Solidification Behavior and the Evolution of Phase in Laser Rapid Forming of Graded Ti6Al4V-Rene88DT Alloy

The graded material of Ti6Al4V-Rene88DT superalloy, which has shown the potential to be applied in aeroengines, was fabricated from prealloyed metal powders using the technique of laser rapid forming (LRF). A compositional gradient, from 100 pct Ti6Al4V to Ti6Al4V-38 pct Rene88DT, was achieved within a thickness of laser deposit of 54 mm. The solidification behavior and the phase evolution of the compositionally graded material were studied. The results of the X-ray diffraction (XRD) analysis together with the metallographic study showed that a series of phase evolutions, α + β → α + β + Ti₂Ni → β + Ti₂Ni, along the compositional gradient have occurred. The hardness value of the graded material was measured along the compositional gradient, and the results were explained in terms of the various phases present. The condition for columnar-to-equiaxed transition observed in the graded material was explained, based on Hunt’s criterion. Finally, the morphology of β + Ti₂Ni anomalous eutectic is discussed.

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Determination of gibbs energy of formation of Ni-B-O system by electromotive force measurement using solid electrolyte

The standard Gibbs energies of formation of Ni₃B, Ni₂B, o-Ni₄B₃(Ni_0.586B_0.414), m-Ni₄B₃(Ni_0.564B_0.436), NiB, and Ni₃B₂O₆ of the Ni-B-O system have been determined by measuring electromotive forces of galvanic cells using a Y₂O₃-stabilized ZrO₂ solid oxide electrolyte. The results are as follows: