Properties of azo‐dye alignment layer on plastic substrates

Abstract— The alignment properties of the azo‐dye photo‐alignment material SD‐1/SDA‐2 on plastic substrates are investigated. Important liquid‐crystal cell parameters, such as azimuthal and polar anchoring energy, pretilt angle, voltage holding ratio, and the corresponding electro‐optical properties are presented. Excellent alignment with high anchoring energy can be achieved with a polarized UV dose less than 1.0 J/cm². A reflective six‐digit flexible passive‐matrix‐driven TN‐LCD for smart‐card applications showing excellent electro‐optical properties is demonstrated.     

New properties and applications of rewritable azo‐dye photoalignment

Abstract— The rewritable azo‐dye photoalignment (ORW) of liquid crystals (LCs) for application in optical rewritable electronic paper has been investigated. It was observed that a periodic change in the azimuthal aligning direction with polarized UV light (365 nm) brings about homeotropic alignment, while utilization of visible light (450 nm) does not affect the LC tilt angle. The wavelength dependence of the ORW photoalignment result and the behavior of the photoinduced anisotropy was explored. The dark amplification of film anisotropy after exposure was observed, which is believed to be the relaxation process related to hydrogen bonding in azo‐dye film. New material, CD1, for azo‐dye rotation photoalignement that possesses a high azimuthal anchoring energy (about 2 × 10^?4 J/m²) was found.     

Evaluation of azimuthal anchoring energy for liquid crystal device equipped with color filter by means of renormalized transmission ellipsometry

In this study, we theoretically investigated the influence of a color filter on the determination of the azimuthal anchoring energy by means of ellipsometric analysis, and the azimuthal anchoring energy of the twisted nematic (TN) liquid crystal devices (LCDs) equipped with/without a color filter was evaluated by means of renormalized transmission ellipsometry. The results indicated no influence in the obtained ellipsometric parameters, such as the phase difference and the angle of amplitude ratio, when a color filter was an isotropic medium. It was experimentally confirmed that the evaluated azimuthal anchoring energy of LCD with a color filter was almost the same as that without a color filter. From the numerical and experimental study, the possibility for the determination of the azimuthal anchoring energy for the commercial TN LCD products was demonstrated.     

Anchoring and gliding of easy axis of 5CB on photoaligning PVCN‐F surface

Abstract— The photoaligning properties of the popular photoaligning material polyvinyl‐4(fluorocinnamate) (PVCN‐F) are presented. The aligning quality and azimuthal and zenithal anchoring energy were measured and the drift of the easy orientation axis (gliding effect) on the PVCN‐F surface, depending on UV exposure, was studied. Special attention is paid to unraveling the contribution of the adsorption liquid‐crystal molecules onto the aligning surface to the anchoring properties of PVCNF and measuring the drift of the easy orientation axis over the PVCN‐F surface. It is shown that a relatively weak azimuthal anchoring energy (W_az ～ 10^?7 ? 10^?5 J/m²) leads to strong drift of the easy axis in the azimuthal plane that was observed in a moderate (～0.1–0.3 T) magnetic field. A much stronger polar anchoring (W_zen ～ 10^?4 J/m²) allowed us to observe the essential gliding of the easy axis in the zenithal plane in a rather strong electric field (～5 V/μm).     

Azo‐dye aligning layers for liquid‐crystal cells

Abstract— The photo‐induced alignment of liquid crystal onto a photochemical stable azo‐dye film was studied for liquid‐crystal display (LCD) applications. The photo‐aligning of azo dye takes place due to the pure reorientation of the molecular absorption oscillators perpendicular to the UV‐light polarization. The order parameters S = ?0.4 (80% of the maximum absolute value S_m = ?0.5) was measured at a wavelength of 372 nm from the polarized absorption spectra. The temperature‐stable pretilt angle of 5.3° was obtained by a two‐step exposure of azo‐dye film using normally incident polarized light followed by oblique non‐polarized light. The azimuthal anchoring energy of the photo‐aligned substrate was A_? > 10^?4 J/m², which is of the same magnitude as the anchoring of the rubbed PI layer. The VHR value of the photo‐aligned LC cell was also found to be very high (98–99%) at room temperature and more than 95% at T=80°C. The thermal stability of the photo‐aligned azo‐dye layers is sufficiently high, while UV stability has to be improved, _e.g., by polymerization. The new LCD aligning technology based on photochemical stable azo‐dye layers is envisaged.     

Parameters on the LC alignment of organosilicon compound films

Abstract— The aligning properties of a set of organosilicon compounds (OSC) were examined. The aligning films of the OSC were obtained. Pretilt angles and the polar and azimuthal anchoring energy of the LC materials on the OSC films were measured by optical and voltage‐capacity methods. The influence of both OSC and LC molecular structure on the results obtained was analyzed and discussed.     

Bistable C1 ferroelectric liquid crystal device for e-paper application

Recent progress in both low pretilt and high pretilt defect-free C1 surface stabilized ferroelectric liquid crystal (SSFLC) devices for e-paper application is reviewed. First, by using numerical calculation to investigate the balance between surface azimuthal anchoring energy and bulk elastic energy within the confined chevron layer geometry of C1 and C2, we found it is possible to achieve a zigzag-free C1 state by low azimuthal anchoring alignment with a low pretilt angle. The critical azimuthal anchoring coefficient for defect-free C1 state is calculated. Its relationship with elastic constants, chevron angle, and surface topography effect are also discussed. Second, by using 5° oblique SiO deposition alignment, a defect-free, large memory angle, high contrast ratio, and bistable C1 SSFLC display, which has potential for electronic paper applications has also been developed. The electro-optical properties and bistability of this device have been investigated. Various aspects of defect control are also discussed.     

Liquid‐crystal photoaligning by azo dyes (Invited Paper)

Abstract— Liquid‐crystal (LC) photoalignment using azo dyes is described. It will be shown that this photoaligning method can provide a highly uniform alignment with a controllable pretilt angle and strong anchoring energy of the LC cell, as well as a high thermal and UV stability. The application of LC photoalignment to the fabrication of various types of liquid‐crystal displays, such as VAN‐LCDs, FLCDs, TN‐LCDs, and microdisplays, on glass and plastic substrates is also discussed. Azo‐dye photoaligned super‐thin polarizers and phase retarders are considered as new optical elements in LCD production, in particular for transflective displays.     

Plasma beam alignment for the large‐area substrates: Equipment and process

Abstract— We have developed an effective method for liquid‐crystal alignment of the large‐area substrates. This method is based on the oblique treatment of the alignment substrates with a “sheet” of accelerated plasma generated by the anode layer source of the “race track” geometry. During this treatment, the substrate or source is cyclically translated in the direction perpendicular to the plasma “sheet.” This method provides planar, tilted, and vertical liquid‐crystal alignment with excellent uniformity and reproducibility and easy axis control in the azimuthal and polar planes.     

Flexible bistable chiral nematic liquid crystal display with enhanced memory characteristic by surface treatment

We proposed a flexible bistable chiral splay nematic liquid crystal display with the enhanced memory characteristics by the surface treatment with reactive mesogen (RM). With the polymerized RM structure on alignment layers adopted, the energy barrier between splay and π‐twisted states in the bistable chiral splay nematic liquid crystal mode is increased because of the enhancement of the azimuthal anchoring energy, and thus, the spontaneous relaxation from the π‐twisted state to the initial splay state is remarkably impeded. As a result, the memory retention time became twice as long as that of the conventional cell without the polymerized RM structure, and the stable memory characteristics were maintained against the external deformation.     

Relationship between rubbing‐induced anisotropy and surface azimuthal anchoring energy of nematic liquid crystals

The relationship between the rubbing‐induced anisotropy of alignment films and the surface azimuthal anchoring energy of nematic liquid crystals was investigated using three kinds of rubbing cloths. Reflection ellipsometry revealed that the optical surface anisotropy of polyimide alignment films increases monotonically with increasing RS. The surface azimuthal anchoring energy measured by the torque balance method depends on the rubbing‐induced anisotropy of alignment films. This indicates that liquid crystal molecular alignment can be controlled by monitoring the rubbing‐induced optical anisotropy of alignment films when a suitable rubbing cloth is used.     

A dual‐cell‐gap transflective liquid‐crystal display with identical response time in transmissive and reflective regions

Abstract— A dual‐cell‐gap transflective liquid‐crystal display (TR‐LCD) with identical response time in both the transmissive and reflective regions is demonstrated. In the transmissive region, strong anchoring energy is used to decrease the response time, while in the reflective region, weak anchoring energy is used to increase the response time. And overdrive voltage technology is adopted to make the response time identical in both the transmissive and reflective regions. The device structure and operating principle of the TR‐LCD was analyzed, the anchoring energy in the transmissive and reflective regions was designed, and the response time and electro‐optic characteristics of the TR‐LCD was calculated. The simulated dual‐cell‐gap TR‐LCD demonstrated good performances.     

Nanoscale engineering of photo aligning Cibacron Brilliant Yellow

Photoalignment properties on commercially available textile dye Cibacron Brilliant Yellow exhibit excellent alignment quality. Thin layer of solid films (about 20–100 nm in thickness) shows high thermal and photo stability. Excellent surface energy values (both azimuthal and polar) were achieved. The distinguished alignment properties of this dye extend the field of the sulfuric azo dyes effective for photoalignment. An attractive feature of this dye is its low curing temperature, which is essential for plastic substrates to use it as flexible devices.     

Anisotropic thin films formation rate on PEDOT : PSS layer with high azimuthal anchoring

Oriented organic layers have great potential for organic electronics devices because of the unique modification of material properties without extensive chemical synthesis. Such layers can be prepared by wet coating of anisotropic organic molecules on top of specific surface of alignment layer. One of the most important parameter that indicates alignment properties of the surface is the anchoring energy. In this paper, we investigate azimuthal anchoring energy of pure and glycerol‐doped PEDOT : PSS layers and study the influence of the alignment layer preparation on the order parameter of the top wet‐coated oriented organic emitter. We confirm that the azimuthal anchoring energy increase leads to improvement of both dichroic ratio and contrast ratio of polarized emitter layer rod‐coated on top of the PEDOT : PSS. Suggested mechanism of anisotropic emitter formation at wet deposition grounds possibility of linear deposition rate of 2 m/s on top of PEDOT : PSS layer with obtained azimuthal anchoring above >10^?4 J/m².     

Bistable nano‐structured photoalignment surface by nanoimprint lithography

A novel nano‐structured photoalignment surface is proposed and demonstrated. Such alignment surface has bistable azimuthal alignment directions for the liquid crystal molecules. The new alignment surface has a structure of stacking a photo‐polymerizable photoalignment polymer on top of a nano‐sized groove surface. The photoalignment polymer and groove surface have different azimuthal alignment directions but the same azimuthal anchoring energies. The fabrication of the nano‐sized groove is based on nano‐imprint lithography. Hence, the size and depth are controllable, where no random process is involved. The alignment surface is robust, stable, reliable, reproducible and suitable for mass manufacturing. Such alignment surface can be applied to fabricate a π/2 bistable twisted nematic (π/2‐BTN) display which has better optical performances than the traditional π‐BTN display.     

Defect‐free half‐V‐mode ferroelectric liquid‐crystal device

Abstract— The horizontal chevron defect found in a half‐V‐mode ferroelectric‐liquid‐crystal (HV‐FLC) device can be suppressed by lowering the FLC's total free energy. The energy levels between spontaneous polarization (PS) up and down domains were degenerated by asymmetrical‐alignment treatments. The difference in the polar surface coefficient (γ²) was the key to suppressing the alignment defect. Alignment layers with opposite surface polarities and different anchoring energies were applied to control the sign and value of γ². The asymmetric cells of PIrub ‐ PIplasma (rubbed polyimide and plasma‐treated polyimide surfaces), PVArub ‐ PIplasma (rubbed polyvinyl alcohol and plasma‐treated polyimide surfaces), and PVArub ‐ PIplasma (both rubbed PI and PVA) alignment conditions presented defect‐free alignment textures under a slow‐cooling process. Among these different alignment treatments, the PVArub ‐ PIrub treated cell demonstrated the best alignment result, benefited by the largest difference in polar surface coefficient.     

Photo‐aligned photonic ferroelectric liquid crystal fibers

Preliminary studies of photonic crystal fibers (PCFs) partially infiltrated with photo‐aligned ferroelectric liquid crystals (FLCs) under the influence of external electric field are reported. The proper alignment of the FLC molecules is achieved by generating a photo‐aligning layer on the inner side of the PCF microcavities. The sulfonic azo dye, which is used as an alignment layer, offers a variable anchoring energy depending on the irradiation energy, and thus, a good control on the FLC alignment inside microchannels is possible. Moreover, a state of polarization of the light being guided inside the PCF infiltrated selectively with FLC changes under the influence of external electric field.     

Electrically suppressed helix ferroelectric liquid crystals for modern displays

In this article, we disclose electrically suppressed helix ferroelectric liquid crystal (ESHFLC) that is characterized by high optical quality and fast response time at the cost of extremely small driving voltage. These unique features of the ESHFLCs are highly sensitive to the anchoring energy that should be smaller and comparable to the elastic energy of the ferroelectric liquid crystal helix. The photo alignment, which offers good control on the anchoring energy by means of the irradiation energy, is critically important to lock the optimum parameters of the ESHFLC display cell. An example of field sequential color display with the frame frequency of 240 Hz at the driving voltage of 2 V has been demonstrated.     

Relation between dichroism of photoalignment azo dyes and their orientation under light wave field

To date, azo dyes are widely used for liquid crystal photoalignment in flat panel displays. The relation of dichroism of azo dyes with their orientation under intensive light wave field is considered. Values of a parameter, which characterizes orientation order of both molecules and dimers, were obtained as well as energy of their orientation process. Number of cooperatively oriented dye molecules was estimated. The angles distribution functions for different dimers were derived. Dipole electrical transition moments directed on angles close to 90° to the direction of maximal polarizability of dimers were revealed.