Crude Oil Fouling in a Pilot-Scale Parallel Tube Apparatus

Maya crude oil fouling reveals a seemingly straightforward dependency of initial fouling rate on surface temperature, but a maximum is found in the initial fouling rate–velocity relationship, which mirrors that found in a model chemical system of styrene polymerization. The linear dependency of the logarithm of the pre-exponential factor on apparent activation energy for the crude oil is also found in the styrene system. The apparent activation energy for the crude oil ranged from 26.4 kJ/mol at 1.0 m/s to 245 kJ/mol at 4.0 m/s. Such strong dependencies of apparent activation energy on velocity, even at high velocity, are consistent with Epstein's mass transfer reaction attachment model. Surface temperatures at which the fouling rate becomes velocity independent are 274°C and 77°C for Maya crude oil and styrene, respectively. For surface temperatures in excess of this isokinetic temperature, an increase in velocity would lead to an increase in the rate of fouling.     

Energy consumption during Refractance Window® evaporation of selected berry juices

The Refractance Window^® evaporator represents a novel concept in the design of evaporation systems for small food processing plants. In this system thermal energy from circulating hot water is transmitted through a plastic sheet to evaporate water from a liquid product flowing concurrently on the top surface of the plastic. The objectives of this study were to investigate the heat transfer characteristics of this evaporator, determine its energy consumption, and capacity at different tilt angles and product flow rates. The system performance was evaluated with tap water, raspberry juice, and blueberry juice and puree as feed. With a direct steam injection heating method, the steam economy ranged from 0.64 to 0.84, while the overall heat transfer coefficient (U) was 666 W m^?2 °C^?1. Under this condition, the highest evaporation capacity was 27.1 kg h^?1 m^?2 for blueberry juice and 31.8 kg h^?1 m^?2 for blueberry puree. The energy consumption was 2492–2719 kJ kg^?1 of water evaporated. Installation of a shell and tube heat exchanger with better temperature control minimized incidences of boiling and frequent discharge of condensate. The steam economy, highest evaporation rate and overall heat transfer coefficient increased to 0.99, 36.0 kg h^?1 m^?2 and 733 W m^?2 °C^?1, respectively. Copyright © 2004 John Wiley & Sons, Ltd.     

Performances and improvement potential of solar drying system for palm oil fronds

In this study, an indirect forced convection solar drying system was tested for drying of palm oil fronds. The drying of 100 kg of palm oil fronds via solar drying system reduced the moisture content from 60% (w.b) to 10% (w.b) in 22 h (3 d of drying). During the drying process, the daily mean values of the drying chamber inlet temperature, drying chamber outlet temperature, drying chamber air temperature, and solar radiation ranged from 26 °C to 75 °C, 25 °C–65 °C, 26 °C–67 °C, and 96 W/m² to 1042 W/m² respectively, with corresponding average values of 53 °C, 46 °C, 48 °C, and 580 W/m². At average solar radiation of about 600 W/m² and air flow rate 0.13 kg/s, the collector, drying system and pick-up efficiencies were found about 31%, 19% and 67% respectively. The specific moisture extraction rate (SMER) was 0.29 kg/kWh. The exergy efficiency varied between 10% and 73%, with an average of 47%. In addition, the improvement potential of solar drying system for palm oil fronds ranged from 8 W to 455 W, with an average of 172 W.     

Particulate Fouling and On-Line Cleaning of Ferric Oxide Particles in Internally Enhanced Tubes

This paper describes the results of accelerated particulate fouling tests performed on three enhanced tubes and a plain tube. The tests were performed using ferric oxide as the foulant material. Three enhanced tubes included 25 start, 10 start helically ribbed tube and a ripple tube. Effect of the water velocity (1.2–1.7 m/s) on fouling resistance was investigated. The maximum fouling resistance occurred in the 25 start helically ribbed tube (about 8.0 × 10^?5 m²K/W after 100 hours). For the 10 start helically ribbed tube, the fouling resistance was relatively small (less than 1.8 × 10^?5 m²K/W). The rippled and plain tubes show almost negligible fouling resistance. High velocity flushing was effective for all the tubes except for the 25 start helically ribbed tube. On-line brush cleaning maintained the fouling resistance below 1.8 × 10^?5 m²K/W for all tubes. The fouling concentrations used in the tests were significantly higher than would be expected in commercial heat exchangers. Also, the velocity range investigated was lower than would be expected in heat exchanger operation.     

Shell-and-Tube Heat Exchanger Geometry Modification: An Efficient Way to Mitigate Fouling

Abstract

Crude oil fouling of a shell-and-tube heat exchanger sized according to TEMA standard is compared to a No-Foul design under industrial operating conditions. For similar operating conditions, TEMA and No-Foul heat exchangers have the same behavior regarding fouling. Since the No-Foul one has less tubes by design for the same heat duty, shear stress is increased. Consequently, the No-Foul heat exchanger is less prone to fouling at the same throughput. Impact of tube bundle geometry is then investigated. Helically finned tubes are compared to plain tubes in the No-Foul heat exchanger. Under similar operating conditions, fouling rates measured are up to an order of magnitude lower than plain tubes (respectively 10^?11 and 10^?10 m² K/J). However, pressure drop across the tube-side in both No-Foul plain and finned setup are increased in comparison to the TEMA heat-exchanger.     

Reactor start-up strategy as key for high and stable hydrogen production from cheese whey thermophilic dark fermentation

Using the right start-up strategy can be vital for successful hydrogen production from thermophilic dark fermentation (55 °C), but it needs to be affordable. Hence, three start-up strategies modifying only influent concentration and temperature were assessed in a reactor fed with cheese whey: (i) high temperature (55 °C) and a high organic loading rate (OLR_A - 15 kgCOD m^?3 d^?1) right at the beginning of the operation; (ii) slowly increasing temperature up to 55 °C using a high OLR_A and (iii) slowly increasing temperature and OLR_A up to the desired condition. Strategy (iii) increased hydrogen productivity in 39% compared to the others. The combination of high temperature and low pH thermodynamically favored H₂ producing routes. Synergy between Thermoanaerobacterium and Clostridium might have boosted hydrogen production. Three reactors of 41 m³ each would be needed to treat 3.4 × 10³ m³ year^?1 of whey (small-size dairy industry) and the energy produced could reach 14 MWh month^?1.     

Study of thermal conductivity,permeability, and adsorption performance of consolidated composite activated carbon adsorbent for refrigeration

Composite adsorbents, comprising activated carbon and expanded natural graphite, have been developed, and their thermal conductivity, permeability and adsorption performance were tested. The thermal conductivity varied with the ratio of activated carbon to expanded natural graphite. Thermal conductivity increased as the ratio of expanded graphite increased. Considering that the density of activated carbon for the composite adsorbent should not be lower than 200 kg/m³, otherwise the volumetric cooling capacity would be unacceptably low, the highest thermal conductivity obtained from experiments was 2.47 W m^?1 K^?1. The permeability was also measured, and the best result obtained was 4.378 × 10^?12 m². In order to evaluate the influence of heat and mass transfer on adsorption performance, the adsorption rate was tested using a Rubotherm magnetic suspension balance, and results showed that for the freezing conditions lower than ?10 °C the performance of granular activated carbon was better than that of solidified adsorbent because of the reduced mass transfer of ammonia at low saturated pressure. The adsorption performance of consolidated adsorbents increased rapidly when the evaporating temperature was higher than ?10 °C. When the evaporating temperature was 8 °C, the adsorption rate of consolidated adsorbent was improved by 29% if compared with that of granular adsorbent.     

Biogas production from co-digestion of a mixture of cheese whey and dairy manure

In this study, daily amount of biogas of different mixtures of cheese whey and dairy manure, rates of production of methane, removal efficiencies of chemical oxygen demand (COD), total solid (TS) matter and volatile solid (VS) matter from the mixtures were investigated at 25 and 34 °C. In the experimental studies, two different solid matter rates (8% and 10%) were studied. The hydraulic retention times (HRTs) were 5, 10 and 20 days. Removal efficiencies and amount of biogas produced in each HRT were determined. Maximum daily biogas production was obtained as 1.510 m³ m^?3 d^?1 at HRT of 5 days in the mixture containing 8% total solid matters at 34 °C and the methane production rate was around 60 ± 1% in all experiments. Maximum removal efficiencies for TS, VS and COD were found as 49.5%, 49.4% and 54%, respectively at HRT of 10 days in the mixture containing 8% total solid matters at 34 °C.     

Thermal degradation of corn starch based biodegradable plastic plates and determination of kinetic parameters by isoconversional methods using thermogravimetric analyzer

Oil shortage and awareness of environment pollution leads to the extensive use of biodegradable starch-based materials against synthetic plastics. The accumulated wastes of these plastics takes more time for natural recycling and the process is complex. Therefore the best option of recycling would be to convert these polymers into a source of energy by pyrolysis. So to understand the pyrolytic behaviour, kinetics of such waste plastics is studied by using thermogravimetric analysis at different heating rates of 10 °C, 20 °C, 40 °C, 60 °C, 80 °C and 100 °C in nitrogen atmosphere followed by characterization of the pyrolysis products. The kinetic parameters are obtained for two major stages of decomposition in two different temperature ranges 250–620 °C and 620–855 °C by iso-conversional methods such as Friedman, Coats-Redfern, FWO and Kissinger methods. The regression coefficient data (>0.9) of kinetic plots obtained for different methods best fits to the kinetic equation. Empirical formula of the compound is determined by ultimate analysis is CH_2.214S_0.0018O_0.6910. Proximate analysis gives the idea of volatile component which is74.33%. The range of average value of activation energy is 120.7013 kJ/mol to 140.7707 kJ/mol for the biodegradable plastic plate with different conversion (0.1–0.6) and (0.1–0.3) respectively at two different temperatures. The pyrolysis products obtained using a semi-batch reactor are characterized to know their composition and other properties.     

Fouling of Some Canadian Crude Oils

A thermal fouling study was undertaken using three sour Canadian crude oils. Experiments were carried out in a re-circulation fouling loop equipped with an annular (HTRI) electrically heated probe. Fluids at pressures of about 1000–1340 kPa under a nitrogen atmosphere were re-circulated at a velocity of 0.75 m/s for periods of 48 hours, and the decline in heat transfer coefficient followed under conditions of constant heat flux. Bulk temperatures were varied over a range of 200–285^?C, and initial surface temperatures ranged from 300–380^?C. Heat fluxes were in a range of 265–485 kW/m².

Surface temperature effects on fouling of the three oils were compared, and fouling activation energies were estimated. For the lightest oil, a more detailed study of velocity and bulk and surface temperature effects was carried out. The fouling rate decreased slightly with increasing velocity but increased with both surface and bulk temperatures; a rough correlation was developed using a modified film temperature weighted more heavily on the surface temperature. Deposits showed high concentrations of sulfur and minerals, indicating the importance of iron sulfide deposition.     

Novel inorganic binary mixture for low‐temperature heat storage applications

In this study, an inorganic mixture based on bischofite (industrial by‐product) was developed and characterized for its application as a phase change material for low‐temperature thermal energy storage. The most appropriate composition was established as 40 wt% bischofite and 60 wt% Mg(NO₃)₂ · 6H₂O. Thermophysical properties were defined and compared with those of the mixture with synthetic MgCl₂ · 6H₂O. The heat of fusion and melting temperature were measured as 62.0°C and 132.5 kJ kg^?1 for the mixture with MgCl₂ · 6H₂O and 58.2°C and 116.9 kJ kg^?1 for the mixture with bischofite. The specific heat capacity values, cycling, and thermal stability for both mixtures were also determined. For the mixture with MgCl₂ · 6H₂O, the densities of the solid and liquid states were 1517 kg m^?3 (ambient temperature) and 1515 kg m^?3 (at 60‐70°C), respectively. For the mixture with bischofite, the densities of the solid and liquid states were 1525 kg m^?3 (ambient temperature) and 1535 kg m^?3 (at 60‐70°C), respectively. Both mixtures show supercooling of about 23.4 and 34.1°C for the mixture with bischofite and MgCl₂ · 6H₂O, respectively. In addition, it was shown that supercooling may be reduced by increasing the quantity of material tested. Thereby, it was established that an inorganic mixture based on bischofite is a promising PCM for low‐temperature thermal energy storage applications.     

Thermal analysis of constant flow partitioned solar pond

This paper presents the thermal analysis of the process of heat extraction by circulating water layer through the convective zone of a partitioned solar pond. The observed variation of atmospheric air temperature and solar intensity is assumed periodic. Explicit expressions for the transient rate and temperature at which heat can be extracted by circulation of water at constant flow rate, are derived. Numerical computations corresponding to solar heat flux and atmospheric air temperature measurement at New Delhi during the year 1974 have been made, and the optimization of the flow rate as well as the depth of the convective-non-convective zones in the pond have been investigated. The optimum heat retrieval efficiency of 27.5%, 34% and 40% corresponding to heat retrieval temperatures of 97°C, 60.5°C and 45.5°C, respectively, are predicted for water flow rates of 2 × 10^?4, 5 × 10^?4 and 10^?3 kg/s.m², respectively. The load levelling in retrieved heat flux improves as flow rates are lowered, and the non-convective zone is oversized. With the non-convective zone depth near optimum, an increase in the depth of the heat extraction zone considerably influences the retrieved heat flux; it shifts its maximum to winter months and deteriorates the load levelling. The variability in flow rate required for the maintenance of constant temperature of the heat extraction zone is also investigated. It is found that the required variability is less for higher temperatures of the extraction zone and larger depths of non-convective zone.     

Activity and stability of TiO2 samples with different phase compositions in the decomposition of formaldehyde in SCW

TiO₂ samples with different crystal sizes and compositions were synthesized using a sol-gel method at different calcination temperatures (350–900 °C). The activity and stability of TiO₂ samples were determined by the gasification of formaldehyde in supercritical water (SCW) and by treatment in SCW. Increasing calcination temperature and SCW gasification (SCWG)/SCW treatment decreased the surface area of anatase TiO₂ samples due to growing crystallite size via agglomeration and sintering. Among anatase TiO₂ samples, the TiO₂ calcinated at 450 °C was found as the most suitable material under SCW conditions. However, the surface area of rutile TiO₂ slightly increased from 17.2 m² g^?1 to 19.8 m² g^?1 with the weakly crumbling of particles during SCWG. The highest hydrogen formation (63%) from formaldehyde in the SCW was obtained in the presence of anatase TiO₂ calcined at 350 °C and rutile TiO₂ calcined at 800 °C. CO₂ formation in the presence of anatase TiO₂ is higher than rutile TiO₂ because of the presence of active lattice oxygen species (O^?, O^2?) based on O₂-TPD.     

Electrochemical and thermal properties of SmBa0.5Sr0.5Co2O5+δ cathode impregnated with Ce0.8Sm0.2O1.9 nanoparticles for intermediate-temperature solid oxide fuel cells

SmBa_0.5Sr_0.5Co₂O_5+δ (SBSC55) impregnated with nano-sized Ce_0.8Sm_0.2O_1.9 (SDC) powder has been investigated as a candidate cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs). The cathode chemical compatibility with electrolyte, thermal expansion behavior, and electrochemical performance are investigated. For compatibility, a good chemical compatibility between SBSC55 and SDC electrolyte is still kept at 1100 °C in air. For thermal dilation curve, it could be divided into two regions, one is the low temperature region (100–265 °C); the other is the high temperature region (265–850 °C). In the low temperature region (100–265 °C), a TEC value is about 17.0 × 10^?6 K^?1 and an increase in slope in the higher temperatures region (265–800 °C), in which a TEC value is around 21.1 × 10^?6 K^?1. There is an inflection region ranged from 225 to 330 °C in the curve of d(δL/L)/dT vs. temperature. The peak inflection point located about 265 °C is associated to the initial temperature for the loss of lattice oxygen and the formation of oxygen vacancies. For electrochemical properties, the polarization resistances (R_p) significantly reduced from 4.17 Ω cm² of pure SBSC55 to 1.28 Ω cm² of 0.65 mg cm^?2 of SDC-impregnated SBSC55 at 600 °C. The single cell performance of SBSC55∣SDC∣Ni-SDC loaded with 0.65 mg cm^?2 SDC exhibited the optimum power density of 823 mW cm^?2 at operating temperature of 800 °C. Based on above-mentioned properties, SBSC55 impregnated with an appropriate SDC is a potential cathode for IT-SOFCs.     

Investigation of Pyrolysis Kinetics of Humic Acids from Low Rank Anatolian Coal by Thermal Analysis

Abstract

Thermogravimetric analysis (TGA) of humic acid samples from low rank Anatolian (east of Turkey, Bingol) coal were investigated under atmospheric pressure. The samples were subjected for the decomposition of organic matter ambient to 800°C at four different heating rates (5, 10, 15, and 20°C min^?1). The humic acid samples were started at decomposition between 170–206°C and amount of residues varied 55–60% according to heating rate. Each of samples was showed a single step mass loss. TG/DTG data of samples were analyzed to determine activation energy values by Coats and Redfern method and Arrhenius method. Activation energy values are similar obtained from Coats and Redfern method and Arrhenius method and varied from 25 to 29 kJ mol^?1.     

Methane OSR over Pt-Ni/δ-Al2O3: Performance and power law type kinetics

Methane oxidative steam reforming (OSR) performance of two bimetallic Pt-Ni/δ-Al₂O₃ catalysts, having Pt:Ni loadings, 0.2:10 and 0.3:10, were tested first. In the tests, residence time (W/F), carbon-to-oxygen (C/O₂) feed ratio, and temperature were used as the experimental parameters. Increase in temperature resulted in direct and indirect - through enhanced TOX yielding higher energy - increase in SR rate. As Pt:Ni metal loading ratio did not lead to significant changes in activity, the preliminary kinetic tests to determine merely kinetically controlled region were conducted over 0.2Pt-10Ni catalyst. Considering the outcomes of the preliminary tests, the kinetic experiments were performed for practical reaction conditions extending up to 20% methane conversion with feed ratio intervals of 4.0 < C/O₂ < 7.34 and 2.03 < S/C < 3.08 at two different residence time (W/F) values to obtain a power-law type rate equation. Reaction orders were estimated as 0.81, 1.60 and 0.44 for methane, oxygen and steam, respectively, by using multivariable non-linear optimization function of MATLAB?. The apparent activation energy of methane OSR was calculated as 24.61 kJ mol^?1 and pre-exponential factor as 0.110 μmol mgcat^?1 s^?1 kPa^?2.85 for the 375–450 °C temperature interval. The same analysis performed for a narrower temperature range, 375–425 °C, gave k₀ and E_A values as 0.251 μmol mgcat^?1 s^?1 kPa^?2.85 and 29.17 kJ mol^?1, respectively, confirming the high sensitivity of OSR pathway to temperature.     

Hot deformation behaviour of niobium in temperature range 700–1500°C

Abstract

Niobium was hot deformed in vacuum in uniaxial compression to a true strain of 0·6 in the temperature range of 700–1500°C and the strain rate range of 10^?3–10 s^?1. Strain rate sensitivity was calculated from the compression tests data and mapped out in contour plots with the aim to optimise the hot workability of niobium. The domain of hot workability was identified in the temperature range of 1200–1500°C and strain rate range of 10^?2–1 s^?1. In this domain the strain rate sensitivity was ～0·15, the stress exponent 7·5 and the activation energy 246 kJ mol^?1. Microstructure of the deformed samples showed features of dynamic recrystallisation within the high strain rate sensitivity domain and features of flow instability in the regime of low strain rate sensitivity. Compared to a previous study on Nb–1Zr–0·1C alloy, Nb showed a lower flow stress and an optimum hot working domain at lower temperatures.     

Thermal efficiency of solid electrolyte fuel cells with mixed conduction

The effect of mixed anionic and n-type electronic conduction in solid electrolytes on the thermal efficiency of a fuel cell system was analyzed quantitatively. The mixed conduction observed when electrolytes based on ceria are used in H₂/air fuel cell applications lowers the maximum attainable cell thermal efficiency to below 40%. Neither the zirconia nor the ceria based solid oxide electrolytes studied to date can be used in a low temperature (700 °C) system that meets simultaneously the requirements of power density and thermal efficiency for electric utility power plants. The material properties required for an advanced fuel cell power plant solid electrolyte were derived in terms of the ionic conductivity and the Schmalzried parameters P⊕ and P? : σ_ion > 0.033 (ω-cm)^?1, P⊕ > 10³ atm., P? < 10^?23 atm. at 700 °C.     

FeCo alloys in-situ formed in Co/Co2P/N-doped carbon as a durable catalyst for boosting bio-electrons-driven oxygen reduction in microbial fuel cells

Non-noble metal catalyst with high catalytic activity and stability towards oxygen reduction reaction (ORR) is critical for durable bioelectricity generation in air-cathode microbial fuel cells (MFCs). Herein, nitrogen-doped (iron-cobalt alloy)/cobalt/cobalt phosphide/partly-graphitized carbon ((FeCo)/Co/Co₂P/NPGC) catalysts are prepared by using cornstalks via a facile method. Carbonization temperature exerts a great effect on catalyst structure and ORR activity. FeCo alloys are in-situ formed in the catalysts above 900 °C, which are considered as the highly-active component in catalyzing ORR. AC-MFC with FeCo/Co/Co₂P/NPGC (950 °C) cathode shows the highest power density of 997.74 ± 5 mW m^?2, which only declines 8.65% after 90 d operation. The highest Coulombic efficiency (23.3%) and the lowest charge transfer resistance (22.89 Ω) are obtained by FeCo/Co/Co₂P/NPGC (950 °C) cathode, indicating that it has a high bio-electrons recycling rate. Highly porous structure (539.50 m² g^?1) can provide the interconnected channels to facilitate the transport of O₂. FeCo alloys promote charge transfer and catalytic decomposition of H₂O₂ to ?OH and ?O₂^?, which inhibits cathodic biofilm growth to improve ORR durability. Synergies between metallic components (FeCo/Co/Co₂P) and N-doped carbon energetically improve the ORR catalytic activity of (FeCo)/Co/Co₂P/NPGC catalysts, which have the potential to be widely used as catalysts in MFCs.     

Thermophysical properties of molten tungsten measured with an electrostatic levitator

Thermophysical properties of liquid and supercooled tungsten were measured using non‐contact techniques in combination with an electrostatic levitator. Over the 3125–3707 K temperature range, the density measurements can be expressed as ρ (T) = 16.7(± 0.33)× 10³ ? 1.08(± 0.08) (kg? m^?3) with T_m = 3695 K, leading to a volume expansion coefficient of 6.6×10^?5 K^?1. In addition, over the 3398–3695 K temperature range, the surface tension (γ) and viscosity (η) data can be expressed respectively as γ (T) = 2.48× 10³(± 75) ? 0.31(± 0.08) (T ? T_m) (10^?3 N? m^?1) and η (T) = 0.11(± 0.02) exp[12.8(± 4.1) × 10⁴/(RT)] (10^?3 Pa? s). © 2006 Wiley Periodicals, Inc. Heat Trans Asian Res, 35(2): 152–164, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20101