共查询到20条相似文献,搜索用时 15 毫秒
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《国际聚合物材料杂志》2012,61(3):215-229
A novel matrix resin system, poly(keto-sulfide)–epoxy resin, has been developed. The poly(keto-sulfide)s (PKS), based on various ketones, formaldehyde, and sodium hydrogen sulfide (NaSH), were prepared by the reported process. These (PKS) having terminal thiol (–SH) groups were used for curing commercial epoxy resin (i.e., diglycidyl ether of bisphenol A – DGEBA), to fabricate crosslinked epoxy-poly(keto-sulfide) resin glass fiber-reinforced composites (GRC). Various epoxy/hardener (PKS) mixing ratios were used, and the curing of epoxy-PKS has been monitored using differential scanning calorimetry (DSC) in dynamic mode. Based on DSC parameters the GRC of epoxy-PKS were prepared and characterized by thermal and mechanical methods. The variation in resin/hardener ratio led to variations in thermal and mechanical properties. 相似文献
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Okpara Enyioma C. Wojuola Olanrewaju B. Fayemi Omolola E. Oyewo Opeyemi A. Onwudiwe Damian C. 《Journal of Inorganic and Organometallic Polymers and Materials》2022,32(9):3445-3458
Journal of Inorganic and Organometallic Polymers and Materials - Nanocrystalline brownmillerite Ca2Fe2O5 (CFO) has been prepared by sol–gel technique and the samples are presented as CFO1 and... 相似文献
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Tetsuya Tanigami Akio Konishi Tetsunori Ochiai Koji Tanaka Manabu Takahashi Shuji Matsuzawa 《Journal of Inorganic and Organometallic Polymers》2001,11(2):85-104
The structure and thermal properties of poly[bis(-phenoxyethoxy)phosphazene)] (PBPEP) newly synthesized by us were investigated. The crystallization from the melt, the volumetric relaxation in the amorphous phase in the upper vicinity of the glass transition temperature (T
g) and the enthalpy of relaxation of the glass in the lower vicinity of the T
g were shown to be very slow. These slow rates may be related to the low chain mobility due to the bulky side chain. Two kinds of crystal forms, called and forms were found in the melt-crystallized sample. These forms were clearly seen as individual types of spherulites by optical microscopy. The melting temperature of these crystals were analyzed by the Hoffmann–Weeks plot. The so-called T(1) transition that had often been detected in many crystalline polyphosphazenes as the transition from the crystal phase to the mesophase was not observed by x-ray diffraction at elevated temperatures. 相似文献
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P. Kumar P. Mishra S. Sonia 《Journal of Inorganic and Organometallic Polymers and Materials》2013,23(3):539-545
0.5[Ba(Zr0.2Ti0.8)O3]–0.5[(Ba0.7Ca0.3)TiO3]/[BZT–BCT]–polyvinylidene difluoride/[PVDF] 0–3 composites were prepared by uniaxial hot-press method for different volume fractions of BZT–BCT ceramic powder in a PVDF polymer matrix. The structural, microstructural and dielectric properties were investigated and discussed. There was an increase in relative permittivity (εr) and dielectric loss (tan δ) of the composites with increase in the volume fraction of the ceramics. At room temperature and at 1 kHz frequency, 0.25[BZT–BCT]–0.75[PVDF] composite showed a highest relative permittivity (εr) ~41. 相似文献
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A new nonlinear optical crystal [Ca2B5O9]·[H(OH)2] (1) has been synthesized under hydrothermal condition. Compound 1 crystallizes in the monoclinic space group C2 with lattice constants a = 10.111(2) Å, b = 7.754(11) Å, c = 6.198(14) Å, β = 127.04(3)° and Z = 2. The fundamental building block (FBB) of 1 is a [B5O12] unit with two BO3 triangles and three BO4 tetrahedra. 1 was characterized by single-crystal X-ray diffraction, IR and UV–Vis spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) respectively. Also, powder second harmonic generation (SHG) measurements indicate that 1 is phase matchable and displays a SHG response of about 3.5 times that of KDP (KH2PO4). 相似文献
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《国际聚合物材料杂志》2012,61(5):483-498
A new soluble luminescent poly[2-decyloxy-5-(2′,5′-bis(decyloxy)phenyl)-1,4-phenylenevinylene] (DBDP-PPV) is prepared by the dehydrohalogenation of 1,4-bis(bromomethyl)-2-decyloxy-5-(2′,5′-bis(decyloxy)phenyl) benzene (as monomer) in this study. The above monomer bearing decyloxy and 2′,5′-bis(decyloxy)phenyl substituents was prepared via such chemical reactions as alkylation, bromination, and Suzuki coupling reactions. The two asymmetric substituents on the phenylene ring make the DBDP-PPV soluble in organic solvents and eliminate the tolan-bis-benzyl (TBB) structure defects. The structure and properties of the DBDP-PPV are examined by 1H-NMR, FT-IR, UV/Vis, TGA, photoluminescence (PL), and electroluminescence (EL) analyses. The DBDP-PPV film exhibits a PL peak at 519 nm. With the DBDP-PPV acting as a light-emitting polymer, a device is fabricated with a sequential lamination of ITO/PEDOT/DBDP-PPV/Ca/Ag. The EL spectrum of the device shows a maximum emission at 507 nm. The turn on voltage of the device is about 15.6 V. Its maximum brightness is 4.67 cd/m2 at a voltage of 16.8 V. 相似文献
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José E. Báez Ángel Marcos-Fernández Antonio Martínez-Richa Plácido Galindo-Iranzo 《Polymer-Plastics Technology and Engineering》2017,56(8):889-898
α,ω-Hydroxy telechelic poly(ε-caprolactones) were prepared by ring-opening polymerization of the ε-caprolactone catalyzed by ammonium decamolybdate in the presence of different aliphatic diols [HO–(CH2)m–OH, where m?=?2, 4, 6, 8, 10, 12, 14, and 16] as initiators to obtain a family of α,ω-hydroxy telechelic poly(ε-caprolactone) [HO–PCL–O–(CH2)m–O–PCL–OH, m?=?2, 4, 6, 8, 10, 12, 14, and 16]. The content of the alkyl group (AG) (–(CH2)m–) had an important effect on the crystallinity (xi) of α,ω-hydroxy telechelic poly(ε-caprolactone), showing a proportional relationship. In poly(ester-urethanes) derived from α,ω-hydroxy telechelic poly(ε-caprolactones) and 1,6-hexamethylene diisocyanate, the AG also showed a similar effect on the xi and eventually on the mechanical properties, increasing the values of the modulus. Therefore, AG content was a factor to induce a plastic behavior in poly(ester-urethanes). The effect of AG on the water uptake of poly(ester-urethanes) after 1 week was negligible. 相似文献
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Jyh-Hong Wu Chien-Wen Chen Chen-Wei Chen Yu-Lun Hsu Ping-Hung Kuan 《Polymer-Plastics Technology and Engineering》2013,52(9):877-884
The objective of this study is to fabricate the PLA/α-cellulose composites and to investigate the effect of α-cellulose short fibers on the toughness improvement of PLA. To homogeneously disperse the polar α-cellulose in the non-polar PLA matrix, the as-received α-cellulose was subjected to surface modification using stearic acid to impart the hydrophobic characteristics to the short fibers. The α-cellulose fibers dispersed more homogeneously in PLA through this modification, and consequently, the fiber pull-out and longer micro-crack length could improve the toughness and damping property of the resulting PLA composites. The inclusion of α-cellulose short fibers considerably decreased the spherulite dimension of the PLA/α-cellulose composites to accommodate larger deformation through grain boundary sliding. The PLA/α-cellulose composite improved its toughness by three times that of the neat PLA with low α-cellulose content (~4 wt.%), and maintained its transparency. 相似文献
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Lan Cao Mitchell A. Winnik Ian Manners 《Journal of Inorganic and Organometallic Polymers》1998,8(4):215-224
The novel block copolymers, polystyrene-b-poly(ferrocenylphosphine) and polyisoprene-b-poly(ferrocenylphosphine), were synthesized by anionic polymerization, utilizing the living organic anions to initiate the ring-opening polymerization of a phosphorus-bridged [1]ferrocenophane. The resulting block copolymers possess narrow polydispersities and have potentially coordinating phosphorus sites in the polymer backbone. These materials are of interest as precursors to metallized self-assembled nanoscale architectures. 相似文献
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Zhao-Xi Wang Bao-Lin Liu Jun Wang You Song 《Inorganic chemistry communications》2009,12(12):1179-1181
An octacyanotungstate(V)-manganese(II) bimetallic assembly [Mn(Me2-bipy)2]3[W(CN)8]2·9H2O (1) (Me2-bipy = 4,4′-dimethyl-2,2′-bipyridine) was synthesized in methanol and characterized by X-ray crystallography. X-ray analysis shows that complex 1 is a neutral, one-dimensional (1D) infinite chain polymer. Magnetic data analysis demonstrates a long-range magnetic interaction and two different antiferromagnetic coupling constants obtained by fitting between Mn and W ions in 1. 相似文献
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《国际聚合物材料杂志》2012,61(10):803-814
Aniline (ANI) was polymerized under inert atmosphere in the presence and absence of natural clay initiated by peroxydisulphate (PDS) in an aqueous acidic medium. While increasing the amount of clay the rate of polymerization (Rp) was decreased and showed first order dependence with respect to amount of clay. The % yield was also decreased while increasing the amount of clay due to the confinement of monomer radical cation by the clay. The FTIR spectrum confirmed the presence of benzenoid and quinoid units in the polyaniline (PANI) structure. DSC inferred the absence of Tm due to cross-linking reaction of PANI because of de-doping process. AFM showed the distorted spherical morphology of uniformly dispersed clay platelets in the PANI. The % weight residue remain above 700°C is increased with the increase of amount of clay, which was confirmed by TGA method. Due to confinement effect the intrinsic viscosity value of PANI—nanocomposites were decreased with the increase of amount of clay in the system. PANI-nanocomposites showed improved d.c. conductivity value than the pristine PANI. Suitable mechanism was proposed to explain the experimental results obtained. 相似文献