Spectral definition of the macro-algae Ulva curvata in the back-barrier bays of the Eastern Shore of Virginia,USA

We have developed methods to determine the visible (VIS) to near-infrared (NIR) spectral properties of thalli and epiphytes of bloom-forming and green macrophyte Ulva curvata in back-barrier lagoons in Virginia, USA. A 2% increase in NIR thalli reflectance from winter to summer (ca. 9.5%) matched the drop in summer NIR transmittance (ca. 90%). In contrast, summer and winter VIS reflectance (reaching 6%) were nearly identical while winter transmittance (ca. 85%) was 10–20% higher. NIR absorption remained at 5% but VIS absorption increased by 10–20% from winter to summer. Replicate consistency substantiated the high transmittance difference indicating thallus composition changed from summer to winter. Epiphytes increased thallus reflectance (<ca. 4%) and decreased transmittance (<ca. 10%) and exhibited broadband VIS and NIR absorptions in summer and selective peaks in winter. A simulation coupling water extinction with thallus reflectance and transmittance found seven submerged thalli maximized the surface reflectance enhancement (ca. 2.5%).     

Evaluating temporal variability in the spectral reflectance response of annual ryegrass to changes in nitrogen applications and leaching fractions

A two‐year study was conducted in 2002 and 2003 at the University of Nevada, Las Vegas's center for urban water conservation to assess canopy spectral response of annual ryegrass (Lolium multiflorum Lam.) grown under various combinations of N and irrigation (based on leaching fraction: LF) treatments. Multispectral measurements were acquired using a ground‐based spectroradiometer (200–1100 nm) on a biweekly basis during the growing season (October–May) in 2002 and 2003. Multispectral parameters were correlated with soil–plant parameters and temporal variability was investigated. Results showed that the normalized difference vegetation index (NDVI), stress index (SI), photochemical reflectance index (PRI) and canopy reflectance at 693 nm, were highly correlated with tissue N concentration (TN), tissue moisture content (TM), TN×TM and canopy colour, as influenced by N and LF treatment combinations. Coefficients of determination ranged from 0.50 to 0.79 (P<0.001) based on single‐day correlations and correlations established over the entire growing period in 2002 and in 2003. TN was mainly predicted from wavelengths in the VIS portion of the spectrum, while TM was predicted from wavelengths in the VIS and NIR. Correlations were inconsistent between spectral parameters and physiological parameters throughout the study confirming the problem of temporal variation associated with spectral signatures of turfgrass species. However, spectral reflectance showed significant potential for monitoring turfgrass N and moisture status, and was able to capture temporal variability over the same growing period and from one year to another. The results provide a sound basis for future validation of ground‐based remote sensing for turfgrass management on golf courses.     

Inverting a forest canopy reflectance model to retrieve the overstorey and understorey leaf area index for forest stands

In this article, the Kuusk–Nilson forest reflectance and transmittance (FRT) model was inverted to retrieve the overstorey and understorey leaf area index (OU-LAI) of forest stands in the Longmenhe forest nature reserve in China. Data from detailed sample sites were collected in 30 forest stands representing the typical vegetation community in the study area. An uncertainty and sensitivity matrix (USM) was used to analyse the sensitivity of the FRT model parameters based on these data. The results indicated that overstorey LAI strongly influenced stand reflectance, whereas understorey LAI had a much lower impact. To predict OU-LAI in forest stands, FRT model inversion is carried out by minimizing a merit function that provides a measure of the difference between the reflectance simulated by the FRT model and the reflectance originating from optimal band selection of Hyperion data. Various combinations of Hyperion bands were tested to evaluate the most effective wavelengths for the inversion of OU-LAI. The best estimates from 17 Hyperion bands (5 VIS, 8 NIR, 4 SWIR) by the FRT model inversion showed an R ²?=?0.41 and RMSE/mean?=?0.21 for overstorey LAI and R ²?=?0.49 and RMSE/mean?=?0.91 for understorey LAI. Advantages and disadvantages of FRT inversion for retrieval OU-LAI combined with Hyperion data are discussed.     

Classification of shoreline vegetation in the Western Basin of Lake Erie using airborne hyperspectral imager HSI2, Pleiades and UAV data

Mapping land and aquatic vegetation of coastal areas using remote sensing for better management and conservation has been a long-standing interest in many parts of the world. Due to natural complexity and heterogeneity of vegetation cover, various remote sensing sensors and techniques are utilized for monitoring coastal ecosystems. In this study, two unsupervised and two supervised standard pixel-based classifiers were tested to evaluate the mapping performance of the second-generation airborne NASA Glenn Hyperspectral Imager (HSI2) over the narrow coastal area along the Western Lake Erie’s shoreline. Furthermore, the classification results of HSI2 (using the whole Visible-Near Infrared (VIS+ NIR) hyperspectral dataset, and also the spectral subset of Visible (VIS) spectral bands) were compared to multispectral Pleiades (VIS+ NIR) and Unmanned Aerial Vehicle (UAV) VIS classified images. The goal was to explore how different spectral ranges, and spatial and spectral resolutions impact the unsupervised and supervised classifiers. While the unsupervised classifiers depended more on the spectral range, spectral or spatial resolutions were important for the supervised classifiers. The Support Vector Machine (SVM) was found to perform better than other classification methods for the HSI2 images over all twenty-two study sites with the overall accuracy (OA) ranging from 82.6%–97.5% for VIS, and 81.5%–95.6 % for VIS + NIR. Considerably better performance of the supervised classifiers for the HSI2 VIS data over the Pleiades data (OA = 74.8–83.4%) suggested the importance of spectral resolution over spectral range (VIS vs. VIS+ NIR) for the supervised methods. The unsupervised classifiers exhibited low accuracy for both HSI2 VIS and UAV VIS imagery (OA< 30.0%) while the overall accuracy for the HSI2 VIS+ NIR and Pleiades data ranged from 60.4%–78.4 % and 42.1%–66.4%, respectively, suggesting the importance of spectral range for the unsupervised classifiers.     

山区可见光—近红外遥感影像浓密植被暗像元自动识别方法研究

暗目标法是目前气溶胶光学厚度遥感反演中应用最为广泛的方法,浓密植被暗像元的识别是暗目标法的基础。针对可见光—近红外影像缺少中红外波段难以有效识别浓密植被暗像元的问题,引入红波段直方图阈值法识别山区可见光—近红外影像的浓密植被暗像元。该方法利用浓密森林像元在可见光波段反射率低的特点,通过搜索红波段直方图的最小峰值自动识别浓密植被暗像元。试验中选取Landsat TM影像前4个波段利用红波段直方图阈值法识别可见光—近红外影像的浓密植被暗像元,并与在中红外波段影像和可见光—近红外影像中广泛应用的两种暗像元识别方法进行对比分析,探讨红波段直方图阈值法的有效性,最后将该方法应用于环境减灾卫星(HJ-1)CCD影像的暗像元识别和气溶胶反演。实验结果表明:红波段直方图阈值法明显优于常用的可见光—近红外影像暗像元识别方法,识别精度接近传统的中红外波段影像识别方法,相似度指数小于2和小于3的暗像元分别为83.12%和93.48%。该方法为山区可见光—近红外影像浓密植被暗像元自动识别提供了一种新的适用方法,识别结果能够满足暗目标法反演气溶胶光学厚度的要求。     

Improvement of the visibility of concealed features in artwork NIR reflectograms by information separation

Near Infrared (NIR) reflectography, coupled to visible (VIS) one, is a spectrophotometric imaging technique employed to probe both the inner and the outer layers of artworks. NIR reflectograms may partially contain information pertinent to the visible spectrum (due to the poor pigment transparency in NIR) and this decreases their comprehensibility. This work presents an innovative digital processing methodology for accentuating information contained in the infrared reflectograms. The proposed method consists of inducing minor changes in pixel intensity by suppressing VIS information content from NIR information content. The method creates such enhanced NIR reflectogram by extrapolating VIS reflectogram to a reflectogram recorded in NIR range and by subtracting it from the measured values in the near infrared spectral sub-band. As an extrapolator we suggest a feed forward artificial neural network (ANN). Significant results of improved visualization are exemplified on reflectograms acquired with a VIS-NIR $〈400,2250〉\text{nm}$ scanning device on real paintings such as Madonna dei Fusi attributed to Leonardo da Vinci. Parameters of the method, artificial neural network and separability of used pigments are discussed.     

On the correlation of indices of vegetation and surface temperature over south-eastern Australia

Abstract

Relationships between radiant surface temperature (T _R) and vegetation indices for scenes with equal areas of forest and agricultural land use were studied using a Landsat Thematic Mapper (TM) scene during spring and a NOAA-Advanced Very High Resolution Radiometer (AVHRR) scene during summer. The relationships between TR and the Normalized Difference (ND) index of vegetation for agricultural land use were different from those for forests. At the same T _R, the forests had lower near infrared reflectance. This caused the ND of forests to fall below the T _R/ND relationships formed by agricultural land use. This difference between forest and agricultural land use did not exist when visible reflectance (VIS) was used as the index of vegetation. When the two land use systems were combined VIS accounted for about 86 per cent of the variance in T _R. The slope of the relationships between VIS and T _R differed for TM and AVHRR scenes. This was explained by differences in the T _R and VIS reflectance of surfaces with near-zero evaporation. These surfaces were predominantly bare soil in the TM scene and senesced vegetation in the AVHRR scene.     

Nondestructive prediction model of internal hardness attribute of fig fruit using NIR spectroscopy and RF

Hardness is one of the most important quality characteristics, which has an important influence on the processing and product quality of figs. A rapid non-destructive detection method for the hardness of figs was proposed based on visible/near infrared (VIS/NIR) spectroscopy technology. This study attempts to optimize the construction of a fig hardness model and predict the accuracy of thereof. An NIR spectrometer was used to collect the diffuse reflectance spectrum data in the wavelength range of 950–1700 nm, while the hardness index was measured using texture analyzer. Random forest (RF) and partial least square (PLS) methods were used to model the spectral data and hardness, respectively, and a better algorithm for the model construction was obtained. The RF model performed better in the characteristic band (1150.83–1232.43 nm), with correlation coefficient (R²), root mean square error of calibration (RMSEC), and root mean square error of prediction (RMSEP) of 0.76, 67.61, and 83.94 respectively. The PLS model worked well at the full band (R²?=?0.77, RMSEC?=?59.20, RMSEP?=?91.84). However, the prediction time of the PLS was slightly shorter than that of RF model (0.0004 s?<?0.0098 s). The results show that it is feasible to detect the hardness of figs without destroying them by using VIS/NIR diffuse reflectance spectroscopy combined with sample set partitioning based on joint x–y distances (SPXY), RF, and PLS algorithms. This study provides new technical means for fig products enterprises to determine the hardness of figs in the early stages of production rapidly and evaluate the processing quality of fig products, which has a high practical application potential.

     

Comparison between in situ and MODIS-derived spectral reflectances of snow and sea ice in the Amundsen Sea,Antarctica

The spectral albedo and directional reflectance of snow and sea ice were measured on sea ice of various types, including nilas, grey ice, pancake ice, multi-year pack ice, and land-fast ice in the Ross, Amundsen and Bellingshausen seas during a summer cruise in February through March 2000. Measurements were made using a spectroradiometer that has 512 channels in the visible and near-infrared (VNIR) region in which 16 of the 36 bands of the Moderate Resolution Imaging Spectroradiometer (MODIS) are covered. Directional reflectance is also retrieved from the MODIS radiometrically calibrated data (Level 1B) concurrently acquired from the first National Aeronautics and Space Administration (NASA) Earth Observing System (EOS) satellite, Terra. The locations of the ground ice stations are identified accurately on the MODIS images, and the spectral albedo and directional reflectance values at the 16 VNIR MODIS bands are extracted for those pixel locations. MODIS-derived reflectance is then corrected for the intervening atmosphere whose parameters are retrieved from the MODIS atmospheric profiles product (MOD07_L2) for the same granule. The corresponding spectral albedo and directional reflectance with the same viewing geometry as MODIS are derived from our ground-based spectroradiometer measurements. Because the footprint of the ground spectroradiometer is much smaller than the pixel sizes of MODIS images, the averaged spectral reflectance and albedo in the vicinity of each ice station are simulated for the corresponding MODIS pixel from the ground spectral measurements by weighting over different surface types (various ice types and open water). An accurate determination of ice concentration is important in deriving ground reflectance of a simulated pixel from in situ measurements. The best agreement between the in situ and MODIS measurements was found when the ground had 10/10 ice concentration (discrepancy range 0.2–11.69%, average 4.8%) or was oneice-type dominant (discrepancy range 0.8–16.9%, average 6.2%). The more homogeneous the ground surface and the less variable the ground topography, the more comparable between the in situ and satellite-derived reflectance is expected.     

Quantifying arsenic-induced morphological changes in spinach leaves: implications for remote sensing

Arsenic (As) is a common soil contaminant that can be accumulated into plant parts. The ability to detect As in contaminated plants is an important tool to minimize As-induced health risks in humans. Near-infrared (NIR) spectra are strongly affected by leaf structural characteristics. Therefore, quantitative analyses of structural changes in the arrangement of mesophyll cells caused by As will help to explain spectral responses to As. The objectives of this study were to use stereological methods to quantify internal structural changes in leaves with As treatment in spinach plants, and to relate these changes to leaf spectral properties in NIR spectra. Hydroponically grown spinach was treated with 0, 5, 10 and 20 μmol l^?1 for four weeks in a growth chamber. Spectral properties of leaves were obtained for visible and infrared frequencies. Leaf structural properties, such as mesophyll thickness and mesophyll surface area, were measured using stereological methods. Quantitative analysis of leaf structure showed that total leaf thickness and intercellular spaces in spongy mesophyll cells decreased with increasing As treatment. Changes in leaf reflectance in NIR wavelengths were strongly correlated with leaf As concentration and leaf structural changes. Multiple linear regression of leaf reflectance values at the highest correlated wavelengths (1048, 1098 and 1080 nm) generated an R ² value of 0.69. Results from this study support the hypothesis that relationships between leaf structure and reflectance may be useful in the interpretation of spectral data to detect plant leaf As concentration.     

The assessment of leaf water content using leaf reflectance ratios in the visible,near‐, and short‐wave‐infrared

The common features of spectral reflectance from vegetation foliage upon leaf dehydration are decreasing water absorption troughs in the near‐infrared (NIR) and short‐wave‐infrared (SWIR). We studied which leaf water index in the NIR and SWIR is most suitable for the assessment of leaf water content and the detection of leaf dehydration from the laboratory standpoint. We also examined the influence of the thickness of leaves upon leaf water indices. All leaf water content indices examined exhibited basic correlations with the relative water content (RWC) of leaves, while the R ₁₃₀₀/R ₁₄₅₀ leaf water index also demonstrated a high signal strength and low variability (R ²>0.94). All examined leaf reflectance ratios could also be correlated with leaf thickness. The thickness of leaves, however, was not independent of leaf RWC but appeared to decrease substantially as a result of leaf dehydration.     

Foliar spectral properties following leaf clipping and implications for handling techniques

After leaves are clipped their reflectance properties change over time at variable rates. Spectral change can in part be attributed to the changing water content of the leaf, which affects absorption in the VIS, NIR and the SWIR. Maintaining water volume within samples has been the motivation behind many leaf handling techniques. This study has assessed the time constraints between leaf collection and spectral measurement. Specifically the relationship between leaf water content and foliar spectra (350-2500 nm) was examined over time for five tropical trees (common guava (Psidium guajava), purple guava (Psidium littorale), weeping fig (Ficus benjamina), floss silk (Chorisia speciosa), and coffee (Coffea arabica)). This investigation was carried for leaves wrapped with moist gauze around their petiole (treatment leaves) and leaves with no treatment. Spectral measurements and mass measurements were repeated for each leaf once every hour for the first 12 h, then every 4-6 h for 18 h, followed by one measurement after 12 h, and finally once a day until the control samples became air-dry. Foliar reflectance in the visible spectrum was not immediately responsive to water content changes and did not change until wilting of the leaf was observed. The NIR and SWIR wavelength regions were affected immediately by small changes in water content. Thus, by the time wilting was first observed the NIR and SWIR foliar reflectance differed considerably from corresponding fresh leaf reflectance. No common time limit could be observed for leaf clipping and reflectance measurement. Leaves have a variety of water contents and dehydration rates hence measurement time constraints are dependent on the properties of the leaf or species. Rather than using a time limit it is recommended that leaf handling techniques be based upon managing leaf water content and leaf structure. The results of this study indicate that leaves with petioles wrapped in moist paper towel and placed within plastic bags will maintain leaf reflectance longer than equivalent leaves without treatment; samples tested here lasted a minimum of 7 days. θ and D indices (“angle difference” and “root mean square difference”, respectively) revealed a stronger relationship between leaf water content and spectral shape than between leaf water and raw reflectance magnitude. The ratio of 1187/1096 nm, when compared with θ and D indices and individual reflectance bands, showed the highest coefficient of determination with leaf water content (r² = 0.952).     

Estimation of LAI and FAPAR by constraining the leaf and soil spectral characteristics in a radiative transfer model

We evaluated the estimation of the leaf area index (LAI) and the fraction of absorbed photosynthetically active radiation (FAPAR) of green plant canopies from top-of-the-canopy (TOC) spectral indices by using the PROSAIL model under the possible constraints of leaf and soil spectra. For the LAI estimation, the ratios (B1 – B3)/(B1?+?B3) and B1/B3 provided fewer estimation errors than (B4 – B3)/(B4?+?B3) or B4/B3 when the variation in the soil spectral reflectance was small or LAI was large. Here, B1, B3 and B4 denote the blue, red and near-infrared bands of Landsat ETM+, respectively. For the FAPAR estimation, the ratios (B5 – B7)/(B5?+?B7) and B5/B7 provided fewer estimation errors than (NIR – R)/(NIR?+?R) or NIR/R for a FAPAR value of 0.3–0.7 when the variation in the soil spectral reflectance was large. Here, B5 and B7 denote the bands with wavelengths 1.55–1.75 and 2.09–2.35 μm, respectively. These were maintained for various conditions of the solar incident zenith angle (θ_s), leaf angle distribution (LAD), canopy hotspot parameter (s ₁) and clumping index (Ω).     

Assessing the potential of SeaWiFS and MODIS for estimating chlorophyll concentration in turbid productive waters using red and near-infrared bands

Bio-optical algorithms for remote estimation of chlorophyll-a concentration (Chl) in case-1 waters exploit the upwelling radiation in the blue and green spectral regions. In turbid productive waters other constituents, that vary independently of Chl, absorb and scatter light in these spectral regions. As a consequence, the accurate estimation of Chl in turbid productive waters has so far not been feasible from satellite sensors. The main purpose of this study was to evaluate the extent to which near-infrared (NIR) to red reflectance ratios could be applied to the Sea Wide Field-of-View Sensor (SeaWiFS) and the Moderate Imaging Spectrometer (MODIS) to estimate Chl in productive turbid waters. To achieve this objective, remote-sensing reflectance spectra and relevant water constituents were collected in 251 stations over lakes and reservoirs with a wide variability in optical parameters (i.e. 4 ≤ Chl ≤ 240 mg m^− 3; 18 ≤ Secchi disk depth ≤ 308 cm). SeaWiFS and MODIS NIR and red reflectances were simulated by using the in-situ hyperspectral data. The proposed algorithms predicted Chl with a relative random uncertainty of approximately 28% (average bias between − 1% and − 4%). The effects of reflectance uncertainties on the predicted Chl were also analyzed. It was found that, for realistic ranges of R_rs uncertainties, Chl could be estimated with a precision better than 40% and an accuracy better than ± 35%. These findings imply that, provided that an atmospheric correction scheme specific for the red-NIR spectral region is available, the extensive database of SeaWiFS and MODIS images could be used to quantitatively monitor Chl in turbid productive waters.     

Detection of stressed oil palms from an airborne sensor using optimized spectral indices

Existing vegetation indices and red-edge techniques have been widely used for the assessment of vegetation status and vegetation health from remote-sensing instruments. This study proposed and applied optimized Airborne Imaging Spectrometer for Applications (AISA) airborne hyperspectral indices in assessing and mapping stressed oil palm trees. Six vegetation indices, four red-edge techniques, a standard supervised classifier and three optimized AISA spectral indices were compared in mapping diseased oil palms using AISA airborne hyperspectral imagery. The optimized AISA spectral indices algorithms used newly defined reflectance values at wavelength locations of 734 nm (near-infrared (NIR)) and 616 nm (red). The selection of these two bands was based on laboratory statistical analysis using field spectroradiometer reflectance data. These two bands were then applied to the AISA airborne hyperspectral imagery using the three optimized algorithms for AISA data. The newly formulated AISA hyperspectral indices were D2 = R ₆₁₆/R ₇₃₄, normalized difference vegetation index a (NDVIa)?=?(R ₇₃₄ – R ₆₁₆)/(R ₇₃₄?+?R ₆₁₆) and transformed vegetation index a (TVIa)?=?((NDVIa?+?0.5)/(abs (NDVIa?+?0.5))?×?[abs (NDVIa?+?0.5)]^1/2. The classification results from the optimized AISA hyperspectral indices were compared with the other techniques and the optimized AISA spectral indices obtained the highest overall accuracy. D2 and NDVIa obtained 86% of overall accuracy followed by TVIa with 84% of overall accuracy.     

An integrated approach to a biophysiologically based classification of floating aquatic macrophytes

Globally, invasive species are identified as one of the most serious threats to ecological stability and biodiversity. Water hyacinth (Eichhornia crassipes), an aggressive invasive aquatic species, has caused severe economic and ecological impacts in the Sacramento-San Joaquin River Delta in California. In the Delta, water hyacinth co-occurs with native pennywort (Hydrocotyle umbellata L.) and non-native water primrose (Ludwigia spp.). All of the species express a wide range of phenotypic variability, making it difficult to map them with remote sensing techniques because their spectral response is highly variable. We present an integrated approach to mapping these floating species using a sequence of hyperspectral methods, such as spectral angle mapper (SAM), linear spectral unmixing (LSU), continuum removal and several indices in a decision tree format. The ensuing tree, based on biophysiological differences between the species, was robust and consistent across three separate years and over multiple flightlines each year, spread across an area of approximately 2500 km². The most important inputs used to create the tree were reflectance in the short-wave infrared (SWIR), Red Edge Index, near-infrared (NIR) reflectance, LSU fractions and SAM rule values. The floating species were mapped with average accuracy of 88% for water hyacinth, 87% for pennywort and 71% for water primrose.     

A Review of: “Environmental Information Management and Analysis: Ecosystem 10 global scales”. Edited by W. K. MICHENER,J. W. BRUNT and S. G. STAFFORD (London: Taylor &: Francis Ltd, 1994). [Pp. 535.] Price £55,00.

Abstract

Satellite indices of vegetation from the Australian continent were calculated from May 1986 to April 1987 from NOAA-9 AVHRR (Advanced Very High Resolution Radiometer) and Nimbus-7 SMMR (Scanning Multichannel Microwave Radiometer) satellite data. The visible (VIS) and near infrared (N1R) reflectances and their combination, the Normalized Difference (ND) Vegetation Index were calculated from the AVHRR sensor. From the SMMR, the microwave Polarization Difference (PD) was calculated as the difference between the vertically and horizontally polarized brightness temperatures at 37 GHz. The AVHRR data were gridded to match the 25 km spatial resolution of the SMMR 37 GHz data and both data sets were analysed to provide a temporal resolution of one month. Using a one month lag, the ND, PD, VIS and NIR, indices were plotted against rainfall and water balance estimates of evaporation, calculated using the monthly rainfall data and long term averages of pan evaporation from 74 locations covering a range of vegetation types. The monthly plots had wide scatter. This scatter was reduced markedly by aggregating the data over twelve months, leading to the conclusion that direct satellite monitoring of annual evaporation across the Australian continent using PD or VIS is feasible for areas with evaporation less than 600 mm y^?1. The ND relationship was limited by scatter and the PD and VIS relationships by their saturation above 600 mm y^?1, which spanned about two-thirds of the continental range studied. Scatter was reduced and ND had a predictive range above 600 mm y^?1 if evaporation was normalized by evaporative demand. But prior knowledge of potential evaporation is needed in this approach. The NIR reflectance of forests were consistently lower than neighbouring areas of agriculture, thus ND may underpredict the evaporation of forests relative to agriculture. Temporal resolution of the satellite indices over periods of one month could not be evaluated due to spatial and temporal variability of climatic and biological factors not accounted for in the water balance estimates of evaporation.     

Using hyperspectral data to quantify water-quality parameters in the Wabash River and its tributaries,Indiana

A hand-held spectrometer was used to collect above-water spectral measurements for measuring optically active water-quality characteristics of the Wabash River and its tributaries in Indiana. Water sampling was undertaken concurrent with spectral measurements to estimate concentrations of chlorophyll (chl) and total suspended solids (TSS). A method for removing sky and Sun glint from field spectra for turbid inland waters was developed and tested. Empirical models were then developed using the corrected field spectra and in situ chl and TSS data. A subset of the field measurements was used for model development and the rest for model validation. Spectral characteristics indicative of waters dominated by different inherent optical properties (IOPs) were identified and used as the basis of selecting bands for empirical model development. It was found that the ratio of the reflectance peak at the red edge (704 nm) with the local minimum caused by chl absorption at 677 nm was a strong predictor of chl concentrations (coefficient of determination (R²) = 0.95). The reflectance peak at 704 nm was also a good predictor for TSS estimation (R² = 0.75). In addition, we also found that reflectance within the near-infrared (NIR) wavelengths (700–890 nm) all showed a strong correlation (0.85–0.91) with TSS concentrations and generated robust models. Results suggest that hyperspectral information provided by field spectrometer can be used to distinguish and quantify water-quality parameters under complex IOP conditions.     

Detection of leaf and canopy EWT by calculating REWT from reflectance spectra

The spectral characteristics of and the interaction between leaves and light were analysed based on the optical absorption coefficients of foliar water and biochemical components. The equations for calculating the radiative-equivalent water thickness (REWT) of leaves and canopy were presented based on the difference in reflectance at 945 and 975 nm. Because of the direct reflection on leaf surface and the leaf internal scattering, the REWT derived from the Beer–Lambert principle was different from the leaf or canopy equivalent water thickness (EWT). Two independent datasets at canopy or leaf scales were designed to calibrate and validate the relationships between EWT and REWT. The results show that (1) the leaf or canopy REWT can be calculated from the reflectance difference between 945 and 975 nm; (2) the leaf REWT was 3.3 times larger than the EWT with a significant determination coefficient (R ²) of 0.80 for our dataset and 0.86 for the Leaf Optical Properties Experiment (LOPEX'93) dataset; (3) the canopy REWT was 1.4 times larger than the EWT with a significant R ² of 0.56 for the winter wheat canopy spectral dataset in 2002, and 0.61 for the 2004 dataset. Therefore, the leaf or canopy EWT can be detected by calculating REWT from the difference in reflectance at 945 and 975 nm. Furthermore, because the relationship between REWT and EWT reflected the interaction of light with leaves or canopy, the multiple scattering optical pathlength in the near-infrared (NIR) bands can also be calculated by the ratio of REWT to EWT.     

Detecting near-surface moisture stress in Sphagnum spp.

Estimating near-surface moisture conditions from the reflectance spectra (400-2500 nm) of Sphagnum moss offers great opportunities for the use of remote sensing as a tool for large-scale detailed monitoring of near-surface peatland hydrological conditions. This article investigates the effects of changes in near-surface and surface moisture upon the spectral characteristics of Sphagnum moss. Laboratory-based canopy reflectance data were collected from two common species of Sphagnum subjected to drying and subsequent rewetting. Several spectral indices developed from the near infra-red (NIR) and shortwave infra-red (SWIR) liquid water absorption bands and two biophysical indices (REIP and the chlorophyll index) were correlated with measures of near-surface moisture. All spectral indices tested were significantly correlated with near-surface moisture (with r between 0.27 and 0.94). The strongest correlations were observed using indices developed from the NIR liquid water absorption features (fWBI₉₈₀ and fWBI₁₂₀₀). However, a hysteretic response was observed in both NIR indices when the canopies were re-hydrated, a finding which may have implications for the timing of remote sensing image acquisition. The Moisture Stress Index (MSI), developed from the SWIR liquid water absorption feature also showed strong correlations with near-surface wetness although the range of moisture conditions over which the index was able to detect change was highly dependent on Sphagnum species. Of the biophysical spectral indices tested (REIP and the chlorophyll index), the most significant relationships were observed between the chlorophyll index and near-surface wetness. All spectral indices tested were species specific, and this is attributed to differences in canopy morphology between Sphagnum species. The potential for developing estimations of surface and near-surface hydrological conditions across northern peatlands using remote sensing technology is discussed.