical (OH), formaldehyde (H2CO), and temperature using the Jet in Hot Coflow (JHC) burner. The fuels considered are natural gas, ethylene, and LPG (each diluted with hydrogen 1:1 by volume). Hydrogen addition to the primary fuel was found necessary to stabilise the flames. Further to the role of hydrogen in the stabilisation of the flames, hydrogen addition also leads to the reaction zone exhibiting similar structure for different primary fuel types. The independence of the reaction zone structure with hydrogen addition suggests that a wide variety of fuels may be usable for achieving MILD combustion.  相似文献   

9.
Hydrogen-blending effects in flame structure and NO emission behaviour are numerically studied with detailed chemistry in methane–air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane to the blending fuel of methane–hydrogen through H2 molar addition up to 30%. Flame structure, which can be described representatively as a fuel consumption layer and a H2–CO consumption layer, is shown to be changed considerably in hydrogen-blending methane flames, compared to pure methane flames. The differences are displayed through maximum flame temperature, the overlap of fuel and oxygen, and the behaviours of the production rates of major species. Hydrogen-blending into hydrocarbon fuel can be a promising technology to reduce both the CO and CO2 emissions supposing that NOx emission should be reduced through some technologies in industrial burners. These drastic changes of flame structure affect NO emission behaviour considerably. The changes of thermal NO and prompt NO are also provided according to hydrogen-blending. Importantly contributing reaction steps to prompt NO are addressed in pure methane and hydrogen-blending methane flames. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

10.
In the present study, the effects of hydrogen enrichment of methane are investigated numerically from the diffusion flame structure and emissions aspect. Fluent code is utilised as the simulation tool. In the first part of the study, four experiments were conducted using natural gas as fuel. A non-premixed burner and a back-pressure boiler were utilised as the experimental setup. The natural gas fuel consumption rate was changed between 22 Nm3/h and 51 Nm3/h. After the experimental studies, the numerical simulations were performed. The non-premixed combustion model with the steady laminar flamelet model (SFM) approach was used for the calculations. The methane-air extinction mechanism was utilised for the calculation of the chemical species. The numerical results were verified with the experimental results in terms of the flue gas emissions and flue gas temperature values. In the second part of the study, four different hydrogen-enriched methane combustion cases were simulated using the same methane-air extinction mechanism, which included the hydrogen oxidation mechanism as a sub mechanism. The same energy input (432 kW) was supplied into the boiler for all the studied cases. The obtained results show that the hydrogen addition to methane significantly change the diffusion flame structure in the combustion chamber. The hydrogen-enriched flames become broader and shorter with respect to the pure methane flame. This provides better mixing of the reactants and combustion products in the flame regions due to the use of a back-pressure boiler. In this way, the maximum flame temperature values and thermal NO emissions are reduced in the combustion chamber, when the hydrogen addition ratio is less than 15% by mass. The maximum temperature value is calculated as 2030 K for the case with 15% hydrogen addition ratio by mass, while it is 2050 K for the case without hydrogen enrichment. Therefore, it is determined that the hydrogen-enriched methane combustion in a back-pressure combustion chamber has the potential of reducing both the carbon and thermal NO emissions.  相似文献   

11.
In this investigation the role of hydrogen addition in a reverse flow configuration, consisting of both non-premixed and premixed combustion modes, have been examined for the CDC flames. In the non-premixed configuration the air injection port is positioned at combustor exit end while the fuel injection port is positioned on the side so that the fuel is injected in cross-flow with respect to air injection. The thermal intensity of the flames investigated is 85 MW/m3 atm to simulate high thermal intensity gas turbine combustion conditions. The results are presented on the global flame signatures, exhaust emissions, and radical emissions using experiments and flowfield using numerical simulations. Ultra low NOx emissions are found for both the premixed and non-premixed combustion modes. Addition of hydrogen to methane fuel resulted in only a slight increase of NO emission, significant decrease of CO emission and extended the lean operational limit of the combustor.  相似文献   

12.
This study experimentally examined a cylindrical multi-hole premixed burner for its potential use for a condensing gas boiler, which produces less NOx emissions and performs better. In this study, the hole diameters and the arrangement of a multi-hole burner were investigated using a flat burner model. The combustion characteristics for the flame stability as well as the NOx and CO emissions were examined using a cylindrical burner. For an optimal operating condition, the equivalence ratio for the cylindrical burner was between 0.70 and 0.75. For this condition, the turn-down ratio was 3:1 or higher, which was suitable for appropriate control of the boiler operation. The NOx and CO emissions were less than 40 ppm and less than 30 ppm, respectively, for a 0% O2 basis. The LPG and LNG were able to be used in this type of burner because there was no phenomenal difference in the stable combustion region between them.  相似文献   

13.
In an effort to elucidate the influence of hydrogen addition on soot formation and oxidation, a series of numerical investigations was performed for fuel rich laminar C2H2/air premixed flat flames using a modified CHEMKIN-II PREMIX code with a detailed soot chemistry mechanism. To clarify the influence of hydrogen addition, the hydrogen content (in volume %) in the fuel mixture was gradually increased from 10 to 50%. The hydrogen addition was found to slow the oxidation of C2H2 near the burner surface. The lowered rate of C2H2 oxidation coupled with lower C2H2 concentration near the burner surface impedes the formation of benzene. However, the formation of benzene was enhanced with the hydrogen addition as the height above burner (HAB) was increased. This was due to the increased reverse rate of the H abstraction reaction that prevents the radical formation process. Through the identical mechanism, the hydrogen addition slows further growth of benzene to larger polycyclic aromatic hydrocarbons (PAHs), eventually lowering the rate of particle inception. Numerical results also indicated that reductions in the soot emissions were mainly attributed to a significant reduction in the mass growth of soot particles. The abundance of hydrogen in the flames deactivated the surface site of soot particles covered with C-H bonds, lowering the surface growth rate (which leads to reductions in the mass growth of soot particles).  相似文献   

14.
The effects of hydrogen addition on NO formation in fuel-rich, burner-stabilized methane, ethane and propane flames are reported. Profiles of temperature and NO mole fraction were obtained using spontaneous Raman scattering and laser-induced fluorescence (LIF), respectively. Experiments were performed at equivalent ratio of 1.3, with 0 and 0.2 mole fraction of hydrogen in the fuel; and the mass flux through the burner was varied for each mixture. The addition of hydrogen only modestly affects the flame temperature and NO mole fraction. For the vast majority of the flames studied, the temperature and NO decrease by less than 40 K and 20% (relative), respectively, upon hydrogen addition. The decrease in NO fraction is more distinct in methane and propane flames, and more modest for ethane. The comparison of the experimental data obtained for a given fuel in near-adiabatic CnH2n+2/H2/O2/N2 and burner-stabilized CnH2n+2/Air flames shows that the NO mole fraction at a given mass flux is practically independent of the composition of the oxidizer. Comparison of the experimental profiles with the predictions of one-dimensional flame calculations with detailed chemical mechanisms indicates that the decrease in the Fenimore NO formation with hydrogen addition arises from the concomitant decrease in CH fraction. Analysis of the computational results suggests that the reaction NCN + H → CH + N2 returns a considerable fraction of NCN back to N2.  相似文献   

15.
Lean premixed combustion of hydrogen–syngas/methane fuel mixtures was investigated experimentally to demonstrate fuel flexibility of a two-section porous burner. The un-insulated burner was operated at atmospheric pressure. Combustion was stabilized at the interface of silicon-carbide coated carbon foam of 26 pores per centimeter (ppcm) and 4 ppcm. Methane (CH4) content in the fuel was decreased from 100% to 0% (by volume), with the remaining amount split equally between carbon monoxide (CO) and hydrogen (H2), the two reactive components of the syngas. Experiments for different fuel mixtures were conducted at a fixed air flow rate, while the fuel flow rate was varied to obtain a range of adiabatic flame temperatures. The CO and nitric oxide (NOxNOx) emissions were measured downstream of the porous burner, in the axial direction to identify the post-combustion zone and in the transverse direction to quantify combustion uniformity. For a given adiabatic flame temperature, increasing H2/CO content in the fuel mixture decreased both the CO and NOxNOx emissions. Presence of H2/CO in the fuel mixture also decreased temperature near the lean blow-off limit, especially for higher percentages of CO and H2 in the fuel.  相似文献   

16.
The effect of the addition of hydrogen (H2) on the combustion process and nitric oxide (NO) formation in a H2-diesel dual fuel engine was numerically investigated. The model developed using AVL FIRE as a platform was validated against the cylinder pressure and heat release rate measured with the addition of up to 6% (vol.) H2 into the intake mixture of a heavy-duty diesel engine with exhaust gas recirculation (EGR). The validated model was applied to further explore the effect of the addition of 6%–18% (vol.) H2 on the combustion process and formation of NO in H2-diesel dual fuel engines. When the engine was at N = 1200 rpm and 70% load, the simulation results showed that the addition of H2 prolonged ignition delay, enhanced premixed combustion, and promoted diffusion combustion of the diesel fuel. The maximum peak cylinder pressure was observed with addition of 12% (vol.) H2. In comparison, the maximum peak heat release rate was observed with the addition of 16% (vol.) H2. The addition of H2 was a crucial factor dominating the increased NO emissions. Meanwhile, the addition of H2 reduced soot emissions substantially, which may be due to the reduced diesel fuel burned each cycle. Furthermore, proper combination of adding H2 with EGR can improve combustion performance and reduce NO emissions.  相似文献   

17.
Flame characteristics of swirling non-premixed H2/CO syngas fuel mixtures have been simulated using large eddy simulation and detailed chemistry. The selected combustor configuration is the TECFLAM burner which has been used for extensive experimental investigations for natural gas combustion. The large eddy simulation (LES) solves the governing equations on a structured Cartesian grid using a finite volume method, with turbulence and combustion modelling based on the localised dynamic Smagorinsky model and the steady laminar flamelet model respectively. The predictions for H2-rich and CO-rich flames show considerable differences between them for velocity and scalar fields and this demonstrates the effects of fuel variability on the flame characteristics in swirling environment. In general, the higher diffusivity of hydrogen in H2-rich fuel is largely responsible for forming a much thicker flame with a larger vortex breakdown bubble (VBB) in a swirling flame compare to the H2-lean but CO-rich syngas flames.  相似文献   

18.
Influence of hydrogen addition on appearance of swirling and non-swirling inverse diffusion flame (IDF) along with emissions characteristics are investigated experimentally. The combustion characteristics including flame length, axial and radial temperature variation, and noise level are analysed for hydrogen addition in methane by mass basis for constant energy input and by volume basis for constant volumetric fuel flow rate. Hydrogen addition in methane IDF produces shorter flame by compressing entrainment zone, mixing zone, reaction zone, and post-combustion zone. Hydrogen addition shift these zones towards fuel and air exit from the burner. Enrichment of methane with hydrogen on a mass basis up to 6% reduces CO emission considerably and increases NOx emission moderately. Effect of H2 addition on combustion and emission characteristics is more prominent in non-swirling IDF. Combustion noise is augmented with the hydrogen addition and the magnitude of sound level depends on the hydrogen concentration.  相似文献   

19.
The utilization of hydrogen as a fuel in free jet burners faces particular challenges due to its special combustion properties. The high laminar and turbulent flame velocities may lead to issues in flame stability and operational safety in premixed and partially premixed burners. Additionally, a high adiabatic combustion temperature favors the formation of thermal nitric oxides (NO). This study presents the development and optimization of a partially premixed hydrogen burner with low emissions of nitric oxides. The single-nozzle burner features a very short premixing duct and a simple geometric design. In a first development step, the design of the burner is optimized by numerical investigation (Star CCM+) of mixture formation, which is improved by geometric changes of the nozzle. The impact of geometric optimization and of humidification of the combustion air on NOx emissions is then investigated experimentally. The hydrogen flame is detected with an infrared camera to evaluate the flame stability for different burner configurations. The improved mixture formation by geometric optimization avoids temperature peaks and leads to a noticeable reduction in NOx emissions for equivalence ratios below 0.85. The experimental investigations also show that NOx emissions decrease with increasing relative humidity of combustion air. This single-nozzle forms the basis for multi-nozzle burners, where the desired output power can flexibly be adjusted by the number of single nozzles.  相似文献   

20.
ABSTRACT

In this study, the effects on combustion characteristics and emission were investigated in a direct injection diesel engine. In experimental and numerical studies, the engine was operated at 2000 rpm. The analyzes were made in the AVL-FIRE ESE Diesel part with Computational Fluid Dynamics (CFD) software. Standard combustion chamber (SCC) and Modified combustion chamber (MCC) geometry were compared in the modeling. By means of the designed MCC combustion chamber geometry, the fuel released from the injector was directed to the piston bowl area. Therefore, the mixture was homogenized and the combustion had been improved. In addition, the evaporation rate of the mixture increased with the MCC geometry. Also, lower NO and CO emissions were obtained with the MCC model compared to the SCC model. On the other hand, diesel fuel and mass 5% hydrogen fuel was used into diesel fuel as fuel in the study. The combustion process was investigated using hydrogen in different combustion chambers. The use of hydrogen as additional fuel resulted in higher combustion pressure, temperature and NO emissions. Compared to SCC type combustion chamber in the MCC type combustion chamber used diesel fuel, CO emission decreased of 6% and 3% for hydrogen-added mixture fuel. Also, compared to SCC type combustion chamber in the MCC type combustion chamber used diesel fuel, NO emission decreased of 11% and 32% for hydrogen-added mixture fuel. Moreover, flame velocity, heat release rate and flame propagation increased with the addition of hydrogen fuel.  相似文献   

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