Particulate Fouling and Challenges of Metal Foam Heat Exchangers

ABSTRACT

In recent years, open-cell metal foam has gained attention for utilization for exhaust gas recirculation coolers due to its large surface area and porous structure. Theoretically, the porous foam structure would have better transfer heat through conduction and convection processes. However, the exhaust gases that enter the cooler would carry particulate matter, which may deposit within the foam structure. The existing fouling studies cannot explain the underlying mechanisms of particulate deposition thoroughly within the foam structure. This study reviews the particulate fouling of heat exchangers, particularly in the exhaust gas recirculation system. Some past approaches to investigate fouling, particle transport, and deposition in the metal foam heat exchangers for many different applications are also included. In addition, this study also includes the challenges that lie ahead in implementing the metal foam heat exchangers in the industries.     

Optimization of Flow Direction to Minimize Particulate Fouling of Heat Exchangers

The influence of flow direction with respect to gravity on particulate fouling of heat exchangers is investigated experimentally to determine the optimal flow direction to minimize fouling. Four orientations of flow have been investigated: horizontal flow, upward flow, downward flow, and a flow under an angle of 45°. It is observed that fouling starts at the point of stagnation irrespective of the flow direction, and also at the top of the heat exchanger tubes. Particulate fouling grows from these two points till they meet and the fouling layer covers the whole surface of the heat exchanger tube. Fouling at the upper half of the tubes is much faster than the lower half of the tubes, and the fouling rate is faster at the bottom tubes of the heat exchanger section than at the upper tubes. The best orientation for lingering particulate fouling is the downward flow, where the flow stagnation point coincides with the top point of the heat exchanger tubes and the growth of the fouling layer only starts from one point.     

Effect of Geometry and Flow Conditions on Particulate Fouling in Plate Heat Exchangers

This article describes particulate fouling experiments performed on small-scale and full-scale plate heat exchangers for three different corrugation angles (30 deg, 45 deg and 60 deg). The velocity effect has been studied as well as the particle type and concentration effects. The test duration ranges between 20 and 1,500 h in order to reach asymptotic behavior. The results clearly indicate that the corrugation angle has a major influence on the asymptotic fouling resistance. Increasing the corrugation angle leads to lower values for the fouling resistance. Furthermore, for a given corrugation angle, the asymptotic fouling resistance is inversely proportional to the velocity squared. Finally, the asymptotic fouling resistance is proportional to the particle concentration. Fouling mitigation can be obtained by taking into account at the design stage the heat exchanger geometry and fluid velocity.     

板式换热器颗粒污垢特性的实验研究

以纳米氧化镁颗粒溶液为实验工质,进行了板式换热器颗粒污垢特性的实验研究,分析了颗粒质量浓度、颗粒粒径、流速和低温介质温度对颗粒污垢热阻的影响.结果表明:板式换热器颗粒污垢无明显诱导期存在,结垢速率和污垢热阻渐进值均随颗粒质量浓度的增大而增大,且增大幅度逐渐减小;颗粒粒径对污垢热阻的影响较明显,在相同质量浓度下,颗粒粒径越小,结垢速率越快,且污垢热阻越大;流速对污垢热阻的影响较为复杂,高流速下的结垢速率略大于低流速下,且高流速下达到稳定时的污垢热阻渐进值小于低流速下;低温介质温度对颗粒污垢热阻的影响不明显.     

Modeling of Particulate Fouling on Heat Exchanger Surfaces: Influence of Bubbles on Iron Oxide Deposition

Studies of iron oxide deposition on Alloy-800 heat exchanger tubes have been part of a continuing research program at the University of New Brunswick (UNB); the present work formulates mechanisms for the effect of bubbles on deposition in water under boiling conditions. To supplement results from earlier deposition experiments in a fouling loop at UNB, measurements of bubble frequency and departure diameter as a function of heat flux were performed. High-speed movies of bubbling air/water systems indicated that a pumping action moved particles from adjacent areas at the surface to bubble nucleation sites. To explain the observations, the model considers deposition and concomitant removal. Deposition includes microlayer evaporation and filtration through the porous deposit. The deposit is sparse in the first stage, when the dominant process is microlayer evaporation including particle trapping and pumping, creating spots of deposit. Filtration becomes more important as the deposit thickens to a stage when microlayer evaporation becomes negligible. Chimney effects then control. Turbulence due to detaching and collapsing bubbles affects removal. In subcooled boiling, collapsing bubbles generate enough turbulence to maintain much of the deposit labile, while in bulk boiling bubble detachment from the nucleation site is dominant and a smaller portion of the deposit is labile and subject to removal. Model predictions are presented and shown to agree quite well with experimental data.     

Modeling and Prediction of Shell-Side Fouling in Shell-and-Tube Heat Exchangers

Fouling is a challenging, longstanding, and costly problem affecting a variety of heat transfer applications in industry. Mathematical models that aim at capturing and predicting fouling trends in shell-and-tube heat exchangers typically focus on fouling inside the tubes, while fouling on the shell side has generally been neglected. However, fouling deposition on the shell side may be significant in practice, impairing heat transfer, increasing pressure drops, and modifying flow paths. In this paper, a new model formulation is presented that enables capturing fouling on the shell side of shell-and-tube heat exchangers including the effect of occlusion of the shell-side clearances. It is demonstrated by means of an industrial case study in a crude oil refinery application. The model, implemented in an advanced simulation environment, is fitted to plant data. It is shown to capture the complex thermal and hydraulic interactions between fouling growth inside and outside of the tubes, the effect of fouling on the occlusion of the shell-side construction clearances, and to unveil the impact on shell-side flow patterns, heat transfer coefficient, pressure drops, and overall exchanger performance. The model is shown to predict the fouling behavior in a seamless dynamic simulation of both deposition and cleaning operations, with excellent results.     

Influence of Spiral Angle on Heat Transfer during Condensation inside Spiralled Micro-Fin Tubes

This paper reports the influence of the spiral angle on the heat transfer performance during condensation inside spiraled micro-fin tubes having constant geometric parameters such as fin height, pitch, shape (apex angle), and fin number, as various papers previously published in this field had not clearly established this influence. Tests were conducted for condensation of R-22, R-134a, and R-407C inside a smooth tube (9.52 mm outer diameter) and three micro-fin tubes with approximately the same diameter and spiral angles of 10°, 18°, and 37°, respectively. Experimental results indicated a heat transfer augmentation with spiral angle increase. A new semi-empirical predictive correlation was developed for the practical design of spiraled micro-fin tubes. The proposed new correlation predicted the majority of experimental results of the present study within a deviation zone of ±20 percent.     

污水换热器污垢生长特性试验研究

污水换热器污垢是影响污水冷热源应用的主要因素.了解污垢的形成规律是污水换热器应用与研究的基本要求.基于工程现场实验,通过热阻法测定污水换热器管程内污垢的热阻变化模型Rf(θ)=8×10-4[1-exP(-θ/188)].提出了污垢形成过程有效热阻与有效总传热系数的概念.并通过热阻模型提出了渐进型污垢形成过程的压降模型△(△p)=A-Bexp[-t/t0).为进一步的研究与应用提供了理论基础.     

Influence of Scaling on the Performance of Shell-and-Tube Heat Exchangers

Fouling in shell-and-tube heat exchangers was modeled by combining Hasson's ionic diffusion model for scaling from CaCO₃ solutions with a model for predicting the temperature distribution developed by Gaddis and Schlünder. Using the computed results, clean heat exchanger design rules were tested for fouling conditions. The effects of fouling on the efficiency of heat exchanger configurations were determined.     

Two-Phase Flow Distribution to Tubes of Parallel Flow Air-Cooled Heat Exchangers

Abstract

This paper addresses two-phase flow distribution phenomena in multiple header–tube junctions used in heat exchangers. Because of phase separation, it is very difficult to obtain uniform two-phase flow distribution to the branch tubes. The flow distribution is strongly influenced by the header orientation (horizontal or vertical) and the number of branch tubes. Other factors that influence the flow distribution are the flow direction in the header (upflow or downflow), the header shape and tube end projection into the header, and the location and orientation of the inlet and exit connections. The source of maldistribution is the flow in the dividing headers. Work performed by the authors and others (including patents) are discussed. The possibilities for eliminating two-phase flow maldistribution are identified and discussed. This investigation shows that solutions, which provide uniform flow distribution, are very design-specific. Change of the geometry or operating parameters will require modification of the design.     

Double-Pipe and Multitube Heat Exchangers with Plain and Longitudinal Finned Tubes

This article attempts to update the rather sketchy methods for double pipe exchangers in the present literature, especially those for longitudinal finned tubes. Areas and conditions for the most useful application of double and multitube exchangers are outlined. Calculation methods are presented for plain double pipe units, as well as finned tube units, with a new development in the important transition region with “cut-and-twist” turbulency promoters. Equations for the mean temperature difference for units with flow in series-parallel are also given.     

A Critical Review of Basic Crystallography to Salt Crystallization Fouling in Heat Exchangers

Fouling formation on heat exchanger surfaces due to crystallization of inverse solubility salts is one of the fundamental problems in process industries. Despite numerous studies carried out in recent years, comprehensive understanding of crystallization fouling mechanism remains a challenge to chemical engineers. In this review, we first focus on the basic crystallography during deposition of calcium salts, paying attention to crystal structures and crystal forms, as well as nucleation and the subsequent crystal growth process. We then endeavor to relate a number of factors to fouling rate, which may be classified into three categories: solution composition, operating parameters, and heat exchanger surface characteristics. Each aspect is discussed from the crystallization viewpoint (science) and in terms of possible industrial applications (practice). Combining the basic knowledge of crystallography with the information from experimental investigations, several fouling mitigation methods have also been described that may reduce fouling. It is hoped that some of the ideas discussed here will provide possible economic and environmental benefits. Finally, we also try to throw some light on the future direction for research.     

Petroleum Stability and Heteroatom Species Effects in Fouling of Heat Exchangers by Asphaltenes

Petroleum stability effects on heat exchanger fouling were studied using mixtures of heavy oil containing asphaltenes, and carrier fluids consisting of a fuel oil cut with varying amounts of added aliphatic or aromatic fluid. Fouling was measured in a recirculation loop using an annular, electrically heated probe. The effects of carrier fluid composition, dissolved oxygen, and heteroatomic species additions were investigated. Insolubles formed in the mixtures, measured by hot filtration, and deposits on the probe had compositions similar to asphaltenes. Fouling rates were correlated with instability indices, and with the concentrations of suspended asphaltenes.     

Thermal Fouling of Heat Exchanger Tubes due to Heavy Hydrocarbon Droplets Impingement

ABSTRACT

This work discusses fouling in the vapor–steam mixture overheater in the convection section of an industrial steam cracker due to the thermal degradation of heavy hydrocarbon droplets deposited on the tube wall. A spray of heavy hydrocarbon multicomponent droplets is injected in a tube of the vapor–steam mixture overheater and the path of the droplets through the tube is followed by an Eulerian–Lagrangian computational fluid dynamics simulation. To study tube fouling, the droplet impingement behavior on the wall, the evaporation of the deposited liquid, and a coking model describing thermal coke formation due to degradation of heavy hydrocarbons are required. To describe the droplet impingement behavior, a regime map for single component millimeter-sized droplets is taken from the literature. Two simulations are performed to study fouling problems in a vapor-mixture overheater tube. Simulation results are found to be grid sensitive. By analyzing and comparing simulation results it is concluded that reliable fouling data require a regime map for the impingement of multicomponent heavy hydrocarbon micron-sized droplets.     

Effect of Condensable Species on Particulate Fouling

The flue gases emanating from the combustion of fuels or gasification process invariably comprise particulate matter and many chemical species in vapor form. The temperature of the flue gases gradually reduces when passing through different sections of heat exchanger, such as the superheater, evaporator, and so on. If the temperatures of the heat exchanger tube surface and the gas phase are favorable for condensation, the chemical species in the vapor form will condense on the particles and on the tube surface. The particle deposition behavior under these conditions is drastically different from the one observed in dry particulate fouling. In order to model the particle deposition under such circumstances, it is important to evaluate the criteria for particle adhesion to the surface. Impaction experiments of particles impacting a surface coated with a thin liquid film and particles that are coated with a liquid film impacting over a dry surface are performed to evaluate the limiting parameters under which a particle sticks to the surface without rebounding. The effects of liquid viscosity, liquid film thickness, and interacting material properties are evaluated. The experimental results are compared to the results of existing models and a suitable model for fouling is proposed. Controlled fouling experiments are performed for varying liquid films coated over a deposition tube under various process conditions to mimic the condensation effects on fouling. The results are compared with detailed impaction experiments.     

Optimum Design of Cross-Flow Shell and Tube Heat Exchangers with Low Fin Tubes

This paper presents a simple, efficient, robust, optimum design methodology for the design of a high heat transfer and low pressure drop cross-flow shell and tube heat exchanger with integral low fin tubes. This type of heat exchanger has the potential for application in the design of coolers in hypersonic wind tunnels to cool the air that emerges from the diffuser section of the wind tunnel. The methodology described here allows for the design and optimization of any type of heat exchanger that has constraints on pressure drop, as well as the design of an exchanger for very low pressure drop on the shell side fluid.     

影响换热面结垢诱导期的表面特性研究

换热面结垢是一个普遍存在的问题,而结垢诱导期的长短对污垢形成过程具有重要的影响,即使在相同实验条件下,不同材料换热面的结垢诱导期仍相差较大.因此本文通过对附着在换热面上的半球形污垢晶核进行受力分析,发现污垢晶核与换热面之间的附着力对其结垢诱导期长短起决定性作用,然后根据颗粒与平板间附着力模型,计算了污垢晶核与具有不同表面能的换热面间附着力,并与相应的结垢诱导期进行对比.结果表明:结垢诱导期的长短与换热面的表面能、污垢晶核与换热面间的附着力及表面粗糙度尺度有关.     

A Large Eddy Simulation of Plate-Fin and Tube Heat Exchangers with Small Diameter Tubes

Plate-fin and tube heat exchangers are extensively studied both experimentally and numerically. However, data on the fluid flow and heat transfer in the exchanger passage with small diameter tubes have not been accumulated enough. With a large eddy simulation technique (LES), this study performs a detailed investigation of the fluid flow and heat transfer in a plate-and-tube channel with tubes of diameters as small as 5.2 mm. The conservation equations for mass, heat, and momentum were solved by the proposed LES model. It was found that the LES model is appropriate to predict the fluid flow and heat transfer. Compared to heat exchangers of larges tubes, the heat exchangers exhibit much higher heat transfer coefficients with small tubes. The fin efficiencies are improved with small tubes.     

Experimental Analysis of the Effects of Particulate Fouling on Heat Exchanger Heat Transfer and Air-Side Pressure Drop for a Hybrid Dry Cooler

It is well known that significant fouling by particulate matter can have a deleterious effect on the performance of enhanced surface heat exchangers, and the same is true for hybrid heat exchangers. Hybrid heat exchangers are heat exchangers that are typically run in dry mode to reject heat. When the ambient conditions require more heat rejection than can be provided by sensible heat transfer, a water pump is turned on and water flows over the fins, and the evaporation of water provides a further cooling effect. Fouling in dry-mode operation is physically similar to that of air-cooled heat exchangers, but in evaporative mode the flow of the water over the coil eliminates the impact of fouling. A hybrid dry cooler heat exchanger of 60 cm × 60 cm frontal area has been installed in a well-instrumented wind tunnel to measure the heat exchanger's performance. Hot water flows through the coil to provide the load, and air flows over the coil to provide cooling. During evaporative mode operation another stream of water flows over the outside face of the coil, adhering mainly to the louvered fins. The louvered fins are specially designed for optimized water flow during wetting mode. The fins are made of aluminum, the tubes are copper, and protection against corrosion is realized by a special E-coating. This coil has been tested clean and fouled with ASHRAE standard dust, for both dry and wet operation. Results are presented for the air-side pressure drop and overall heat transfer conductance of the coil under all conditions for which 50% increases in air-side pressure drop are found under heavy fouling. The influence of fouling on heat transfer is small. Also, using the wetting water to wash the fouling off the coil is investigated and is found to be of some limited utility.