电铸制备SiC颗粒增强镍基复合材料的工艺与性能

采用电铸技术(氨基磺酸镍电铸液)成功制备了SiC颗粒增强镍基复合材料;用Leica Qwin图形分析软件和显微硬度计分析了电铸工艺参数对SiC颗粒增强镍基复合材料中SiC颗粒含量以及SiC含量对该复合材料显微硬度的影响;用场发射扫描电镜分析了复合材料的截面形貌和SiC分布.结果表明:在SiC加入量50 g·L-1、电流密度3 A·dm-2和磁力搅拌强度1.5次/min条件下,复合材料中SiC颗粒体积分数达到最高值27%,其显微硬度值也最高,为710 HV.     

SiC颗粒增强铝基复合材料的制备及性能

利用粉末冶金法制备出了SiC颗粒增强铝基复合材料(SiCp/Al),研究了SiC颗粒添加量对复合材料布氏硬度、抗拉强度及显微结构的影响。结果表明:SiC颗粒在基体材料中分布均匀,界面清晰;SiCp/Al复合材料的硬度与抗拉强度随SiC颗粒含量的增加先升高后降低,在SiC颗粒添加量为7 Wt%时,硬度与抗拉强度达到最大值,分别为89.4HBS与311MPa。     

挤压铸造SiCp/2A50铝基复合材料的组织和力学性能研究

研究了在常规铸造工艺下使用挤压铸造方法制备SiC颗粒增强2A50的复合材料,分析了复合材料及增强相的微观组织,检测复合材料的室温力学性能,并探讨复合材料中SiC的强韧化机理以及SiC颗粒体积分数对力学性能的影响。研究表明,使用挤压铸造工艺制备的材料力学性能明显高于铝合金基体;SiCp/2A50复合材料力学性能的提高是位错强化、界面强化和时效强化等机制共同作用的结果;SiCp颗粒的体积分数应控制在20%左右,才能提高复合材料的力学性能。     

超高强7090/SiCP复合材料的组织和性能

对喷射共沉积7090/SiCP复合材料坯经过挤压及不同热处理后棒材的微观组织和力学性能进行了研究,对其热处理工艺进行了确定.结果表明复合材料坯经挤压后组织细小均匀,SiC颗粒均匀分布;采用470℃×1 h+490℃×1 h的双级固溶处理及120℃×28 h时效后,挤压棒材的抗拉强度可达785 MPa,弹性模量超过100GPa;双级固溶+时效复合材料的力学性能明显优于单级固溶+时效态的力学性能;复合材料的断裂主要是由SiC颗粒断裂和界面脱粘引起.     

SiC颗粒表面处理对SiC/Cu复合材料性能的影响

将SiC颗粒在1 100℃和空气气氛下锻烧6 h得到氧化态的SiC颗粒,在5%HF酸中浸泡24 h得到酸洗过的SiC颗粒;然后采用非均相沉淀包裹法制得铜包裹不同状态SiC复合粉体,采用热压烧结工艺制备了含有35%SiC(体积分数)的SiC/Cu复合材料;对复合材料的微观结构和性能进行了研究和分析。结果表明:与原始态SiC颗粒的复合材料相比,对SiC颗粒进行高温氧化和酸洗后使得SiC/Cu复合材料具有不同的界面结合状态,均能提高复合材料的强度和硬度,酸洗态SiC颗粒制备的复合材料强度和硬度均最高。     

SiCp／ZL101复合材料的性能研究

采用液态搅拌法制备SiCp／ZL101复合材料,研究了SiC颗粒含量对材料抗拉伸强度和硬度的影响规律,同时还研究了固溶温度和时效温度对材料硬度的影响规律。结果表明,在本试验的SiC颗粒含量范围内,SiC颗粒含量越高,SiCp／ZL101复合材料的抗拉强度越高,伸长率越低;在排除缺陷等外来影响因素的条件下,SiCp／ZL101复合材料的硬度随着SiC含量的增加而提高。     

真空热压烧结SiC_p/Al复合材料的界面元素扩散及增强断裂机理

采用真空热压粉末冶金烧结工艺制备了含SiC颗粒体积分数分别为 5 %、15 %和 2 5 %的SiC颗粒增强铝基复合材料 ,结合其力学性能、扫描电镜和界面微区能谱分析结果 ,分析了SiC/Al复合材料的真空烧结过程中的界面现象 ,以及材料增强和断裂机理。结果表明 ,真空烧结过程中出现了界面反应 ,改善了界面结合强度 ,断裂破坏主要在基体上进行。随着SiC粒子体积分数的增加 ,SiCp/Al复合材料的抗拉强度增加 ,弹性模量显著增加 ,延伸率降低 ,材料脆性增加。     

SiC粒径对铜基复合材料载流磨损性能影响

采用粉末冶金法制备不同SiC粒径改性的SiC/C/Cu复合材料,研究SiC颗粒大小对材料组织结构和物理性能的影响;在载流摩擦磨损试验机上进行载流磨损试验,研究不同滑动速度下,SiC粒径对材料磨损率的影响。结果表明：在SiC/C/Cu复合材料中小颗粒SiC偏聚于C/Cu界面处,而大颗粒SiC均卡嵌在铜基体内,并且随着SiC颗粒的增大,复合材料硬度和密度稍有增加,孔隙率迅速降低,导电率增加;在较低滑动速度下,复合材料的磨损量随SiC粒径增大不断降低;在较高滑动速度下,随SiC粒径增大,复合材料的磨损率先降低后升高,25 μm SiC改性的复合材料具有最低的磨损率。     

SiC粒径对铜基复合材料载流磨损性能的影响

采用粉末冶金法制备不同SiC粒径改性的SiC/C/Cu复合材料,研究SiC颗粒大小对材料组织结构和物理性能的影响;在载流摩擦磨损试验机上进行载流磨损试验,研究不同滑动速度下,SiC粒径对材料磨损率的影响。结果表明:在SiC/C/Cu复合材料中小颗粒SiC偏聚于C/Cu界面处,而大颗粒SiC均卡嵌在铜基体内,并且随着SiC颗粒的增大,复合材料硬度和密度稍有增加,孔隙率迅速降低,导电率增加;在较低滑动速度下,复合材料的磨损量随SiC粒径增大不断降低;在较高滑动速度下,随SiC粒径增大,复合材料的磨损率先降低后升高,25μmSiC改性的复合材料具有最低的磨损率。     

SiC和WS2颗粒协同改性铜/聚酰亚胺树脂基复合材料的摩擦磨损性能

采用粉末冶金法制备了总质量分数为20％SiC与WS2的铜/聚酰亚胺树脂基复合材料,WS2和SiC质量比分别为1:3,3:5,1:1,5:3,3:1,研究了固体润滑剂WS2与增强相SiC质量比对复合材料微观形貌和摩擦磨损性能的影响.结果表明:当WS2与SiC质量比为3:5时,复合材料中开始形成以WS2颗粒为核、SiC颗粒...     

钙和锶对Mg_2Si/AZ91D复合材料组织和性能的影响

将铝-硅合金加入到AZ91D镁合金中,制备了原位合成Mg2Si/AZ91D复合材料,并研究了添加钙和锶对于复合材料铸态组织和力学性能的影响。结果表明:硅的加入在AZ91D镁合金中生成了高熔点、高硬度的Mg2Si强化相,但尺寸较大;元素钙和锶的综合作用可以显著细化复合材料基体的铸态组织,同时还可以明显改善Mg2Si的形态和分布,提高复合材料的强度。     

Effect of Wettability Enhancement of SiC Particles on Impact Toughness and Dry Sliding Wear Behavior of Compocasted A356/20SiCp Composites

In this study, the effect of wettability improvement of SiCp on the impact and sliding wear behavior of A356/20 wt% SiCp composites produced by a compocasting technique has been investigated. The result showed an increase of incorporation and uniform distribution of SiCp in the A356 matrix by elimination of SiCp segregation. Desired bonding between SiCp and the aluminum matrix due to improved wettability resulted in enhanced properties in terms of improved impact toughness and wear resistance. This improvement was also associated with partial refinement of coarse eutectic silicon due to increased incorporation and distribution of SiCp reinforcements. The highest enhancement was obtained when 1% Mg was added into the melt in addition to pretreated SiCp. The impact toughness value increased by 10 and 26% and the wear rate decreased by 5 and 30% when the SiC was treated and when Mg was added, respectively, compared to as-received SiCp. The impact fracture surfaces showed fewer decohered and well-bonded SiC particles in A356–(SiC-treated-Mg) composite. The highest wear resistance of A356/SiCp composites was achieved by A356–(SiC-treated-Mg) composite for applied loads of 10 and 20 N compared to other fabricated composites. The worn surface revealed mild abrasion and adhesion wear mechanisms.     

SiCp/Cu复合材料的显微组织和力学性能

采用非均相沉淀包裹法制得铜包SiC复合粉体,利用热压烧结工艺制备了含有体积分数为20%～65%SiC颗粒的SiCp/Cu复合材料.用X射线衍射仪、扫描电镜、能谱分析等测试方法对试样进行了成分和微观形貌分析.结果表明:包裹法制得的SiCp/Cu复合材料中基体铜形成连续的结构,SiC分散较均匀;随着SiC含量的增加,试样孔隙率提高,抗弯强度下降;而硬度则先增后降,并在SiC体积分数为35%时出现最大值;所有试样均表现为脆性断裂.     

喷射沉积SiC_p/Al-20Si复合材料高周疲劳行为研究

采用喷射沉积法制备15%(体积分数)4.5 m SiCp/Al-20Si复合材料及其基体合金,研究该组材料的微观组织、力学性能、高周疲劳性能以及疲劳断口形貌。结果表明:SiC颗粒的加入有利于提高材料的力学性能;复合材料及其基体的高调疲劳寿命随应力幅值的减小而增加,在相同应力幅值下,复合材料的疲劳寿命远远高于基体合金。疲劳裂纹从大颗粒的初晶Si的断裂以及Si相脱离处形核,并开始扩展。对于复合材料而言,SiC颗粒尺寸较小,不容易发生断裂,在形核过程中,当裂纹遇到SiC颗粒时,裂纹或者避开增强体,或者受阻于SiC颗粒,只能在基体合金中扩展,从而扩大了疲劳形核区的面积,提高了材料的疲劳寿命。Si颗粒的脱离、Si相的断裂以及SiC颗粒与基体界面的脱粘是复合材料疲劳断裂失效的主要机制。     

等温变形参数对15％SiC颗粒增强铝基复合材料组织性能的影响

研究了15％SiC铝基复合材料等温变形后的显微组织和室温拉伸性能的变化,得出结论为在经过等温变形后晶粒有一定的变化,但程度较小,变形速度加快时SiC颗粒的分布出现局部的聚集现象;而拉伸性能随总变形量的增大而提高,变形温度升高和变形速度加快时拉伸性能降低,而变形火次的影响很小。     

Producing of AZ91/SiC composite by friction stir processing (FSP)

Friction stir processing (FSP) was used to fabricate SiC/AZ91 composite layer. Effect of process parameters such as rotational and traverse speeds, tool penetration depth and tilt angle on the formation of defects such as cracks, tunnelling cavity and also on sticking of matrix material to the tool was investigated. Also, effect of these parameters was studied on the mechanical properties and microstructures of specimens. Microstructure studies were carried out by optical and SEM. Results showed that FSP is an effective process to fabricate SiC/AZ91 composite layer with uniform distribution of SiC particles, good interfacial integrity and significant grain refinement. Increasing the rotational speed leads to a decrease in the grain size and an increase in the traverse speed leads to a decrease in the grain size. There are upper and lower limitations for these speeds which were determined. PD is a more effective parameter to produce sound surface layer. PD value was affected by traverse and rotational speeds and the tilt angle values. This study shows that by using 5 μm SiC particles, the stir zone grain size reduces from 150 to 7.17 μm and stir zone hardness increases from 63 to 96 Hv.     

Fabrication of Carbon Nanotubes and Rare Earth Pr Reinforced AZ91 Composites by Powder Metallurgy

It can be known from a large number of research results that improving the dispersibility of CNTs can effectively opti-mize the mechanical properties of the corresponding metal matrix composites.However,the crucial issue of increas-ing the bonding of CNTs and the matrix is still unsolved.In this paper,a novel method was developed to increase interfacial bonding strength by coating titanium oxide(TiO2)on the surface of CNTs.The rare earth Pr and TiO2@CNTs-reinforced AZ91 matrix composites were successfully fabricated by powder metallurgy.Hot press sintering and hot extrusion of the milled powder was performed.After hot extrusion,the influence of TiO2@CNTs on the microstruc-ture and mechanical properties of the composites were investigated.The results showed that the coating process can improve the distribution of CNTs in Mg alloy.The CNTs refined the grains of the matrix,and the CNTs were presented throughout the extrusion direction.When the TiO2@CNTs content was 1.0 wt.％,the yield strength(YS),ultimate ten-sile strength(UTS),and elongation of the alloy attained maximum values.The values were improved by 23.5％,82.1％,and 40.0％,respectively,when compared with the AZ91 alloy.Good interfacial bonding was achieved,which resulted in an effective tensile loading transfer at the interface.CNTs carried the tensile stress and were observed on the tensile fracture.     

高体积分数SiCp脚复合材料高速铣削力影响因素研究

通过PCD刀具高速铣削高体积分数SiCp／A1复合材料试验,研究了铣削速度、进给量、铣削深度和铣削宽度对三向铣削分力的影响,并进行了SiCp／A1复合材料基体材料的铣削力对比。研究结果表明,进给量和铣削深度对三向铣削分力的影响较大,而铣削速度和铣削宽度对三向铣削分力的影响较小,并且SiC颗粒增加了材料的强度,使三向铣削分力数值增大。在只考虑控制铣削力大小的情况下应选取适中的铣削参数,如铣削速度、较大的铣削宽度和较小的进给量及铣削深度。     

SiC颗粒增强镁-锌-锆基复合材料的阻尼性能

采用热压烧结法制备了三种不同成分的SiC颗粒增强镁-锌-锆基复合材料,使用LMR-1型低频力学弛豫谱测试系统研究了铸态镁-锌-锆合金及热压烧结SiCp/镁-锌-锆基复合材料的阻尼性能随频率和温度的变化关系.结果表明:SiC颗粒的加入使复合材料的阻尼性能比基体合金有显著提高;另外随着合金中锌含量的增加,复合材料的内耗值不断下降;在频率为3×10-3～7Hz范围内,基体合金及复合材料的内耗值均随着频率的增加先快速减小随后又逐渐增大;在本试验条件下SiCp/Mg-0.93%Zn-0.70%Zr基复合材料的内耗值最大,该复合材料在50～100℃的温度范围内出现弛豫内耗峰.