H08Mn2Si钢高速线材控轧控冷试验

研究了生产Ｈ０８Ｍｎ２Ｓｉ高速线材控轧控冷工艺参数,分析了终轧温度和冷却速率对力学性能的影响,得出最佳工艺为终轧温度８５０℃,７５０￣５８０℃之间的冷却速度〈１℃／ｓ。     

60Si2Mn弹簧扁钢崩料分析与改进研究

针对江西长力汽车簧股份有限公司轧制厂60Si2Mn弹簧扁钢生产中的崩料问题,进行了现场调研和试验研究分析,指出钢中氧、氮含量高,成分偏析,扁钢韧性下降是崩料产生的主要原因,并指出了改进措施,通过实施跟踪证明,取得了满意的效果。     

Effect of manganese and potassium addition on CeO2-Al2O3 catalyst for hydrogenation of benzoic acid to benzaldehyde

A series of Mn/CeO2-Al2O3 and K/CeO2-Al2O3 catalysts for hydrogenation of benzoic acid to benzaldehyde were prepared to in-vestigate the effect of Mn, K addition on CeO2-Al2O3 catalyst. X-ray diffraction (XRD) and H2-temperature-programmed reduction (H2-TPR) results suggested that the interaction between CeO2 and MnOx enhanced the reducibility of catalysts and therefore benzoic acid conversion.The addition of K increased the number of basic number on the catalyst which leads to a high selectivity to benzaldehyde, but excessive addition imposed negative effects on the catalyst performance. A Mn-K/CeO2Al2O3 catalyst was developed and investigated in the reaction. The simul-taneous addition of Mn and K enhanced not only the catalytic activity but also the capacity to resist the coke formation over catalyst.     

Effect of multiple additives (Mn and Zr) on microstructure of P/M 7000 series aluminum alloys

Mesoalite series alloys were formed using rapid solidification powder metallurgy (RS-P/M) by hot extrusion. The addition of Mn and Zr to the basic Mesoalite alloy (Meso10) in excess led to continuous dynamic recrystallization (DRX) in the alloy during hot extrusion through a different mechanism. In order to achieve a synergistic effect, Mn and Zr additives were used simultaneously. It was found that the DRX mechanism was governed by the addition of Mn, while the Zr addition was effective in coarsening control.     

0Cr19Ni15Mn5Mo2NbN铸钢晶界高温相析出及对力学性能的影响

利用光学显微镜、扫描电镜及透射电镜,结合Thermo-Calc热力学分析,研究了铌稳定化0Cr19Ni15Mn5Mo2NbN奥氏体不锈钢铸钢晶界处高温相析出行为及其对力学性能的影响。结果表明,0Cr19Ni15Mn5Mo2NbN钢晶界处存在Nb Cr(CN)、Nb(CN)2种大尺寸高温析出相,均为凝固末期液析形成。在铌含量确定条件下,这2种大尺寸晶界析出相在凝固末期的竞争析出行为受碳含量的影响。碳含量存在临界成分,碳含量低于临界成分时,Nb Cr(CN)首先液析形成;碳含量高于临界成分时,Nb(CN)首先液析形成。液析形成的NbCr(CN)热稳定性较高,1 050℃固溶处理无法使之完全溶入奥氏体。沿晶界分布的大尺寸析出相,对0Cr19Ni15Mn5Mo2NbN铸钢固溶热处理后的塑性及冲击韧性损害较大。     

控轧控冷工艺参数对60Si2MnA线材中珠光体形态的影响

研究了60Si2MnA线材控轧控冷工艺参数对所析出的珠光体的影响.结果表明:在其他工艺参数相同的情况下,珠光体平均片层间距主要取决于吐丝到集卷过程的冷却,这一过程冷速越快,珠光体平均片层间距越小;珠光体平均片层间距随着吐丝温度或终轧温度的升高呈下降的趋势;终轧后快冷容易出现退化珠光体,并巨其含量随相变区冷速的加快而明显增多;较低的终轧温度使珠光体球团直径明显减小.     

Effect of CaF2 and SiO2 modification on phosphorus utilisation in P-bearing slag

Abstract

In order to recycle phosphorus in P-bearing converter slag for slag phosphate fertiliser, the effect of CaF₂ and SiO₂ modification on P-bearing steelmaking slag on phosphorus-bearing phases, P₂O₅ solubility and magnetic separation behaviour has been researched. The results show that the phosphorus-rich phase is mainly n2CaO·SiO₂–3CaO·P₂O₅ (nC₂S–C₃P for short) and exists along with fluorapatite phase [Ca₅(PO₄)₃F] after the addition of CaF₂. The fluorapatite cannot be dissolved in 2% citric acid solution, which decreases the P₂O₅ solubility in slag. Although adding CaF₂ can increase the P₂O₅ content of phosphorus-rich phase, it can improve its metallisation and magnetisation of RO phase, increase the amount of recovered magnetic substances, and separate incompletely phosphorus and iron, therefore it is adverse to the phosphorus recovery from P-bearing slag by magnetic separation. P₂O₅ content of phosphorus-rich phase is more than 31% and P₂O₅ solubility of slag is increased to 96% in fluorine-free modified slag, which can meet the requirement of P₂O₅ content and P₂O₅ solubility of the phosphate fertiliser. Meanwhile, 87.1% of the phosphorus in the fluorine-free modified slag is contained in non-magnetic substance, and most of the phosphorus was recycled.     

连接层和退火对 HVAF 喷涂Cr3C2-NiCr 涂层性能的影响

本文使用HVOF和HVAF技术在铜合金上喷涂Cr_3C_2-50wt%Ni Cr涂层,并就NiCr连接层和退火对HVAF喷涂层的耐磨性和耐腐蚀性进行研究。通过对涂层物相组成、显微结构、力学性能、摩擦磨损性能以及电化学动力学曲线进行测试。结果发现:HVAF喷涂层具有比HVOF更高的结合强度,且磨损体积差异较小,但致密的HVOF喷涂层其耐腐蚀性能优于HVAF喷涂层;NiCr连接层的添加提高了复合涂层的结合强度,且致密的连接层结构可阻碍腐蚀液向基体的侵蚀,使复合涂层的耐腐蚀性能提升;退火处理通过消除涂层内部缺陷提高组织致密性,使得耐腐蚀性增强,并且退火处理降低了涂层内部残余应力,导致涂层结合强度和耐磨性能提升;300℃磨损条件下,喷涂层的磨损机制包括黏着磨损、磨粒磨损和局部氧化磨损。     

Effect of ball milling on reaction between TiO<Subscript>2</Subscript> and Al

Titanium Aluminide based composites with Al₂O₃ reinforcement can be produced via reaction of Al with TiO₂. These composites are considered as low price materials for high temperature applications. In this research, the effect of ball milling on 3TiO₂/7Al system was investigated. On the basis of obtained results, ball milling for 0 to 60 h does not lead to reduction of TiO₂ by Al. but reduces the temperature of exothermic reaction. The article is published in the original.     

Effect of CaO/Al2O3 ratio on viscosity and crystallisation behaviour of mould flux for high Al non-magnetic steel

In order to facilitate the development of CaO–Al₂O₃ based mould flux for casting high aluminium, non-magnetic steel, the effect of CaO/Al₂O₃ ratios from 0.6 to 3.2 on viscosity and crystallisation characteristics were investigated with the aid of a rotational viscometer, Fourier transform infrared spectroscopy, a single hot thermocouple technique and X-ray diffraction analysis. The results showed that, at temperatures above 1543?K (1270°C), the viscosity first decreased and then became stable with increase in the CaO/Al₂O₃ ratio. At temperatures below 1543?K (1270°C), the viscosity again first decreased but then increased, with the CaO/Al₂O₃ ratio. This viscosity behaviour can be attributed to changes in the network structure characteristics and the precipitation of solid particles within the liquid flux. Increase in the CaO/Al₂O₃ ratio also first inhibited and then enhanced crystallisation as demonstrated by the changes in initial crystallisation temperatures and incubation times. The X-ray diffraction results confirmed that, at both low and high CaO/Al₂O₃ ratios, the dominant precipitates were compounds with high melting points. On the other hand, with CaO/Al₂O₃ ratios in the midrange, the dominant precipitates were compounds with relatively low melting temperatures. It is concluded that mould flux with a CaO/Al₂O₃ ratio in the range 1.1–1.6 is the most appropriate for casting high aluminium, non-magnetic steels.     

Effect of the firing temperature and the added MgO on the reduction swelling index of the pellet with low SiO2 content

The use of pellet with low SiO₂ content in blast furnace (BF) will reduce the slag amount as well as fuel rate and increase the productivity. In this paper, the effect of the firing temperature and the added MgO on the reduction swelling index (RSI) and the compressive strength of the reduced pellet with low SiO₂ content was investigated, and the microstructure of the fired and reduced pellets was analysed by means of the electron microscopy. It was found that the decrease of SiO₂ content will raise the RSI and reduce the compressive strength of reduced pellet. When the SiO₂ content of pellet is 4.8%, the RSI is 16.5% and compressive strength of reduced pellet is 423 N/P. When the SiO₂ content is 2.8 and 1.8% fired at 1280°C, the RSI of the reduced pellet will increase to 34.5 and 55.8% and the compressive strength is reduced to less than 200 and 80 N/P. However, if some MgO was added, the RSI and the compressive strength of the reduced pellet could be improved significantly. When pellet’s MgO content was over 1.7% and SiO₂ content was 2.8% or MgO content was 2.5% and SiO₂ content was 1.8% fired at 1280°C, the RSI of the two pellets could drop to less than 20% and the compressive strength could increase to more than 300 N/P. Then, the technical index of pellet will meet the requirement of the charging in large BF. The added MgO pellet with low SiO₂ content have been used in 5500?m³ BF in Shougang Jingtang Corporation and delivered sustainable improvement of cost reduction.