Thermoeconomic analysis and artificial neural network based genetic algorithm optimization of geothermal and solar energy assisted hydrogen and power generation

The study aims to optimize the geothermal and solar-assisted sustainable energy and hydrogen production system by considering the genetic algorithm. The study will be useful by integrating hydrogen as an energy storage unit to bring sustainability to smart grid systems. Using the Artificial Neural Network (ANN) based Genetic Algorithm (GA) optimization technique in the study will ensure that the system is constantly studied in the most suitable under different climatic and operating conditions, including unit product cost and the plant's power output. The water temperature of the Afyon Geothermal Power Plant varies between 70 and 130 °C, and its mass flow rate varies between 70 and 150 kg/s. In addition, the solar radiation varies between 300 and 1000 W/m² for different periods. The net power generated from the region's geothermal and solar energy-supported system is calculated as 2900 kW. If all of this produced power is used for hydrogen production in the electrolysis unit, 0.0185 kg/s hydrogen can be produced. The results indicated that the overall energy and exergy efficiencies of the integrated system are 4.97% and 16.0%, respectively. The cost of electricity generated in the combined geothermal and solar power plant is 0.027 $/kWh if the electricity is directly supplied to the grid and used. The optimized cost of hydrogen produced using the electricity produced in geothermal and solar power plants in the electrolysis unit is calculated as 1.576 $/kg H₂. The optimized unit cost of electricity produced due to hydrogen in the fuel cell is calculated as 0.091 $/kWh.     

Assessment of geothermal energy use with thermoelectric generator for hydrogen production

In this work, a new model for producing hydrogen from a low enthalpy geothermal source was presented. Thermal energy from geothermal sources can be converted into electric power by using thermoelectric modules instead of Organic Rankine Cycle (ORC) machines, especially for low geothermal temperatures. This electrical energy uses the water electrolysis process to produce hydrogen. Simulation and experiments for the thermoelectric module in this system were undertaken to assess the efficiency of these models. TRNSYS software is used to simulate the system in Hammam Righa spa, the temperature of this spring is 70 °C. Obtained results reveal that in hammam righa spa in Algeria, 0.5652 Kg hydrogen per square meter of thermoelectric generator (TEG) can be produced in one year.     

Thermal analysis of multigeneration system using geothermal energy as its main power source

The study presented in this paper examines the operation of an integrated system. The study aims to present a method for utilizing geothermal energy in a way that minimizes energy waste and delivers maximum efficiency. A high-temperature geothermal well with a temperature of 300 °C is used as its primary source of energy. The system produces space heating, space cooling, electric power, hot water, freshwater and hydrogen as its outputs. These outputs utilize the excess energy that is obtained from the geothermal well, and by doing so, reduces waste, and increases the overall efficiency of the system. Among these outputs, freshwater and hydrogen are considered the most valuable, as water is an essential life resource and hydrogen is a prized form of energy. The novelty of this system compared to other geothermal sources is that it does not rely on any other source of input energy. It produces both freshwater, hydrogen and considerable amounts of electric power for commercial, industrial and/or residential use. Electric power is produced by two power cycles; the first one is a double flash steam cycle in the geothermal system and the second one is an organic Rankine cycle. 40% of the total electric power produced is sent to an electrolyzer to produce hydrogen gas. Freshwater is produced by single flash desalination. The system produces 22.1 MW of power as net electricity output. The system is assessed energetically and exergetically; it is found that the energy efficiency is 49.1%, while the exergy efficiency is 67.9%. Further parametric studies are carried out using Engineering Equation Solver (EES) to investigate the influence of operating conditions on the energy and exergy of the system. Moreover, major exergy destruction areas in the system are also identified.     

The integration of parabolic trough solar collectors and evacuated tube collectors to geothermal resource for electricity and hydrogen production

In this study, electricity and hydrogen production of an integrated system with energy and exergy analyses are investigated. The system also produces clean water for the water electrolysis system. The proposed system comprises evacuated tube solar collectors (ETSCs), parabolic trough solar collectors (PTSCs), flash turbine, organic Rankine cycles (ORC), a reverse osmosis unit (RO), a water electrolysis unit (PEM), a greenhouse and a medium temperature level geothermal resource. The surface area of each collector is 500 m². The thermodynamics analysis of the integrated system is carried out under daily solar radiation for a day in August. The fluid temperature of the medium temperature level geothermal resource is upgraded by ETSCs and PTSCs to operate the flash turbine and the ORCs. The temperature of the geothermal fluid is upgraded from 130 °C to 323.6 °C by the ETSCs and PTSCs. As a result, it is found that the integrated system generates 162 kg clean water, 1215.63 g hydrogen, and total electrical energy of 2111.04 MJ. The maximum energy and exergy efficiencies of the overall system are found as 10.43% and 9.35%, respectively.     

Comparison of three different solar collectors integrated with geothermal source for electricity and hydrogen production

In this study, an integrated system is proposed for mainly electricity and hydrogen production. Energy and exergy analyses of the system are also examined by using Engineering Equation Solver (EES, version 2019) under solar radiation during day time on 1st July. The proposed system consists of a middle-temperature geothermal source with fluid temperature 93 °C, three solar collectors (SCs of 300 m²) namely parabolic trough solar collectors (PTSCs), evacuated tube solar collectors (ETSCs), flat plate solar collectors (FPSCs), an organic Rankine cycle (ORC), proton exchange membrane (PEM), a compressor, hot water storage tank and a mushroom cultivation room. The temperature of the geothermal fluid is upgraded via solar collectors by harvesting solar radiation to operate the ORC. Thus the generated electricity is used in the PEM electrolysis system for producing hydrogen. When the PTSCs, ETSCs, and FPSCs are integrated with the geothermal source separately, it is found that 2758.69 g, 1585.27 g, and 634.42 g of hydrogen can be produced, respectively for a day. The highest overall energetic and exergetic performance of the system is calculated as to be 5.67% and 7.49%, respectively.     

Buoyancy organic Rankine cycle

In the scope of renewable energy, we draw attention to a little known technique to harness solar and geothermal energy. The design here proposed and analyzed is a conceptual hybrid of several patents. By means of a modified organic Rankine cycle, energy is obtained utilizing buoyancy force of a working fluid. Based on thermodynamic properties we propose and compare the performance of Pentane and Dichloromethane as working fluids. Theoretical efficiencies up to 0.26 are estimated for a 51 m (Pentane) and 71.5 m (Dichloromethane) high column of water in a regime below 100 °C operation temperature. These findings are especially relevant in the scope of distributed energy systems, combined cycle plants, and low-temperature Rankine cycles.     

Hydrogen production from solar energy powered supercritical cycle using carbon dioxide

A hydrogen production method is proposed, which utilizes solar energy powered thermodynamic cycle using supercritical carbon dioxide (CO₂) as working fluid for the combined production of hydrogen and thermal energy. The proposed system consists of evacuated solar collectors, power generating turbine, water electrolysis, heat recovery system, and feed pump. In the present study, an experimental prototype has been designed and constructed. The performance of the cycle is tested experimentally under different weather conditions. CO₂ is efficiently converted into supercritical state in the collector, the CO₂ temperature reaches about 190 °C in summer days, and even in winter days it can reach about 80 °C. Such a high-temperature realizes the combined production of electricity and thermal energy. Different from the electrochemical hydrogen production via solar battery-based water splitting on hand, which requires the use of solar batteries with high energy requirements, the generated electricity in the supercritical cycle can be directly used to produce hydrogen gas from water. The amount of hydrogen gas produced by using the electricity generated in the supercritical cycle is about 1035 g per day using an evacuated solar collector of 100.0 m² for per family house in summer conditions, and it is about 568.0 g even in winter days. Additionally, the estimated heat recovery efficiency is about 0.62. Such a high efficiency is sufficient to illustrate the cycle performance.     

Performance evaluation of a geothermal based integrated system for power,hydrogen and heat generation

In the present study, an integrated system is proposed and thermodynamically analyzed to reduce greenhouse gas (GHG) emissions while improving overall system performance. The integrated system is comprised of a supercritical carbon dioxide (CO₂) Rankine cycle cascaded by an Organic (R600) Rankine cycle, an electrolyzer, and a heat recovery system. It is designed to utilize a medium-to-high temperature geothermal energy source for power and hydrogen production, and thermal energy utilization for space heating. Therefore, parametric studies for the supercritical CO₂ cycle, the Organic (R600) cycle, and the overall system are conducted. In addition, the effect of various operational conditions, such as geothermal source, ambient and cooling water temperatures on the performance of each cycle and the integrated system, is illustrated. It is found that increasing geothermal source temperature results in slight increases of the exergetic efficiency of the overall system. The energy efficiencies of the CO₂ and Organic Rankine cycles do not considerably vary with source temperature changes. The decay of the cooling water temperature leads to a decrease in the overall system exergetic efficiency. The system configuration, which is introduced, is capable of producing about 180 kg/h for the geothermal source of mass flow rate of 40 kg/s and a temperature of 473 K.     

Energy,exergy and economic analyses and multiobjective optimization of a novel solar multi-generation system for production of green hydrogen and other utilities

Renewable energy based multi-generation systems can help solving energy-related environmental problems. For this purpose, a novel solar tower-based multi-generation system is proposed for the green hydrogen production as the main product. A solar-driven open Brayton cycle with intercooling, regeneration and reheat is coupled with a regenerative Rankine cycle and a Kalina cycle-11 as a unique series of power cycles. Significant portion of the produced electricity is utilized to produce green hydrogen in an electrolyzer. A thermal energy storage, a single-effect absorption refrigeration cycle and two domestic hot water heaters are also integrated. Energy, exergy and economic analyses are performed to examine the performance of the proposed system, and a detailed parametric analysis is conducted. Multiobjective optimization is carried out to determine the optimum performance. Optimum energy and exergy efficiencies, unit exergy product cost and total cost rate are calculated as 39.81%, 34.44%, 0.0798 $/kWh and 182.16 $/h, respectively. Products are 22.48 kg/h hydrogen, 1478 kW power, 225.5 kW cooling and 7.63 kg/s domestic hot water. Electrolyzer power size is found as one of the most critical decision variables. Solar subsystem has the largest exergy destruction. Regenerative Rankine cycle operates at the highest energy and exergy efficiencies among power cycles.     

Investigation of hydrogen production performance of chlor-alkali cell integrated into a power generation system based on geothermal resources

In present study, hydrogen production performance of chlor-alkali cell integrated into a power generation system based on geothermal resource is studied. The basic elements of the novel system are a separator, a steam power turbine, an organic Rankine cycle (ORC), an air cooled condenser, a saturated NaCl solution reservoir tank and a chlor-alkali cell. To enhance the performance of the cell, the saturated NaCl solution is heated by the waste heat from the ORC. So, this integrated system generates significant amount of electricity for the city grid and also yields three main products those are hydrogen, chlorine and sodium hydroxide. According to the parametric study, when the temperature of a geothermal resource varies from 140 to 155 °C, the electrical power generation increases from nearly 2.5 MW to 3.9 MW and hydrogen production increases from 10.5 to 21.1 kg-h. Thus, when the geothermal resource temperature of 155 °C, the energy efficiency of the system is 6.2% and the exergetic efficiency is 22.4%. As a result, the geothermal energy potential plays a key role on the integrated system performance and the hydrogen production rate.     

Artificial Neural Networks based thermodynamic and economic analysis of a hydrogen production system assisted by geothermal energy on Field Programmable Gate Array

In this study, the thermodynamic and economic analysis of a geothermal energy assisted hydrogen production system was performed using real-time Artificial Neural Networks on Field Programmable Gate Array. During the modeling of the system in the computer environment, a liquid geothermal resource with a temperature of 200 °C and a flow rate of 100 kg/s was used for electricity generation, and this electricity was used as a work input in the electrolysis unit to split off water into the hydrogen and oxygen. In the designed system, the net work produced from the geothermal power cycle, the overall exergy efficiency of the system, the unit cost of the produced hydrogen and the simple payback period of the system were calculated as 7978 kW, 38.37%, 1.088 $/kg H₂ and 4.074 years, respectively. In the second stage of the study, Feed-Forward Artificial Neural Networks model with a single hidden layer was used for modeling the system. The activation functions of the hidden layer and output layer were Tangent Sigmoid and Linear functions, respectively. The system was implemented on Field Programmable Gate Array using the Matlab-based model of the system as a reference. The maximum operating frequency and chip statistics of the designed unit of Field Programmable Gate Array based geothermal energy assisted hydrogen production system were presented. The result can be used to gain better knowledge and optimize hydrogen production systems.     

Desalinated water and hydrogen generation from seawater via a desalination unit and a low temperature electrolysis using a novel solar-based setup

This study investigates the proficiency of employing solar energy in a novel setup geared towards simultaneous production of desalinated water and hydrogen wielding parabolic trough solar collectors (prime mover) in three solar radiation approaches; low radiation, high irradiation and no radiation. Targeted for coastal areas, this setup generates electricity using an organic Rankine cycle; utilizing its waste heat, a desalination unit applying humidification and dehumidification processes, yields desalinated water. Subsequently, hydrogen is produced through exploiting a proton exchange membrane electrolyser as a low temperature electrolyser fed by electricity and water. One of the cardinal points of this system is the production of hydrogen by means of electricity and desalinated water obtained from previous stages. With the purpose of determining the efficiency of this setup, a parametric study has been conducted grounded on the effect of important parameters on production rates and different efficiencies. Ensuing, multi-objective optimization is set forth by implementing a genetic algorithm in order to effectuate the optimal design state. The results indicated that the desalination rate in the three solar radiation approaches mentioned are 1.76 kg/s, 1.07 kg/s and 1.36 kg/s, respectively, and the hydrogen production rate are 4.33 g/s, 2.62 g/s and 3.54 g/s, correspondingly.     

Assessment of power and hydrogen production performance of an integrated system based on middle-grade geothermal source and solar energy

In this study, power and hydrogen production performance of an integrated system is investigated. The system consists of an organic Rankine cycle (ORC), parabolic trough solar collectors (PTSCs) having a surface area of 545 m², middle-grade geothermal source (MGGS), cooling tower and proton exchange membrane (PEM). The final product of this system is hydrogen that produced via PEM. For this purpose, the fluid temperature of the geothermal source is upgraded by the solar collectors to drive the ORC. To improve the electricity generation efficiency, four working fluids namely n-butane, n-pentane, n-hexane, and cyclohexane are tried in the ORC. The mass flow rate of each working fluid is set as 0.1, 0.2, 0.3, 0.4 kg/s and calculations are made for 16 different situations (four types of working fluids and four different mass flow rates for each). As a result, n-butane with a mass flow rate of 0.4 kg/s is found to be the best option. The average electricity generation is 66.02 kW between the hours of 11⁰⁰-13⁰⁰. The total hydrogen production is 9807.1 g for a day. The energy and exergy efficiency is calculated to be 5.85% and 8.27%, respectively.     

Investigation of green hydrogen production and development of waste heat recovery system in biogas power plant for sustainable energy applications

In this study, biogas power production and green hydrogen potential as an energy carrier are evaluated from biomass. Integrating an Organic Rankine Cycle (ORC) to benefit from the waste exhaust gases is considered. The power obtained from the ORC is used to produce hydrogen by water electrolysis, eliminate the H₂S generated during the biogas production process and store the excess electricity. Thermodynamic and thermoeconomic analyses and optimization of the designed Combined Heat and Power (CHP) system for this purpose have been performed. The proposed study contains originality about the sustainability and efficiency of renewable energy resources. System design and analysis are performed with Engineering Equation Solver (EES) and Aspen Plus software. According to the results of thermodynamic analysis, the energy and exergy efficiency of the existing power plant is 28.69% and 25.15%. The new integrated system's energy, exergy efficiencies, and power capacity are calculated as 41.55%, 36.42%, and 5792 kW. The total hydrogen production from the system is 0.12412 kg/s. According to the results of the thermoeconomic analysis, the unit cost of the electricity produced in the existing power plant is 0.04323 $/kWh. The cost of electricity and hydrogen produced in the new proposed system is determined as 0.03922 $/kWh and 0.181 $/kg H₂, respectively.     

The performance assessment of a combined organic Rankine-vapor compression refrigeration cycle aided hydrogen liquefaction

In this study, the performance of the combined cooling cycle with the Organic Rankine power cycle, which provides cooling of the hydrogen at the compressor inlet which compresses the constant temperature in the Claude cycle used for hydrogen liquefaction, on the system is examined. The Organic Rankine combined cooling cycle was considered to be using a geothermal source with a flow rate of 120 kg/s at a temperature of 200 °C. The first and second law performance evaluations of the whole system were made depending on the heat energy at different levels taken from the geothermal source. The thermodynamic analysis of the equipment making up the system has been done in detail. The temperature values at which the hydrogen can be effectively cooled were determined in the presented combined system. The efficiency coefficient of the total system was calculated based on varying pre-cooling values. As a result of the study, it was determined that cold entry of hydrogen into the Claude cycle reduced the energy consumption required for liquefaction. Amount of hydrogen cooled to specified temperature increase by increase in mass flow of geothermal water and its temperature. Liquefaction cost is calculated to be 0.995 $/kg H₂ and electricity produced by itself is calculated to be 0.025 $/kWh by the new model of liquefaction system. Cost of the liquefaction in the proposed system is about 39.7% lower than direct value of hydrogen liquefaction of 1.650 $/kg given in the literature.     

Investigation of electricity,and hydrogen generation and economical analysis of PV-T depending on different water flow rates and conditions

In this paper, the electricity and hydrogen generation performance of a system contains a cooled photovoltaic-thermal (PV-T) panel, a parabolic trough solar collector (PTSC), and a proton exchange membrane (PEM) for investigation thermodynamically. The proposed system is also evaluated with respect to energetic and exergetic efficiency. Meanwhile, the water, whose temperature rises by cooling the PV-T, is sent to the PTSCs to reach a higher temperature. Then, it is stored in a storage tank for domestic use. This parametric study is carried out for two different operating conditions. Firstly, the flow rate of the water used to cool the PV-T is gradually increased from 5 g/s to 50 g/s and the simulations are made according to these mass flow rates. Also, an economical analysis of the PV-T is found for these ten mass flow rates, Secondly, the efficiency of the system is determined by changing the ambient temperature from 0 °C to 30 °C under 400 W/m² solar radiation and by fixing the cooling water flow rate to 50 g/s. All the analyses of the system are made utilizing the Engineering Equation Solver. It is aimed to enhance the hydrogen production performance of the system by increasing the electricity production of the PV-T by removing the excess heat of the solar cells with the water flow. As the flow rate of the cooling water increased, the electrical energy generated by the PV-T increased, so the highest electricity production is achieved when the flow rate was 50 g/s. Also, while the cooling mass flow rate is increased from 5 g/s to 50 g/s, the payback time of PV-T decreases from 8.093 to 7.734 years. The electricity produced is delivered to PEM and hydrogen was produced by electrolysis of water heated by PTSC. As a result, it is obtained that the electricity and hydrogen generation of the system is higher in the summer months than in the other nine months. Accordingly, it is found that while 351.1 g of hydrogen is produced in July, only 144.1 g of hydrogen could be produced in January. On the other hand, it is found that the amount of electricity and hydrogen produced by the system decreases as the ambient temperature increases. However, it was found that the electricity and hydrogen production performance of the system increased when the wind energy coming to the PV-T's surface increased from 1 m/s to 5 m/s.     

Design and thermodynamic assessment of a biomass gasification plant integrated with Brayton cycle and solid oxide steam electrolyzer for compressed hydrogen production

In this paper, a comprehensive thermodynamic evaluation of an integrated plant with biomass is investigated, according to thermodynamic laws. The modeled multi-generation plant works with biogas produced from demolition wood biomass. The plant mainly consists of a biomass gasifier cycle, clean water production system, hydrogen production, hydrogen compression, gas turbine sub-plant, and Rankine cycle. The useful outputs of this plant are hydrogen, electricity, heating and clean water. The hydrogen generation is obtained from high-temperature steam electrolyzer sub-plant. Moreover, the membrane distillation unit is used for freshwater production, and also, the hydrogen compression unit with two compressors is used for compressed hydrogen storage. On the other hand, energy and exergy analyses, as well as irreversibilities, are examined according to various factors for examining the efficiency of the examined integrated plant and sub-plants. The results demonstrate that the total energy and exergy efficiencies of the designed plant are determined as 52.84% and 46.59%. Furthermore, the whole irreversibility rate of the designed cycle is to be 37,743 kW, and the highest irreversibility rate is determined in the biomass gasification unit with 12,685 kW.     

A parametric study of a renewable energy based multigeneration system using PEM for hydrogen production with and without once-through MSF desalination

The importance of renewable energy compared to fossil fuels is increasing due to growing energy demand and environmental challenges. Multi-generation systems use one or more energy sources and produce several useful outputs. The present study aims at investigating and comparing solar energy based multi-generation systems with and without once-through MSF desalination unit from the thermodynamic point of view. Firstly, hydrogen, electricity, and hot water for space heating and domestic usage are produced using the system, which consists of a parabolic trough collector, an organic Rankine cycle (ORC) and a PEM electrolyzer and heat exchanger as sub-systems. The performance of the entire system is evaluated from the energetic and exergetic points of view. Various parameters affecting hydrogen production rate and efficiency values are also investigated with the thermodynamic model implemented in the Engineering Equation Solver (EES) package. The system can produce hydrogen at a mass flow rate of 20.39 kg/day. The results of the study show that the energy and exergy efficiency values of the ORC are calculated to be 16.80% and 40% while those for the overall system are determined to be 78% and 25.50%, respectively. Secondly, once-through MSF desalination unit is integrated to the system between ORC evaporator and heat exchanger producing domestic hot water in the solar cycle in order not to affect hydrogen production rate while thermodynamic values are compared. Fresh water production capacity of the system is calculated to be at a volumetric flow rate of 5.74 m³/day with 10 stages.     

Investigation of biomass gasification hydrogen and electricity co-production with carbon dioxide capture and storage

Biomass is one of the renewable energy resources which can be used instead of fossil fuels to diminish environment pollution and emission of greenhouse gases. Hydrogen as a biomass is considered as an alternative fuel which can be derived from a variety of domestically available primary sources. In this paper, a hydrogen and electricity co-generation plant with rice husk is proposed. Rice husk with water vapor and oxygen produces syngas in gasifier. In this design, electricity is generated by using two Rankine cycles. The Results show that the net electric efficiency and hydrogen production efficiency are 1.5% and 40.0%, respectively. Hydrogen production is 1.316 kg/s in case which carbon dioxide is gathered and stored. The electricity generation is 5.923 MW_e. The main propose of implementing Rankine cycle is to eliminate hydrogen combustion for generating electricity and to reduce NO_x production. Furthermore, three kinds of membranes are studied in this paper.     

Evaluation of the thermodynamic analysis of hydrogen production from a middle-temperature intensity solar collector,a case study

In today, the basic necessity for the economic and social development of countries is to have a cheap, reliable, sustainable, and environmentally friendly energy source. For this reason, renewable energy sources stand out as the most important key. Solar energy-based multi-energy generation systems are one of the most important options among the current scenarios to prevent global warming. In this presented study, electricity and hydrogen production from a solar collector with medium temperature density is investigated. In this system, 34 pipes evacuated tube solar collector (ETSC) is used for thermal energy generation, organic Rankine cycle (ORC) for electricity generation, and Proton exchanger membrane electrolyzer (PEMe) for hydrogen production. In addition, the energy and exergy efficiencies of the whole system calculated as 51.82% and 16.30%, respectively. Moreover, the amount of hydrogen obtained in PEM is measured as 0.00527 kg/s.