共查询到19条相似文献,搜索用时 171 毫秒
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润滑剂YI对聚氯乙烯塑料流变性能的影响 总被引:3,自引:0,他引:3
采用毛细管流变仪,考察润滑剂YI用量对PVC流变性能的影响。实验表明,流体非牛顿指数n<1,并随YI用量增加而下降。YI使PVC熔体粘度大幅度减少,在硬质PVC中,YI用量在0.6~1.0PHR作用最明显;在软质PVC中,当剪切速率γ>500s-1时,少量YI就能使熔体粘度下降。并测定了不同YI用量PVC的流动活化能,随YI用量增加,Eη略有下降,切应力对Eη影响不明显 相似文献
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PA1010/MGEPR共混物的流变性能研究 总被引:2,自引:0,他引:2
以尼龙1010(PA1010)为基体,以马来酸酐接枝乙丙橡胶(MGEPR)为增韧剂,采用Brabender PLE331型塑化仪制备了PA1010/MGEPR共混增韧尼龙材料,测试了PA1010/MGEPR共混物的表观粘度、非牛顿指数和粘液活化能等流变能数,并重点讨论了其流变性能。实验结果表明:共混物的表观粘度随温度升高而降低;粘流活化能随剪切速率的增而而减小。共混物熔体的表观粘度随剪切速率和剪切应力的增大而降低,非牛顿指数n小于1,符合假塑性流体流动规律。 相似文献
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采用熔融共混法制备了Mg(OH)2阻燃乙烯-乙酸乙烯酯塑料(EVAC),并采用毛细管流变仪对其流变性能进行了研究。讨论了温度、剪切速率和剪切应力对熔体表观黏度的影响;研究了黏流活化能与剪切速率的变化规律。结果表明,熔体的表观黏度随温度的升高而降低,随剪切速率和剪切应力的增大而减小;黏流活化能随剪切速率的增大而降低。其非牛顿指数小于1,说明Mg(OH)2阻燃EVAC为假塑性流体。当剪切应力无限小时,由Spencer-Dillon公式外推得到阻燃EVAC的零切黏度。 相似文献
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高聚合度PVC改性电缆料的研制 总被引:2,自引:0,他引:2
本文介绍采用不同改性剂对高聚合度PVC进行改制造橡胶类改性热塑性电缆料,考察了塑化温度、改性剂、增塑化温度为175℃;丁腈胶N-41是PVC的良好改性剂;当CaCO3用量为30份,DOP用量为65-75份(均以PVC/N-41为90/10,共计100)时,可制得性能良好的改性电缆料。 相似文献
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Odd Fredriksen 《应用聚合物科学杂志》1969,13(1):69-80
Capillary rheometer measurements show that stearic acid can be characterized as a normal lubricant. If the content of stearic acid is increased in rigid PVC formulations, the melt viscosity will decrease. This leads to a corresponding increase of shear rate and volumetric flow rate. The influence of calcium stearate is opposite to the normal characteristic of a lubricant. Increasing amounts of calcium stearate lead to an increased melt viscosity and a decreased shear rate and volumetric flow rate. In the extrusion of rigid PVC, the apparent “lubricating” effect of calcium stearate is probably due to the increased friction with resulting heat evolution and higher mass temperature, leading to a decreased viscosity of the plastic melt. This is in agreement with the results of the extrusion experiments. Both mass temperature and power consumption decrease when stearic acid is added and increase when calcium stearate is added to the formulation. 相似文献
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Pravin L. Shah 《Polymer Engineering and Science》1974,14(11):773-777
A rheological investigation of the saturated fatty acids as lubricants for PVC was made in a Sieglaff-McKelvey rheometer over a wide temperature range. Results reveal that with an increase in carbon chain, fatty acids became more effective in reducing the melt viscosity of PVC. It was also discovered that the maximum viscosity variation due to these materials was observed at 350°F. At test temperatures of 400°F and above, no major viscosity differences were observed. Furthermore, the changes in the melt viscosity were more pronounced at shear rates less than 200 sec?1. The usefulness of the measured viscosity variations at the critical test temperature of 350°F was shown by extrusion. An excellent correlation between the apparent melt viscosity and extrusion melt temperature was found. The criticalness of the test temperature in assessing the effect of lubricants on PVC flow is discussed. 相似文献
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The melt rheological behavior of calcium silicate‐filled isotactic polypropylene, with filler volume contents of 0–17.8%, was determined at 493 K. The composites followed the power law in shear stress versus shear rate variations and were shear thinning. Initially, apparent melt viscosity decreased until a critical filler volume content of 8.5% was reached. However, on further increase in calcium silicate concentration, apparent melt viscosity increased. Melt elasticity also showed an initial decrease until 8.5% filler content was reached and then an increase beyond this filler content. Surface treatment of calcium silicate with a titanate coupling agent, LICA 38, modified the rheological properties because of the plasticizing/lubricating effect of LICA 38. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1511–1518, 2003 相似文献
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EPDM橡胶的流变特性实验研究 总被引:1,自引:0,他引:1
为了研究橡胶熔体流变性能对其加工成型的影响,利用毛细管流变仪对三元乙丙橡胶(EPDM)的流变特性进行了实验研究。实验结果表明:EPDM橡胶在毛细管挤出时,剪切速率对剪切应力、剪切粘度和挤出胀大的影响最大;挤出温度对三者有一定的影响;在长径比相同时,毛细管半径对剪切应力和剪切粘度几乎没有影响,但对挤出胀大影响较大。 相似文献
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定向碳纳米管/高密度聚乙烯复合材料体系流变行为的研究 总被引:1,自引:0,他引:1
对定向碳纳米管进行酸化处理以后,采用机械共混法制备了定向碳纳米管/高密度聚乙烯复合材料,利用毛细管流变仪研究了高密度聚乙烯和定向碳纳米管/高密度聚乙烯复合材料的流变行为.讨论了剪切应力、剪切速率、温度以及定向碳纳米管的加入对体系流变行为的影响。结果表明:高密度聚乙烯和定向碳纳米管/高密度聚乙烯复合材料都属于假塑性流体.高密度聚乙烯的非牛顿性要大于定向碳纳米管/高密度聚乙烯复合材料;随剪切速率和剪切应力的增大及温度的升高.熔体表现粘度均减小;随着定向碳纳米管含量的增加,定向碳纳米管/高密度聚乙烯复合材料的表观粘度先减小后增大。 相似文献
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Copolymers of vinyl chloride–vinyl acetate have been prepared with different vinyl acetate contents and molecular weights and under different polymerization conditions. A rheological study of these copolymers indicates that they behave in some ways like externally plasticized PVC. For instance, as the vinyl acetate content increases, the melt viscosity decreases, the flow activation energy decreases, and the copolymer becomes more Newtonian. However, the critical shear rate for melt fracture increases, resembling the addition of elastic polymers to PVC. An increase in copolymer molecular weight has a similar effect on the rheological behavior as in PVC, except that the flow activation energy is observed to increase rather than decrease. Decreasing the polymerization temperature affects the flow properties of the copolymer, probably due to changes in degree of branching and crystallinity. A copolymer made by the delayed addition of vinyl chloride, having a more random structure than one made by the conventional batch method, exhibited quite different flow behavior. It had a lower melt viscosity, higher critical shear rate, and lower flow activation energy. 相似文献
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《塑料、橡胶和复合材料》2013,42(10):436-442
AbstractAn experimental study of the rheological behaviour of ethylene/octene copolymer compounds in extrusion containing blowing agent has been carried out. The cell morphology development was studied using scanning electron microscopy. Rheological properties of unfilled and precipitated CaCO3 filled systems with various blowing agents, extrusion temperatures, and shear rates were studied using a capillary rheometer. The total extrusion pressure, apparent shear stress, apparent viscosity, and die swell of the unfilled and CaCO3 filled compounds were also determined and the effect of blowing agent on the rheological properties of the compounds studied. It was observed that there is reduction of stress and viscosity with blowing agent loading. Incorporation of blowing agent led to decreased shear thinning behaviour resulting in an increase in the power law index. The viscosity reduction factor of the unfilled compound was found to be dependent on the concentration of blowing agent, the shear rate, and the temperature. 相似文献
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用熔体流动速率仪测定了8种ABS树脂的熔体质量流动速率,并用毛细管流变仪对8种ABS树脂流变性能进行了研究。结果表明,1、7、8号样的流动性最好;8种树脂的非牛顿指数n都小于1,属于假塑性流体;同时8种ABS树脂的表观黏度随剪切速率、剪切应力的增加而降低,当剪切速率、剪切应力足够高时,它们对8种ABS树脂表观黏度的影响趋于一致。 相似文献