Active matrix field sequential color electrically suppressed helix ferroelectric liquid crystal for high resolution displays

In this article, we disclose a 3‐inch 250ppi active matrix field sequential color (FSC) display based on electrically suppressed ferroelectric liquid crystal (ESHFLC). ESHFLC's ultra‐fast response time (~10 μs at 6.67 V/μm) enables the display resolution to be tripled via FSC technique. The photo‐alignment technology provides ESHFLC with optimal anchoring energy that contributes to a high contrast ratio over 10 K:1 on single pixel level measurement. A specific 3T1C pixel circuit is designed to generate continuous gray scale from FLC binary switching by utilizing the pulse width modulation concept. The low temperature poly silicon thin‐film transistor array has been used to fabricate the FSC ESHFLC display panel. We achieved an 8‐bit gray level for each color subframe, that is, R, G, and B colors that results in 24‐bit color images. We believe, because of the good optical quality and cost‐effective fabrication, this display may replace in‐plane switching or fringe‐field switching in the near future for the portable device market. Moreover, high resolution FSC ESHFLCs can find applications in the emerging virtual reality displays.     

Ferroelectric liquid crystals: Excellent tool for modern displays and photonics

The ferroelectric liquid crystals, because of their fast electro‐optical response, are one of the most important classes of liquid crystals. Here, in this review, we have summarized the different electro‐optical modes for ferroelectric liquid crystals. Clark–Lagerwall effect (surface stabilized ferroelectric liquid crystal), deformed helix ferroelectric (DHF) effect, electrically suppressed helix (ESH) mode, DHF orientational Kerr effect, and ESH diffraction modes have been discussed. All of the crucial features, that is, optics, electro‐optics, dynamics, and their dependence on material parameters, operational regime, and applications, have been reviewed.     

Photo‐aligned photonic ferroelectric liquid crystal fibers

Preliminary studies of photonic crystal fibers (PCFs) partially infiltrated with photo‐aligned ferroelectric liquid crystals (FLCs) under the influence of external electric field are reported. The proper alignment of the FLC molecules is achieved by generating a photo‐aligning layer on the inner side of the PCF microcavities. The sulfonic azo dye, which is used as an alignment layer, offers a variable anchoring energy depending on the irradiation energy, and thus, a good control on the FLC alignment inside microchannels is possible. Moreover, a state of polarization of the light being guided inside the PCF infiltrated selectively with FLC changes under the influence of external electric field.     

Transmissive electrowetting‐based displays for portable multimedia devices

Abstract— Electrowetting‐based displays have been successfully demonstrated in reflective mode, showing video capability and high optical performance. However, because this technology is based on a high‐efficiency optical switch operating between a light‐absorbing state and a light‐transmitting state, the technology lends itself naturally to a transmissive mode enabling a complete range of applications. This paper describes the first active‐matrix full‐color transmissive electrowetting displays including its main technical and system aspects. Two architectures have been demonstrated: one uses color filters, the other field‐sequential‐color illumination. The paper also introduces alternative concepts for more efficient color transmissive electrowetting displays with multiple absorbing layers.     

Plasma‐beam alignment technique for ferroelectric liquid crystals

Abstract— The plasma‐beam alignment procedure earlier developed for the alignment of nematic liquid crystals is successfully extended to ferroelectric liquid crystals (FLC). The highly uniform alignment of the “chevron” structure (before electrical treatment of FLC cells) and “quasi bookshelf” structure (after the electrical treatment) are realized. The contrast of bistable switching larger than 350:1 is achieved. This makes the non‐contact plasma‐beam alignment procedure especially attractive for high‐contrast bistable LCDs on an LCOS base, particularly used in PDA and e‐books. Fast switching and realization of gray scale in the plasma‐beam aligned FLC cells makes this technique also promising for full‐color displays including color LCD TV.     

Multistable electro‐optical modes in ferroelectric liquid crystals

Abstract— Multistable electro‐optical modes exist under certain conditions in ferroelectric liquid‐crystal (FLC) cells, which means that any light‐transmission level can be memorized after the driving voltage is switched off. The multistability is responsible for three new electro‐optical modes with different shapes of the gray‐scale curve that can be either S‐shaped (double or single dependent upon the applied‐voltage pulse sequence and boundary conditions) or V‐shaped dependent upon boundary conditions and FLC cell parameters. The origin of these modes will be described.     

Anisotropic fluorophors for liquid crystal displays

Liquid crystal displays (LCDs) are commonly found in portable equipment. The main criticisms aimed at these displays are their asymmetric angle-of-view and dull grey appearance, which is particularly acute in low ambient lighting. However, by the inclusion of a fluorescent dye, it is possible to fabricate partially-emissive LCDs with a virtually hemispherical angle-of-view. This effect has been demonstrated succesfully for a range of dyes based on the perylene diester chromophor. An energy transfer mechanism between the liquid crystal host and dye molecule has been identified. This effect was used to enhance the fluorescence intensity.     

Multiple color high resolution reflective cholesteric liquid crystal displays

Abstract— A high-resolution multiple-color and black-on-white surface-stabilized reflective cholesteric liquid-crystal display with reflectivities as high as 40% is reported. The double-stacked 1/8-VGA, 100-dpi prototype shows four vivid colors with negligible parallax. The potential for eight colors and ultimately full color is demonstrated in a high-resolution triple-stacked prototype.     

Novel photo‐aligned LC‐polymer compensation film for wide‐view TN displays

Abstract— We demonstrate a novel TN‐display compensation film with excellent contrast and minimal color shift, meeting the requirements for avionics displays. The film configuration was identified via extensive computer modeling. The experimental implementation based on ROLIC's LPP/LCP (linearly photopolymerizable polymer/liquid‐crystal polymer) technology results in excellent agreement with theoretical predictions.     

Towards nanoscale molecular switch-based liquid crystal displays

Cholesteric liquid crystals (Ch-LCs) have been extensively studied due to their unique self-organized helical molecular structures and selective Bragg reflection properties, which exhibit great potentials for color displays and other practical applications. When functional, nanoscale molecular switches are doped in liquid crystals (LCs), the phases of the LCs or the molecular structures of the Ch-LCs can be changed upon the influence of external stimuli, such as light and temperature. In this paper, the photoresponsive molecular switch-based LCs for display applications are reviewed. The progress and effort in developing molecular switches, the principles of light-tuning, photo-addressed color displays, information processing, bistable displays and flexible displays are presented.     

Substrate‐free cholesteric liquid‐crystal displays

Abstract— This paper demonstrates the first substrate‐free cholesteric liquid‐crystal displays. The encapsulated cholesteric displays are ultra‐thin (with a total thickness around 20 μm) and ultra‐lightweight (0.002 g/cm²). The displays exhibit unprecedented conformability, flexibility, and drapability while maintaining electro‐optical performance and mechanical integrity. All functional display layers are sequentially coated on a preparation substrate and then lifted‐off from the preparation substrate to form a free‐standing display. The display fabrication process, electro‐optical performance, and display flexibility are discussed.     

Multiplane displays based on liquid crystals for AR applications

Multiplane displays are capable of displaying 3D scenes with correct focus cues by creating multilayer 2D images in the display volume. Hence, such a 3D display technique could effectively address the accommodation‐vergence conflict (AVC) problem, which is prevalent in augmented reality (AR) displays. In this paper, we review the recent progress on multiplane AR displays based on liquid crystals (LCs) for AR applications. The working principle of multiplane AR displays is illustrated, the electro‐optical properties of the tunable LC devices are investigated and display prototypes are demonstrated. Finally, we discuss the prospects and challenges of multiplane AR displays based on LCs.     

Smectic dynamic scattering in laser-addressed liquid crystal projection displays

Two viable methods of producing high-uniformity scattering, suitable for laser-scanned high- resolution light-on-dark contrast liquid crystal projection displays, are reported. The advantages of dynamic scattering over heat-pulse-induced scattering are outlined in terms of power consumption, addressability, uniformity and thermal management.     

V‐shaped electro‐optical mode based on deformed‐helix ferroelectric liquid crystal with subwavelength pitch

Abstract— V‐shaped electro‐optical response is shown, both theoretically and experimentally, to be an inherent property of a deformed‐helix ferroelectric liquid‐crystal cell (DHFLC) under a special choice of the applied rectangular alternating‐electric‐field waveform, frequency, and cell geometry. In contrast to other known V‐shaped ferroelectric liquid‐crystal (FLC) modes, the discovered V‐shaped switching is observed in a broadband frequency range including 1 kHz, and not at a certain characteristic frequency. This type of V‐shaped switching allows for a drastic increase in the operating frequency of field‐sequential‐color (FSC) LCD cells in comparison with fast nematic liquid‐crystal (NLC) modes.     

Motion‐blur‐free LCD for high‐resolution virtual reality displays

A new liquid crystal display device with fast response time, high transmittance, and low voltage for virtual reality is reported. When driven at 90 Hz with 17% duty ratio, the motion picture response time is 1.5 ms, which is comparable with cathode‐ray tube, leading to indistinguishable motion blur. Moreover, this device enables high‐resolution density because only one thin‐film transistor per pixel is needed and it has a built‐in storage capacitor.     

Electrically commanded surfaces: A new liquid‐crystal‐display concept

Abstract— Fast in‐plane switching of the optic axis was realized in liquid‐crystal displays (LCDs) based on the concept of Electrically Commanded Surfaces (ECS). According to this concept, the liquid‐crystal layer in such a display is aligned by means of thin ferroelectric liquid‐crystal‐polymer (FLCP) film deposited onto the inner side of the display substrates. An electric field, applied normal to the substrates, switches the molecules of the ferroelectric film, representing the commanded surface that, via elastic forces, further transfers to the liquid‐crystal layer. The concept of electrically commanded surfaces opens the door to a new generation of advanced LCDs exhibiting extraordinary performance such as fast in‐plane switching.     

Defect‐free deformed‐helix ferroelectric liquid‐crystal mode in a vertically aligned configuration (Invited Paper)

Abstract— A novel deformed‐helix ferroelectric liquid‐crystal (DHFLC) mode in a vertically aligned (VA) configuration is described. In this configuration, several unique features of display performance such as uniform alignment, fast response, and analog gray‐scale capability are obtained. Particularly, this VA‐DHFLC mode allows for the defect‐free uniform alignment of both the FLC molecules and the smectic layers over a large area without employing additional processes such as rubbing or electric‐field treatment that are generally required for planar FLC modes. Based on the VA‐DHFLC mode, a transflective display having a single‐gap geometry with in‐plane electrodes on two substrates in the transmissive regions and on one substrate in the reflective regions is described.     

A submillisecond‐response liquid crystal for color sequential projection displays

We report a new LC with low viscosity and high clearing point (T_c ~102 °C) for color‐sequential projection displays. Using a 1.95‐µm mixed‐mode twisted nematic cell, the averaged gray‐to‐gray response time is less than 1 ms, which is ~3.6× faster than the current state of the art. Such a mixed‐mode twisted nematic liquid‐crystal‐on‐silicon can be used for near‐to‐eye wearable projection displays and head‐up displays in vehicles.     

Auto‐calibration of drive condition for cholesteric liquid crystal displays

Dynamic drive scheme (DDS) is known widely as passive matrix addressing that obtains both high‐speed re‐writing and a high contrast ratio in the field of cholesteric liquid crystal displays (LCDs). However, DDS has a serious problem in that the proper drive condition is very narrow and it is largely influenced by individual differences in LCDs that arise during their production. We have developed a new auto‐calibration system that adjusts both the contrast ratio and color balance automatically using capacitances of effective pixels and temperature compensation models that utilize the physical properties of cholesteric LCDs. We have managed to optimize the driving conditions between 5 and 35 °C with this method, and obtained both stable and high‐quality color images where the reflectance is 36%, contrast ratio is 8, and NTSC ratio is 20%. This auto‐calibration system has been able to greatly improve the production yield of cholesteric LCDs and made it possible to make practical use of cholesteric LCDs.     

Cholesteric liquid crystals for detection of organic vapours

Studies on the use of cholesteric liquid crystals (CLCs) as sensing phase for detection of organic vapours in air are described. Stock solutions of 1.0% (w/v) cholesteryl nonanoate (CN) and cholesteryl chloride (CC) were prepared in tetrahydrofuran. Binary mixtures, with compositions ranging from 0.18 to 0.25% of CC and 0.82–0.75% of CN, respectively, were prepared by appropriate mixing of the stock solutions. Films were cast by pipetting three 10 μl aliquots of the CLC solution mixture onto a glass disk, whose reverse side was made black to absorb unscattered light. The glass disk was adapted to the common end of a bifurcated optical fibre bundle and placed in a glass vial, which provided a headspace of organic vapours. Measurements were carried out at 27±1 °C, a temperature in which the CLC mixtures maintain their liquid crystalline properties. The responses of the CLC mixtures to vapours of ethanol, acetone, benzene, pyridine and hexane were investigated. The colour of the sensing phases depended on their compositions and exposure to organic vapours gives rise to a change in the optical characteristics of liquid crystals. It was found that the CLC layers containing 0.23–0.25% of CC had no significant change in optical properties when exposed to organic vapours and that ethanol did not cause any optical changes in the liquid crystal layers. Benzene as well as hexane always turned all the coloured liquid crystalline layers to colourless. The CLC layers exhibited different behaviours to vapours of acetone and pyridine. For example, the wavelengths of maximum scattering for the 0.19% CC layer were 530 nm in air, 545 nm in pyridine and 580 nm in acetone. The CLC layers showed reversibility. The lifetimes of these layers (interval of time in which the liquid crystalline phase exists, before crystallisation) were investigated by employing acetone and n-hexane vapours. Average lifetimes of 14–15 min were found for films in contact with these vapours, while a lifetime of 205 min was possible when the CLC film was exposed to air.