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通过3,3′,4,4′-二苯醚四甲酸二酐(ODPA)和六氟二酐(6FDA)分别与11-氨基十一烷酸反应,合成了两种酰亚胺二酸单体,再用合成的酰亚胺二酸单体按照不同配比和对苯二胺反应合成了6FDA物质的量分数(在两种酰亚胺二酸单体中)分别为10%和25%的含氟共聚酰胺酰亚胺(PAI–F10和PAI–F25),同时按照相同工艺合成了不含6FDA的共聚酰胺酰亚胺(PAI–F0)。利用差示扫描量热仪测试了这3种聚合物的非等温结晶过程及其熔融行为,发现PAI–F10的结晶能力最强,其次为PAI–F0,PAI–F25的结晶现象不明显。采用Jeziorny法和Mo法分析了PAI–F0和PAI–F10的非等温结晶动力学,发现在较低降温速率下,PAI–F10生成晶体的能力更强,结晶度更高。进一步利用Kissinger方程求得PAI–F0和PAI–F10结晶活化能,发现PAI–F10具有更低的结晶活化能。以上研究结果表明含氟基团在低含量时可以促进聚酰胺酰亚胺的结晶能力,而在高含量时却抑制了聚酰胺酰亚胺的结晶。 相似文献
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光学纯的氨基酸在制药工业和农业化学方面有着广泛的应用。主要介绍了抽提法和生物转化法生产氨基酸的研究进展以及几种重要氨基酸的合成方法。 相似文献
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含氟聚酰胺酰亚胺自粘电磁线漆的合成与性能研究 总被引:2,自引:0,他引:2
合成了一种新型含氟二胺单体2-三氟甲基-4,4'-二氨基二苯醚(3FODA),该单体具有较高的反应活性和溶解性。使用3FODA替代4,4'-二胺基二苯醚(ODA),与偏苯三酸酐(TMA)、二甲苯甲烷二异氰酸酯(MDI)通过两步法合成了含氟聚酰胺酰亚胺自粘电磁线漆。试验证明,含氟基团三氟甲基的引入明显提高了漆膜的柔韧性和附着力。 相似文献
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本文用偏苯三酸酐4—胺氯与4,4′—二氨基二苯醚,通过溶液缩合聚合反应,先合成聚酰胺酸,再经过热处理而得聚酰胺酰亚胺。并用红外光谱法、元素分析、热分析等方法,比较了聚酰胺酸和聚酰胺酰亚胺的组成、结构和性能。 相似文献
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张亨 《化学推进剂与高分子材料》2014,(3):18-24
介绍了一种重要的含氟精细化工产品和医药中间体4,4′–二氟二苯甲酮的理化性质、光谱性质及应用。综述了4,4′–二氟二苯甲酮国内外的合成研究情况,其合成方法主要包括Fridel–Crafts烷基化水解法、Fridel–Crafts酰基化法、卤素置换法、重氮化氧化法、催化羰基化法、4,4′–二氟二苯二氯乙烯氧化法、4,4′–二氟二苯甲烷氧化法等。 相似文献
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Shadpour Mallakpour Seyede Elmira Moosavi 《Polymer-Plastics Technology and Engineering》2015,54(14):1448-1456
The objective of this article was fabrication and characterization of novel optically active poly(amide-imide)/zinc oxide nanocomposites with different modified ZnO nanoparticle contents under ultrasonic irradiation technique. For better dispersion of ZnO nanoparticles in a polymer matrix, their surface was modified with poly(vinyl alcohol) as a coupling agent. Effects of poly(vinyl alcohol) modifier on dispersity of nanoparticles, morphological structures, and thermal stability of the obtained nanoparticles were studied by several techniques. According to the transmission electron microscopy images of the nanocomposite, the average diameter of particles was around 7–15 nm in the poly(amide-imide). 相似文献
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Summary Thermally stable and optically active poly(amide-imide)s (PAIs) have been synthesized and their properties such as optical activity, solubility, thermal stability were studied. Polymers
were synthesized by solution polymerization of 4,4’–(hexafluoroisopropylidene)-N,N’-bis-(phthaloyl-L-methionine) diacid chloride and various aromatic diamines by three different methods. The compounds obtained
were characterized by elemental C, H and N analysis, solubility, FTIR, 1H NMR and 19F NMR spectroscopy. Thermogravimetric curves were also recorded. All data agree with the proposed structures. 相似文献
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Hsun-Lien Lin Huey-Ling Chang Tzong-Yuan Juang Rong-Ho Lee Shenghong A. Dai Ying-Ling Liu Ru-Jong Jeng 《Dyes and Pigments》2009,82(1):76-83
Poly(N-acylurea)–clay nanocomposites consisting of a modified montmorillonite and poly(N-acylurea) were prepared from which poly(amide-imide)–clay nanocomposites were subsequently obtained via the sequential self-repetitive reaction of poly(N-acylurea). The moderate Tg of poly(N-acylurea) allows the nonlinear optically active polymer to exhibit high poling efficiency; in situ poling and curing increased the Tgs of poly(amide-imide)–clay nanocomposites. Electro-optical coefficients, r33 of ~17–20 pm/V (830 nm), were achieved; high temporal stability (120 °C) and waveguide optical losses of 3.4–3.9 dB/cm at 1310 nm were also obtained for poly(amide-imide)–clay nanocomposites. 相似文献
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Hong Xue Yong‐An Xu Nai‐Heng Song Lian‐Xun Gao Meng‐Xian Ding 《Polymer International》2003,52(8):1321-1325
Optically active and racemic poly(meth)acrylates with pendant 1,1′‐binaphthalene moiety of 2‐methacryloyloxy‐ and 2‐acryloyloxy‐2′‐methoxy‐1,1′‐binaphthalene (MAMBN and AMBN) were synthesized by anionic, group transfer and free radical polymerization methods. Their polymerizability and chiroptical properties are somewhat different, depending on the three types of polymerization methods used. The yields for poly(MAMBN)s are lower than for poly(AMBN)s. The optical rotation of the optically active polymers is identical to that of the corresponding monomers. The values of specific rotation of optically active poly(AMBN)s are much larger than those of optically active poly(MAMBN)s. © 2002 Society of Chemical Industry 相似文献
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Summary The present paper is an extension of microwave method describing the synthesis of the new optically active poly(amide-imide)s. The main focus of this work is the design of new effective microwave method for preparing optically active poly(amide-imide)s. Imide-acid (3) was synthesized by the reaction of 3,3,4,4-diphenylsulfonetetracarboxylic dianhydride (1) with (s)-(+)-valine (2) in acetic acid. The compound 3 was coverted to diacid chloride 4 by reaction with excess amount of thionyl chloride. Polycondensetion reaction of diacid chloride 4 with several aromatic diamines such as 4,4-sulfonyldianiline (5a), 4,4-diaminodiphenyl methane (5b), 4,4-diaminodiphenylether (5c), p-phenylenediamine (5d), m-phenylenediamine (5e), 2,4-diaminotoluene (5f) and 4,4-diaminobiphenyl (5g) was carried out in the presence of small amount of o-cresol under microwave irradiation as well as conventional heating method. We obtained a series of optically active poly(amide-imide)s with high yield and inherent viscosity ranging from 0.22-0.35 dL/g. These new polymers were characterized by FT IR, 1H NMR, elemental analyses and specific rotation techniques. 相似文献
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Six new optically active poly(amide-imide)s were synthesized by poly condensation reaction of 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole
(8) with six chiral N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic)-bis-l-amino acids (3a–f) in a medium consisting of N-methyl-2-pyrrolidone (NMP), triphenylphosphite (TPP), calcium chloride (CaCl2), and pyridine. Chiral N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic)-bis-l-amino acids (3a–f) were obtained by the reaction of bicyclo[2.2.2]-oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (1) with two equimolar of l-alanine (2a), l-valine (2b), l-leucine (2c), l-isoleucine (2d), l-phenyl alanine (2e), and l-2-aminobutyric acid (2f) in acetic acid. The poly condensation reaction produced a series of novel poly(amide-imide)s (9a–f) in high yield and with inherent viscosities between 0.30 and 0.52 dL/g. The resulting polymers were characterized by elemental
analysis, viscosity measurement, solubility testing, thermo-gravimetric analysis (TGA), 1H-NMR, and FT-IR techniques. 相似文献
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Shadpour Mallakpour Mohammad Dinari 《Polymer-Plastics Technology and Engineering》2015,54(14):1439-1447
Hybrid of acid functionalized multiwalled carbon nanotubes and layered double hydroxides were prepared by coprecipitation reaction of the Al(NO3)3·9H2O, Mg(NO3)2·6H2O, and acid functionalized multiwalled carbon nanotubes under ultrasonic irradiation. An optically active amino acid containing poly(amide-imide) was synthesized by the direct polycondensation reaction of the N,N′-(pyromellitoyl)-bis-L-isoleucine diacid and diamine using molten tetra-n-butylammonium bromide. These three-dimensional nanofillers were used as reinforcing agent to enhance the performance of chiral poly(amide-imide). The structure and morphology of the hybrid materials were confirmed by Fourier transformed infrared spectroscopy, X-ray diffraction, field emission and transmission electron microscopy, and thermogravimetry analysis techniques. 相似文献
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Mohammad Ali Takassi Amin Zadehnazari 《Polymer-Plastics Technology and Engineering》2017,56(12):1358-1365
A new salicylic acid-containing diacid monomer was synthesized by an established synthetic procedure from readily available reagents. The obtained diacid was used in the preparation of a thermally stable poly(amide-imide) by direct polycondensation with 4,4′-diphenylmethanediamine using 1,3-diisopropylimidazolium bromide ionic liquid as a green medium. The prepared polymer was used as matrix for preparation of multiwalled carbon nanotube/poly(amide-imide) composites in three multiwalled carbon nanotube concentrations (5, 10, and 15?wt%). The products were characterized for assessing the spectroscopic, thermal, and morphological properties by several methods. A homogeneous dispersion of multiwalled carbon nanotubes in the poly(amide-imide) matrix was observed by microscopy techniques. 相似文献
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Summary In this research work, 4,4-oxydiphthalic anhydride (1) was reacted with L-phenylalanine (2) in acetic acid and the resulting imide-acid 3 was obtained in high yield. This imide-acid 3 was converted to diacid chloride 4 by reaction with thionyl chloride. The polycondensation reaction of diacid chloride 4 with several aromatic diamines such as 4,4-sulfonyldianiline (5a), 4,4-diaminodiphenyl methane (5b), 4,4-diaminodiphenylether (5c), p-phenylenediamine (5d), m-phenylenediamine (5e), and 4,4-diaminobiphenyl (5f) was performed by two conventional methods: low temperature solution polycondensation and short period reflux conditions. Several new thermally stable optically active poly(amide-imide)s with inherent viscosity ranging from 0.34–0.62 dL/g were obtained with high yield. All of the above polymers were fully characterized by 1H-NMR, FT-IR, elemental analyses and specific rotation techniques. Some structural characterizations and physical properties of this new optically active poly (amide-imide)s are reported. 相似文献
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Shadpour Mallakpour Mohammad Dinari 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(5):929-937
This work concerns the preparation of novel optically active nanocomposite materials derived from Cloisite Na+ clay, which has been functionalized by protonated l-methionine amino acid as a swelling agent for sufficient compatibilization with the poly(amide-imide) (PAI) matrix. The polymer chains were formed from the polycondensation reaction of N,N′-(pyromellitoyl)-bis-phenylalanine diacid chloride with 4,4′-diaminodiphenylether. Interaction between the two phases was established by modifying the PAI chains with amine end groups and free acid groups of the organoclay (OC). The effect of OC dispersion and the interaction between OC and PAI chains on the properties of resulting bionanocomposite material was studied using Fourier transform infrared spectroscopy, X-ray diffraction (XRD), transmission electron microscopy, field emission scanning electron microscopy and thermogravimetric analysis techniques. The XRD pattern and morphological investigation revealed the formation of intercalated and exfoliated OC platelets in the matrix. Because of the existence of naturally occurring amino acids as biological chiral resources, it is predictable that these materials may be potentially biodegradable and biocompatible. 相似文献