共查询到20条相似文献,搜索用时 62 毫秒
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有机-无机复合固态电解质是锂离子电池材料的研究热点,由于其兼有聚合物与无机电解质的优点而有望成为下一代全固态锂离子电池的重要组成部分.在这篇综述中,以不同种类的无机填料为依据,总结了常见的复合电解质研究形式,对其最新进展进行了综述.从工作的新颖性、性能提升和实用性等方面考察,对最新研究的不同种类无机填料对复合电解质性能... 相似文献
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在包含锂盐和聚合物的固态聚合物电解质体系中,无机纳米材料通常用作填充材料,以改善电解质的电化学性能和结构稳定性.然而,这种复合型固态电解质通常具有低室温离子电导率.因此,无机材料的种类和几何形状的优化是进一步提高复合电解质导电性的关键.本文对现有的无机填料种类及其衍生物进行简单介绍,分析了在复合型固态电解质中离子传导原... 相似文献
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制备具有高孔隙率、高热稳定性、高离子传导性以及优异机械性能和高储存模量的电解质是当今锂离子电池研究领域的热点问题,但是使用单一聚合物基质基本无法满足这些特性,向单一聚合物电解质中添加无机纳米粒子,制备复合电解质是一种简便的、有效的途径制备综合性能优异的电解质体系。无机纳米粒子不仅能够改善聚合物电解质的物理特性,而且还能够抑制锂枝晶的生长,提升电池的循环性能。本文详细讨论了无机纳米颗粒在锂离子电池电解质改性中的应用,包括无机纳米颗粒的填充、涂覆、原位生成以及填充非织造电解质等;为进一步研究和开发具有机械稳定性、化学惰性和优异电化学性能的新型复合电解质体系提供了新的思路和方向。 相似文献
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以PEO为基质,复配少量纳米无机填料及低分子乙氧化物,制备出了新型的固态纳米复合聚合物电解质膜,利用交流阻抗法测试了聚合物电解质的离子电导率,对离子导电性能进行了研究。采用CPE元件的模拟电路具有很好的适用性。结果表明当低分子乙氧化物的加入量超过80%时电解质膜的电导率大幅提高,并且PEGDME优于PEG300。电导率在LiPF6加量在O:Li为8:1时达到最大,随着LiClO4加量的增加持续增加,随无机盐加量增加电解质膜的成膜性能变差。用多微孔高比表面的纳米SiO2粒子复合有利于改善聚合物的电导率。聚合物电解质离子电导率对温度的依赖关系符合Arrhenius方程。 相似文献
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人们对开发新一代电池系统越来越感兴趣,这种新电池系统要比锂电池有更高的能量密度.镁电池因其高电极电位、优越的安全性和丰富的镁金属储量而成为最终取代锂离子电池的最可行的选择.但是,由于电解质的发展受阻,迄今为止,镁离子电池还没有普及.缺乏合适的电解质材料.Mg2+电导率上有一定的挑战性.镁电池无机固态电解质的发展决定着镁... 相似文献
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目前商业化的锂离子电池多使用有机液态电解质,存在易燃易爆、易泄露等安全风险,而采用固态电解质替代有机液态电解质可以有效提高电池安全性。锂离子电池用固态电解质又可分为无机固态电解质和有机——即聚合物固态电解质。无机固态电解质对高温或其他腐蚀性环境适应性好,适用于在极端工作环境中刚性电池等领域;聚合物固态电解质在柔韧性和可加工性上则优势明显,适用于柔性电池等领域,但这些材料均尚有问题待解决。无机-有机复合的方式,有望综合两种材料的优势,取长补短,提高固态电解质的综合性能和实用价值。 相似文献
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This paper presents the effect of (La,Sr)MnO3 (LSM) stoichiometry on the polarization behaviour of LSM/Y2O3-ZrO2 (YSZ) composite cathodes. The composite cathode made of A-site deficient (La0.85Sr0.15)0.9MnO3 (LSM-B) showed much lower electrode interfacial resistance and overpotential losses than that made of stoichiometric (La0.85Sr0.15)1.0MnO3 (LSM-A). The much poorer performance of the latter is believed to be due to the formation of resistive substances such as
La2Zr2O7/SrZrO3 between LSM and YSZ phases in the composite electrode. A slight A-site deficiency (∼0.1) was effective in inhibiting the
formation of these resistive substances. A power density of ∼1 W cm−2 at 800 °C was achieved with an anode-supported cell using an LSM-B/YSZ composite cathode. In addition, the effects of cathodic
current treatment and electrolyte surface grinding on the performance of composite cathodes were also studied. 相似文献
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Electro-organic synthesis without supporting electrolyte: Possibilities of solid polymer electrolyte technology 总被引:1,自引:0,他引:1
J. Jörissen 《Journal of Applied Electrochemistry》2003,33(10):969-977
The application of ion exchange membranes as solid polymer electrolytes (SPE) in fuel cells is state-of-the-art. This technology needs no supporting electrolyte; consequently it can be applied for electro-organic syntheses in order to save process steps. In this case the process is not predetermined to a maximized energy efficiency so that the selection of the cell design, of the electrode materials and of the operating conditions can be focused on a high selectivity of the electrode reactions. The electro-osmotic stream, which is caused by the solvation shells of the ions during their migration through the membrane, and hence is a typical property of SPE technology, has a significant effect on the electrode reactions. It generates enhanced mass transfer at the electrodes, which is beneficial for reaction selectivity. It can be influenced by the choice of, and possibly by the preparation of, the membrane. An additional remarkable advantage of SPE technology is the exceptional long durability of oxide coated electrodes. By combination of several process engineering methods stable operation of SPE cells has been realized, even for examples of non-aqueous reaction systems. Experiments up to 6000 h duration and in cells of up to 250 cm2 membrane area show the potential for industrial application. 相似文献
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Y. Jiang 《Electrochimica acta》2010,55(22):6415-6419
Three types of alkyl-substituted poly(N-alkyl-1-vinyl-imidazolium) iodides were synthesized and plasticized using succinonitrile as a solid plasticizer to develop a series of novel solvent-free plastic-polymer composite electrolytes. All these electrolytes appeared as a soft solid at room temperature and became sticky gel state at high temperature of 100 °C. Among the as-prepared plastic-polymer electrolytes, the SCN-PMVII (succinonitrile-poly(1-vinyl-3-methylimidazolium) iodide) electrolytes with a SCN content of 40-60 wt.% showed a room temperature conductivity of 1.0-1.6 mS cm−1and a photoconversion efficiency of >4.1%, which are comparable to those observed from liquid organic carbonate electrolyte and the DSSCs using the liquid electrolyte at the same experimental conditions. Also, the DSSCs assembled with the SCN-PMVII electrolytes maintained their photoconversion efficiency very steadily during aging test of 50 days despite of being placed at 40 °C under 1 sun illumination or stored at 60 °C in an oven. Since these plastic-polymer electrolytes are solvent-free, highly conductive and electrochemically compatible, it is possible to use this type electrolyte for development of practical DSSCs. 相似文献
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《Ceramics International》2020,46(10):16224-16234
Alumina powders have been widely used in lithium-ion batteries such as separator coating, electrode surface modification and electrolyte fillers. Rod-like alumina with its special aspect ratio is expected to open up a new application direction. In this work, alumina nanorods were prepared by a facile hydrothermal method. The aspect ratio and morphology of alumina nanorods were optimized by adjusting the hydrothermal temperature, hydrothermal synthesis time, volume ratio, directing agent, and sintering temperature. γ-Al2O3 nanorods with a diameter of 200–300 nm and a mean length of 5 μm and α-Al2O3 with a diameter of 100–200 nm and mean length of 5 μm were obtained by calcining the alumina precursor (AACH) at 800 °C and 1200 °C, respectively. The prepared alumina nanorods were added into polymer solid electrolyte, which promoted the dissociation of the lithium salt and stabilized the propylene polycarbonate (PPC) polymer, resulting in an improved potential window (4.5 V) and ionic conductivity (3.7 × 10−4 S/cm) of the PPC-based polymer solid electrolyte (SE). An NCM622/SE/Li solid-state battery showed enhanced electrochemical performance at ambient temperature with an initial discharge capacity of 188.5 mAh/g and a retention capacity of 158.1 mAh/g after 200 cycles at a current density of 0.5 C. These alumina nanorods have potential to be widely used in high-performance solid electrolytes. 相似文献
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Electrolytic synthesis of succinic acid in a flow reactor with solid polymer electrolyte membrane 总被引:2,自引:0,他引:2
S.S. Vaghela G. Ramachandraiah P.K. Ghosh D. Vasudevan 《Journal of Applied Electrochemistry》2002,32(11):1189-1192
This paper describes the galvanostatic synthesis of succinic acid from maleic acid in an ion exchange membrane flow cell. The electrolysis was carried out at stainless steel, lead and copper cathodes under variable conditions of current density and substrate concentration. Depending upon the experimental conditions, the yield of succinic acid varied from 95 and 99% with a coulombic efficiency of 80–99%. The product was characterized by various physicochemical techniques, viz. 1H-NMR, IR and UV–Visible spectroscopy and elemental analysis. The operational conditions giving maximum yield of product were identified. The mechanism of electrochemical reduction of maleic acid and advantages of using a catholyte without supporting electrolyte are discussed. 相似文献