Epoxy, ZnO, and PTFE nanocomposite: friction and wear optimization

To lower the friction coefficient and increase the wear resistance of epoxy, nanoparticles of zinc oxide and polytetrafluoroethylene (PTFE) were added in small volume percents to an epoxy matrix. Tribological testing of the samples in this study was completed on a linear reciprocating tribometer with a 250 N normal load and a 50.8 mm/s sliding speed. Several samples were made and tested following a modified Simplex Method optimization procedure in order to find a volume percent for optimized wear resistance and friction coefficient. The sample with the optimum wear rate consisted of 1 volume percent of zinc oxide nanoparticles and 14.5 volume percent of PTFE nanoparticles. It had a wear rate of k = 1.79 × 10⁻⁷ mm³/Nm; 400× more wear resistant than neat epoxy. The sample with the optimum friction coefficient consisted of 3.5 volume percent of zinc oxide nanoparticles and 14.5 volume percent of PTFE nanoparticles and had a friction coefficient of μ = 0.113, which is almost a 7× decrease in friction coefficient from neat epoxy.     

Lubricated wear of PTFE and graphited PTFE

Tribological behaviour of PTFE and graphited PTFE have been evaluated under lubricated conditions and compared with dry wear. The stress selected is in the range of 0.44 to 1.64 MPa, and the data generated are relevant to conformal contacts. Mineral oil lubrication can reduce wear of PTFE by one to two orders of magnitude. With graphited PTFE the lubricant effect is lower in comparison to that observed with PTFE. Specific wear rates are plotted on a histogram.     

Environmental dependence of ultra-low wear behavior of polytetrafluoroethylene (PTFE) and alumina composites suggests tribochemical mechanisms

Composites of polytetrafluoroethylene (PTFE) and alpha phase alumina produce wear rates that can be nearly five orders of magnitude less than the wear rates of virgin PTFE. The mechanism for this reduction in wear cannot be explained solely by mechanical effects. The influences of oxygen and humidity on the tribological performance of both unfilled PTFE and PTFE/alumina composites were studied. The wear rate of PTFE/alumina composites is dependent on the humidity of the environment; this dependence suggests a tribochemical mechanism is responsible for the ultra-low wear behavior of these PTFE/alumina composites.     

Friction and wear of PTFE seal materials

Shaft seals made from polytetrafluoroethylene (PTFE) materials, called PTFE lip seals, have been successfully used for decades in the chemical industry. Owing to their chemical and thermal stability, PTFE lip seals are used instead of elastomeric lip seals in many automotive and hydraulic applications. This paper deals with the fundamental tribological properties and effects of filled PTFE materials employed in rotary shaft seals, mainly on the basis of experimental work done in the authors' laboratory. The tribological components of a sealing system and the main influences on the sealing function are briefly surveyed. The test methods and conditions used are also described. The experimental results show that the fillers used in the PTFE compounds, as well as the topography of the shaft, play a crucial role in fluid sealing.     

Transfer film bonding and wear studies on CuS-nylon composite sliding against steel

The tribological behaviour of nylon 11 reinforced with lead sulphide filler was studied. The composite specimens with different filler proportions were made by compression moulding. The friction and wear experiments were run under ambient conditions in a pin-on-disk machine with the composite pin riding on the flat surface of a steel disk. It was found that 35 vol.% PbS-nylon composite had the highest wear resistance. The friction and wear tests were run with this composite at different loads, speeds and counterface roughnesses. The wear rate increased considerably when the load was increased from 19.6 N to 39.2 N and the sliding speed from 1 m/s to 2 m/s, but the effect of these increases on the coefficient of friction was very small. The wear rate also increased abruptly when the surface roughness was increased from 0.11 to 0.3 μm but the coefficient of friction was not affected. It was found that the wear process was dominated by the transfer film that formed on the counterface. The transfer film and the worn surfaces were studied by scanning electron microscopy. XPS analysis indicated chemical bonding between the polymer composite transfer film and the steel counterface.     

Friction and wear of PTFE composites at cryogenic temperatures

This paper presents investigations on the tribological behaviour of PTFE composites against steel at cryogenic temperatures. The results showed that the friction coefficient decreases with temperature down to 77 K, but did not follow a linear evolution further down to extreme low temperatures. It can be stated that the cryogenic environment has a significant influence on the tribological performance of the polymer composites. The effect of low temperatures was more clearly detected at low sliding speed, where friction heat is reduced. A change in wear mechanism from adhesive to abrasive was observed in this case. SEM and AFM analyses showed that the PTFE matrix composites investigated under these experimental conditions have transferred material onto the disc down to very low temperatures. Chemical analyses indicate the presence of iron fluorides.     

Reduction in wear of metakaolinite-based geopolymer composite through filling of PTFE

Metakaolinite-based geopolymer composite containing 5-30% (volume fraction) polytetra-fluoroethylene (PTFE) was synthesized using compound activator composed of aqueous NaOH and sodium silicate at room temperature. Flexural strength, compressive strength and elastic modulus of the composite were measured. Tribological behaviour of the composite sliding against AISI-1045 steel was investigated on an MM-200 friction and wear tester. SEM, EDS and XPS analysis were conducted on worn surfaces and wear debris. The results show that mechanical strength of the composite was lower than corresponding geopolymer while the wear model became mild. The friction process was stable and the wear rate was dramatically reducted by 86-99.4%. The improvement of tribological properties of the composite was attributed to form a brown soft thin layer on the worn surface of the composite containing Fe₂O₃ came from tribochemical reaction. EDS analysis on the worn surfaces indicate the content of Fe increase along with the increase of volume content of PTFE in the composite. Furthermore, the counterpart, the steel ring was also protected from terrible wear as occurred when friction with geopolymer without any filling of solid lubricant. There is a brown thin layer mainly composed of Fe₂O₃ on the steel ring.     

Friction and wear behaviour of electron beam modified PTFE filled EPDM compounds

The friction and wear of non-modified and electron beam modified polytetrafluoroethylene (PTFE) filled ethylene–propylene–diene–monomer (EPDM) rubber investigated with the help of pin on disk tribometer showed different behaviour during the sliding contact with hard spherical steel-ball. The friction coefficient (μ) and specific wear rate (k) of modified PTFE filled EPDM increased with an absorbed dose of PTFE powder while non-modified PTFE filled EPDM showed the lowest μ and k values. This variation in friction and wear behaviour of PTFE filled EPDM compounds is caused by the influence of radiation induced chemical changes in PTFE powder on the radical initiated peroxide crosslinking. It results from the lower crosslinking efficiency and consequently in the deterioration of the bulk properties. The electron modification of PTFE powder reduces the hardness (modulus) and increases the energy dissipation (tan delta) of compounds. Beside other factors, these variations in bulk properties have been shown to have deleterious effects on the friction and wear properties of electron beam modified PTFE filled EPDM.     

Microstructural modeling of adaptive nanocomposite coatings for durability and wear

Adaptive thin-film nanocomposite coatings comprised of crystalline ductile phases of gold and molybdenum disulfide, and brittle phases of diamond like carbon (DLC) and ytrria stabilized zirconia (YSZ) have been investigated by specialized microstructurally based finite-element techniques. One of the major objectives is to determine optimal crystalline and amorphous compositions and behavior related to wear and durability over a wide range of thermo-mechanical conditions. The interrelated effects of microstructural characteristics such as grain shapes and sizes, local material behavior due to interfacial stresses and strains, varying amorphous and crystalline compositions, and transfer film adhesion on coating behavior have been studied. The computational predictions, consistent with experimental observations, indicate specific interfacial regions between DLC and ductile metal inclusions are critical regions of stress and strain accumulation that can be precursors to material failure and wear. It is shown by varying the composition, resulting in tradeoffs between lubrication, toughness, and strength, the effects of these critical stresses and strains can be controlled for desired behavior. A mechanistic model to account for experimentally observed transfer film adhesion modes was also developed, and based on these results, it was shown that transfer film bonding has a significant impact on stress and wear behavior.     

Dry sliding wear behaviour of PTFE filled with glass and bronze particles

Abstract

The wear behaviour of polytetrafluroethylene (PTFE) filled with 25% glass and 40% bronze particles was studied on a pin on disc test rig. Solid lubricant composite materials were prepared by compression moulding technique. The wear parameters considered for the study were applied load, sliding speed and sliding distance. The experimental results indicate that the weight loss increases with increasing load, sliding speed and sliding distance, as expected. Sliding distance has more effect on weight loss followed by applied load. The 40% bronze+PTFE composite exhibits better wear resistance compared to other types. The dominant interactive wear mechanisms during sliding of PTFE and its composites are discussed in this paper.     

Remarks on the wear of a journal bearing lubricated by a grease containing a powdered PTFE additive

This paper presents the results of tests on wear of a journal bearing lubricated by a grease containing a powdered polytetrafluorethylene (PTFE) additive. The wear of the bearing lubricated by such a grease is initially greater than the wear of the bearing lubricated by the grease without the PTFE additive, but the total wear of the bearing lubricated by the PTFE loaded grease is almost 2.8 times less than the wear on a similar bearing lubricated by the unloaded grease. An explanation of this phenomenon is suggested.     

Friction and wear behavior of self-lubricating and heavily loaded metal–PTFE composites

A new 16 MnNb steel–PTFE composite (A) containing 60% area proportion of PTFE composite was developed. Another type of common solid lubricant embedded C86300 bronze–PTFE composite (B) containing 35% area proportion of PTFE composite was also selected for a comparative investigation under similar testing conditions. Friction and wear experiments were performed in an oscillating sliding tribotester at an oscillating frequency of 0.13 Hz, contact mean pressures from 15 to 80 MPa and counterface roughness of 0.10 μm R_a. The composites A and B slid against a 38CrMoAlA steel shaft. Results showed that the composite A exhibited low coefficient of dry friction and long wear life as compared to that of the composite B. It was found that the surface of PTFE composite was higher than that of steel backing at the intervals of testing. This was because modulus of the elasticity of PTFE composite was much lower than that of 16 MnNb steel backing; under a same load condition the elastic deformation amount of PTFE composite was much bigger than that of steel backing. Thus, the composite A provided sufficient lubrication during the whole tests.     

Effects of humidity on nanometer scale wear of a carbon film

Influence of environmental humidity on scanning-scratched wear tests of a carbon film deposited by electron cyclotron resonance plasma sputtering are evaluated in both air and nitrogen with an atomic force microscope and a diamond tip. Wear depth is larger in higher humidity and also larger in air than in nitrogen. Effect of humidity on scratch load dependence and repeated scanning-scratch tests are larger in nitrogen than in air. Effect of humidity on wear is clearer in the repeated scanning-scratch test than in the scratch load dependence test especially in air, and also clearer at larger scratch load. In scratch velocity dependence test, there is a tendency that wear depth decreases with increase in logarithm of scratch velocity both in air and nitrogen. Wear models to explain the experimental results are discussed.     

A comparison of the relative friction and wear responses of PTFE and a PTFE-based composite when tested using three different types of sliding wear machines

In this work, the tribological behavior of a commercially available polytetrafluoroethylene-based composite material filled with polyimide microparticles has been thoroughly investigated using different approaches. Specifically, two standard tribological tests, i.e., pin-on-disc and thrust washer measurements, have been compared with sliding tests performed on real components using a specially designed lab bench. The obtained results demonstrated that, despite the different testing methods (continuous rotation vs. reciprocating linear movement for the pin-on-disc/thrust washer and sliding tests, respectively), the different techniques provide highly comparable data within the adopted experimental conditions and can be successfully combined to assess the overall tribological features of this PTFE-based polymer composite.     

On dry sliding friction and wear behavior of PPESK filled with PTFE and graphite

Novel poly(phthalazinone ether sulfone ketone) (PPESK) resins have become of great interest in applications such as bearing and slider materials. In this paper, dry sliding wear of polytetrafluoroethylene (PTFE) and graphite-filled PPESK composites against polished steel counterparts were investigated on a block-on-ring apparatus at the same sliding velocities and different loads. The results indicated that the addition of 5–25 wt% PTFE and 5–30 wt% graphite contribute to an obvious improvement of tribological performance of PPESK at room temperature. Worn surfaces were investigated using a scanning electron microscope (SEM). As a result, the friction coefficient and wear rate of the PPESK composites decreased gradually with addition of fillers. A moderately low friction coefficient and specific wear rate were reached when the filler contents were above 20 wt%. The mechanical properties of PPESK composites were also investigated. The tensile and impact strength of PPESK composites decrease slightly as the addition of fillers contents were below 15 wt%.     

Different aspects of the role of wear debris in fretting wear

Two different aspects of the role of oxide wear debris in fretting wear are studied by allowing them to escape from the interface during sliding. This is accomplished by laser surface texturing that forms regular micro-pores topography on the friction surfaces which enables this escape. It is found that the role of oxide wear debris depends on the dominant fretting wear mechanism. Their presence in the interface protects the friction surfaces when the dominant wear mechanism is adhesive and harms the friction surfaces when this mechanism is abrasive. The escape of oxide wear debris into the micro-pores results in up to 84% reduction in the electrical contact resistance of the textured fretting surfaces.     

Influence of PTFE content in PEEK-PTFE blends on mechanical properties and tribo-performance in various wear modes

Few papers are available on the optimum composition of PEEK-PTFE blends for the best possible combination of mechanical and tribological properties in the adhesive wear mode. Nothing is reported in this context on low amplitude oscillating/fretting wear mode. Moreover, the influence of increasing amounts of PTFE in the blend on abrasive wear behaviour along with a correlation with strength properties is not reported. Hence, in this work, five injection-moulded blends of PEEK with PTFE (in the range of 0-30 wt.%) were evaluated on a pin-on-disc configuration on an SRV Optimol Tester for their tribo-behaviour in the low amplitude oscillating wear mode. The data in the abrasive wear mode were generated by abrading a pin loaded against an abrasive paper fitted on the rotating disc. Data on neat PTFE were also included for comparison. It was observed that inclusion of PTFE affected the adhesive wear and low amplitude oscillating wear (LAOW) in a beneficial way. With an increase in PTFE contents, coefficient of friction in both the wear modes (adhesive and low amplitude oscillating) decreased but the trends in wear performance differed. In the adhesive wear mode, the specific wear rate showed minima for 7.5% PTFE inclusion followed by a slow increase for further PTFE addition. In the case of LAOW mode, on the other hand, the wear rate continuously decreased for the selected compositions. The 30% PTFE blend showed excellent combination of μ, wear rate and limiting pressure-velocity (PV) values. Unfilled PEEK proved to be fairly good wear-resistant material but exhibited high μ, a stick-slip tendency and a low PV limit value. Abrasive wear performance of the blends on the other hand, deteriorated with increasing amount of PTFE. Fairly good correlation was observed between the wear rate and product of H and S (H-hardness and S-ultimate tensile strength) rather than Ratner-Lancaster plot (product of S and e, where e is elongation to break).Thus, with increase in PTFE contents, though adhesive and LAOW performance increased substantially, it was at the cost of deterioration in all mechanical properties (except impact strength) and abrasive wear performance.     

Friction and wear properties of metal powder filled PTFE composites under oil lubricated conditions

Four kinds of polytetrafluoroethylene (PTFE)-based composite, pure PTFE, PTFE+30vol.%Cu, PTFE+30vol.%Pb and PTFE+30vol.%Ni composite, were prepared. The friction and wear properties of these metal powder filled PTFE composites sliding against GCr15 bearing steel under both dry and lubricated conditions were studied using an MHK-500 ring-block wear tester. The worn surfaces of the PTFE composites and the transfer films formed on the surface of GCr15 bearing steel were examined using scanning electron microscopy (SEM) and optical microscopy respectively. Experimental results show that the friction and wear properties of the PTFE composites can be greatly improved by liquid paraffin lubrication. The wear of these PTFE composites can be decreased by at least 1 to 2 orders of magnitude compared with that under dry friction conditions, while the friction coefficients can be decreased by 1 order of magnitude, SEM and optical microscopy investigations of the rubbing surfaces show that metal fillers of Cu, Pb and Ni not only raise the load carrying capacity of the PTFE composites, but also promote transfer of the PTFE composites onto the counterfaces, so they greatly reduce the wear of the PTFE composites. However, the transfer of these PTFE composites onto the counterfaces can be greatly reduced by liquid paraffin lubrication, but transfer still takes place.     

Dynamic modelling of wear evolution in rolling bearings

Condition monitoring tools aim to monitor the deterioration process i.e. wear evolution of defects. The wear evolution is quite complex process due to the involvement of several wear and stress concentration mechanisms. Therefore, the purpose of this paper is to provide a dynamic model of wear evolution that considers the topographical and tribological changes over the lifetime. The model suggests the use of multiple force diagrams to simulate the dynamic impact and utilises several models of contact mechanics to estimate the transition points between the wear evolution stages. The simulated results of the developed evolution model are in principal agreement with the experimental results.     

Effect of wear on EHD film thickness in sliding contacts

A theoretical solution to the elastohydrodynamic (EHD) lubrication problem in sliding contacts, which takes into consideration the effect of the change in shape of the gap due to wear on the load‐carrying capacity, is presented. The model of such a contact is based on assumptions of Grubin and Ertel (von Mohrenstein). The resultant dimensionless Reynolds and film profile equations have been solved numerically for a number of cases with several values of thickness of the worn layer. Iteration of the EHD film thickness is performed by means of the secant method. Values of the calculated dimensionless film thickness are presented as a function of dimensionless wear. The conclusions concern the influence of the linear wear on the film thickness in heavily loaded sliding contacts. Copyright © 2006 John Wiley & Sons, Ltd.