Effect of ignition timing and compression ratio on the performance of a hydrogen–ethanol fuelled engine

This paper presents the results obtained of a compression ignition engine (modified to run on spark ignition mode) fuelled with hydrogen–ethanol dual fuel combination with different percentage substitutions of hydrogen (0–80% by volume with an increment of 20%) under variable compression ratio conditions (i.e. 7:1, 9:1 and 11:1) by varying the spark ignition timing at a constant speed of 1500 rpm. The various engine performance parameters studied were brake specific fuel consumption, brake mean effective pressure and brake thermal efficiency. It was found from the present study that for specific ignition timing the brake mean effective pressure and the brake thermal efficiency increases with the increase of hydrogen fraction in ethanol and all hydrogen substitutions showed the maximum increase in brake thermal efficiency and reduction in brake specific fuel consumption value at around 25^° CA advanced ignition timing. The best operating conditions were obtained at a compression ratio of 11:1 and the optimum fuel combination was found to be 60–80% hydrogen substitution to ethanol.     

Experimental and modeling study of performance and emissions of SI engine fueled by natural gas–hydrogen mixtures

Based on CFD software and reaction kinetics software, multi-dimensional CFD Model coupled with detail reaction kinetics is built to study the combustion process in H₂/CNG Engine. Detail reaction mechanism is used to simulate the chemistry of combustion and a combustion model considering the turbulent mixing effects was also applied. To reduce the computation time, the coupled software is reprogrammed to have the function of parallel computing and the revised software is computed in a Massively Parallel Processor. The model is validated using the experiment data from a modified diesel engine. The results show: cylinder pressure from simulation has a good agreement with experiment data and CO and NO_x emission is well predicted by the model in a wide range.     

Effect of spark timing on the performance of a hybrid hydrogen–gasoline engine at lean conditions

Hydrogen addition is an effective way for improving the performance of spark-ignited (SI) engines at stoichiometric and especially lean conditions. Spark timing also heavily influences the SI engine performance. This paper experimentally investigated the effect of spark timing on performance of a hydrogen-enriched gasoline engine at lean conditions. The experiment was carried out on a four-cylinder, port-injection gasoline engine which was modified to be an electronically controlled hybrid hydrogen–gasoline engine (HHGE) by adding a hydrogen port-injection system on the intake manifolds while keeping the original gasoline injection system unchanged. A hybrid electronic control unit (HECU) was developed to govern the injection timings and durations of hydrogen and gasoline to enforce the timely mixing of hydrogen and gasoline in the intake ports at the expected blending levels and excess air ratios. During the test, the engine speed was fixed at 1400 rpm and the manifolds absolute pressure (MAP) was kept at 61.5 kPa. The hydrogen volume fraction in the intake was increased from 0% to 3% through adjusting the hydrogen injection duration. For a specified hydrogen addition level, gasoline injection duration was reduced to ensure the engine operating at two excess air ratios of 1.2 and 1.4, respectively. The spark timing for a specified hydrogen addition level and excess air ratio was varied from 20 to 50 °CA BTDC with an interval of 2 °CA. The test results showed that the indicated mean effective pressure (Imep) first increased and then decreased with the increase of spark advance. The optimum spark timing for the max. Imep (OST) was retarded for the HHGE at a specified excess air ratio. The max. indicated thermal efficiency appeared at the OST. Flame development period was shortened whereas flame propagation period was prolonged with the decrease of spark advance. The coefficient of variation in indicated mean effective pressure generally gained its minimum value at the OST. HC and NOx emissions were continuously decreased with the retarding of spark timing. However, the effect of spark timing on CO emission was found insignificant.     

A comparative evaluation of the performance of different fuel induction techniques for blends hydrogen–methane SI engine

Mixtures of hydrogen and methane are considered viable alternative fuels to gasoline due to lower overall pollutant emissions.     

An experimental study on performance and emission characteristics of a methane–hydrogen fuelled gasoline engine

In this paper, the performance and emission characteristics of a conventional twin-cylinder, four stroke, spark-ignited (SI) engine that is running with methane–hydrogen blends have been investigated experimentally. The engine was modified to realize hydrogen port injection by installing hydrogen feeding line in the intake manifolds. The experimental results have been demonstrated that the brake specific fuel consumption (BSFC) increased with the increase of hydrogen fraction in fuel blends at low speeds. On the other hand, as hydrogen percentage in the mixture increased, BSFC values decreased at high speeds. Furthermore, brake thermal efficiencies were found to decrease with the increase in percentage of hydrogen added. In addition, it has been found that CO₂, NO_x and HC emissions decrease with increasing hydrogen. However, CO emissions tended to increase with the addition of hydrogen generally increase. It has been showed that hydrogen is a very good choice as a gasoline engine fuel. The data are also very useful for operational changes needed to optimize the hydrogen fuelled SI engine design.     

Theoretical and experimental study on the performance of a diesel engine fueled with diesel–biodiesel blends

This study reports the effects of engine load and biodiesel percentage on the performance of a diesel engine fueled with diesel–biodiesel blends by experiments and a new theoretical model based on the finite-time thermodynamics (FTT). In recent years, biodiesel utilization in diesel engines has been popular due to depletion of petroleum-based diesel fuel. In this study, performance of a single cylinder, four-stroke, direct injection (DI) diesel engine fueled with diesel–biodiesel mixtures has been experimentally and theoretically investigated. The simulation results agree with the experimental data. After model validation, the effects of engine load and biodiesel percentage on engine performance have been parametrically investigated. The results showed that, effective power increases constantly, effective efficiency increases to a specified value and then starts to decrease with increasing engine load at constant biodiesel percentage and compression ratio. However, effective efficiency increases, effective power decreases to a certain value and then begins to increase with increasing biodiesel percentage at constant equivalence ratio and compression ratio.     

Zero-dimensional single zone engine modeling of an SI engine fuelled with methane and methane-hydrogen blend using single and double Wiebe Function: A comparative study

Combustion modeling plays a key role in an engine simulation to predict in-cylinder pressure development and engine performance with a high level accuracy. Wiebe function, representing mass fraction burned (MFB) as a function of crank angle position, is widely used to predict the combustion process. The work presents a predictive zero-dimensional (Zero-D) single zone engine modeling of an SI engine fuelled with methane and methane-hydrogen blend. In this work, the single and double forms of Wiebe function were used to estimate the combustion process in the modeling. For this purpose, the single and double-Wiebe functions' parameters were calculated using the least squares method by fitting to the MFB curves calculated from experimental pressure data. These Wiebe functions were, then, introduced to the Zero-D single zone engine model developed for the methane and methane-hydrogen blend fueled SI engine to obtain in-cylinder pressure development and gross indicated mean effective pressure (GIMEP) for the engine performance prediction. The results show that the model with double-Wiebe Function fit better than that with single-Wiebe function. In addition, the fitted double-Wiebe function has a significant improvement in the GIMEP prediction for methane-hydrogen blend fueled SI engine modeling rather than the methane-fueled modeling.     

Experimental study on combustion and emissions performance of a hybrid hydrogen–gasoline engine at lean burn limits

Lean combustion is an effective way for improving the spark-ignited (SI) engine performance. Unfortunately, due to the narrow flammability of gasoline, the pure gasoline-fueled engines sometimes suffer partial burning or misfire at very lean conditions. Hydrogen has many excellent combustion properties that can be used to extend the gasoline engine lean burn limit and improve the gasoline engine performance at lean conditions. In this paper, a 1.6 L port fuel injection gasoline engine was modified to be a hybrid hydrogen–gasoline engine (HHGE) fueled with the hydrogen–gasoline mixture by mounting an electronically controlled hydrogen injection system on the intake manifolds while keeping the original gasoline injection system unchanged. A self-developed hybrid electronic control unit (HECU) was used to flexibly adjust injection timings and durations of gasoline and hydrogen. Engine tests were conducted at 1400 rpm and a manifolds absolute pressure (MAP) of 61.5 kPa to investigate the performance of an HHGE at lean burn limits. Three hydrogen volume fractions in the total intake gas of 1%, 3% and 4.5% were adopted. For a specified hydrogen volume fraction, the gasoline flow rate was gradually reduced until the engine reached the lean burn limit at which the coefficient of variation in indicated mean effective pressure (COVimep) was 10%. The test results showed that COVimep at the same excess air ratio was obviously reduced with the increase of hydrogen enrichment level. The excess air ratio at the lean burn limit was extended from 1.45 of the original engine to 2.55 of the 4.5% HHGE. The engine brake thermal efficiency, CO, HC and NO_x emissions at lean burn limits were also improved for the HHGE.     

Transient performance of a two-dimensional salt gradient solar pond—A numerical study

Solar ponds have recently become an important source of energy that is used in many different applications. The technology of the solar pond is based on storing solar energy in salt-gradient stratified zones. Many experimental and numerical investigations concerning the optimum operational conditions and economical feasibility of solar ponds have been published in the last few decades. In the present study, a novel two-dimensional mathematical model that uses derived variables is developed and presented. This model utilizes vorticity, dilatation, density, temperature and concentration as dependent variables. The resulting governing partial differential equations are solved numerically in order to predict the transient performance of a solar pond in the two-dimensional domain. The boundary conditions are based on measured ambient and ground temperatures at Kuwait city. Based on the present formulation, a computer code has been developed to solve the problem at different operating conditions. The results are compared with the available experimental data and one-dimensional numerical results. Two-dimensionality effects are found to depend mainly on the aspect ratio of the pond. A parametric study is conducted to determine the optimum pond dimensions and operating conditions.     

Solidification inside a sphere—an experimental study

This paper presents the investigations of the solidification of an n-hexadecane inside a spherical enclosure. The effect of solidification process was investigated for three different constant surface temperature conditions (13 °C, 8 °C and 3 °C) and for three different initial superheats of n-hexadecane (8 °C, 2 °C and 0 °C). It was observed that the solidification phase front propagates uniformly inwards towards the centre of the sphere. The concentricity of the solid–liquid phase front deteriorates as time progresses due to shrinkages causing formation of voids inside the sphere. A lower constant surface temperature results in a larger solidified mass fraction. The effect of the initial liquid superheats of the PCM on the solidification is insignificant.     

Modeling of a catalytic membrane reactor for CO removal from hydrogen streams – A theoretical study

Typical industrial hydrogen streams arising from reforming processes contain about 1% of carbon monoxide (CO). For fuel cell applications hydrogen should contain less than 10 ppm of CO, since it poisons the platinum catalysts in the electrodes. Traditionally, this is carried out through a selective oxidation reactor – PROX reactor. However, the parallel oxidation of hydrogen to water should be avoided. This work proposes the use of a catalytic membrane reactor (MR) whose design is based on a CO permselective membrane containing the selective catalyst loaded in the permeate side. It is considered plug-flow pattern and segregated feed of CO and oxygen. This strategy should improve the selective oxidation, as the permselective membrane enhances the CO/H₂ ratio at the catalyst surface.     

Experimental investigation of SI engine characteristics using Acetone-Butanol-Ethanol (ABE) – Gasoline blends and optimization using Particle Swarm Optimization

This study conducts an experimental investigation of spark ignition (SI) engine characteristics using gasoline blended with Acetone-Butanol-Ethanol (ABE) that act as hydrogen and oxygen carriers. The number of experiments is planned and executed according to a design of experiments with full-factorial design, wherein ABE blend percentage and speed are taken as input parameters and brake thermal efficiency (BTE), emissions of carbon monoxide (CO), hydrocarbon (HC), and oxides of nitrogen (NOx) are taken as the responses. In the present study, a multi-objective optimization technique, Particle Swarm Optimization (PSO), is used to optimize spark ignition engine performance and emission parameters. The results predicted by the regression model are compared with the experimental results. PSO is used to study the Pareto front of BTE, CO, HC, and NOx, respectively. The results indicated that when the engine is run at 1500 rpm, with the fuel blend having 5.4% ethanol, a minimum value of 0.58% CO, 211 ppm of HC are obtained, giving a maximum BTE of 28%. Similarly, when the engine is run at 2264 rpm with a 5% ethanol blend, minimum NOx emission of 1029 ppm and a maximum BTE of 30% are obtained.     

Effects of hydrogen direct injection on engine stability and optimization of control parameters for a combined injection engine

As engine stability is a crucial issue for engine performance and toxic emissions, an experimental research has been conducted to analyze the effects of hydrogen direct injection on engine stability. The experiments have been divided into two parts. The first set is aimed to analyze different parameter characteristics with and without hydrogen direct injection, and the second set tries to find optimal control regions. Excess air ratios, spark timings, engine speeds and engine loads are chosen as primary parameters in the study. The results show hydrogen addition can increase brake thermal efficiency by a range from 6% to 13%, enhancing the lean burn performance. Combustion duration has been shortened to about 80% by adding 10% hydrogen mixture into gasoline. Besides, Hydrogen addition makes the mixture further insensitive to ignition timings, and narrows the optimal regions with higher excess air ratios. Under medium engine speeds, the highest CoV_IMEP locates in the low load region for pure gasoline, while this maximum value appears in the medium load region for 10% hydrogen mixture. In addition, the specific value of CoV_IMEP with 10% hydrogen is rather small compared to pure gasoline. Thus, hydrogen direct injection can significantly improve engine stability and reduce controlling difficulties.     

Diborane–tetraborane conversion in C60 vesicles—a theoretical study

Diborane–tetraborane conversion in a C₆₀ cage is theoretically considered by using AM1-RHF type semiempirical quantum chemical approach. Molecular orbital characteristics of some endohedrally boron hydride doped C₆₀ composite systems are investigated and the likeliness of diborane–tetraborane conversion in a C₆₀ vesicle for the purpose of hydrogen storage is discussed.     

Endohedrally hydrogen doped C58H4 vesicles—a theoretical study

Endohedrally, various numbers (1–5) of hydrogen molecules doped C₅₈H₄ nanovesicles are considered for semiempirical molecular orbital treatment at the level of AM1(RHF) method as well as molecular mechanics calculations (MM+) to investigate the possible usage of these, yet nonexistent, structures as hydrogen storage media.     

Experimental study of a single-cylinder engine fueled with natural gas–hydrogen mixtures

The objective of this study is to evaluate the power, efficiency and emissions of an electronic-controlled single-cylinder engine fueled with pure natural gas and natural gas–hydrogen blends, respectively. Replacing the nature gas with hydrogen/methane blend fuels was found to have a significant influence on engine performance. The effects of excess air ratio and spark timing were discussed. The results show that under certain engine conditions the maximum cylinder gas pressure, maximum heat release rate increased with the increase of hydrogen fraction. The increase of hydrogen fraction in the blends contributed to the increase of NO_x and the decrease of HC and CO. The brake specific fuel consumption decreased with the increase of hydrogen fraction. Using HCNG at relatively leaner fuel–air mixtures and retarded spark timing totally improved the engine emissions without incurring the performance penalty.     

A study of the performance,emission and combustion characteristics of a compression ignition engine using methyl ester of paradise oil–eucalyptus oil blends

The significance of this study is the complete replacement of diesel fuel with bio-fuels. For this purpose; bio-fuels, namely, methyl ester of paradise oil and eucalyptus oil were chosen and used as fuel in the form of blends. Various proportions of paradise oil and eucalyptus oil are prepared on a volume basis and used as fuels in a single cylinder, four-stroke DI diesel engine, to study the performance and emission characteristics of these fuels. In the present investigation a methyl ester derived from paradise oil is considered as an ignition improver. The results show a 49% reduction in smoke, 34.5% reduction in HC emissions and a 37% reduction in CO emissions for the Me50–Eu50 blend with a 2.7% increase in NO_x emission at full load. There was a 2.4% increase in brake thermal efficiency for the Me50–Eu50 blend at full load. The combustion characteristics of Me50–Eu50 blend are comparable with those of diesel.     

Optimization of synthesis parameters for catalytic performance of Ni–B catalysts using response surface methodology

Hydrogen production through hydrolysis of sodium borohydride (NaBH₄) by using metal catalysts is promising for fuel cell applications. Nickel (Ni) and its alloys are favorable due to their high catalytic activity, relatively low cost and availability. In present study, the effects of temperature, pH, reduction rate and reducing agent concentration, which significantly affect the catalyst performance, were investigated using the response surface methodology (RSM). A mathematical model was derived according to results which were obtained from four-level orthogonal Taguchi L16 (4⁴) experimental design used for the optimization of multiple parameters in the process. From the RSM analyses, that compatible with the predicted experimental results, maximum hydrogen generation rate (HGR) 49.81 L min^?1 g_cat^?1 was obtained temperature of 278.12 K, pH of 5.52, reducing agent concentration of 85.96 NaBH₄.water^?1 and reduction rate of 6.82 mL min^?1. Analysis of variance reveals that both pH and rate of reduction have significant effect than the temperature on the HGR.     

An experimental study on the development of a β-type Stirling engine for low and moderate temperature heat sources

In this study, a β-type Stirling engine was designed and manufactured which works at relatively lower temperatures. To increase the heat transfer area, the inner surface of the displacer cylinder was augmented by means of growing spanwise slots. To perform a better approach to the theoretical Stirling cycle, the motion of displacer was governed by a lever. The engine block was used as pressurized working fluid reservoir. The escape of working fluid, through the end-pin bearing of crankshaft, was prevented by means of adapting an oil pool around the end-pin. Experimental results presented in this paper were obtained by testing the engine with air as working fluid. The hot end of the displacer cylinder was heated with a LPG flame and kept about 200 °C constant temperature throughout the testing period. The other end of the displacer cylinder was cooled with a water circulation having 27 °C temperature. Starting from ambient pressure, the engine was tested at several charge pressures up to 4.6 bars. Maximum power output was obtained at 2.8 bars charge pressure as 51.93 W at 453 rpm engine speed. The maximum torque was obtained as 1.17 Nm at 2.8 bars charge pressure. By comparing experimental work with theoretical work calculated by nodal analysis, the convective heat transfer coefficient at working fluid side of the displacer cylinder was predicted as 447 W/m² K for air. At maximum shaft power, the internal thermal efficiency of the engine was predicted as 15%.