共查询到17条相似文献,搜索用时 125 毫秒
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生物质能源是唯一可再生、可替代化石能源转化成气态、液态和固态燃料以及其它化工原料或者产品的碳资源。随着化石资源的枯竭和人类对全球性环境问题的关注,生物质能源替代化石能源利用的研究和开发,已成为国内外众多学者研究和关注的热点。本系列讲座主要讲述以生物质资源为主要原料,通过不同途径转化为洁净的、高品位的气体、液体或固体燃料。本讲主要综述了生物质高压液化、快速热解液化制备液体燃料油技术现状、工艺及设备,并在总结生物质热解液体燃料油特性的基础上,总结了生物热解液体燃料油的物理法精制技术(包括脱水、添加溶剂和乳化)和化学法精制技术(包括催化加氢、催化裂解、催化酯化、水蒸气重整)的研究现状,并对其精制机理、优缺点进行了分析。随着制备和精制技术的深入研究,生物质热解液体燃料油可望替代汽油、柴油等化石燃料而越来越受到人们的关注。 相似文献
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Detailed CFD modelling of fast pyrolysis of different biomass types in fluidized bed reactors
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Renewable chemicals are of growing importance in terms of opportunities for environmental concerns over fossil‐based chemicals. Lignocellulosic biomass can be converted into energy and chemicals via thermal and biological processes. Among all the transformation processes available, fast pyrolysis is the only one to produce a high yield of a liquid‐phase product called bio‐oil or pyrolysis oil. Bio‐oil is considered to be a promising substitute for phenol in phenol formaldehyde (PF) resin synthesis. In this work, bio‐based phenolic resins have been formulated, partially substituting phenol by bio‐oils from two Canadian whole‐tree species. The new resins are produced by replacing 25, 50, and 75% of phenol with bio‐oil for each species (three bioresins per species). The aim of this study is to synthesize renewable resins with competitive price and satisfactory quality. The results obtained have shown that substitution degree up to 50% provided reactivity and performance equal or superior to the pure PF resin. They also present a good storage stability, improved shear strength, and thermal stability comparable to the pure PF. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2014 , 131, 40014. 相似文献
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Shaolong Wan Trung Pham Sarah Zhang Lance Lobban Daniel Resasco Richard Mallinson 《American Institute of Chemical Engineers》2013,59(7):2275-2285
The results of catalytic treatment of vapors exiting a g/min pyrolysis unit before product condensation to the liquid phase using a Ru/TiO2 catalyst for oak and switchgrass pyrolysis are reported. The pyrolysis is conducted at 500°C and the catalysis at 400°C at atmospheric pressure with a hydrogen partial pressure of 0.58 atm. It is found that the catalytic treatment provides significant conversion of light oxygenates to larger, less oxygenated, molecules and, simultaneously, bio‐oil phenolics are also converted to less oxygenated phenolics with methoxy methyl groups transferred to the ring. The activity of the catalyst gradually diminished with increasing biomass fed to the system. Untreated pyrolysis oil forms a single liquid phase with some tarry material, consistent with the literature, whereas the treated liquid product forms separate oil and aqueous phases, the latter of which is about 80% water. The oil from the treated vapors has a lower initial viscosity with only a small increase upon accelerated aging compared to the untreated product oil, which has a dramatic increase in viscosity after aging. This is indicative of poor oil stability for untreated oil that is further confirmed by large increases in molecular weight, while the treated oil has a small increase in molecular weight after accelerated aging. In an effort to understand compatibility with refinery streams, the solubility of the oils in tetralin was examined. The untreated oil was found to have very limited solubility in tetralin, whereas the treated oil phase was completely soluble except for a small aqueous phase that appeared. There are a number of challenges in developing a high yield process for pyrolysis based conversion of biomass to transportation fuels. The Ru/TiO2 catalyst used here shows promise for conducting multiple types of favorable reactions in the presence of the full spectrum of primary pyrolysis products that creates significant product stability under mild conditions. This could lead to higher liquid yields of stable, refinery compatible, product oil. © 2013 American Institute of Chemical Engineers AIChE J, 59: 2275–2285, 2013 相似文献
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A continuous atmospheric pressure flash pyrolysis process for the production of organic liquids from cellulosic biomass has been demonstrated at a scale of 1–3 kg/hr of dry feed. Organic liquid yields as high as 65–70% of the dry feed can be obtained from hardwood waste material, and 45–50% from wheat straw. The fluidized sand bed pyrolysis reactor operates on a unique principle so that char does not accumulate in the bed and treatment of the sand is not necessary. The product gas, about 15% of the yield, has a medium heating value. The liquid product is an acidic fluid, which pours easily and appears to be stable. A preliminary economic analysis suggests that if the pyrolysis oil can be used directly as a fuel, its production cost from wood waste is probably competitive with conventional fuel oil at the present time. 相似文献
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