超级风冷二冲程汽油机油的排烟性能

利用烟度模拟试验，热管氧化试验，板式成焦器详细考察了聚异丁烯加入量，聚异丁烯分子量，加氢聚异丁烯和非加氢聚异丁烯与油品排烟性能，清净性能的关系，使用高低分子量聚异丁烯复合成功研制出了满足ＪＡＳＯＭ３４５规格要求的低烟型超级风冷二冲程汽油机油。     

超级风冷二冲程汽油机油的排烟性能

利用烟度模拟试验、热管氧化试验、板式成焦器试验详细考察了聚异丁烯加入量、聚异丁烯分子量、加氢聚异丁烯和非加氢聚异丁烯与油品排烟性能、清净性能的关系,使用高低分子量聚异丁烯复合研制了满足JASO M345规格要求的低烟型超级风冷二冲程汽油机油。     

低分子聚异丁烯在二冲程汽油机油中的应用

本文通过对聚异丁烯（ＰＩＢ）性能分析及分解机理的论述，结合有关具体试验，论证了低分子ＰＩＢ在二冲程汽油机油中具有改善油品的高温润滑性、燃烧清净性及排烟等性能，是二冲程汽油机油不可缺少的组份。     

ECD风冷二冲程汽油机油的研制

ＥＧＤ风冷二冲程汤油机油采用Ⅱ类基础油、无异味煤油、低分子聚异丁烯及多种国产添加剂配制而成。该油品满国际标准化组织ＩＳ为Ｌ－ＥＧＤ风冷二冲程油质量指标，具有优良的高温清净性、润滑性和低排烟性能。     

FC二冲程汽油机油研制

论述了ＦＣ二冲程汽油机油的研制过程，该研制油品可以满足日本ＪＡＳＯＭ３４５ＦＣ级油品的质量要求，文中还简述了几种国外，国内及加氢精帽的聚异丁烯热氧化性能，聚异丁二冲程汽油机油中的应用机理。并给出了试验数据和评定数据。     

EGD风冷二冲程汽油机油的研制

EGD风冷二冲程汽油机油采用Ⅱ类基础油、无异味煤油、低分子聚异丁烯及多种国产添加剂配制而成。该油品满足国际标准化组织ISOL EGD风冷二冲程油质量指标 ,具有优良的高温清净性、润滑性和低排烟性能。     

FC级可生物降解二冲程汽油机油的研究

为满足国内外日益严格的环保要求,开发研制了FC级可生物降解二冲程汽油机油.以酯类油、聚异丁烯、矿物油为基础油,加入4.5%的复合添加剂,考察了添加剂与基础油的相溶性,并对油品的可生物降解性能、清净性能、润滑性能进行模拟评定,确定配方.研制油品通过了FC级二冲程汽油机油全套台架评定,并且可生物降解率超过了60%.油品具有良好的使用性能和可生物降解性能.     

Ⅰ档(L-ERA)、Ⅱ档(L-ERB)、Ⅲ档(L-ERC)二冲程汽油机油研究

本文介绍了国家“七五”重点科技攻关项目二冲程汽油机油系列产品的研制。二冲程汽油机油系列产品是以石蜡基中性油、光亮油及聚异丁烯为基础油,加有清净分散剂、抗氧剂、降凝剂等多种添加剂调制而成。经标准台架程序评定,全尺寸二冲程汽油机500h耐久性能试验,1.6×10~4km行车试验及各厂家使用试验。结果表明,油品具有积炭少而松软,低温流动性及混溶性能好,润滑性能优良,燃油比可达50:1,油品质量达到80年代国际水平。该系列产品适用于分离式润滑或预混合式润滑的各种空冷式二冲程汽油机的润滑。     

TC—WⅡ水冷二冲程汽油机油的研制

ＴＣ－ＷⅡ水冷二冲程汽油机油采用茂名石化公司生产的矿物油、溶剂及国产聚异丁烯为基础油组分，添加无灰清净分散剂、防锈剂、抗氧剂、减摩剂等配制而成。通过了ＡＳＴＭＤ４８５８－８８、Ｄ４８６３－８８水冷二冲程汽油机油规格，满足了舷外机、摩托车等水冷二冲程点燃式汽油发动机的需要。     

FC超级风冷二冲程汽油机油的研究

通过对不同配比的基础油、不同相对分子质量的聚异丁烯及不同的添加剂组成进行排烟性、润滑性、清净性及排气堵塞等测试，确定了配方。评定结果表明，研制的ＦＣ超级风冷二冲程汽油机油性能达到中国石化总公司暂定技术标准和ＩＳＯ规格。该汽油机油还具有排放低、环境污染小的优点     

FC级风冷二冲程汽油机油的研制

用大庆基础油、无异味煤油、低分子量聚异丁烯及国产添加剂调制成二冲程发动机油，该油满足日本ＪＡＳＯＭ３４５－９３ＦＣ级指标要求，并于１９９７年４月通过了中国石化总公司技术鉴定。     

均匀设计在FC二冲程汽油机油开发中的应用

以HVI150N,HVI500N加氢裂化基础油及适量的聚异丁烯,煤油馏分调制FC级二冲程汽油机油,通过均匀设计,以较少次数的实验,确定了各因素与考察变量间的关系,所调制的油品的润滑性,清生都超过已通过台架鉴定的参比油。     

The Lubrication Properties of Binary Blends of S-4: Polyisobutene and S-4: Polyalpholephine-100

The lubrication behavior of two series of binary blends containing S-4: PAO-100 or S-4: PIB have been followed. Each series contains 5%, 10%, 15%, 20%, and 25% of PAO-100 or PIB. The results indicate that upon addition of PAO-100, viscosities, viscosity index, and flash point increase in a linear fashion. Meanwhile, pour point, TAN, and specific gravity remain constant. In the case of PIB, viscosities increase in an exponential manner, viscosity index increases then remains constant, flash point drops, and then leftovers remain constant. Other properties do not change considerably. The rheological properties of 15% and 25% blends of S-4: PAO-100 blends are similar to S-6 and S-8, respectively. Similar conditions exist for 5% and 10% of S-4: PIB blends. A motor oil which has been formulated by 15% S-4: PAO blend and a hydraulic oil which has been formulated by 5% S-4: PIB blend have shown good performance characteristics.     

不同相对分子质量聚异丁烯对无灰分散剂性能的影响

以不同相对分子质量的聚异丁烯（PIB）为原料,与胺、烯酐、稀释剂等在不同条件下反应,制备润滑油无灰分散剂聚异丁烯丁二酰亚胺（PIBSI）,并测试其分散性能和抗氧化性能;考察PIB相对分子质量、中间产物聚异丁烯丁二酸酐（PIBSA）的合成工艺对PIBSI性能的影响。结果表明：随着原料PIB相对分子质量的增加,PIBSI的分散性能与抗氧化性能均有提升;与氯化法工艺相比,自由基法工艺不仅能耗低、污染小,而且合成的PIBSI性能更好;其中,由数均相对分子质量为2 300的PIB原料经自由基法工艺制备的PIBSI分散性能最佳,其油泥斑点分散值（SDT）最高可达73.15%。     

The Application of Heavy Alkyl Benzene in Engine Oil and Hydraulic Fluid Formulations

Heavy alkyl benzene (HAB) is a byproduct in the process of linear alkyl benzene (LAB) production. It is used as heat transfer oil and lubricating greases. In this article the potential of the usage of HAB in the formulation of gasoline and diesel engine oils as well as hydraulic fluid is indicated. With the aim of passing 5W30, 5W40, 10W40, and 15W40 standards, different engine oils have been formulated. The formulations contain various amounts of HAB as minor component, and miscellaneous quantities of solvent neutral 100 (SN-100), SN-150, and SN-650 as major component. The measurement of typical properties of obtained oils indicates that some of them do have the intended criteria. Test field of the recent oils designate that they have good performance. In the next step, different blends of HAB as major component and polyisobutene (PIB) as minor component have successfully been employed in the formulation of several ISO grade hydraulic fluids. The achieved materials do have suitable air release and demulsibility.     

变频调速器在低分子聚异丁烯装置反应器压力控制中的应用

在聚异丁烯反应器压力控制中安装变频调速器 ,解决了反应器压力波动大 ,泵不能平稳运转的缺点 ,使PIB操作快速、平稳 ,有利于设备和装置安稳长运行     

A molecular dynamics study and detonation parameters calculation of 5,5’-dinitramino-3,3’-bi[1,2,4-triazolate] carbohydrazide salt (CBNT) and its PBXs

ABSTRACT

Molecular dynamics (MD) simulation has been used to investigate the new explosive 5,5?-dinitramino-3,3?-bi[1,2,4-triazolate] carbohydrazide salt (CBNT) and its polymer-bonded explosives (PBXs) with polymethyl methacrylate (PMMA), polyisobutylene (PIB), cellulose acetate butyrate (CAB) and polyurethane (Estane 5703). The binding energy, isotropic mechanical properties (tensile modulus, bulk modulus, shear modulus, and Poisson’s ratio) and moldability are reported for CBNT and its based PBXs. Moreover, the detonation parameters (detonation velocity, detonation pressure, detonation temperature, and detonation heat) of CBNT and CBNT-based PBXs are calculated using EXPLO5. The binding energy between each of the crystalline surfaces and each polymer is different, of which the descending order is CBNT/CAB > CBNT/Estane5703 > CBNT/PMMA > CBNT/PIB. The obtained mechanical properties results indicate that the mechanical properties of the CBNT can be effectively improved by adding a tiny amount of polymer binders and the ability of different polymer binders improving the plasticity and moldability of CBNT in the descending order of Estane 5703 > CAB > PMMA > PIB. The calculated detonation performances show that when 5% binders are added, the detonation velocity and detonation pressure of PBXs are lower than those of pure CBNT, of which the detonation velocity is higher than 8500 m/s and the detonation pressure is higher than 26 GPa. Due to the high enthalpy of formation, the detonation temperature and detonation heat of CBNT/CAB are larger than those of pure CBNT.     

含硫原油研制水冷二冲程机油

以中国石化茂名分公司生产的含硫原油基础油、无异味煤油和PIB为基础油组分,加入国产降凝剂、防锈剂、抗氧剂、抗磨剂和无灰分散剂研制出的水冷二冲程油具有较好的润滑性能和清净性能,达到TC-WⅡ规格要求。     

不同催化剂体系对聚异丁烯端基结构的影响

通过测定异丁烯的聚合物产物聚异丁烯的末端结构,着重研究了BF3／醇、BF3／H2O和AICI3／H2O催化剂体系对聚异丁烯的末端结构的影响。实验结果表明,BF3／醇配位催化剂体系聚合得到的聚异丁烯的末端结构主要是α－烯烃结构;而BF3／H2O和AICI3／H2O体系聚合得到的聚异丁烯末端结构主要是β－烯烃结构。在BF3／醇催化剂中,当BF3与醇的摩尔比为1时,聚异丁烯的末端α－烯烃含量达到80％以上并且相对分子质量分布系数为2。