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1.
In the present study, microstructure and creep behavior of an Al–1.9%Ni–1.6%Mn–1%Mg alloy were studied at temperature ranging from 493 to 513 K and under stresses between 420 and 530 MPa. The creep test was carried out by impression creep technique in which a flat ended cylindrical indenter was impressed on the specimens. The results showed that microstructure of the alloy is composed of primary α(Al) phase covered by a mantle of α(Al)+Ni3Al intermetallic compound. Mn segregated into AlxMnyNiz or Al6Mn phases distributed inside the matrix phase. It was found that the stress exponent, n, decreases from 5.2 to 3.6 with increasing temperature. Creep activation energies between 115 kJ/mol and 151 kJ/mol were estimated for the alloy and it decreases with rising stress. According to the stress exponent and creep activation energies, the lattice and pipe diffusion- climb controlled dislocation creep were the dominant creep mechanism.  相似文献   

2.
Creep behavior of a cast MRI153 magnesium alloy was investigated using impression creep technique. The tests were carried out under constant punching stress in the range of 360–600 MPa at temperatures between 425 and 490 K. Microstructure of the alloy was composed of α(Mg) matrix phase besides Mg17Al12 and Al2Ca intermetallic compounds. Stress exponent of minimum creep rate, n, was found to vary between 6.45 and 7. Calculation of the activation energy showed a slight decrease with increasing stress such that the creep activation energy of 115.2 kJ/mol under σimp/G = 0.030 decreased to 99.5 kJ/mol under σimp/G = 0.040. The obtained stress exponent and activation energy data suggested that the pipe diffusion dislocation climb controlled creep as the dominant mechanism during the creep test.  相似文献   

3.
The work presented in this study was carried out on Al–Si–Cu–Mg 319-type alloys to investigate the role of solution heat treatment on the dissolution of copper-containing phases (CuAl2 and Al5Mg8Cu2Si6) in 319-type alloys containing different Mg levels, to determine the optimum solution heat treatment with respect to the occurrence of incipient melting, in relation to the alloy properties. Two series of alloys were investigated: a series of experimental Al–7 wt% Si–3.5 wt% Cu alloys containing 0, 0.3, and 0.6 wt% Mg levels. The second series was based on industrial B319 alloy. The present results show that optimum combination of Mg and Sr in this study is 0.3 wt% Mg with 150 ppm Sr, viz. for the Y4S alloy. The corresponding tensile properties in the as-cast condition are 260 MPa (YS), 326 MPa (UTS), and 1.50% (%El), compared to 145 MPa (YS), 232 MPa (UTS), and 2.4% (%El) for the base alloy with no Mg. At 520 °C solution temperature, incipient melting of Al5Mg8Cu2Si6 phase and undissolved block-like Al2Cu takes place. At the same time, the Si particles become rounder. Therefore, the tensile properties of Mg-containing alloys are controlled by the combined effects of dissolution of Al2Cu, incipient melting of Al5Mg8Cu2Si6 phase and Al2Cu phase, as well as the Si particle characteristics.  相似文献   

4.
Permanent mold (PM) and high pressure die cast (HPDC) AlMg5Si2Mn are employed to investigate the microstructure, fatigue strength and corrosion resistance. Results indicated that the mechanical properties (Rm, R0.2 and δ) of HPDC specimens (314 MPa, 189 MPa and 7.3%) are significantly better than those of PM specimens (160 MPa, 111 MPa and 2.5%) due to the finer grain size and less cast defects. Fatigue cracks of PM samples dominantly initiated from shrinkage pores and obscure fatigue striations are observed in crack growth region. Corrosion and pitting potentials of PM and HPDC AlMg5Si2Mn alloy are around −1250 mV, −760 mV and −1220 mV, −690 mV respectively. Numerous pits are observed around the grain boundaries because the corrosion potential of Mg2Si is more anodic than that of α-Al matrix. In addition, the superior corrosion resistance of HPDC samples can be attributed to the fine grain size and the high boundary density which improved the formation of oxide layer on the surface and prevented further corrosion.  相似文献   

5.
Structure and mechanical properties of the novel casting AJ62 (Mg–6Al–2Sr) alloy developed for elevated temperature applications were studied. The AJ62 alloy was compared to commercial casting AZ91 (Mg–9Al–1Zn) and WE43 (Mg–4Y–3RE) alloys. The structure was examined by scanning electron microscopy, x-ray diffraction and energy dispersive spectrometry. Mechanical properties were characterized by Viskers hardness measurements in the as-cast state and after a long-term heat treatment at 250 °C/150 hours. Compressive mechanical tests were also carried out both at room and elevated temperatures. Compressive creep tests were conducted at a temperature of 250 °C and compressive stresses of 60, 100 and 140 MPa. The structure of the AJ62 alloy consisted of primary α-Mg dendrites and interdendritic nework of the Al4Sr and massive Al3Mg13Sr phases. By increasing the cooling rate during solidification from 10 and 120 K/s the average dendrite arm thickness decreased from 18 to 5 μm and the total volume fraction of the interdendritic phases from 20% to 30%. Both factors slightly increased hardness and compressive strength. The room temperature compressive strength and hardness of the alloy solidified at 30 K/s were 298 MPa and 50 HV 5, i.e. similar to those of the as-cast WE43 alloy and lower than those of the AZ91 alloy. At 250 °C the compressive strength of the AJ62 alloy decreased by 50 MPa, whereas those of the AZ91 and WE43 alloys by 100 and 20 MPa, respectively. The creep rate of the AJ62 alloy was higher than that of the WE43 alloy, but significantly lower in comparison with the AZ91 alloy. Different thermal stabilities of the alloys were discussed and related to structural changes during elevated temperature expositions.  相似文献   

6.
TLP diffusion bonding of two dissimilar aerospace alloys, Ti–6Al–4V and Al7075, was carried out at 500 °C using 22 μm thick Cu interlayers for various bonding times. Joint formation was attributed to the solid-state diffusion of Cu into the Ti alloy and Al7075 alloy followed by eutectic formation and isothermal solidification along the Cu/Al7075 interface. Examination of the joint region using SEM, EDS and XPS showed the formation of eutectic phases such as, ?(Al2Cu), T(Al2Mg3Zn3) and Al13Fe along grain boundaries within the Al7075 matrix. At the Cu/Ti alloy bond interface a solid-state bond formed resulting in a Cu3Ti2 phase formation along this interface. The joint region homogenized with increasing bonding time and gave the highest bond strength of 19.5 MPa after a bonding time of 30 min.  相似文献   

7.
《Materials Research Bulletin》2006,41(11):2102-2110
Tensile creep test at temperature <0.35 Tm was carried out to investigate the creep behavior in nanostructured Mg alloy with an average grain size of 45 nm consolidated from mechanically alloyed powders using power creep law. The stress exponent is found to be larger than one and with a threshold stress. The activation energy for the creep is measured to be 76 kJ mol−1 smaller than that for grain boundary diffusion in Mg. It is deduced that creep behavior is affected by the presence of impurities and nanovoids inherited from the processing history.  相似文献   

8.
Through texture and grain boundary control by continuous unidirectional solidification, the continuous columnar-grained polycrystalline Cu71.8Al17.8Mn10.4 shape memory alloys were prepared and possess a strong 〈0 0 1〉 texture along the solidification direction and straight low-energy grain boundary. The alloys show excellent superelasticity of 10.1% improved from 3% for ordinary polycrystalline counterpart and with a tiny residual strain of less than 0.3% after unloading. There are some reasons for the enhanced superelasticity: (1) The martensitic transformation of all grains with strong 〈0 0 1〉-oriented texture occur at the same time under the tensile loading, which can avoid the significant stress concentration problem and transformation strain incompatibility at the grain boundaries due to the high elastic anisotropy in ordinary polycrystalline alloy. (2) High phase transformation strain can be obtained along 〈0 0 1〉 grain orientation. (3) Straight low-energy grain boundary and the absence of grain boundary triple junctions of continuous columnar-grained polycrystals can significantly reduce the blockage of martensitic transformation at the grain boundaries. These results provide a reference to structure design of high-performance polycrystalline Cu-based shape memory alloys.  相似文献   

9.
The effects of 0.5, 1.0 and 2.0 wt.% Y additions on the microstructure and creep behavior of the as-cast AZ80 alloy were investigated by impression tests. The tests were performed at temperatures in the range 423–523 K, under punching stress in the range 150–650 MPa. At low temperatures up to 473 K, the AZ80 + 0.5Y alloy had the highest creep resistance among all materials tested, whereas with increasing temperature from 473 K to 523 K, the AZ80 + 1.0Y alloy had a better performance. This can be attributed to the fact that at low temperatures the presences of β-Mg17Al12 and Al2Y phases together with solid solution hardening effects of Al in the Mg matrix strengthen the AZ80 + 0.5Y alloy. At higher temperatures, AZ80 + 1.0Y with a higher volume fraction of the more thermally stable Al2Y and lower amounts of the less stable β-Mg17Al12 exhibits better creep behavior. The stress exponents and activation energies were almost the same for all alloy systems studied, 6.0–8.8 and 90–119 kJ/mol, respectively. The observed decreasing trend of creep-activation energy with stress suggests that two parallel mechanisms of lattice and pipe-diffusion-controlled dislocation climb are competing. Climb of dislocations with an additional particle strengthening effect controlled by dislocation pipe diffusion is dominant at high stresses, whereas climb of dislocations is the controlling mechanism at low stresses.  相似文献   

10.
The influences of stress and temperature on creep deformation behavior and the creep crack growth rates of the super α2 Ti3Al alloy were investigated with respect to its safe application at high temperatures. In a temperature range of 1033–1093 K at low applied stress levels, the stress exponent was equal to 1.5. At an intermediate stress range (10?3 < σ/E < 3 × 10?3), a stress exponent of 3.3 was observed. As the applied stress was increased, the stress exponent changed from 3.3 to 4.4. The high temperature crack growth rate of the Ti3Al alloy can be correlated with stress intensity factor K rather than C1 at 1033 K due to environmental embrittlement.  相似文献   

11.
The evolution of microstructure and mechanical properties of Al-0.4Cu-0.14Si-0.05Mg-0.2Fe (wt.%) alloys, micro-alloyed with Zr, Ti and Sc, were investigated. The addition of 0.2%Zr to base alloy accelerates the precipitation of Si-rich nano-phase in α-Al matrix, which plays an important role in improving the mechanical properties of an alloy. The tensile strength increases from 102 MPa for the base alloy to 113 MPa for the Zr-modified alloy. Adding 0.2%Zr + 0.2%Ti to base alloy effectively refines α-Al grain size and accelerates the precipitation of Si and Cu elements, leading to heavy segregation at grain boundary. By further adding 0.2%Sc to Zr + Ti modified alloy, the segregation of Si and Cu elements is suppressed and more Si and Cu precipitates appeared in α-Al matrix. Accompanied with the formation of coherent Al3Sc phase, the tensile strength increases from 108 MPa for the Zr + Ti modified alloy to 152 MPa for the Sc-modified alloy. Due to excellent thermal stability of Al3Sc phase, the Sc-modified alloy exhibits obvious precipitation hardening behavior at 350 °C, and the tensile strength increases to 203 MPa after holding at 350 °C for 200 h.  相似文献   

12.
Y and Nd are simultaneously added into Mg–5Li–3Al–2Zn alloy. It is found that there exist the phases of α-Mg, AlLi, Al11Nd3 and Al2Y in the alloys. When the contents of Y and Nd are 1.2% and 0.8%, respectively, the grain is the finest with an average size of 30 μm, and the tensile strength of the alloy reaches 231 MPa, the elongation reaches 16%. When the ratio of Y to Nd is 1.2:0.8, there is a synergistic strengthening effect.  相似文献   

13.
We developed new wrought Mg–2Sn–1Ca wt.% (TX21) and Mg–2Sn–1Ca–2Zn wt.% (TXZ212) alloys with high strength and ductility simultaneously, produced by conventional casting, homogenization and indirect extrusion. A partial dynamically recrystallized microstructure, with the micron-/nano-MgSnCa particles and G.P. zones dispersing, was obtained in TX21 alloy extruded at 260 °C (TX21-260). The TX21-260 alloy exhibited yield strength (YS) of 269 MPa, ultimate tensile strength (UTS) of 305 MPa, while those of the TX21 alloy extruded at 300 °C decreased to be 207 MPa and 230 MPa respectively. For TXZ212-260 alloy, on the other hand, MgSnCa, MgZnCa and MgZn2 phases were observed, and the average grain size increased to be ∼5 μm. The YS and UTS of TXZ212-260 alloy evolved to be 218 MPa and 285 MPa, and the elongation (EL) reached as high as 23%. The high strengths of TX21-260 alloy were expected due to the high number density of nano-MgSnCa phases, G.P. zones and ultra-fine grain size (∼0.8 μm). The high EL of 23% in TXZ212-260 alloy was consistent with the high work-hardening rate, which was attributed to the larger grain size, more high angular grain boundaries, presence of more nano-particles and the weaker texture.  相似文献   

14.
In this study, Al2O3 particles were employed to improve the microstructure of LM24 and therefore, to increase the yield strength and tensile strength of this kind of alloy. In situ Al2O3 particles were obtained by direct reaction between oxygen and Al melt at 750–800 °C. Microstructure examination shows that the size of in situ formed Al2O3 particles was about 1–2 μm, and interestingly, with addition of in situ Al2O3 particles, the coarse primary Si phase was disappeared completely. More important, the yield strength and the tensile strength of Al2O3/LM24 are increased by 52 MPa, 16 MPa than that of LM24 alloy with 0.1% Sb addition. The value of 181 MPa and 315 MPa is for yield strength and tensile strength of Al2O3/LM24 respectively. Besides, the yield strength and tensile strength are 180 MPa and 314 MPa respectively for Al2O3/LM24 alloy after remelting and casting. This verifies that the improvement of mechanical properties of such kind of material possesses stability and reliability.  相似文献   

15.
In this paper, we report a novel kind of eutectic Al–Si–Cu–Fe–Mn alloy with ultimate tensile strength up to 336 MPa and 144.3 MPa at room temperature and 300 °C, respectively. This kind of alloy was prepared by metal mold casting followed by T6 treatment. The microstructure is composed of eutectic and primary Si, α-Fe, Al2Cu and α-Al phases. Iron-rich phases, which were identified as BCC type of α-Fe (Al15(Fe,Mn)3Si2), exist in blocky and dendrite forms. Tiny blocky Al2Cu crystals disperse in α-Fe dendrites or at the grain boundaries of α-Al. During T6 treatment, Cu atoms aggregate from the super-saturation solid solution to form GP zones, θ″ or θ′. Further analysis found that the enhanced mechanical properties of the experimental alloy are mainly attributed to the formation of α-Fe and copper-rich phases.  相似文献   

16.
The structural stability and stress rupture properties of a Ni–Fe based alloy, considered as boiler materials in 700 °C advanced ultra-supercritical (A-USC) coal-fired power plants, was studied. Investigation on the structural stability of the existing alloy GH984 shows that the most important changes in the alloys are γʹ coarsening, the γʹ to η transformation and the coarsening and agglomeration of grain boundary M23C6 during thermal exposure. The stress rupture strength was found to be slightly lower than the requirement of 700 °C A-USC. The fracture mode of creep tested specimens was intergranular fracture. Detailed analysis revealed that η phase precipitation is sensitive to Ti/Al ratio and can be suppressed by decreasing Ti/Al ratio. The coarsening behavior of γʹ phase is related to Fe content. Adding B and P was suggested to stabilize M23C6 and increase grain boundary strength. Based on the research presented and analysis of the data, a modified alloy was developed through changes in composition. For the modified alloy, η phase is not observed and M23C6 is still blocky and discretely distributes along grain boundary after thermal exposure at 700 °C for 20,000 h. Moreover, the creep strength is comparable to the levels of Ni-based candidate alloys for 700 °C A-USC.  相似文献   

17.
A high strength Mg-5.1Zn-3.2Y-0.4Zr-0.4Ca(wt%) alloy containing W phase(Mg_3Y_2Zn_3) prepared by permanent mold direct-chill casting is indirectly extruded at 350?C and 400?C, respectively. The extruded alloys show bimodal grain structure consisting of fine dynamic recrystallized(DRXed) grains and unrecrystallized coarse regions containing fine W phase and β2' precipitates. The fragmented W phase particles induced by extrusion stimulate nucleation of DRXed grains, leading to the formation of fine DRXed grains, which are mainly distributed near the W particle bands along the extrusion direction. The alloy extruded at 350?C exhibits yield strength of 373 MPa, ultimate tensile strength of 403 MPa and elongation to failure of 5.1%. While the alloy extruded at 400?C shows lower yield strength of 332 MPa,ultimate tensile strength of 352 MPa and higher elongation to failure of 12%. The mechanical properties of the as-extruded alloys vary with the distribution and size of W phase. A higher fraction of DRXed grains is obtained due to the homogeneous distribution of micron-scale broken W phase particles in the alloy extruded at 400?C, which can lead to higher ductility. In addition, the nano-scale dynamic W phase precipitates distributed in the un DRXed regions are refined at lower extrusion temperature. The smaller size of nano-scale W phase precipitates leads to a higher fraction of un DRXed regions which contributes to higher strength of the alloy extruded at 350?C.  相似文献   

18.
Magnetic properties and microstructure of new Fe84−xNb2B14Cux nanocrystalline alloys were investigated. We found that the microstructure was refined and soft magnetic properties of this alloy system were enhanced with proper Cu addition and annealing conditions. It was also discovered that the mean grain size firstly increases, then decreases to a minimum, and finally increases again with increasing annealing temperature for Fe83Nb2B14Cu1 nanocrystalline alloy, and this phenomenon was interpreted by the grain growth mechanism. Moreover, after annealing at 813 K for 180 s, Fe83Nb2B14Cu1 nanocrystalline alloy shows a fine microstructure with mean grain size of 16 nm, and exhibits excellent soft magnetic properties, such as high saturation magnetic flux density (1.7 T), low coercivity (7 A/m) and high permeability (2.8 × 104). The result indicates that this alloy should have a promising application in the soft magnetic industry.  相似文献   

19.
Monotonic and cyclic tests were used to assess the influence of micro-additions of Ti, V and Zr on the deformation behavior of the Al–7Si–1Cu–0.5Mg (wt.%) alloy in as-cast and T6 heat treated conditions and to compare the results with alloys of similar chemistry described in the literature. The microstructure of the as-cast alloy consisted of α-Al, eutectic Si, and Cu, Mg and Fe based phases Al2.1Cu, Al8.5Si2.4Cu, Al7.2Si8.3Cu2Mg6.9 and Al14Si7.1FeMg3.3. In addition, the micro-size Zr–Ti–V-rich phases Al21.4Si4.1Ti3.5VZr3.9, Al6.7Si1.2TiZr1.8, Al2.8Si3.8V1.6Zr and Al5.1Si35.4Ti1.6Zr5.7Fe were present in the as-cast state. During solution treatment, Cu based phases were completely dissolved, while the eutectic silicon, Fe- and Zr–Ti–V-rich intermetallics experienced only partial dissolution. The monotonic test results showed that the T6 heat treated alloy achieved a tensile strength of 343 MPa and a compressive strength of 418 MPa. Also, the cyclic yield stress of the studied alloy in the T6 temper condition was higher than the monotonic value and reached 335 MPa. The fatigue life of the studied alloy was substantially longer than that of the reference alloy with the same base but lower additions of V, Zr and Ti, reported in the literature. The fractography revealed the tensile crack propagation through the eutectic Si and primary phases, exhibiting intergranular fracture along with some cleavage-like features of the plate-shape Zr–Ti–V-rich intermetallics with a presence of fatigue striations on the latter, indicating their ductile nature. It is believed that the intermetallic precipitates containing Zr, Ti and V improve the fatigue life of the studied alloy in the T6 condition.  相似文献   

20.
The correlation between the microstructure and mechanical behavior during tensile loading of Ti68.8Nb13.6Al6.5Cu6Ni5.1 and Ti71.8Nb14.1Al6.7Cu4Ni3.4 alloys was investigated. The present alloys were prepared by the non-equilibrium processing applying relatively high cooling rates. The microstructure consists of a dendritic bcc β-Ti solid solution and fine intermetallic precipitates in the interdendritic region. The volume fraction of the intermetallic phases decreases significantly with slightly decreasing the Cu and Ni content. Consequently, the fracture mechanism in tension changes from cleavage to shear. This in turn strongly enhances the ductility of the alloy and as a result Ti71.8Nb14.1Al6.7Cu4Ni3.4 demonstrates a significant tensile ductility of about 14% combined with the high yield strength of above 820 MPa already in the as-cast state. The results demonstrate that the control of precipitates can significantly enhance the ductility and yet maintaining the high strength and the low Young's modulus of these alloys. The achieved high bio performance (ratio of strength to Young's modulus) is comparable (or even superior) with that of the recently developed Ti-based biomedical alloys.  相似文献   

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