Friction and wear behavior of hybrid glass/PTFE fabric composite reinforced with surface modified nanometer ZnO

Nano-ZnO was successfully grafted with 2,4-toluenediisocyanate (TDI) and β-aminoethyltrimethoxylsilane (OB551) to avoid the agglomeration of nano-ZnO in composite. The hybrid glass/PTFE fabric composites reinforced with the untreated, OB551 and TDI modified nano-ZnO, respectively, were prepared by dip-coating of the hybrid fabric in a phenolic adhesive resin containing the nanoparticles to be incorporated and the successive curing. The friction and wear behaviors of various nano-ZnO reinforced hybrid glass/PTFE fabric composites sliding against AISI-1045 steel in a pin-on-disk configuration were evaluated on a Xuanwu-III high-temperature friction and wear tester, with the unfilled one as a reference. The morphologies of the worn surfaces of the composites and of the counterpart pins were analyzed using scanning electron microscopy. In addition, FTIR spectrum was taken to characterize the untreated and treated nano-ZnO. It is found that the untreated and treated nano-ZnO reinforced hybrid glass/PTFE fabric composites exhibit improved wear resistance and friction-reduction in comparison with the unfilled one. The TDI modified nano-ZnO reinforced composite can obtain the best friction and wear performance under different applied load; followed by the OB551 modified nano-ZnO reinforced one. Sliding conditions, such as environmental temperature and lubricating condition, significantly affect the tribo-performances of the unfilled and filled hybrid glass/PTFE fabric composites.     

Wear behavior of Cu–La2O3 composite with or without electrical current

A new type Cu–La₂O₃ composite was fabricated by internal oxidation method using powder metallurgy. Sliding wear behavior of the Cu–La₂O₃ composites was studied by using a pin-on-disk wear tester under dry sliding conditions with or without electrical current, rubbing against GCr15 type bearing steel disk at a constant sliding speed of 20 m/s. The influence of varying applied load and electrical current was investigated. The worn surfaces were examined using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) to determine the wear mechanisms. The results showed the Cu–La₂O₃ composites had an electrical conductivity of 81.9% IACS (International Annealed Copper Standard, 100% IACS = 58 MS/m) and a hardness of HV105. The wear rate of the Cu–La₂O₃ composite pins increased with the increase in the electrical current at high sliding speed. The main wear mechanisms of the Cu–La₂O₃ composites were found to be adhesive wear, abrasive wear and arc erosion.     

纳米和微米SiO2颗粒对PPESK复合材料摩擦学性能的影响

用热压成型法制备了纳米、微米SiO2填充聚醚砜酮(PPESK)复合材料，考察了复合材料的硬度和抗弯强度，并研究了干摩擦条件下纳米、微米SiO2颗粒对复合材料摩擦磨损性能的影响，用扫描电镜观察分析了复合材料磨损表面形貌及磨损机理。结果表明：干摩擦条件下，纳米SiO2填充PPESK主要是轻微的磨粒磨损；而微米SiO2填充PPESK主要是严重的磨粒磨损。     

基于UHMWPE/纳米ZnO复合材料的滑动摩擦磨损机制

用热压成型法制备了超高分子量聚乙烯(UHMWPE)纳/米ZnO复合材料,采用销盘式摩擦磨损试验机考察了载荷和相对滑动线速度对复合材料摩擦学性能的影响;采用扫描电子显微镜观察了复合材料磨损表面形貌。结果表明:在低载荷试验条件下磨损机制为粘着磨损,在高载荷试验条件下磨损机制为粘着磨损和疲劳磨损。而在一定载荷试验条件下,无论相对滑动线速度高或低,复合材料的磨损机制主要表现为粘着磨损,只是在高速情况下粘着磨损程度加大,局部还出现了表面撕裂的痕迹。     

Dry-Sliding Tribological Properties of Bronze–Graphite Composites

Bronze-uncoated and nickel-coated graphite composites were fabricated by powder metallurgy route. The tribological behaviors of composites sliding against AISI52100 steel ball under dry sliding condition were studied using a ball-on-disk tribometer. The nickel-coated graphite composites showed much better tribological properties in comparison with bronze and uncoated graphite composite. The friction coefficient of nickel-coated graphite composites decreased with increasing nickel-coated graphite content. However, the specific wear rate increased with the increase in nickel-coated graphite. The composite containing 15?wt% nickel-coated graphite showed the best self-lubricating properties because the compacted and stable mechanical mixed layer was formed on the worn surfaces. The wear mechanism of bronze 663 is adhesive wear and abrasive wear. The uncoated nickel-coated graphite composite shows the adhesive wear and delamination characteristics. However, the wear mechanism of nickel-coated composites is mildly abrasive wear.     

Tribological behavior of natural fiber reinforced PLA composites

The application spectrum of natural fiber reinforced polymer composites is growing rapidly in various engineering fields. The present study explores the possibilities of reinforcing thermoplastic bio-polymer with locally available inexpensive plant fibers for developing a new tribo-material. Three different types of natural fibers (nettle, grewia optiva and sisal) were incorporated into PLA polymer to develop laminated composites using a hot compression technique. TGA analysis was carried out to investigate the thermal stability of developed composites. Wear and frictional characteristics of developed composites were investigated under dry contact condition at different operating parameters, such as applied load (10–30 N), sliding speed (1–3 m/s) and sliding distance (1000–3000 m). The experimental results indicate that incorporation of natural fiber mats into PLA matrix significantly improves the wear behavior of neat polymer. There was 10–44% reduction in friction coefficient and more than 70% reduction in specific wear rate of developed composites as compared to neat PLA. The worn surface morphology was studied using scanning electron microscope (SEM) to analyze the wear mechanism in different types of developed composites.     

Effect of filler composition and crosslinker concentration on the tribological behavior of spent germ particle-based polymeric composites

Thermosetting composites have been prepared by the use of a biobased resin and spent germ filler, which is a byproduct from a wet ethanol production plant. Microscale tribological measurements were performed on samples with different concentrations of the filler as well as the crosslinker using a ball-on-flat reciprocating microtribometer. Microscale friction and wear behavior during dry sliding were evaluated using a spherical silicon nitride probe (radius 1.2 mm) and a conical diamond (radius 100 μm, cone angle 90°) probe to impose different contact conditions. Finally, a pin-on-disc tribometer was used to study the macroscale wear properties at high loads against an alumina pin. Scanning electron microscopy (SEM) images of wear tracks on the samples were obtained to elucidate deformation mechanisms. All samples showed evidence of abrasive wear in both micro- and macro-scales. It was found that an increase in the concentration of the filler resulted in higher friction coefficients against Si₃N₄, while an increase in the concentration of the crosslinker lowered the abrasive wear depth. These results provide some insight into the effectiveness of using biobased spent germ–tung oil polymer composites as potential tribomaterials.     

纳米ZnO填充的PTFE基复合材料摩擦学性能研究

得胜０００型摩擦磨损试验机研究了不同体积含量的纳米氧化锌（ＺｎＯ）填充的ＰＴＦＥ基复合材料在于摩擦条件下与不风对摩时的摩擦学性能,并利用扫描电子微镜（ＳＥＭ）对ＰＴＦＥ及纳米ＺｎＯ／ＰＴＦＥ复合材料的微观结构、磨损表面和转移膜进行了观察和分析。结果表明,纳米ＺｎＯ／ＰＴＦＥ复合材料的摩擦性能与纯ＰＴＦＥ基本相当,但耐磨性明显优于后者,纳米ＺｎＯ在复合材料中的最佳含量为１５ｖｏｌ．％左右。     

Influence of graphite content on the dry sliding and oil impregnated sliding wear behavior of Al 2024–graphite composites produced by in situ powder metallurgy method

The influence of graphite content on the dry sliding and oil impregnated sliding wear characteristics of sintered aluminum 2024 alloy–graphite (Al/Gr) composite materials has been assessed using a pin-on-disc wear test. The composites with 5–20 wt.% flake graphite particles were processed by in situ powder metallurgy technique. For comparison, compacts of the base alloy were made under the same consolidation processing applied for Al/Gr composites. The hardness of the sintered materials was measured using Brinell hardness tester and their bending strength was measured by three-point bending tests. Scanning electron microscopy (SEM) was used to analyze the debris, wear surfaces and fracture surfaces of samples. It was found that an increase in graphite content reduced the coefficient of friction for both dry and oil impregnated sliding, but this effect was more pronounced in dry sliding. Hardness and fracture toughness of composites decreased with increasing graphite content. In dry sliding, a marked transition from mild to severe wear was identified for the base alloy and composites. The transition load increased with graphite content due to the increased amount of released graphite detected on the wear surfaces. The wear rates for both dry and oil impregnated sliding were dependent upon graphite content in the alloy. In both cases, Al/Gr composites containing 5 wt.% graphite exhibited superior wear properties over the base alloy, whereas at higher graphite addition levels a complete reversal in the wear behavior was observed. The wear rate of the oil impregnated Al/Gr composites containing 10 wt.% or more graphite particles were higher than that of the base alloy. These observations were rationalized in terms of the graphite content in the Al/Gr composites which resulted in the variations of the mechanical properties together with formation and retention of the solid lubricating film on the dry and/or oil impregnated sliding surfaces.     

Comparison of tribological behavior of nylon composites filled with zinc oxide particles and whiskers

Mechanical properties and tribological behavior of nylon composites filled with zinc oxides were investigated in this paper. Different effects of ZnO particles and ZnO whiskers filling on the friction and wear behavior of nylon 1010 (PA1010) composites under dry friction condition were observed. The hardness, tensile strength and scratch coefficients of two kinds of nylon composites filled with the ZnO particles and whiskers were measured. Experimental results show that ZnO particles and ZnO whiskers improve the mechanical and tribological properties of nylon composites without affecting the crystallinity of nylon matrix. Hardness, tensile strength and scratch coefficient of composites are increased by the addition of ZnO particles and ZnO whiskers. Filler shape has little effect on the friction coefficients of nylon-based composites. These composites filled with particles and whiskers have nearly the same friction coefficients which locate between 0.4 and 0.45. The wear rates of composites are strongly dependent on filler shape and filler content. Particle-filled composites exhibit the lower wear rates than whisker-filled composites when the content of filler is lower than 10 wt.%. After that, the case is reversed. Ploughing and adhesion are the main wear mechanisms of composites with the addition of both ZnO particles and ZnO whiskers.     

Tribological Properties of Organic Functionalized ZrB<Subscript>2</Subscript>–Al<Subscript>2</Subscript>O<Subscript>3</Subscript>/Epoxy Composites

The tribological behaviors of epoxy composites filled with organic functionalized ZrB₂–Al₂O₃ were environmentally investigated and compared with those with as-received fillers under both dry and oil sliding conditions in this work. The worn surfaces and the transfer films on the counterparts were characterized by scanning electronic microscope (SEM), and the frictional temperature rising was investigated by infrared thermometer. The results demonstrated that the coefficient of friction (CoF), the wear rate, as well as the frictional temperature rise of the epoxy composites were all decreased due to the introduction of ZrB₂–Al₂O₃ fillers. And with the increase in filler content, similar variation tendencies of CoF and wear rate of epoxy composites were observed under the different sliding conditions. Besides, the organic functionalization of ZrB₂–Al₂O₃ fillers, which made the epoxy composites exhibit lower CoF and wear rate than those with as-received fillers, lowered the frictional temperature as well. In comparison, the epoxy composites filled with 5 vol% modified fillers presented better tribological properties, suggesting a stronger interfacial bonding between modified fillers and epoxy matrix. The dominant wear mechanisms of filled composites under dry and oil sliding conditions could be inferred as the combination of adhesive wear and abrasive wear and the fatigue wear, respectively, on the basis of SEM images of worn surfaces.     

Mechanical and tribological properties of carbon fabric composites filled with several nano-particulates

The carbon fabric composites filled with the particulates of nano-SiO₂, nano-TiO₂, and nano-CaCO₃, respectively, were prepared by dip-coating of the carbon fabric in a phenolic resin containing the particulates to be incorporated and the successive curing. The friction and wear behaviors of the resulting carbon fabric composites sliding against AISI-1045 steel in a pin-on-disc configuration were evaluated on a Xuanwu-III high temperature friction and wear tester. The tensile strength and adhesion strength of the filled carbon fabric composites were determined on a DY35 universal materials test machine. The morphologies of the worn surfaces of the unfilled and filled carbon fabric composites and the transfer films on the counterpart steel pins were analyzed by means of scanning electron microscopy, and the elemental plane distributions on the transfer films were analyzed with an energy dispersive X-ray analyzer (EDAX). It was found that the nano-particles as the fillers contributed to significantly improve the mechanical properties and wear-resistance of the carbon fabric. Nano-CaCO₃ as the filler was the most effective in increasing the wear-resistance, while nano-SiO₂ was the most effective in increasing the friction-reducing ability and mechanical properties. This was because the nano-particulates as the fillers contributed to enhance the bonding strength between the carbon fabric and the adhesive resin. Moreover, the friction and wear properties of the carbon fabric composites were closely dependent on the characteristics of the transfer films formed on the counterpart steel pin surfaces and on the environmental temperature as well. Namely, the differences in the wear-resistance of various filled carbon fabric composites were related to the differences of their transfer films on the counterpart steel pin surface. The wear rates of the composites at elevated temperature above 180 °C were much larger than that below 180 °C, which was attributed to the degradation and decomposition of the adhesive resin at excessively elevated temperature.     

Friction and Wear Behavior of Ultra-High Molecular Weight Polyethylene Sliding Against GCr15 Steel and Electroless Ni–P Alloy Coating Under the Lubrication of Seawater

The friction and wear behavior of ultra-high molecular weight polyethylene (UHMWPE) sliding against GCr15 steel and electroless Ni-P alloy coating under the lubrication of seawater was investigated and compared with that under dry sliding and lubrication of pure water and 3.5 wt.% NaCl solution, respectively. It was found that under the lubrication of aqueous medium, the friction and wear behavior of UHMWPE mainly depended on the corrosion of counterface and the lubricating effect of the medium. Because of serious corrosion of counterface by the medium, the wear rates of UHMWPE sliding against GCr15 under the lubrication of seawater and NaCl solution were much larger than that under other conditions, and such a kind of wear closely related to the corrosion of counterface can be reckoned as indirect corrosive wear. However, when sliding against corrosion-resistant Ni–P alloy under the lubrication of seawater, the lowest coefficient of friction and wear rate of UHMWPE were obtained, owing to superior lubricating effect of seawater. Moreover, periodic ripple patterns were observed on the worn surfaces of UHMWPE sliding against GCr15 under the lubrication of seawater and NaCl solution, which were ascribed to the intelligent reconstruction of surface microstructure of UHMWPE upon large plowing effect of the counterface asperities. Based on scanning electron microscopic (SEM) and three-dimensional (3D) profile analyses of the worn surfaces of UHMWPE, a stick–slip dynamic mechanism was proposed to illustrate the pattern abrasion of UHMWPE. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Wear resistance of composites based on ultrahigh molecular weight polyethylene filled with graphite and molybdenum disulfide microparticles

Tribological characteristics of ultrahigh-molecular-weight polyethylene (UHMWPE)-based compositions with graphite and molybdenum disulfide are studied under conditions of dry friction, boundary lubrication, and abrasive wear. It is shown that, under dry sliding friction, the wear rate of UHMWPE-graphite and UHMWPE-MoS2 polymer compositions is halved as compared to that of pure UHMWP, while their mechanical characteristics change only slightly. Under the conditions of abrasive wear, the wear resistance of these composites increases by 1.3–1.5 times. Concentrations of the fillers, which are optimum for improving the wear resistance, are determined. The supramolecular structure and the topography of worn surfaces of the UHMWPE compositions with various concentrations of the fillers are examined. A comparative analysis of the wear resistance of the composites under conditions of dry friction and lubrication is carried out. Mechanisms of the wear of the UHMWPE-graphite and UHMWPE-MoS₂ polymer compositions under conditions of dry sliding friction and abrasive wear are discussed.     

Wear properties of Saffil/Al,Saffil/Al2O3/Al and Saffil/SiC/Al hybrid metal matrix composites

The purpose of this study is to investigate the wear properties of Saffil/Al, Saffil/Al₂O₃/Al and Saffil/SiC/Al hybrid metal matrix composites (MMCs) fabricated by squeeze casting method. Wear tests were done on a pin-on-disk friction and wear tester under both dry and lubricated conditions. The wear properties of the three composites were evaluated in many respects. The effects of Saffil fibers, Al₂O₃ particles and SiC particles on the wear behavior of the composites were elucidated. Wear mechanisms were analyzed by observing the worn surfaces of the composites. The variation of coefficient of friction (COF) during the wear process was recorded by using a computer. Under dry sliding condition, Saffil/SiC/Al showed the best wear resistance under high temperature and high load, while the wear resistances of Saffil/Al and Saffil/Al₂O₃/Al were very similar. Under dry sliding condition, the dominant wear mechanism was abrasive wear under mild load and room temperature, and the dominant wear mechanism changed to adhesive wear as load or temperature increased. Molten wear occurred at high temperature. Compared with the dry sliding condition, all three composites showed excellent wear resistance when lubricated by liquid paraffin. Under lubricated condition, Saffil/Al showed the best wear resistance among them, and its COF value was the smallest. The dominant wear mechanism of the composites under lubricated condition was microploughing, but microcracking also occurred to them to different extents.     

Sliding/rolling wear performance of plasma nitrided H11 hot working steel

H11 steel discs were tested by considering sliding/rolling friction under dry and lubricated conditions. The H11 discs were plasma nitrided at 500 °C and 550 °C for 9 h. Wear tests were conducted at different slip ratios of 1.79%, 10.53% and 22.22%. The test loads were 100 N, 150 N and 200 N. It was determined that plasma-nitrided H11 discs had a surface hardness of 1200–1400 HV0.1. Plasma nitriding produced wear performance much higher than those of the un-nitrided but hardened samples. The wear mechanism of the plasma-nitrided discs was a mixture of adhesive wear, abrasive wear and plastic yielding.     

Friction and wear behavior of pure carbon strip sliding against copper contact wire under AC passage at high speeds

A series of tests on the friction and wear behaviour of pure carbon strip/copper contact wire with alternating current were conducted on a ring-on-block sliding tester at a high speed. The electric current, normal force and sliding velocity have distinct effects on the test results. The worn scar has the smallest size without electric current. The worn scar becomes larger with increasing electric current. Arc ablation pits, dark stream-lines of arc ablation, slipping marks, spalling blocks and the copper-like layer are found on the worn surfaces. Arc erosion, abrasive wear and adhesive wear are main wear mechanisms.     

Effect of electrical current on tribological behavior of copper-impregnated metallized carbon against a Cu–Cr–Zr alloy

A block-on-slip ring-type wear tester was used to investigate the tribological behavior of copper-impregnated metallized carbon against a Cu–Cr–Zr alloy under 2 to 6 N applied load and 0 to 20 A electrical current. The sliding speed was maintained at 25 km/h. The wear loss of copper-impregnated metallized carbon increased with greater electrical current. Under a certain applied load, the wear loss with electrical current was minimized. The tribo-layer had an apparent effect on the friction coefficient. The wear mechanisms were complex, consisting of adhesive wear, abrasive wear and arc erosion.     

Effect of UHMWPE Microparticles on the Tribological Performances of High-Strength Glass Fabric/Phenolic Laminate Composites Under Water Lubrication

The tribological behaviors of ultra-high molecular weight polyethylene (UHMWPE) microparticle-modified high-strength glass fabric/phenolic laminate composites sliding against stainless steel under water lubrication have been investigated. Results showed that the incorporation of UHMWPE microparticles, especially at the mass fraction of 5.0 %, improved the wear resistance of the laminate composite to a significant extent, because UHMWPE microparticle can effectively absorb and dissipate the friction energy through a plastic deformation during the formation of the regular ripple-like abrasion patterns on its worn surface. During the sliding process, after the phenolic resin was firstly worn off, UHMWPE microparticles with much better wear resistance were protruded from the worn surface of the laminate composite, leading to a fundamental change in the contact status of the matched surfaces from rigid resin and fibers/steel to flexible UHMWPE/steel. As a result, low and steady friction coefficient was obtained due to good adaptability of UHMWPE to water lubrication.     

The abrasive wear resistance of TIC and (Ti,W)C-reinforced Fe–17Mn austenitic steel matrix composites

Pin-on-disc dry sliding wear tests have been carried out to study the wear behaviour of 10 vol% TiC and (Ti,W)C-reinforced Fe–17Mn austenitic steel matrix composites. The composites have been synthesized in situ by means of conventional melting and casting route. It has been observed that the abrasive wear resistance of the composites is higher than that of their unreinforced Fe–17Mn austenitic steel. Compared with the TiC-reinforced composite, the abrasive wear resistance of the (Ti,W)C-reinforced composite is better. The abrasive wear resistance and coefficient of friction of both reinforced and unreinforced materials decrease as the load increases.