共查询到20条相似文献,搜索用时 78 毫秒
1.
3.
<正>授权公告号:CN 105384976B授权公告日:2017年5月3日专利权人:衡水中铁建工程橡胶有限责任公司发明人:王红续、赵雅婷、周海军等本发明公开了一种宽温域高阻尼橡胶支座及其制备工艺。该橡胶支座胶料配方为:天然橡胶70~90,丁苯橡胶10~30,超耐磨炭黑50~80,硅土(二氧化硅、三氧化二铝、氧化铁和氧化钙等混合物)5~20,超细粘土10~30,碳酸钙15~30,活性剂4~10,高苯乙烯树脂 相似文献
4.
研究了3种硫化剂——2,3-二巯基-喹喔啉(DNR-12A)、三巯基均三嗪(TCY)和亚乙基硫脲(NA-22)及3种填料——高耐磨炭黑(N330)、木质素-蒙脱土复合物填料(BL-MMT)和碱性木质素(lignin)对共聚型氯醚橡胶(ECO)硫化特性、交联密度、力学性能和老化性能的影响。结果表明,固定填料为N330时,用NA-22硫化的胶料的力学性能最好,但热氧老化性能最差;改变填料后NA-22硫化胶料的老化性能得到提高,固定硫化剂为NA-22时,以碱性lignin为填料的胶料的力学性能与热氧老化性能均最好,拉伸强度达15.5 MPa,断裂伸长率达394%,100%定伸应力达6.4 MPa,老化后拉伸强度保持率为103.2%。 相似文献
5.
6.
7.
采用均聚氟硅橡胶和改性共聚氟硅橡胶,通过机械共混法制备宽温域氟硅橡胶,研究均聚氟硅橡胶/改性共聚氟硅橡胶并用比对胶料物理性能、耐15#航空液压油性能及耐低温性能的影响。结果表明:随着改性共聚氟硅橡胶用量增大,胶料的硬度逐渐降低,拉伸强度变化很小,拉断伸长率和拉断永久变形逐渐增大但增幅不大,耐15#航空液压油性能有所降低,耐低温性能明显提高;当均聚氟硅橡胶/改性共聚氟硅橡胶并用比为50/50时,胶料的脆性温度(多试样法)达到-64.7℃,在-50,-55,-60℃下的压缩耐寒系数分别达到0.51,0.44,0.39,低温回缩试验10%回缩率对应的温度达到-67.2℃;当均聚氟硅橡胶/改性共聚氟硅橡胶并用比为70/30时,胶料的耐低温、耐15#航空液压油综合性能最佳,动密封圈在10个循环周期的台架试验中未出现泄漏、损伤和永久变形现象,在-60~150℃宽温域、15#航空液压油环境中具有良好的密封性能。 相似文献
8.
9.
10.
耐低温氟醚橡胶补强体系的研究 总被引:2,自引:1,他引:2
研究多种填料对耐低温氟醚橡胶性能的影响,结果表明:硅酸钙和喷雾黑是耐低温氟醚橡胶较理想的补强填料,在相同用量下,煤粉补强的胶料耐空气热老化和耐压缩永久变形性能优于喷雾炭黑,高填充量时其补强性能接近喷雾炭黑 相似文献
11.
This study was devoted to the prediction of polymer material aging. The prediction of the shelf time of tire rubber is used as an example in this article. The main steps of the whole procedure are described. They are the design of the experiment, accelerated aging testing, the construction of a multiresponse mathematical model and parameter estimation, and the extrapolation of the model in real‐life settings. The main pitfalls were deduced, and techniques to overcome these pitfalls are described. Novel methods of data modeling, such as evolutionary design of experiment and successive Bayesian estimation, were used. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1275–1284, 2005 相似文献
12.
El Hadi Belhiteche Sébastien Rondot Mustapha Moudoud Philippe Dony Omar Jbara 《Polymer Engineering and Science》2021,61(3):706-715
A contactless method based on energy shift of high-energy cut-off of the x-ray bremsstrahlung, the so-called Duane Hunt Limit and a conventional low voltage electrical technique (three-probes technique) is applied on thermal and corona aged silicone rubber (SiR) to measure, respectively, the surface potential, Vs, and the surface resistivity, ρs. The effect of aging on these quantities, representing the dielectric properties, is studied. The results are highly reproducible and highlight a good correlation between Vs and ρs. It was observed that thermal aging combined with electrical aging deteriorates more the electrical properties of the polymer than thermal aging alone. Explanations for electrical characteristics (Vs, ρs) change with aging are supported by attenuated total reflection Fourier transform infrared spectroscopy spectra analysis and a chemical mechanism of aging in three steps (i.e., oxidation-polycondensation, degradation, and thermal cracking). The surface degradation of the polymer is revealed by images of surface morphology obtained by using scanning electron microscopy (SEM). Roughness is greater for combined thermal and corona aging mode compared to thermal aging alone. In addition, the surface degradation of SiR polymer is confirmed by the loss of its hydrophobicity. 相似文献
13.
Technical properties such as hardness, tensile strength, ultimate elongation, and rebound resilience are popular in quality control, but the trend in these properties shows a generalized picture of the structure–property relations. Test specimens were aged in hot air by systematically varying the time and temperature from 24 to 96 h at 70 to 100°C. For an effective comparison the observed values were plotted as a function of time, temperature, and formulations. The data thus obtained were correlated with shelf‐aging in particular cases, and it was observed that aging at 100°C for 24 h could be used for such formulations. A “sulfur donor” system cured nitrile‐butadiene rubber (NBR) vulcanizate and an ethylene‐propylene‐diene (EPDM) vulcanizate showed the best retention of properties. Although the SEM micrograph of the NBR was in agreement with this observation, the EPDM was not. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 2500–2510, 2000 相似文献
14.
The dynamic properties of rubber bearings frequently used as isolators in structures could be significantly deteriorated because of the change of microstructure in rubber caused by cyclic compression and thermal aging. As a result, a catastrophic failure of bridges and buildings unexpectedly occurs when they are subjected to earthquake attack. Here, the dynamic properties of neoprene rubber bearings before and after different cycles of compressive loading or various periods of thermal aging were first measured and compared to each other. On the basis of the experimental results, the effects of cyclic compression and thermal aging on the stiffness, energy absorption, and equivalent viscous damping coefficient of neoprene rubber bearings are investigated. It is found that the deterioration of dynamic properties of neoprene rubber bearings caused by either cyclic compression or by thermal aging is significant and should be taken into account in designing rubber bearings. © 2007 Wiley Periodicals, Inc. JAppl Polym Sci, 2008 相似文献
15.
16.
This article dealt with the relationship between mechanical properties and crosslinked networks of natural rubber (NR) reinforced by zinc dimethacrylate (ZDMA) after thermal aging. After thermal aging at the present experimental conditions, the covalent crosslink density showed a decrease all the time, whereas the ionic crosslink density was stable at 80°C but decreased at a higher temperature. The decrease in the total crosslink density after aging indicates the degradation of the crosslinked network. However, an experimental phenomenon observed was that the tensile strength and tear strength increased in a certain degree after aging at 80°C or at a 100°C for a short time. In addition, the thermal stability of the NR/ZDMA composite was evaluated by thermal gravimetric analysis. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
17.
采用热空气加速老化试验方法对粘弹性丁基橡胶阻尼材料的老化性能及其老化机理进行了研究,获得了老化前后丁基橡胶阻尼材料力学性能、阻尼性能及其变化规律。研究结果表明:在所选定的热空气老化65℃×310天试验条件下,阻尼材料的拉伸强度提高了1MPa,阻尼性能曲线整体向高温区域平移了10℃,而有效阻尼温域基本保持不变,与模拟计算结果一致,可以满足等效25℃×10年储存条件下的使用要求。同时,采用FTIR和SEM技术分析了阻尼材料在热氧老化条件下分子链结构和微观结构的变化,得到了粘弹性丁基橡胶阻尼材料的热空气老化机理。 相似文献
18.
高温硫化硅橡胶由于其优异的高低温性能、耐候性、表面性能等特点而在航天、电力和医疗器械等领域中得到广泛应用。本文主要介绍了最近五年来,通过化学或物理方法对硅橡胶表面性能和低温性能等进行强化方面的相关研究,以及在实现产品功能化方面取得的进展。此外还介绍了在加速老化条件下不同硅橡胶材料的力学、介电性能等变化及其机理,以及在老化研究方法的精确化、可靠化和可视化方面的研究进展,重点关注多因素影响下的材料寿命分析和预测;并特别关注了水在硅橡胶老化过程中的作用及机理研究成果。最后,对高温硫化硅橡胶改性和老化研究的前景进行了展望。未来,极端环境下的硅橡胶功能化研究以及多因素影响下的材料寿命分析和预测将成为重要的发展方向。 相似文献
19.
The rubber antioxidant N‐(4‐anilinophenyl) methacrylamide (NAPM) was synthesized by a two‐step reaction using thionyl chloride (SOCl2) with methacrylic acid (MAA) and consequently 4‐aminodiphenylamine (ADPA) as precursors. NAPM was characterized by IR, 1H NMR and elemental analysis. Thermal stability, aging property of NAPM and mechanical properties of natural rubber (NR) vulcanizates containing NAPM were investigated and compared with two other commercial antioxidants N‐isopropyl‐N′‐phenyl‐p‐phenylene diamide (4010NA) and N‐(1, 3‐dimethyl butyl)—N′‐phenyl‐p‐phenylene diamide (4020). It was found that NAPM was an effective antioxidant with a better thermal stability and higher antiaging resistance than unreactive antioxidants 4010NA and 4020. And unsaturation level of NR vulcanizates containing NAPM was lower than that of 4010NA and 4020. Moreover, an antiaging resistant mechanism of a surface reaction between NAPM and cis‐1, 4‐polyisoprene in NR was proposed to explain the better properties of NAPM based on the IR and SEM analyses. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献