Flame-vortex interaction and mixing behaviors of turbulent non-premixed jet flames under acoustic forcing

This study examines the effect of acoustic excitation using forced coaxial air on the flame characteristics of turbulent hydrogen non-premixed flames. A resonance frequency was selected to acoustically excite the coaxial air jet due to its ability to effectively amplify the acoustic amplitude and reduce flame length and NO_x emissions. Acoustic excitation causes the flame length to decrease by 15% and consequently, a 25% reduction in EINO_x is achieved, compared to coaxial air flames without acoustic excitation at the same coaxial air to fuel velocity ratio. Moreover, acoustic excitation induces periodical fluctuation of the coaxial air velocity, thus resulting in slight fluctuation of the fuel velocity. From phase-lock PIV and OH PLIF measurement, the local flow properties at the flame surface were investigated under acoustic forcing. During flame-vortex interaction in the near field region, the entrainment velocity and the flame surface area increased locally near the vortex. This increase in flame surface area and entrainment velocity is believed to be a crucial factor in reducing flame length and NO_x emission in coaxial jet flames with acoustic excitation. Local flame extinction occurred frequently when subjected to an excessive strain rate, indicating that intense mass transfer of fuel and air occurs radially inward at the flame surface.     

Time-averaged characteristics of a reacting fuel jet in vitiated cross-flow

This paper describes an experimental study of reacting jets in a high-temperature (1775 K) vitiated crossflow at 6 atm. We present an extensive data set based on high speed chemiluminescence imaging and exhaust gas sampling showing the characteristics of the time-averaged trajectory, width of the flame, flame standoff (or ignition) location, and NO_x emissions over a momentum flux ratio range of 0.75 < J < 240. Key observations are: (1) Depending upon ignition times, reaction can initiate uniformly around the jet, initiate on the leeward side of the jet and spread around to the windward side farther downstream, or initiate further downstream. (2) The time-averaged trajectory generally follows nonreacting trajectories, but penetrates further in the far-field than for what would be expected of a nonreacting jet. (3) The width of heat release zone increases monotonically with downstream location, J, and flame flapping amplitude, but seems to be dominated by the size of the counter-rotating vortex pair. (4) The measured ignition locations were of the same order of magnitude as values based on calculated ignition time scales and mean jet exit velocities, but with some additional variability. (5) The incremental NO_x emissions were controlled primarily by the global temperature rise associated with burning the jet fuel (for the fixed crossflow conditions studied here), and the NO_x emissions increased roughly linearly with the temperature rise.     

Formation of soot and nitrogen oxides in unsteady counterflow diffusion flames

The formation of pollutant species in turbulent diffusion flames is strongly affected by turbulence/chemistry interactions. Unsteady counterflow diffusion flames can be conveniently used to address the unsteady effects of hydrodynamics on the pollutant chemistry, because they exhibit a larger range of combustion conditions than those observed in steady flames.In this paper, unsteady effects on the formation of soot (and its main precursors) and nitrogen oxides (NO_x) are investigated by imposing harmonic oscillations on the strain rate of several counterflow diffusion flames fed with propane. Numerical results confirm that the dynamic response of each species is strongly affected by the strain rate oscillations and the characteristic time governing its chemistry. At low frequencies of imposed oscillations the soot and NO_x profiles show strong deviations from the steady-state profile. At large frequencies a decoupling between the concentration and the velocity field is evident. In particular, the formation of soot and NO_x is found less sensitive to velocity fluctuations for flames with large initial strain rate. The significant increase of soot and NO_x concentrations in unsteady conditions appears to be a function of both forcing frequency and flame global strain rate. Moreover, the cut-off frequency, defined as the minimum frequency above which the strain rate oscillations have negligible effects on the formation of each species, was found to be strongly dependent on the chemical characteristic time and the flame global strain rate, but only marginally affected by the amplitude of imposed oscillations.     

Development of energy efficient porous medium burners on surface and submerged combustion modes

Two compact premixed LPG burners based on submerged and surface combustion modes in porous medium (abbreviated as MSB and SSB respectively) are developed and their combustion and emission characteristics are compared to those of the CB (conventional burner). The preheating and reaction zones of MSB are made from porcelain form and Alumina spheres of 30 mm size, respectively, and the corresponding zones in SSB are made from Alumina (Al₂O₃) foams of pore densities 26 ppcm and 8 ppcm. NO_x emission is reduced by 76% and 75% by the use of MSB and SSB, respectively, compared with the CB, with acceptable CO and SO₂ emissions. For a thermal load of 0.62 kW, the thermal efficiencies of CB, MSB and SSB are estimated to be 47%, 59% and 71%, respectively.     

A numerical study on NOx formation in laminar counterflow CH4/air triple flames

Formation of NO_x in counterflow methane/air triple flames at atmospheric pressure was investigated by numerical simulation. Detailed chemistry and complex thermal and transport properties were employed. Results indicate that in a triple flame, the appearance of the diffusion flame branch and the interaction between the diffusion flame branch and the premixed flame branches can significantly affect the formation of NO_x, compared to the corresponding premixed flames. A triple flame produces more NO and NO₂ than the corresponding premixed flames due to the appearance of the diffusion flame branch where NO is mainly produced by the thermal mechanism. The contribution of the N₂O intermediate route to the total NO production in a triple flame is much smaller than those of the thermal and prompt routes. The variation in the equivalence ratio of the lean or rich premixed mixture affects the amount of NO formation in a triple flame. The interaction between the diffusion and the premixed flame branches causes the NO and NO₂ formation in a triple flame to be higher than in the corresponding premixed flames, not only in the diffusion flame branch region but also in the premixed flame branch regions. However, this interaction reduces the N₂O formation in a triple flame to a certain extent. The interaction is caused by the heat transfer and the radical diffusion from the diffusion flame branch to the premixed flame branches. With the decrease in the distance between the diffusion flame branch and the premixed flame branches, the interaction is intensified.     

The mechanisms of flame stabilization and low NOx emission in an eccentric jet pulverized coal combustor

The mechanisms of flame stabilization and low NO_x emission features of an eccentric jet pulverized coal combustor were studied through numerical modelling and experimental investigation. The results show that the formation of the unique flowfield structure is closely related to the interaction among combustor configuration, the primary jet and the control jet; and that certain rules should be followed in order to obtain the optimum condition for flame stabilization. The distributions of temperature and concentrations of NO, O₂, CO and CO₂ inside the combustor were experimentally measured. The effects of structural and operational parameters on combustion and NO formation were studied. It was found that reduction of primary air, suitable use of control jet and reasonable uptilt angle of the primary jet all contributed to the reduction of NO_x at the combustor exit. A new hypothesis, that reasonable separation of oxygen and fuel within the fuel-rich zone is beneficial to further reduction of NO_x emission, is given. The study showed that good compatibility existed between the capability of flame stabilization and low NO_x emission for this type of combustor. This project was supported by the National Natural Science Foundation of China     

Acoustic excitation effect on NOx reduction and flame stability in a lifted non-premixed turbulent hydrogen jet with coaxial air

The effects of acoustic excitation on the reduction in nitric oxidant (NO_x) emission were experimentally investigated in non-premixed lifted hydrogen jet flames with coaxial air. The purpose of the present work was to analyze the acoustic forcing effect on the flow field, the reaction zone, and NO_x emission, and to study the mechanisms of NO_x reduction and flame stabilization. To analyze of the flow field, a PIV method was used that incorporated two Nd-YAG lasers and a CCD camera. The reaction zone was visualized by taking OH* chemiluminescence images with a 307.1 ± 5 nm narrow band pass filter and an ICCD camera. A flow condition was carefully selected at u_F = 150, 200, 250 m/s and u_A = 12, 16, 20 m/s, which was sustainable for acoustic excitation in a lifted flame region. The frequency was swept from 150 to 1000 Hz in 5 Hz steps. From the measurements of the flow field, the reaction zone, and NO_x emission, we concluded that NO_x emission was reduced and minimized at the resonance frequency. The vortex that was generated by acoustic forcing promoted air entrainment and enhanced the fuel-air mixing rate. This premixing effect resulted in a lower flame temperature, and thus lower NO_x emissions. In addition, the liftoff height periodically fluctuated due to the stretch effect as the vortex interacted with the flame base.     

Experimental flow field characteristics of OFA for large-angle counter flow of fuel-rich jet combustion technology

In this paper, the flow field characteristics of over fired air (OFA) for novel low NO_x pulverized coal combustion technology are studied. The research was conducted with a 300 MWe tangential firing boiler that was adapted for this technology, and a three-dimensional particle-dynamics anemometer (PDA) was employed on the model to measure the characteristics of gas flow in the burnout area and gas/particle flows under the front panel superheater. The impact of a positive offset at 15°, counter offset at 15° and design case without an offset the OFA relative to the direction of the secondary air jet in the main combustion were considered. With different OFA offsets, the deflection characteristics, the velocity and root mean square (RMS) fluctuation velocity of OFA jet are obtained, as well as the gas/particle flows characteristics under the front panel superheater. The results show that, with a positive offset, an over-large tangential circle is formed, which produces slagging and temp-bias under the panel superheater. However, with a counter offset, the OFA is sent into the center of the chamber, and the particle is forced to the water wall. Compared with the other two conditions and combined with the counterflow of primary air, OFA without an offset for the jet contains a proper tangential circle, strong inflexibility and turbulence, which prevents slagging and burn out.     

Numerical study on NOx/CO emissions in the diffusion flames of high-temperature off-gas of steelmaking converter

The combustion of high-temperature off-gas of steelmaking converter with periodical change of temperature and CO concentration always leads to CO and NO_x over-standard emissions. In the paper, high-temperature off-gas combustion is simulated by adopting counterflow diffusion flame model, and some influencing factors of CO and NO_x emissions are investigated by adopting a detailed chemistry GRI 3.0 mechanism. The emission index of NO_x (EINO_x) decreases 1.7–4.6% when air stoichiometric ratio (SR) increase from 0.6 to 1.4, and it dramatically increases with off-gas temperature at a given SR when the off-gas temperature is above 1500 K. High-concentration CO in off-gas can result in high NO_x emissions, and NO_x levels increase dramatically with CO concentration when off-gas temperature is above 1700 K. Both SR and off-gas temperature are important for the increase of CO burnout index (BI_CO) when SR is less than 1.0, but BI_CO increase about 1% when off-gas temperature increases from 1100 K to 1900 K at SR > 1.0. BI_CO increases with CO concentration in off-gas, and the influence of off-gas temperature on BI_CO is marginal. BI_CO increases with the relative humidity (RH) in air supplied, but it increases about 0.5% when RH is larger than 30%.     

Synthesis, characterization, and electrochemical properties of ultrafine β-Ni(OH)2 nanoparticles

Nickel hydroxide was deposited via cathodic electrodeposition from low-temperature 0.005 M NiCl₂ bath without using any surfactant or template. The cathodic current density was 1 mA cm⁻² and stainless steel was used as the cathode. The XRD pattern confirmed that the prepared sample has a pure brucite crystal phase of β-Ni(OH)₂ and the broadening of diffraction peaks showed that the particles size of the prepared β-Ni(OH)₂ is extremely small. Thermal behavior and composition of the prepared β-Ni(OH)₂ were investigated by DSC-TG and FT-IR analyses. Morphological characterization by SEM and TEM revealed that β-Ni(OH)₂ is composed of well dispersed ultrafine particles with size of about 5 nm. The electrochemical properties of the prepared nanoparticles were studied by means of cyclic voltammetry (CV) and galvanostatic charge-discharge tests in 1 M KOH. The prepared β-Ni(OH)₂ nanoparticles showed excellent capacitance behavior of 740 F g⁻¹ in the potential window of 0-0.55 V vs. Ag/AgCl. These results make the β-Ni(OH)₂ nanoparticles as a promising candidate for the supercapacitor electrodes.     

Mechanisms of NO formation in MILD combustion of CH4/H2 fuel blends

The mechanisms of formation and destruction of NO in MILD combustion of CH₄/H₂ fuels blends are investigated both experimentally and numerically. Experiments are carried out at a lab-scale furnace with the mass fraction of hydrogen in fuel ranging from 0% to 15%; furnace temperature, extracted heat and exhaust NO_x emissions are measured. Detailed chemical kinetics calculations utilizing computational fluid dynamics (CFD) and well-stirred reactor (WSR) are performed to better analyze and isolate the different mechanisms.     

A numerical study on the effect of hydrogen/reformate gas addition on flame temperature and NO formation in strained methane/air diffusion flames

This paper investigates the effects of hydrogen/reformate gas addition on flame temperature and NO formation in strained methane/air diffusion flames by numerical simulation. The results reveal that flame temperature changes due to the combined effects of adiabatic temperature, fuel Lewis number and radiation heat loss, when hydrogen/reformate gas is added to the fuel of a methane/air diffusion flame. The effect of Lewis number causes the flame temperature to increase much faster than the corresponding adiabatic equilibrium temperature when hydrogen is added, and results in a qualitatively different variation from the adiabatic equilibrium temperature as reformate gas is added. At some conditions, the addition of hydrogen results in a super-adiabatic flame temperature. The addition of hydrogen/reformate gas causes NO formation to change because of the variations in flame temperature, structure and NO formation mechanism, and the effect becomes more significant with increasing strain rate. The addition of a small amount of hydrogen or reformate gas has little effect on NO formation at low strain rates, and results in an increase in NO formation at moderate or high strain rates. However, the addition of a large amount of hydrogen increases NO formation at all strain rates, except near pure hydrogen condition. Conversely, the addition of a large amount of reformate gas results in a reduction in NO formation.     

The effects of hydrogen addition on Fenimore NO formation in low-pressure,fuel-rich-premixed,burner-stabilized CH4/O2/N2 flames

We investigate the effects of hydrogen addition on Fenimore NO formation in fuel-rich, low-pressure burner-stabilized CH₄/O₂/N₂ flames. Towards this end, axial profiles of temperature and mole fractions of CH and NO are measured using laser-induced fluorescence (LIF). The experiments are performed at equivalent ratios of 1.3 and 1.5, using 0.25 mole fraction of hydrogen in the fuel, while varying the mass flux through the burner. The results are compared with those reported previously for burner-stabilized CH₄/O₂/N₂ flames. The increased burning velocity caused by hydrogen addition is seen to result in a lower flame temperature as compared to methane flame stabilized at the same mass flux. This increase in burner stabilization upon hydrogen addition results in significantly lower CH mole fractions at φ = 1.3, but appears to have little effect on the CH profile at φ = 1.5. In addition, the results show that not only the maximum flame temperature is reduced upon hydrogen addition, but the local gas temperature in the region of the CH profile is lowered as well. The measured NO mole fractions are seen to decrease substantially for both equivalence ratios. Analysis of the factors responsible for Fenimore NO formation shows the reduction in temperature in the flame front to be the major factor in the decrease in NO mole fraction, with a significant contribution from the decrease in CH mole fraction at φ = 1.3. At φ = 1.5, the results suggest that the lower flame temperature upon hydrogen addition further retards the conversion of residual fixed-nitrogen species to NO under these rich conditions as compared to the equivalent methane flames.     

Driving characteristics of a motorcycle fuelled with hydrogen-rich gas produced by an onboard plasma reformer

The driving performance and emission characteristics of a 125 cc motorcycle equipped with an onboard plasma reformer for producing hydrogen-rich gas were investigated. Butane with suitable air flow rate was induced into the plasma reformer to produce hydrogen-rich gas, which was used as supplementary fuel for the internal combustion engine. The motorcycle was run under steady and transient conditions on a chassis dynamometer to assess the driving performance and exhaust emissions.     

The effects of composition on burning velocity and nitric oxide formation in laminar premixed flames of CH4 + H2 + O2 + N2

Experimental measurements of adiabatic burning velocity and NO formation in (CH₄ + H₂) + (O₂ + N₂) flames are presented. The hydrogen content in the fuel was varied from 0 to 35% and the oxygen content in the air from 20.9 to 16%. Nonstretched flames were stabilized on a perforated plate burner at 1 atm. The heat flux method was used to determine burning velocities under conditions when the net heat loss of the flame is zero. Adiabatic burning velocities of methane + hydrogen + nitrogen + oxygen mixtures were found in satisfactory agreement with the modeling. The NO concentrations in these flames were measured in the burnt gases at a fixed distance from the burner using probe sampling. In lean flames, enrichment by hydrogen has little effect on [NO], while in rich flames, the concentration of nitric oxide decreases significantly. Dilution by nitrogen decreases [NO] at any equivalence ratio. Numerical predictions and trends were found in good agreement with the experiments. Different responses of stretched and nonstretched flames to enrichment by hydrogen are demonstrated and discussed.     

Numerical investigation for combustion characteristics of vacuum residue (VR) in a test furnace

It has become inevitable to search for alternative fuels due to current worldwide energy crisis. In this paper combustion characteristics of vacuum residue (VR) is investigated numerically against experimental data in typical operating conditions of a furnace. Heat release reaction is modeled as sequential steps of devolatilization, simplified gas phase reaction and char oxidation as for pulverized coal. Thermal and fuel NO are predicted by the conditional moment closure (CMC) method for estimation of elementary reaction rates. It turns out that Sauter mean diameter (SMD) of VR droplets is a crucial parameter for better combustion efficiency and lower NO. Reasonable agreement is achieved for spatial distributions of major species, temperature and NO for all test cases with different fuel and steam flow rates.     

In situ FT-IR spectroscopic investigations of species from biomass fuels in a laboratory-scale combustor: the release of nitrogenous species

In situ FT-IR absorption spectroscopy was used with a laboratory-scale reactor and thermogravimetric analysis to describe the release of nitrogen-containing compounds from a fixed bed of fibreboard residues. Such in situ detection of NH₃ requires knowledge of the absorption coefficients at high temperatures. These coefficients were obtained from calibrations using a laboratory-scale reactor at temperatures up to 800 °C, as well as from calculations using a database. On the basis of laboratory experiments, the rates of release of N species, of the major C species (CO, CO₂, and CH₄), and of H₂O have been derived. It is concluded that the release of nitrogen from the fuel can be modelled if such parameters as the superficial velocity and the flow rate of oxygen are known. This method allows profiles of the nitrogenous species to be generated and used as input data for CFD calculations based on thermodynamic combustion models for a fixed bed on a grate.     

Hydrogen addition effects in a confined swirl-stabilized methane-air flame

The effect of hydrogen addition in methane-air premixed flames has been examined from a swirl-stabilized combustor under confined conditions. The effect of hydrogen addition in methane-air flame has been examined over a range of conditions using a laboratory-scale premixed combustor operated at 5.81 kW. Different swirlers have been investigated to identify the role of swirl strength to the incoming mixture. The flame stability was examined for the effect of amount of hydrogen addition, combustion air flow rates and swirl strengths. This was carried out by comparing adiabatic flame temperatures at the lean flame limit. The combustion characteristics of hydrogen-enriched methane flames at constant heat load but different swirl strengths have been examined using particle image velocimetry (PIV), micro-thermocouples and OH chemiluminescence diagnostics that provided information on velocity, thermal field, and combustion generated OH species concentration in the flame, respectively. Gas analyzer was used to obtain NO_x and CO concentration at the combustor exit. The results show that the lean stability limit is extended by hydrogen addition. The stability limit can reduce at higher swirl intensity to the fuel-air mixture operating at lower adiabatic flame temperatures. The addition of hydrogen increases the NO_x emission; however, this effect can be reduced by increasing either the excess air or swirl intensity. The emissions of NO_x and CO from the premixed flame were also compared with a diffusion flame type combustor. The NO_x emissions of hydrogen-enriched methane premixed flame were found to be lower than the corresponding diffusion flame under same operating conditions for the fuel-lean case.     

Effect of hydrogen addition on criteria and greenhouse gas emissions for a marine diesel engine

Hydrogen remains an attractive alternative fuel to petroleum and a number of investigators claim that adding hydrogen to the air intake manifold of a diesel engine will reduce criteria emissions and diesel fuel consumption. Such claims are appealing when trying to simultaneously reduce petroleum consumption, greenhouse gases and criteria pollutants. The goal of this research was to measure the change in criteria emissions (CO, NO_x, and PM_2.5) and greenhouse gases such as carbon dioxide (CO₂), using standard test methods for a wide range of hydrogen addition rates. A two-stroke Detroit Diesel Corporation 12V-71TI marine diesel engine was mounted on an engine dynamometer and tested at three out of the four loads specified in the ISO 8178-4 E3 emission test cycle and at idle. The engine operated on CARB ultra-low sulfur #2 diesel with hydrogen added at flow rates of 0, 22 and 220 SLPM.