Abiotic production of methylmercury by solar radiation

Methylmercury [MeHg(I) in the aerobic surface water of lakes is thought to be rapidly degraded, but contrary to expectations, we show that MeHg(I) concentrations often increase during sunlight hours or remain relatively constant. We hypothesized that there were water column processes that generated MeHg(I) and that these processes were linked to dissolved organic matter (DOM) and solar radiation. A 2-day diurnal pattern of MeHg(I) in surface water with corresponding bottled controls was assessed for two contrasting lakes in Kejimikujik, Nova Scotia, Canada. Following this study, a tangential ultrafiltrator was used to size-fractionate and generate a concentration gradient of DOM from four different lakes located near Lac Berthelot, Quebec, Canada. The watersheds of two of these lakes were not substantially logged whereas the other two had been extensively logged. Different size fractions of DOM as well as different concentrations of DOM were exposed to sunlight for varying periods of time. We observed that, in Keiimikujik, the concentration of MeHg(I) in surface waters peaked in the early afternoon. Furthermore, this also occurred in bottled water for one of the lakes, Puzzle, eliminating the possibility that in-lake mixing played a role in this pattern. The formation of MeHg(I) was found to be dependent on the size fraction and amount of DOM present in the water. Specifically, DOM less than 5 kDa or between 30 and 300 kDa generated MeHg(I) when exposed to sunlight, but larger fractions did not. Furthermore, although data are limited, we found that water from lakes with logged watersheds generated MeHg(I) when exposed to sunlight, whereas water from lakes with low levels of logging in the undisturbed watersheds did not. Our results demonstrate that MeHg(I) can be formed in freshwaters of certain lakes in response to solar radiation. This photoproduction of MeHg(I) is dependent on DOM concentrations and type, with the importance of water chemistry not yet clear. The significance of this process to freshwater lakes and the mechanism responsible for MeHg(I) photoproduction is still unclear, but a correction in the conventional wisdom that MeHg(I) is rapidly photodegraded is timely.     

Evidence for elevated production of methylmercury in salt marshes

Depth variations of total mercury (Hg) and methylmercury (MeHg) concentrations were obtained in cores from nonvegetated sediments, sediments colonized by Sarcocornia fruticosa, Halimione portulacoides, and Spartina maritima and below-ground biomass in three Portuguese estuaries. Similar analyses were also performed on the above-ground plant tissues. Concentrations in below-ground biomass exceeded up to 9 (Hg) and 44 (MeHg) times the levels in sediments. Mercury and MeHg in below-ground biomass were up to 400 (Hg) and 4700 (MeHg) times higher than those found in above-ground parts, indicating a weak upward translocation. Methylmercury in colonized sediments reached 18% of the total Hg, which was 70 times above the maximum values found in nonvegetated sediments. Concentrations of MeHg in vegetated sediments were not related to plant type but were linearly proportional to the total mercury levels. The analysis of below-ground biomass at high depth resolution (2 cm) provided evidence that Hg and MeHg were elevated. The higher enrichment factors were found where the shifting of redox conditions suggested high microbial activity. Mercury and MeHg in below-ground tissues were a function of total levels in sediments and again were not plant-specific. These results suggest that the bioremediation of mercury-contaminated sediments is likely to increase the formation of methylmercury.     

Sulfate addition increases methylmercury production in an experimental wetland

Atmospheric mercury is the dominant Hg source to fish in northern Minnesota and elsewhere. However, atmospherically derived Hg must be methylated prior to accumulating in fish. Sulfate-reducing bacteria are thought to be the primary methylators of Hg in the environment. Previous laboratory and field mesocosm studies have demonstrated an increase in methylmercury (MeHg) levels in sediment and peatland porewaters following additions of sulfate. In the current ecosystem-scale study, sulfate was added to half of an experimental wetland at the Marcell Experimental Forest located in northeastern Minnesota, increasing annual sulfate load by approximately four times relative to the control half of the wetland. Sulfate was added on four separate occasions during 2002 and delivered via a sprinkler system constructed on the southeast half (1.0 ha) of the S6 experimental wetland. MeHg levels were monitored in porewater and in outflow from the wetland. Prior to the first sulfate addition, MeHg concentrations (filtered, 0.7 microm) were not statistically different between the control (0.47 +/- 0.10 ng L(-1), n = 12; mean +/- one standard error) and experimental 0.52 +/- 0.05 ng L(-1), n = 18) halves. Following the first addition in May 2002, MeHg porewater concentrations increased to 1.63 +/- 0.27 ng L(-1) two weeks after the addition, a 3-fold increase. Subsequent additions in July and September 2002 did not raise porewater MeHg, but the applied sulfate was not observed in porewaters 24 h after addition. MeHg concentrations in outflow from the wetland also increased leading to an estimated 2.4x increase of MeHg flux from the wetland. Our results demonstrate enhanced methylation and increased MeHg concentrations within the wetland and in outflow from the wetland suggesting that decreasing sulfate deposition rates would lower MeHg export from wetlands.     

食品添加剂监管热点和甜蜜素安全性探讨

回顾中国卫生部门近二年来对食品中因滥用食品添加剂而被判为不合格品基本情况,其中频率最高的为甜蜜素;在输日和输美食品中,因检出日、美禁用甜蜜素而遭退回比例也居第一位。甜蜜素安全性一直是各国议论热点,虽中国、JECFA等80多个国家允许使用;但日、美等45国至今仍未批准使用;近年来对其致癌性、遗传毒性等研究均有进一步报导,以供读者参考。     

Metabolites indicate hot spots of biodegradation and biogeochemical gradients in a high-resolution monitoring well

Anaerobic degradation processes play an important role in contaminated aquifers. To indicate active biodegradation processes signature metabolites can be used. In this study field samples from a high-resolution multilevel well in a tar oil-contaminated, anoxic aquifer were analyzed for metabolites by liquid chromatography-tandem mass spectrometry and time-of-flight mass spectrometry. In addition to already known specific degradation products of toluene, xylenes, and naphthalenes, the seldom reported degradation products benzothiophenemethylsuccinic acid (BTMS), benzofuranmethylsuccinic acid (BFMS), methylnaphthyl-2-methylsuccinic acid (MNMS), and acenaphthene-5-carboxylic acid (AC) could be identified (BFMS, AC) and tentatively identified (BTMS, MNMS). The occurrence of BTMS and BFMS clearly show that the fumarate addition pathway, known for toluene and methylnaphthalene, is also important for the anaerobic degradation of heterocyclic contaminants in aquifers. The molar concentration ratios of metabolites and their related parent compounds differ over a wide range which shows that there is no simple and consistent quantitative relation. However, generally higher ratios were found for the more recalcitrant compounds, which are putatively cometabolically degraded (e.g., 2-carboxybenzothiophene and acenaphthene-5-carboxylic acid), indicating an accumulation of these metabolites. Vertical concentration profiles of benzylsuccinic acid (BS) and methyl-benzylsuccinic acid (MBS) showed distinct peaks at the fringes of the toluene and xylene plume indicating hot spots of biodegradation activity and supporting the plume fringe concept. However, there are some compounds which show a different vertical distribution with the most prominent concentrations where also the precursor compounds peaked.     

Geochemical controls on the production and distribution of methylmercury in near-shore marine sediments

We examined temporal differences in sedimentary production of monomethylmercury (MMHg) at three sites in Long Island Sound (LIS). Sediment-phase concentrations of Hg species decreased from west to east in LIS surface sediments, following the trend of organic matter. However, Hg methylation potentials, measured by incubation with an isotopic tracer (200Hg), increased from west to east. 200Hg methylation potentials were enhanced in August relative to March and June, attributable to differences in activity of sulfate-reducing bacteria. Organic matter and acid-volatile sulfide influenced the distribution coefficient (KD) of inorganic Hg (Hg(II) = total Hg - MMHg) and inhibited 200Hg methylation in surface sediments. 200Hg methylation varied inversely with the KD of Hg(II) and positively with the concentration of Hg(II), mostly as HgS0, in LIS pore waters. Accordingly, we posit that a principal control on MMHg production in low-sulfide, coastal marine sediments is partitioning of Hg(II) between particle and dissolved phases, which regulates availability of Hg substrate to methylating bacteria. Most of the partitioning in LIS sediments is due to Hg-organic associations. This suggests that reductions in the organic content of coastal sediment, a potential result of nutrient abatement programs intended to inhibit eutrophication of near-shore waters, could enhance MMHg production by increasing the bioavailability of the large reservoir of "legacy Hg" buried within the sediment.     

Spatial and seasonal variability of dissolved methylmercury in two stream basins in the eastern United States

We assessed methylmercury (MeHg) concentrations across multiple ecological scales in the Edisto (South Carolina) and Upper Hudson (New York) River basins. Out-of-channel wetland/floodplain environments were primary sources of filtered MeHg (F-MeHg) to the stream habitat in both systems. Shallow, open-water areas in both basins exhibited low F-MeHg concentrations and decreasing F-MeHg mass flux. Downstream increases in out-of-channel wetlands/floodplains and the absence of impoundments result in high MeHg throughout the Edisto. Despite substantial wetlands coverage and elevated F-MeHg concentrations at the headwater margins, numerous impoundments on primary stream channels favor spatial variability and lower F-MeHg concentrations in the Upper Hudson. The results indicated that, even in geographically, climatically, and ecologically diverse streams, production in wetland/floodplain areas, hydrologic transport to the stream aquatic environment, and conservative/nonconservative attenuation processes in open water areas are fundamental controls on dissolved MeHg concentrations and, by extension, MeHg availability for potential biotic uptake.     

十年磨一剑,做好中国食品安全的守望者——2020年食品安全与健康热点科学解读媒体沟通会在京召开

2021年1月8日,由中国科学技术协会指导、中国食品科学技术学会主办、多家媒体支持的“2020年食品安全与健康热点科学解读媒体沟通会”在北京召开,这也是中国食品科学技术学会(以下简称“学会”)连续第10年邀请权威专家对年度热点问题进行解读.本次推出的食品安全与健康十大热点是从60余个热点中筛选而出,其来自于10余家主流...     

造纸机关键部件专利保护状况和热点技术分析

对造纸机关键部件国内外专利申请进行了统计分析.结果表明,中国造纸机市场受到国外企业的高度关注,国内造纸机生产企业在核心技术上无法和世界先进水平相比,国外企业已完成了针对中国企业的专利战略.没有核心技术和自主知识产权的国内造纸装备制造企业,将面临相当大的市场压力,国内企业要加大技术创新力度,制订和实施专利战略.     

Contribution of coexisting sulfate and iron reducing bacteria to methylmercury production in freshwater river sediments

We investigated microbial methylmercury (CH(3)Hg) production in sediments from the South River (SR), VA, an ecosystem contaminated with industrial mercury (Hg). Potential Hg methylation rates in samples collected at nine sites were low in late spring and significantly higher in late summer. Demethylation of (14)CH(3)Hg was dominated by (14)CH(4) production in spring, but switched to producing mostly (14)CO(2) in the summer. Fine-grained sediments originating from the erosion of river banks had the highest CH(3)Hg concentrations and were potential hot spots for both methylation and demethylation activities. Sequencing of 16S rRNA genes of cDNA recovered from sediment RNA extracts indicated that at least three groups of sulfate-reducing bacteria (SRB) and one group of iron-reducing bacteria (IRB), potential Hg methylators, were active in SR sediments. SRB were confirmed as a methylating guild by amendment experiments showing significant sulfate stimulation and molybdate inhibition of methylation in SR sediments. The addition of low levels of amorphous iron(III) oxyhydroxide significantly stimulated methylation rates, suggesting a role for IRB in CH(3)Hg synthesis. Overall, our studies suggest that coexisting SRB and IRB populations in river sediments contribute to Hg methylation, possibly by temporally and spatially separated processes.     

高速热镀锌生产线的研制

为了提高镀锌钢丝产品质量和生产效率,自行设计出较先进的高速热镀锌生产线。该生产线放线采用上抽式放线机,解决了普通放线方式钢丝自身扭转问题;钢丝表面清洗采用盐酸波浪酸洗+电解碱洗,确保了钢丝表面的清洗效果;水帘密封彻底解决了酸、碱雾外泄污染环境的问题;助镀和电磁擦拭有效控制锌层质量和产品品质;收线机的每个头设计大、小2个V形盘,可满足30根不同直径钢丝同时生产。整条生产线采用PLC控制和现场总线技术、人机界面,确保了设备的运行精度。     

Modeling net energy efficiencies as quantitative characteristics in lactating cows

To date, researchers have measured net efficiencies of energy conversion using data from animals in energy chambers. The expense of this approach prevents the establishment of a large data base for quantitative studies. Our purpose was to investigate models that would enable us to use data collectable in normal field conditions to compare dairy cattle for their net energetic efficiency. Data from 357 Holstein cows in seven herds and in various parities consisted of daily measures of DM intake, net energy intake, milk production, biweekly measures of milk components, and bimonthly BW. Eighteen alternative multiple regression models were fitted to each of the cows to estimate simultaneously net efficiency of energy conversion for maintenance, lactation, pregnancy, and BW change during positive energy balance period, negative energy balance period, and whole lactation. Results from several fitted models approximated closely literature results based on data from cows in energy chambers. These comparative results suggest that it is possible to estimate efficiency of energy conversion on individual cows using data obtained from normal animal management situations.     

Biochemical and technological characteristics of hot chicken meat

In the hot breast and leg muscles of broiler chicken the level of ATP, the 'R' value, the lactic acid content, the pH value, the length of sarcomers, the water and fat retention capacity, the fat emulsion stability, thermal drip, and the extractability of protein fraction were investigated. It was found that in the breast muscles the onset of rigor mortis commenced within 30–60 min, and in the leg muscles as early as 15–30 min after killing of the birds. The deepest rigor mortis occurred between the first and fourth hour, and then gradually declined, sooner in the leg than in the breast muscles. The addition of sodium chloride (2.0–2.5%) to the minced pre-rigor meat not later than 40 min after slaughter, or better, an injection of NaCl brine into intact muscles 15 min after slaughter of birds, preserved their good technological properties.
The tenderness and the thermal drip of hot salted and chilled salted muscles showed no significant differences, but water retention and fat emulsifying capacity were better in the hot salted meat samples. The hot salted and cooked muscles were preferred by the sensory panel to corresponding samples of chilled muscles.
From the hot salted chicken meat more sarcoplasmic and myofibrillar proteins were extracted than from meat salted after chilling. However, after frozen storage the extractability of myofibrillar proteins were higher in the salted chilled meat.     

Variation in peak growing season net ecosystem production across the canadian arctic

Tundra ecosystems store vast amounts of soil organic carbon, which may be sensitive to climatic change. Net ecosystem production, NEP, is the net exchange of carbon dioxide (CO(2)) between landscapes and the atmosphere, and represents the balance between CO(2) uptake by photosynthesis and release by decomposition and autotrophic respiration. Here we examine CO(2) exchange across seven sites in the Canadian low and high Arctic during the peak growing season (July) in summer 2008. All sites were net sinks for atmospheric CO(2) (NEP ranged from 5 to 67 g C m(-2)), with low Arctic sites being substantially larger CO(2) sinks. The spatial difference in NEP between low and high Arctic sites was determined more by CO(2) uptake via gross ecosystem production than by CO(2) release via ecosystem respiration. Maximum gross ecosystem production at the low Arctic sites (average 8.6 μmol m(-2) s(-1)) was about 4 times larger than for high Arctic sites (average 2.4 μmol m(-2) s(-1)). NEP decreased with increasing temperature at all low Arctic sites, driven largely by the ecosystem respiration response. No consistent temperature response was found for the high Arctic sites. The results of this study clearly indicate there are large differences in tundra CO(2) exchange between high and low Arctic environments and this difference should be a central consideration in studies of Arctic carbon balance and climate change.     

经编菱形网起绒抗静电面料的设计与生

采用涤纶和防静电纤维(Clacarbo导电纱),在卡尔.迈耶经编机上编织以经平组织为主、菱形网组织为辅的经编菱形网起绒抗静电面料,介绍了其编织工艺、染整工艺及技术要点。为了使面料达到理想的抗静电效果,且又能有效降低成本,通过试验比较,选择Clacarbo导电纱含量为2.3%,导电纤维在织物中的间距为1.2 cm。对面料进行抗静电测试,结果表明:该面料具有优良的抗静电性能和良好的柔软舒适效果以及丰富的毛感,可广泛用于保健服、保暖内衣、工作服内里等。     

Study on kinetics of flow characteristics in hot air drying of pineapple

The aim was to evaluate the kinetic parameters, total color differences (?E*) and browning index differences (?BI) of air flow pineapple drying. The experiments were performed on air temperatures at 60 and 70 °C, and air velocities at 1.5 and 2.0 m/s. The kinetic parameter (k) increased when air temperature was increased for all air velocity. The effective diffusivity coefficient (D_eff) increased as high as the temperature of the heating medium. The variation of D_eff of swirling flow was ranging from 6.72?×?10^?9 to 10.23?×?10^?9 m²/s, while the variation of D_eff of non-swirling flow was ranging from 6.40?×?10^?9 to 9.42?×?10^?9 m²/s. The drying time of swirling flow was shorter than non-swirling flow in each drying condition. Moreover, the ?E* and ?BI of pineapple in swirling flow were lower than that obtained from non-swirling flow. Therefore, the convective drying using swirling flow can be minimized for drying time and color deterioration.     

一线双用钢丝热镀锌生产工艺及设备改进

为了能在一条热镀锌生产线上同时生产架空绞线用镀锌钢丝及铠装电缆用热镀锌低碳钢丝,对现有工艺和生产设备做出改进:(1)铠装电缆用热镀锌低碳钢丝离线退火,架空绞线用镀锌钢丝在线脱脂;(2)采用陶瓷材质固定式压线辊;(3)铠装电缆用热镀锌低碳钢丝增加阻力调节装置;(4)选用镍铬-考铜热电偶对退火炉的测温仪器进行改进,测温点位于退火炉的中部。通过上述工艺及设备改进,生产的Ф1.6 mm铠装电缆用钢丝锌层面质量153～178 g/m2,抗拉强度375～440 MPa,扭转40～53次;2.25～2.75 mm绞线用钢丝锌层面质量237～269g/m2,抗拉强度1390～1570 MPa,扭转22～30次,均满足GB/T 3428—2002要求。     

Replacing human-edible feed ingredients with by-products increases net food production efficiency in dairy cows

Global demand for food is increasing, and use of large amounts of potentially human-edible feedstuffs for dairy cows is an important concern. The present study examined whether feeding a by-product-based concentrate combined with high-quality grass silage to high-producing dairy cows affected feed intake and milk production compared with a conventional diet, as well as the effect on efficiency of human food production. In a changeover experiment with four 21-d periods, 24 dairy cows in mid-lactation were offered 9.6 kg of dry matter per day with 1 of 4 concentrates and high-quality grass silage ad libitum. The control concentrate was based on cereal grain (wheat, oat, and barley) and soybean meal, whereas the 3 by-product-based concentrates contained sugar beet pulp in combination with mainly heat-treated rapeseed meal, distillers grain, or a mixture of both. All diets were formulated to be isoenergetic and isonitrogenous. The cows had 10-fold higher starch intake when fed the control diet than when fed the by-product-based concentrates. Silage intake (13 kg of dry matter/d) and milk production (33 kg of energy-corrected milk/d) were not affected by the change in diet. Therefore, replacing cereals and soybean meal with human-inedible by-products in a high-quality forage diet to dairy cows increased net food protein production substantially without lowering milk production.     

澳洲坚果热风干燥特性研究

以澳洲坚果为对象,分别以40,50,60℃对其进行热风干燥,建立3个温度下果壳、果仁、带壳坚果的热风干燥动力学方程,研究干燥过程中果壳、果仁、带壳坚果的干燥特性及果壳和果仁的相互影响.结果表明:温度对澳洲坚果干燥特性的影响非常显著,温度越高.干燥速率越快,干燥周期越短.整个干燥过程只有降速阶段.在干燥初期,坚果含水率的下降主要是因为果壳水分的迅速蒸发,在果壳出现裂纹后,坚果含水率的下降主要是因为果仁水分的蒸发.