共查询到20条相似文献,搜索用时 62 毫秒
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高含硫气藏气-固两相多组分数值模型 总被引:3,自引:3,他引:0
高含硫气藏属于一类特殊高危性气藏,在开发过程中,伴有元素硫的析出、沉积、气相组成变化和沉积硫堆积在孔隙喉道污染地层等特殊现象。一般气藏数值模型没有考虑这些因素的影响,使得基于一般气藏数值模型的数模软件在模拟中不能反映高含硫气藏的开发特性。因此,文章在综合考虑这些因素的基础上,假设析出的固态硫不随气流运移,建立三维气-固两相多组分数学模型,利用Carman Kozeny沉积伤害模型描述硫沉积对地层孔隙度和渗透率的伤害;使用Roberts所提出的硫溶解关系式描述硫在酸气中溶解度变化;应用IMPES方法将数学模型转换为隐式求解压力、显式求解饱和度的数值模型。在模型中,元素硫的质量守恒关系是从“组分”角度来分析的,因为元素硫在单一的气相或固相中不满足质量守恒。该模型能反映高含硫气藏中元素硫的沉积、气藏流体组分随开发的变化以及沉积硫对储层的伤害等 相似文献
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M. Tavakkoli R. Kharrat M. Masihi M. H. Ghazanfari 《Petroleum Science and Technology》2013,31(9):892-902
Abstract In this work, a thermodynamic approach is used for modeling the phase behavior of asphaltene precipitation. The precipitated asphaltene phase is represented by an improved solid model, and the oil and gas phases are modeled with an equation of state. The Peng-Robinson equation of state (PR-EOS) was used to perform flash calculations. Then, the onset point and the amount of precipitated asphaltene were predicted. A computer code based on the solid model was developed and used for predicting asphaltene precipitation data reported in the literature as well as the experimental data obtained from high-pressure, high-temperature asphaltene precipitation experiments performed on Sarvak reservoir crude, one of Iranian heavy oil reserves, under pressure depletion and CO2 injection conditions. The model parameters, obtained from sensitivity analysis, were applied in the thermodynamic model. It has been found that the solid model results describe the experimental data reasonably well under pressure depletion conditions. Also, a significant improvement has been observed in predicting the asphaltene precipitation data under gas injection conditions. In particular, for the maximum value of asphaltene precipitation and for the trend of the curve after the peak point, good agreement was observed, which could not be found in the available literature. 相似文献
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ʯ������Ԥ�ⷽ�� 总被引:1,自引:1,他引:0
油气开采过程中的蜡质和沥青质等固相沉积问题,是目前国内外研究的热点和难点。在油气生产的各个环节,随着温度、压力和轻质组分逸出等热力学条件的变化所产生的有机固相沉积问题,给油气田生产造成了严重的危害;特别是在注气提高采收率过程中,由于相间传质诱发的石蜡和沥青等固相沉积,将会改变油藏岩石的渗透性和润湿性,从而影响采收率的提高和注气开采效果。本采用状态方程描述气相和液相的相态,根据正规溶液理论校正固相混合物的非理想性;将以状态方程为基础的气—液平衡模型和以溶液理论为基础的液-因平衡模型有机地统一,建立了气下液-固三相相平衡热力学模型。将该气-液-固三相相平衡热力学模型应用于某一油气体系的蜡固相沉积模拟研究,模拟结果表明,在温度、压力改变过程中,出现了气液固三相相态转换;压力对石蜡沉积点温度和石蜡沉积量均有一定程度的影响;压力对蜡沉积点温度的影响在低于饱和压力下更为显。 相似文献
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根据实验研究结果,提出了一个可以预测凝析油气体系蜡沉积的热力学模型。该模型把蜡沉积视为多固相过程,沉积出的蜡由几个固相组成,每个固相都由一个拟组分构成,固相之间彼此互不混合。根据这一认识,提出了气- 液- 多固相物料平衡方程。采用适合凝析油气体系计算溶解热经验方程,结合考虑固相沉积的多相闪蒸数值算法,模型能对析蜡量进行量化模拟计算。模型中气- 液相参数通过状态方程计算获得。通过对凝析油蜡沉积的计算表明,用该模型计算蜡的沉积量和析蜡温度与实验结果非常吻合。 相似文献
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气-液-固三相相平衡热力学模型预测石蜡沉积 总被引:20,自引:0,他引:20
在油气开采过程中,当体系的温度、压力或组成等热力学条件发生改变时,油气体系内的蜡质、胶质、沥青质等有机固相物质将会从体系中析出而沉积,给油气田生产带来严重的危害.采用状态方程和溶液理论相结合而建立了能模拟石蜡沉积的气液固三相相平衡热力学模型.根据正规溶液理论描述固相混合物的非理想性,采用状态方程描述气相和液相的相态.运用该模型对某一含气原油进行了蜡固相沉积模拟计算,计算结果表明,压力对蜡沉积有较大的影响,压力对蜡沉积点温度的影响在低于饱和压力下比高于饱和压力下的影响更为显著. 相似文献
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油气体系气-液-固三相相态模拟 总被引:6,自引:0,他引:6
根据油气烃类体系的组成特点和相态特征,提出了气-液-固三相相平衡的计算方法,采用状态方程描述气相和液相的相态变化;而将固相视为非理想的固态溶液,用正规溶液理论来描述其非理想性,实例计算结结表明,该方法适用于石油开采,集输和加工过程中的气,液,固三相相态模拟研究。也可以用于石蜡,沥青等有机固相沉积的研究。 相似文献
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Taraneh Jafari Behbahani 《石油科学(英文版)》2016,13(1):155-166
A powerful method is necessary for thermodynamic modeling of wax phase behavior in crude oils,such as the perturbed-chain statistical associating fluid theory(PC-SAFT).In this work,a new approach based on the wax appearance temperature of crude oil was proposed to estimate PC-SAFT parameters in thermodynamic modeling of wax precipitation from crude oil.The proposed approach was verified using experimental data obtained in this work and also with those reported in the literature.In order to compare the performance of the PC-SAFT model with previous models,the wax precipitation experimental data were correlated using previous models such as the solid solution model and multi-solid phase model.The results showed that the PC-SAFT model can correlate more accurately the wax precipitation experimental data of crude oil than the previous models,with an absolute average deviation less than 0.4 %.Also,a series of dynamic experiments were carried out to determine the rheological behavior of waxy crude oil in the absence and presence of a flow improver such as ethylene–vinyl acetate copolymer.It was found that the apparent viscosity of waxy crude oil decreased with increasing shear rate.Also,the results showed that the performance of flow improver was dependent on its molecular weight. 相似文献
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注气采油是提高原油采收率的主要方式之一,在此过程中准确描述含有沥青质等高分子有机固相物质的油气体系相平衡十分必要。为此,将沉淀的沥青质视为固相,假设标准状态下必须有沥青质沉淀,将标准状态压力和温度引入沥青质固相逸度计算,并同时考虑了标准状态压力和温度对沥青质固相逸度的影响,建立了能模拟沥青质沉淀的气、液、固三相相平衡热力学模型。据该模型计算的结果表明:①能通过比较液相沥青质逸度和固相沥青质逸度大小来判断固相沥青质沉淀的出现。②当注入某油的气体为烃类混合气体时,烃类混合气体的添加使得含沥青质原油的组分发生变化;温度相同时,注气浓度越高,沉淀的压力越大;浓度相同时,温度越低,沉淀的压力越大;当沉淀量一定时,随着注气浓度增加,油品的饱和压力随之增大;相同注气浓度下,当压力高于饱和压力时,随着压力增大,沉淀量减少。③在温度不变的情况下,注入某油的气体为CO2时,其沥青质沉淀量是注CO2浓度的函数且随着CO2浓度的增加,固相(沥青质)的沉淀量不断增大。④在注气驱油过程中,气体的注入极易引发含沥青质原油中沥青质等重质有机物的沉积。 相似文献
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为了优化Q345B低碳钢的表面使用性能,设计相应的药芯焊丝并采用TIG沉积方法制备了Cu基熔覆层,通过OM、SEM、EDS、XRD和显微硬度测试等方法,研究了Cu基熔覆层的微观组织、元素分布、物相组成、界面元素扩散和表面硬度等。结果显示,在成分过冷的影响下,Cu基熔覆层由界面至顶部形成了不同的晶粒形貌。熔覆层主要由FCC结构的Cu-Ni-Cr-Fe固溶体、富Cr析出相和单质C元素组成,其中,由于微观偏析的存在,固溶体内元素分布不均匀,Ni、Fe元素主要富集在枝晶内,在枝晶间浓度较低;富Cr析出相主要以球状或棒状分布在基体上,少量单质C也在基体内均匀分布。研究表明,得益于合金元素的固溶强化和第二相粒子的第二相强化作用,熔覆层平均硬度达到202.8 HV0.1,高于纯铜和Q345B基体。 相似文献
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S. Naseri M. Bahadori J. Rozyn T. Kashiwao 《Petroleum Science and Technology》2013,31(23-24):1875-1882
The precipitation of asphaltene, a polar fraction of crude oil, during oil production has unfavorable impacts on many parts of the petroleum industry. Within the upstream processes, asphaltene precipitation occurs in crude oil, forming solid deposits in the reservoir during enhanced oil recovery operations and natural depletion. This significantly influences the porosity and permeability of the reservoir, reducing the effectiveness of the recovery process. Precipitation and deposition in downstream processes causes noticeable increases in production costs. Therefore, it is essential to predict the amount of asphaltene precipitation based on pressure, temperature and liquid phase composition using a dependable, precise, and robust strategy. However, the experimental measurement techniques used to estimate amounts are expensive and time consuming, while the thermodynamic models available are also somewhat complex. The authors propose an innovative approach for the simple and prompt prediction of asphaltene precipitation, employing an artificial neural network. The results show that the predicted values were in agreement with the experimental data, with the maximum absolute error deviation for the proposed model no more than 2.46%. A comparison of the proposed model with previously presented models highlight the superiority of the model developed in this study. 相似文献
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固相沉积及气-液-固三相相平衡研究发展综述 总被引:1,自引:0,他引:1
对油气田开发过程中的有机固相沉积问题以及沉积的热力学模型作了系统的阐述.从有机固相沉积对油气田开发过程的影响,气-液-固三相相平衡热力学理论研究现状,蜡、沥青沉积机理及数学模型研究,有机固相沉积研究发展趋势这4个方面叙述了有关固相沉积技术的国内外发展现状,并提出了以后研究的主要方向。 相似文献
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??In this paper,a mathematical model of solid phase particles migration ahd precipitation in farination is set up and a solving process is also presented on the basis of analyzing formation damage caused by solid phase particles in drilling fluid and completion fluid invaded in formation.The experiment proved the correctness of this model. 相似文献
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原油中含有大量的高分子有机固相物质,因此,要准确地描述油气体系相平衡,必须对气液固三相相平衡进行研究,在对高分子有机烃类沥青沉降机理有了一定的认识的基础上,提出了大的交互作用系数,可以描述沥青与原油中轻质不相容性的程度。根据对油气烃类混合物体系的一般性认识与提出的沥青组分特征化方法,导出了与之相应的有其自身特殊性的气液沥青三相相平衡物料平衡方程组,用考虑沥青沉降三相闪蒸数值算法,对沥青沉降进行有效的理化模拟计算,此外,结合实例分析,给出了沥青质参考逸度的计算,饱和压力和沉降量的拟合方法。 相似文献
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介绍 了考虑有机固相沉积的三维四相(油相、气相、水相和有机固相)多组分数学模型和三相相平衡热力学模.型。为检验和评估考虑有机固相沉积作用的三维四相(油相、气相、水相和有机固相)多组分模型,在完成油藏流体的高压PVT实验数据相态和沥青沉积实验的三相相平衡拟合计算以后,对一.组长岩心气水交替驱替实验数据进行了数值模拟对比研究工作。研究结果表明,一方面在注气提高原油采收率过程中,有机固相可能在地层中发生沉积,另一方面表明有机固相沉积将会对数值模拟计算结果产生负面影响。改进的多组分数值模拟软件能更好地描述注气过程中油藏流体在孔隙介质中渗流的力学特征和物理化学特征,从而能更准确地认识注气提高原油采收率过程中油藏的开发动态规律。 相似文献