共查询到17条相似文献,搜索用时 81 毫秒
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微波法合成羧甲基型木薯两性淀粉 总被引:2,自引:0,他引:2
以木薯淀粉为原料,采用微波辐射技术,用湿法工艺,在95%乙醇水溶液介质中以NaOH为催化剂,与氯乙酸、3-氯-2-羟丙基三甲基氯化铵(CHPTMA)反应一步合成高取代度羧甲基两性淀粉,讨论了微波时间、碱化时间、NaOH用量等对合成反应的影响。结果表明,CHPTMA用量为2 g,氯乙酸用量为3 g,微波时间7 min,碱化时间30 min,NaOH用量为3.05 g时,合成了阳离子取代度为0.31、阴离子取代度为0.34的高取代度两性淀粉。通过IR、DSC等检测证实了两性的存在。 相似文献
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用低取代度的醋酸酯淀粉与阳离子醚化剂反应而合成了一种新型两性淀粉印染废水处理剂,通过考察醚化反应体系的p H、反应时间、反应温度及醚化剂的用量对阳离子取代度的影响,确定最佳反应条件为:反应体系p H=11,反应温度45℃,反应时间8 h。并测试了不同阳离子取代度的醋酸酯阳离子两性淀粉水处理剂对印染废水色度去除率,确定阴离子取代度0.074 5、阳离子取代度0.013 1的两性淀粉脱色效果最好。 相似文献
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采用半干法合成药片崩解剂羧甲基淀粉(CMS)。考察了碱和一氯乙酸用量对CMS取代度(DS)的影响;考察了DS和H/Na(CMS中游离羧基和成盐羧基比值)改变对CMS吸水溶胀性能和崩解性能的影响,应用红外光谱、X-射线衍射、扫描电镜等方法探索CMS结构与性能的关系。 相似文献
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药用小麦羧甲基淀粉崩解剂的合成及性能 总被引:1,自引:0,他引:1
采用小麦淀粉为原料,以环氧氯丙烷为交联剂、氯乙酸为醚化剂复合变性合成适用于药片崩解剂的羧甲基淀粉,其崩解性能良好。此法生产的产品在常温下即可快速吸水膨胀而不糊化。原料最佳配比:小麦淀粉∶环氧氯丙烷∶氯乙酸∶氢氧化钠=6∶1∶1∶0郾9,反应温度为50℃,反应时间6—8h。 相似文献
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Clay–starch composites with different aggregate sizes and starch to clay ratios were prepared by a simple precipitation method. The aggregates of the composites were used as fillers to improve the paper properties. The experimental results showed that the paper strengths increased more than 100% for starch‐modified clay compared to untreated clay at 20–30% clay loading. The increase in paper strengths of clay–starch composite‐filled handsheets was mainly due to two reasons, i.e., the relatively large aggregate size and the improved internal bonding. The optical properties compared at same mechanical strength were also improved. The water solubility of starch in the clay–starch composite was less than 3% at 50°C for 30 min, and it could be further reduced by adding crosslinker. Bonding sites between composite and fiber were investigated by scanning electron microscope. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1032–1038, 2006 相似文献
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Crosslinked amphoteric starches (CASs) with quaternary ammonium cationic and carboxymethyl anionic groups were prepared by a hemidry reaction. Their adsorption behavior for Cr(VI) was investigated, and was found to follow the Langmuir isotherm. The adsorption process was found to be dependent on initial pH, concentration of Cr(VI), dose of CAS, and temperature. The adsorption capacity decreased with increasing degree of substitution of anionic groups. The thermodynamic study indicated that the adsorption process was exothermic, and the enthalpy changes (ΔHθ), the entropy changes (ΔSθ), and free energy changes (ΔGθ) for CASs were determined. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 263–267, 2003 相似文献
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星形聚丙烯酰胺接枝淀粉的合成及应用 总被引:3,自引:2,他引:1
介绍了应用水溶液聚合方法合成了星形聚丙烯酰胺(SPAM)的方法。采用正交实验方法研究了不同的引发剂用量、相对分子质量调节剂用量、聚合体系温度对SPAM特性黏数的影响,从中优化出最佳反应条件为单体质量分数为15%,聚合温度为35 ℃,引发剂质量分数为(相对单体质量,下同)0.04%,螯合剂为0.005%,抗交联剂为0.015%,聚合体系pH值为5,得到的星形聚丙烯酰胺特性黏数为989.2 mL/g。星形聚丙烯酰胺在35℃进行氯胺化反应并加到糊化好的淀粉溶液中,在40~50 ℃下反应40 min,即得到星形聚丙烯酰胺接枝淀粉絮凝剂。结果说明,星形聚丙烯酰胺接枝淀粉絮凝剂溶解性好、絮凝能力强,具有良好的絮凝效果。 相似文献
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Starch-g-poly(2-methacryloyloxyethyl trimethyl ammonium chloride-co-acrylic acid) (starch-g-P(DMC/AA)) with different zeta potentials was prepared via the graft copolymerization of acid-thinned cornstarch (ATS) with 2-methacryloyloxyethyl trimethyl ammonium chloride (DMC) and acrylic acid (AA) in aqueous medium using Fe2+–H2O2 initiator. The investigation was carried out to reveal the influence of amphoteric branches grafted onto starch chains upon the adhesion of starch to textile fibers. Zeta potential of starch-g-P(DMC/AA) was adjusted by altering the mole ratio of DMC to AA charged into the copolymerization system. The adhesion was evaluated in terms of bonding strength and specific bonding strength of slightly sized roving based on a legal method (FZ/T 15001-2008) through the comparison of the amphoteric branch-grafted starch with ATS, starch-g-PAA, and starch-g-PDMC for warp sizing. It was found that the charged branches grafted onto starch chains were able to significantly enhance the adhesion. Zeta potential, depending on the mole ratio of DMC to AA units in the grafting branches, showed evident effect on the adhesion and desizability of the grafted starch. Increase in the potential favored to improve the adhesion, but disfavored the removal of the starch from sized warps. Alkali-oxidant agent desizing test confirmed that the starch-g-P(DMC/AA) with neutral potential was desizable. The amphoteric branch-grafted starch exhibited potential application as size base materials in warp sizing operation if its zeta potential was neutral. 相似文献
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两性聚丙烯酰胺处理污水用量少,毒性低,pH适用范围广,绿色环保。采用水分散聚合方法合成了两性聚丙烯酰胺P(AM-co-IA-co-DAC-co-DMC),以1%的高岭土悬浮液模拟废水,考察絮凝剂用量、特性粘数、体系pH值、温度以及阴阳离子单体配比对絮凝效果的影响。结果表明,当阳、阴离子单体摩尔比为3∶1,特性粘数为3.16 dL/g,用量为3 mg/L时,絮凝效果好,常温下透过率达到98.7%。两性聚丙烯酰胺分子链上的正、负两种电荷基团同时发挥电中和作用和架桥作用,絮凝效果受pH变化的影响较小,明显优于阳、阴离子型聚丙烯酰胺。 相似文献