The initial and residual value for subterranean clover of phosphorus from crandallite rock phosphates,apatite rock phosphates and superphosphate

The residual value of phosphorus from superphosphate, crandallite rock phosphate (Christmas Island C-grade ore), 500°C calcined crandallite rock phosphate (Calciphos) and apatite rock phosphate from Queensland, Australia, was measured in a 6 year field experiment sited on lateritic soil in south-western Australia. Different amounts of each fertilizer were applied at the commencement of the experiment, and either left on the soil surface or mixed through the soil by cultivating to a depth of about 10 cm. Dry matter production of subterranean clover measured in spring (August) and bicarbonate-extractable phosphorus determined from soil samples collected in summer (January–February) were used as indicators of fertilizer effectiveness.The effectiveness values calculated for each fertilizer each year were similar for the treatments that were left on the soil surface and those which were mixed through the soil. The effectiveness of both ordinary and triple superphosphate were similar each year. They were the most effective fertilizers for the duration of the experiment. Using pasture yield as an indicator, the effectiveness of the superphosphates decreased by about 50% from year 1 to year 2, and by a further 10% over the remaining 4 years. Using bicarbonate-extracted soil phosphorus the effectiveness of both superphosphates decreased in a more uniform fashion by about 60% from year 2 to year 6. The effectiveness of all the rock phosphate fertilizers was approximately constant through time. As calculated from yield and bicarbonate-soluble phosphorus values, C-grade ore, Calciphos and the Queensland apatite were respectively 5%, 20% and 7% as effective as freshly applied superphosphate.The proportion of the total phosphorus content present in the rock phosphates which was initially soluble in neutral ammonium citrate was a poor predictor of the effectiveness of the phosphorus from these fertilizers determined using herbage yield or the amount of bicarbonate — soluble phosphorus extracted from the soil.The bicarbonate soil test did not predict the same future production for superphosphate and some of the rock phosphates in years 2 and 3 of the experiment, indicating that different soil test calibration curves are needed for the different fertilizers.     

The comparative agronomic effectiveness of rock phosphate and superphosphate for banana

The agronomic effectiveness of three rock phosphates (Idaho, Florida and North Carolina) as influenced by mycorrhizal inoculation withGlomus aggregatum was evaluated using small banana (Musa paradisiaca L.) corms as planting material. The treatments included superphosphate and a no-P control. The soil was fumigated to eliminate mycorrhizal propagules. The amount of P added was based on the quantity of material needed as superphosphate to establish 0.2 mg P L^–1 in solution. Plants were grown in an Oxisol in 9-liter pots for 3 months after growth commenced. Plant dry weight, P percentage in the 3rd leaf, and total P uptake were increased when plants fertilized with insoluble rock phosphates were inoculated with mycorrhiza-producing fungi. Phosphorus uptake by plants fertilized with Idaho, Florida, and North Carolina rock phosphates was 0.18, 0.42, and 0.97 as much as by plants fertilized with superphosphate. The beneficial effect of mycorrhiza on phosphate uptake was 136, 30, 2 and 24% for plants fertilized with Idaho, Florida and North Carolina rock phosphate, and superphosphate, respectively.     

Comparative study of reactivity and agronomic effectiveness of Indian,US, African and Middle East rock phosphates for growing rice

Comparative reactivity and efficiency of eight Indian, six US, two African and one Middle East sources of rock phosphates for growing rice on laterite, red and alluvial soils under flooded conditions were evaluated in pot and laboratory experiments. When applied to moist aerobic soils, 15 days prior to flooding and transplanting rice, all the Indian sources were as poor as theno phosphate control in the three soil types, in respect of P availability in soil, grain yield response and P uptake by rice. North Carolina rock phosphate used in this study was as good as superphosphate in the laterite and red soils, but was also as poor as control in the black soil.NH₄ -citrate was found to interfere in the colorimetric determination of citrate soluble P by the vanado-molybdate colour method. A modified sulpho-molybdate-Sn Cl₂ blue colour method could successfully be used to determine 2–8µg P in the presence of 0.02 to 0.2 meq NH₄ -citrate, especially in rocks containing small amounts of citrate soluble P. All the Indian, as well as Idaho, Missouri and Tennessee rock phosphates were found to be less reactive as they contained much lower amounts of citrate extractable P in eight successive extracts as compared to North Carolina rock phosphate.The cumulative citrate soluble P of 10 rock phosphates determined experimentally in eight successive extracts was significantly correlated with their reported a₀ (length of a axis of unit apatite crystal), mole ratio of CO₃/PO₄ or weight ratio of F/P₂O₅ of rocks. In the absence of X-ray and computer facilities, these regression equations were used to calculate the a₀, CO₃/PO₄, F/P₂O₅, ACS, empirical formula and the apatite content of the unknown Indian rock samples. The Indian rock phosphates had a lower degree of CO₃ and F substitution for PO₄ in the apatite crystal, giving low ACS values and hence were less reactive. This might explain their lower efficiency for direct application for growing rice, obtained in the present experiment. These Indian rock phosphates had also lower apatite content. The use of the statistical method was limited to francolites alone. Scope for the use of this method for other unknown francolite rock phosphate samples has been discussed.     

The residual value of superphosphate and rock phosphates for lateritic soils and its evaluation using three soil phosphate tests

The residual value of superphosphate and several rock phosphates was measured in three field experiments in Western Australia. The rock phosphates were Christmas Island C-grade ore, calcined C-grade ore (Calciphos) and apatite rock phosphates. The predictive capacity of the Colwell, Olsen and Bray 1 soil tests for phosphate were also evaluated.As measured by yields of variously wheat, oats, barley or clover, the effectiveness of an initial application of superphosphate decreased to about 50% of that of newly applied superphosphate between years 1 and 2, and further decreased to about 20% over subsequent years. At low levels of application, all the rock phosphates were between 10–20% as effective as superphosphate in the year of application for all experiments. Relative to newly applied superphosphate their effectiveness remained approximately constant in subsequent years for two experiments and doubled for the other experiment.The Colwell soil test predicted that the effectiveness of superphosphate decreased to about 45% between years 2 and 3, followed by a more gradual decrease to approximately 15%. At low levels of application, the effectiveness of the rock phosphates as predicted by the Colwell soil test values was initially very low relative to superphosphate (2–30%), and remained low in subsequent years (2–20%). For superphosphate treated soil, the proportion of the added phosphorus extracted generally increased as the level of application increased. By contrast, for rock phosphate treated soil, the proportion of added phosphorus extracted decreased as the level of application increased.For all three experiments there were highly significant positive correlations between amounts of P extracted by the three soil tests. Consequently all soil tests were equally predictive of yield but usually for each soil test separate calibrations between yield and soil test values were required for the different fertilizers and for each combination of fertilizer and plant species and for each year.     

The agronomic effectiveness of reactive rock phosphate,partially acidulated rock phosphate and monocalcium phosphate in soils of different pH

The initial and residual fertilizer effectiveness of North Carolina RP (rock phosphate), monocalcium phosphate and partially acidulated RP (made from North Carolina RP at 30% acidulation), both granulated and non-granulated, were measured in a glasshouse experiment. Triticale (xTriticosecale) was grown for 30 days on a soil that had been adjusted to three pH values (4.2, 5.2 and 6.2). Two crops were grown with a six month interval between crops. The effectiveness of the different fertilizers was compared using relationships between (1) yield of dried tops and the amount of P applied and (2) P content (P concentration in tissue multiplied by yield) and the amount of P applied. For the first crop, relative effectiveness (RE) of the fertilizers was calculated relative to granulated monocalcium phosphate, the most effective fertilizer. Monocalcium phosphate was not applied to the second crop, so relative residual effectiveness (RRE) was estimated for each fertilizer relative to the residual effectiveness of granulated monocalcium phosphate.The relative effectiveness of granulated monocalcium phosphate (band application) was greater (RE = 1.00) than of North Carolina RP (0.01–0.02) and partially acidulated RP (0.45–0.76) for all three soil pH values for the first crop. Granulation and band application increased the effectiveness of monocalcium phosphate and partially acidulated RP, but reduced the effectiveness of North Carolina RP. Both non-granulated monocalcium phosphate and partially acidulated RP were less effective than granulated partially acidulated RP for both crops. For the second crop granulated monocalcium phosphate was most effective and the RRE of non-granulated partially acidulated RP (0.16–0.32) and North Carolina RP (0.19–0.28) was greater than for non-granulated monocalcium phosphate (0.12). For the more acidic soil the RE of non-granulated North Carolina RP was four times higher than for the high pH soil for the first crop and 60% higher for the second crop, but it was still poorly effective relative to granulated monocalcium phosphate. Granulated North Carolina RP was least effective among all the fertilizers for all soil pH values and for both crops.     

Long-term residual value of North Carolina and Queensland rock phosphates compared with triple superphosphate

The effectiveness of large single applications of North Carolina reactive rock phosphate, Queensland non-reactive rock phosphate, and Calciphos, were compared to the effectiveness of superphosphate in field experiments in south-western Australia for up to 11 years after application. As measured using plant yield, superphosphate was the most effective fertilizer in the year of application, and relative to freshly-applied superphosphate, the effectiveness of the superphosphate residues declined to be about 15 to 65% as effective in the year after application, and 5 to 20% as effective 9 to 10 years after application. Relative to freshly-applied superphosphate, all the rock phosphates were 10 to 30% as effective in the year of application, and the residues remained 2 to 20% as effective in the 10 years after application. The bicarbonate soil test reagent predicted a more gradual decrease in effectiveness of superphosphate of up to 70% 10 years after application. For rock phosphate, the reagent predicted effectiveness to be always lower than for superphosphate, being initially 2 to 11% as effective in the year after application, and from 10% to equally as effective 10 years later. Therefore rock phosphates are unlikely to be economic alternatives to superphosphate in the short or long term on most lateritic soils in south-western Australia.     

The relative effectiveness of superphosphate and rock phosphate for soils where vertical and lateral leaching of phosphate occurs

Laboratory studies have shown that up to 70% reactive rock phosphate dissolves in three soil types found in the high rainfall (> 800 mm annual average) area of south-western Australia. Three field experiments were undertaken on these soils to compare reactive apatite rock phosphate from North Carolina (NCRP) with single superphosphate (SSP) as fertilizers for subterranean clover (Trifolium subterraneum) pasture. Vertical leaching of phosphorus (P) occurs in one soil, a deep, very sandy, acid peaty sand. Lateral leaching of P occurs in the second soil, a shallow (3 cm) sand over a slowly permeable sandy clay loam. No leaching of P occurs in the third soil, a uniform, permeable red sandy loam with a moderate capacity to sorb P. All the soils remained moist to very wet for the 6 to 8 month growing season. Fertilizers were applied once only to different plots over a four-year period (1992 to 1995). Each year fertilizer effectiveness was determined relative to the effectiveness of freshly-applied (current) SSP using yield and P content of dried clover herbage and bicarbonate-soluble P extracted from the soil (soil test P) as indices of effectiveness.For the two P leaching soils, NCRP was less, equally, or more effective than current SSP in different years. This variation is attributed to the different extents of leaching of P from current SSP in different years which experienced different amounts of rainfall and associated leaching. For the non-P leaching soil, the effectiveness of current NCRP and the residual effectiveness of NCRP were from 5 to 80% the values for current SSP. When measured using soil test P, current NCRP and residual NCRP varied from 40% as effective, to equally or 30% more effective as current SSP at one site, but were about 20% as effective at the other two sites. For the two P leaching soils in some years, the residual value of RP was higher than that of current SSP, presumably due to the rapid leaching of water-soluble P from the SSP. As measured using yield, P content and soil test P, the relative effectiveness of SSP consistently decreased with increasing time from application; the decreases were much less obvious for NCRP.     

The current and residual value of superphosphate for lupins grown in rotation with oats and wheat on a deep sandy soil

In a field experiment on a deep pale-yellow sand in a 600 mm per annum rainfall Mediterranean environment of south-western Australia, six levels of phosphorus (P) as superphosphate (O up to 546 kg P ha^–1) were applied once only, to the soil surface, before sowing lupins (Lupinus angustifolius). The lupins were grown in a continuous arable cropping rotation with, in successive years, oats (Avena sativa), wheat (Triticum aestivum), lupins. Five such rotations were started in the experiment from 1985 to 1989. The experiment continued until the end of 1990.The relationship between lupin seed (grain) yields and the level of P applied was measured in the year of P application for five successive years (1985 to 1989). The relationship had the same general form but it varied between years, largely due to different maximum yields (yield plateaux) in each year.The residual value of superphosphate applied three years previously was measured for lupins on two occasions (1988 and 1989) relative to superphosphate applied in the current year. The residual values was different in the two years. The superphosphate applied three years previously was about 30% as effective as freshly applied superphosphate in 1988, and 12% as effective in 1989.At each harvest, the relationship between grain yield and the P concentration in the grain differed for different species. However, for each species at each harvest, the relationship was similar regardless of when the P was applied in the previous years. Thus each species had the same internal efficiency of P use curve, and yields varied only with P concentration in tissue.Bicarbonate-extractable soil P was determined on soil samples taken in mid-July of 1989 and 1990. These soil test values were related to grain yields at harvest. The relationship between yield and soil test values had the same general form but varied for different species within years and for each species between years. It also varied for each species within years depending on the year the P was applied.     

Effectiveness of two partially acidulated rock phosphates,coastal superphosphate and Ecophos,compared with North Carolina reactive rock phosphate and superphosphate

The effectiveness of coastal superphosphate, a partially acidulated rock phosphate (PARP) made from apatite, and Ecophos, a PARP made from calcium iron aluminium (crandallite millisite) rock phosphate, was compared in pot experiments with the effectiveness of ordinary superphosphate (OSP) and North Carolina reactive apatite rock phosphate (NCRP). There were three experiments using different lateritic soils collected in Western Australia. Fertilizer effectiveness was measured using yield of dried wheat (Triticum aestivum) tops grown for 28 days. Three successive crops were grown. The phosphorous (P) fertilizers were applied and mixed with the soils before sowing the first crop. In addition, OSP was added to extra pots before sowing crops 2 and 3 in order to measure the effectiveness of the original P fertilizers relative to freshly-applied OSP for these crops.As measured using plant yield, coastal superphosphate was the most effective P fertilizer for three crops on an acidic peaty sand (pH water 5.0). Relative to freshly-applied OSP, it was 154% as effective for crop 1, 75% as effective for crop 2, and 36% as effective for crop 3. Corresponding values for Ecophos were 44, 29 and 19%, and for NCRP, 77, 67 and 29%, with the original OSP treatment being 61 and 56% as effective for crops 2 and 3. For three crops on a lateritic gravel loam (pH 6.5), both coastal superphosphate and OSP were the most effective fertilizers, and were equally effective for crop 1, and relative to freshly-applied OSP, were about 31% as effective for crop 2, and 16 and 21 % as effective for crop 3. Corresponding values for Ecophos were 47,15 and 11%, and NCRP, 33,15 and 5%. For two crops in a loamy sand (pH 5.4), OSP was the most effective fertilizer, and, relative to fresh OSP, it was 36% as effective for crop 2. Relative to fresh OSP, the effectiveness for crops 1 and 2 of coastal superphosphate was 57 and 18%, for Ecophos 71 and 27%, and for NCRP 50 and 36%.     

The residual effectiveness of previously applied copper fertiliser for grain yield of wheat grown on soils of south-west Australia

The residual effectiveness of copper (Cu) applied 18 to 21 years previously was estimated for grain yield of wheat. In one field experiment, current levels of Cu fertiliser were applied and its effectiveness was compared to that of the same level of Cu applied previously. The effects of nitrogen (N) fertiliser on the Cu concentration in the youngest emerged blade and in the grain, as well as the effects of N levels on the grain yield of wheat, were also studied.Where the recommended level of Cu fertiliser had been applied previously, its residual effectiveness depended on the soil type. On the grey sands over clay and gravelly sands over clay, the residual Cu would last approximately 20 years where wheat is grown in rotation with a legume crop (Lupinus augustifolius L.) and where N fertiliser is applied at high levels (92 kg N ha^–1). On the yellow brown sandy earths of the Newdegate district, the residual value was in excess of 30 years.When Cu levels in the soil are marginal, high levels of N applied to wheat crops grown on stubbles of legume crops (high soil N) could suffer from induce Cu deficiency which could reduce grain production.Critical concentrations of Cu in the youngest emerged blade of less than 1.2 mg Cu kg^–1 at Gs50–59 would indicate Cu deficiency. Cu concentrations of less than 1.1–1.2 mg Cu kg^–1 in the grain suggest that the wheat crop is marginally supplied with Cu. In both situations, Cu fertiliser needs to be applied before the next crop.     

The fertilizer effectiveness of calcined Christmas Island C-grade aluminium-iron phosphate rock and superphosphate during the early stages of plant growth

A glasshouse trial with wheat (Triticum aestivum L. cv. Gamenya) in which harvests were taken at intervals up to 24 days has shown that the effectivness of calcined Christmas Island C-grade aluminium-iron phosphate rock (C500) relative to superphosphate remained low. Relative growth rates did not change despite a decrease in the concentration of bicarbonate extractable phosphorus in soil fertilized with superphosphate. Different numerical values of relative effectiveness based on plant yield and phosphorus uptake respectively may be attributed to different internal efficiencies of phosphorus use for the two fertilizers.     

Comparison of greenhouse and 32P isotopic laboratory methods for evaluating the agronomic effectiveness of natural and modified rock phosphates in some acid soils of Ghana

Phosphorus deficiency is one of the major constraints for normal plant growth and crop yields in the acid soils of Ghana and therefore addition of P inputs is required for sustainable crop production. This is often difficult, if not impossible for small-scale farmers due to the high cost of mineral P fertilizers and limited access to fertilizer supplies. Direct application of finely ground phosphate rocks (PRs) and their modified forms have been recommended as alternatives for P fertilization. The direct application of the natural and modified PRs to these acid soils implies the need to predict their agronomic effectiveness of the PRs in the simplest and most cost-effective manner. In this study the classical greenhouse pot experiment was compared to the ³²P isotopic kinetics laboratory method for evaluating the agronomic effectiveness of natural and modified Togo PR in six highly weathered Oxisols from southwest Ghana. In the ³²P isotopic kinetics laboratory experiment the six soil samples were each fertilised at the rate of 50 mg P kg^–1 soil in the form of triple superphosphate (TSP), Togo PAPR-50%, and Togo PR, respectively. Controls without P amendment were also included. Isotopic exchange kinetics experiments were carried out on two sets of samples, immediately after P fertilizer additions (without incubation) and after 6 weeks of incubation under wet conditions and at a room temperature of 25 °C. In the greenhouse pot experiment, P fertilizers in the form of Togo PR, Togo PAPR, Mali PR and TSP were each applied to the six soils at rates equivalent to 0, 30, 60, and 120 kg P ha^–1, respectively. The P fertilizers were mixed with the soils and maize (Zea mays L.) variety Obatanpa was grown for 42 days before harvest. The isotopic kinetics data of the control samples indicated that 5 of the studied soils had very low P fertility status as reflected by their low P concentrations in solution (C_P<0.02 mg P l^–1) and low exchangeable P (E₁min < 5 mg P kg^–1). The capacity factor and the fixation index of the soils were variable. Application of water-soluble P as TSP increased both the C_P and E₁ values of all the soils above the critical levels. Togo PR was least effective among the fertilizers tested for all soil soils, except in Boi soil. Acidulation of Togo PR (Togo PAPR-50%) was an effective means to increase its agronomic effectiveness. Direct application of natural Togo PR would be only feasible in the Boi soil series as reflected by its high Pdff% value in soil solution. Incubation with the P fertilizers caused an increase in the soil pH and a decline in the effectiveness of the applied P fertilizers, irrespective of the soil and the fertilizer utilized. Based upon the results of the greenhouse pot experiment, the relative crop response index (RCRI) in terms of increasing dry matter yield and P uptake followed the order of TSP > PAPR = Mali PR >Togo PR = Control. Both the laboratory index, Pdff% in soil solution derived from the isotopic method and the RCRI values obtained from the pot experiment produced similar results in ranking the P fertilizers tested according to their agronomic effectiveness. The isotopic kinetic method may be considered as an alternative to both greenhouse and field methods in the evaluation of agronomic effectiveness of P fertilizers in tropical acid soils when it offers comparative advantages in assessing the soil P status and its changes. But trained staff and adequate laboratory facilities are needed to perform this technique. Also the method can be used as a reference for comparison purposes as in this case. Further research is needed to assess the overall agronomic effectiveness (immediate and residual effects) of PR sources in predominant cropping systems of this region of Ghana.     

Evaluation of the fertilizer value of some indigenous rock phosphates and basic slag of India

Summary Field and pot culture experiments were conducted in terai acid soil (Haplaquoll) to evaluate the fertilizer value of one basic slag and two rock phosphates, such as Purulia rock phosphate (Igneous) and Mussoorie rock phosphate (sedimentary). In the field experiments two crop sequences were followed: (i) Rice — wheat — greengram (ii) Greengram — rice — wheat. In terms of crop yield and P uptake Purulia rock phosphate did not show any significant effect, except in case of greengram grown as the third crop after its application. Mussoorie rock phosphate increased the yield and P uptake through its direct and residual effect in all the crops, except in rice. Irrespective of crop species and crop sequences basic slag showed considerable direct and residual effect in increasing the crop yield and P uptake. Its effect was at par with that of superphosphate. By total yield increase of three consecutive crops due to added P the efficiencies of the fertilizers were graded as basic slag > superphosphate = Mussoorie rock phosphate > Purulia rock phosphate for rice — wheat — greengram rotation and superphosphate > basic slag > Mussoorie rock phosphate > Purulia rock phosphate for greengram — rice —wheat rotation. Composting improved the efficiency of all the insoluble phosphatic fertilizers.     

Evaluation of two rock phosphates and a calcined rock phosphate as maintenance fertilizers for crop — pasture rotations in Western Australia

Two long-term (11 and 12 y) field experiments in south-western Australia are described that measured the relative effectiveness of three rock phosphate fertilizers (C-grade ore, Calciphos and Queensland (Duchess) rock phosphate), single, double and triple superphosphate. The experiments were on established subterranean clover (Trifolium subterraneum) — based pasture that had received large, yearly, applications of single superphosphate for many years before the experiments began so that in the first year the nil phosphorus (P) treatment produced 80 to 90% of the maximum yield. The experiments were conducted using a rotation of one year cereal crop (oats,Avena sativa at one site, and barley,Hordeum vulgare, at the other): 2 y pasture, a typical rotation on farms in the region. Five levels of each P fertilizer were applied every third year with the crop. Grain yield of cereals, P content of grain, pasture yield, and bicarbonate-soluble P extracted from the soil (available P) were used to estimate fertilizer effectiveness values.The three superphosphate fertilizers had identical values of fertilizer effectiveness. Superphosphate was always the most effective fertilizer for producing grain. The rock phosphate fertilizers were one-seventh to one-half as effective per kg P as superphosphate when assessed on the yield or P content (P concentration × yield) of grain within each cropping year. Bicarbonate-extractable soil P values demonstrated that superphosphate was two to fifteen times as effective as the rock phosphate fertilizers. The relationship between grain yield and P content in grain (i.e. the internal efficiency of P use curve) was similar for the different P fertilizers. Thus for all P fertilizers yield was not limited by other factors as it varied solely in response to the P content, which in turn presumably depended on the P supply from the fertilizers.The relative agronomic effectiveness of rock phosphates is greater for marginally P deficient soils than for highly P deficient soils but rock phosphate remains less effective than superphosphate. We conclude that the rock phosphates studied should not be substituted for superphosphate as maintenance fertilizers for soils in Western Australia that are marginally deficient in P. This result is consistent with the results of many field experiments on highly P deficient soils in south-western Australia. These have shown that a wide variety of rock phosphate fertilizers are much less effective than superphosphate in both the short and long term.     

The current and residual value of superphosphate,Christmas Island C-grade ore,and Calciphos as fertilizers for a subterranean clover pasture

The effectiveness in the year of application of three phosphorus fertilizers, superphosphate, Christmas Island C-grade ore, and 500°C calcined Christmas Island C-grade ore (Calciphos), was measured for 5 consecutive years in a field experiment on a lateritic soil. The residual value of the phosphorus fertilizers was also measured for 6 years. Dry matter production of subterranean clover-based pasture and bicarbonate extractable soil phosphorus were used as indicators of fertilizer effectiveness.Despite the use of very large amounts of C-grade ore and Calciphos, the plateau of the pasture yield versus fertilizer applied curve for these fertilizers did not reach the yield plateau achieved with superphosphate in either the short or long term.C-grade ore and Calciphos were 3% and 8% as effective as superphosphate for dry matter production in the year of application. Relative to superphosphate applied in the current year the effectiveness of superphosphate decreased by about 70% between the first and second year after application and decreased by a further 14% from year 3 to year 6. C-grade ore and Calciphos remained about 2% and 9% as effective as currently applied superphosphate each year.The residual value of superphosphate as measured by bicarbonate-extracted soil phosphorus decreased by about 60% from year 2 to year 7. The residual value of Calciphos was very low for year 2, doubled from year 2–4 and thereafter decreased gradually to its original value by year 7. The residual value of C-grade ore was extremely low throughout the experiment. Thus after year 2, compared to pasture yield, bicarbonate extracted soil phosphorus overestimated the residual value of superphosphate and calciphos.It follows that neither C-grade ore or Calciphos are suitable replacement fertilizers for superphosphate for use on pastures growing on lateritic soils in south-western Australia.     

Rock phosphates are not effective fertilizers in Western Australian soils: A review of one hundred years of research

The 1990s mark the centenary of the earliest work to identify the value of rock phosphate fertilizers for Western Australian agriculture. This review summarizes this and subsequent work. We arrive at a simple conclusion: rock phosphates are ineffective fertilizers because they do not dissolve rapidly in Western Australian soils.The effectiveness of different types of rock phosphate fertilizers has been compared with the effectiveness of superphosphate in several long-term field experiments on a variety of non-leaching soils in south-western Australia. These experiments have consistently shown that, all types of rock phosphate fertilizers are between one twentieth to one third as effective as freshly applied superphosphate both in the year of application and in subsequent years. Glasshouse experiments produce similar results. Laboratory studies of soils from these experiments have shown that the poor effectiveness of the rock phosphates is primarily due to the small extent of dissolution of these fertilizers in Western Australian soils. Several factors are responsible for the inability of adequate amounts of rock phosphate to dissolve in these soils. The soils are only moderately acid (pH in water > 5.5) and generally have low pH buffering capacities so can not rapidly contribute a large supply of protons to promote extensive dissolution of rock phosphate. The soils also have low capacities to adsorb the P and Ca released during dissolution of rock phosphate. They also have low water-holding capacities, and in the field under the Mediterranean climate the soil near the surface rapidly dries between rains thereby restricting dissolution of rock phosphates. In the laboratory it has been shown that rock phosphate dissolution is considerably enhanced in permanently-moist, acid soil with high pH buffering capacity, and high P and Ca buffer capacities.Thus the low extent of dissolution of rock phosphate fertilizers in Western Australian soils is responsible for the poor agronomic effectiveness of these fertilizers measured in the field experiments.     

Effectiveness of rock phosphate, coastal superphosphate and single superphosphate for pasture on deep sandy soils

The effectiveness of coastal superphosphate and two rock phosphate fertilizers was compared with the effectiveness of single superphosphate for pasture production on deep, humic, sandy podzols in high rainfall (> 800 mm annual average) areas of south-western Australia. The pastures were subterranean clover (Trifolium subterraneum) or mixed subterraneum clover and serradella (Ornithopus compressus). Coastal superphosphate was made by adding rock phosphate and elemental sulphur to superphosphate during manufacture, as it came out of the den before granulation. One rock phosphate was a 50% mixture of apatite rock phosphate from Nauru and Christmas Islands, and which was also used to make the single and coastal superphosphate used in this study, and superphosphate made in Western Australia at the time these experiments started. The other rock phosphate was Calciphos, the fertilizer produced by heating (calcining), at about 500 °C, Christmas Island C-grade ore, a calcium iron aluminium rock phosphate. There were two types of experiments. In the three Type 1 experiments, levels of each fertilizer were applied annually. In the two Type 2 experiments, levels of fertilizer were applied once only to new plots in different years. Coastal superphosphate was the most effective fertilizer in the Type 1 experiments, with both rock phosphates and single superphosphate being equally effective. All fertilizers were equally effective in the Type 2 experiments. There were large variations in fertiliser effectiveness values between yield measurements in the same or different years. It is known that P leaches from freshly-applied superphosphate in these soils. The extent of this leaching probably varies between yield measurements affecting effectiveness values determined for all fertilizers because the effectiveness values were calculated relative to the effectiveness of single superphosphate. The humic, sandy podzols remain wet during the growing season, are acidic, and are known from laboratory studies to possess adequate hydrogen ions to cause extensive dissolution of North Carolina rock phosphate so that rock phosphates are equally or more effective than single superphosphate in these soils. When elemental sulphur in coastal superphosphate is oxidized to SO₄ hydrogen ions are produced which in previous studies has been shown to enhance dissolution of rock phosphate in biosuper, a mixture of rock phosphate and elemental sulphur.     

Adsorption and desorption of phosphate in some semi-arid tropical Indian Vertisols

Adsorption and desorption of phosphorus in soils are among the key processes governing its availability to crops. There have been very few studies on the phosphorus adsorption and desorption characteristics of Vertisols. The P adsorption and desorption characteristics of four Vertisols belonging to three agriculturally important soil series were studied. The amounts of P adsorbed by the soils at 0.2µg ml^–1 equilibrium solution P concentration was low and ranged from 34.3 to 79.5µg g^–1 soil. The phosphate adsorption was very well described by Langmuir and Freundlich isotherms. The P adsorbed by a Vertisol (BR-1) fertilized with different rates of P in the previous season (0, 10, 20 and 40 kg P ha^–1) was similar (34.3–41.3µg g^–1 soil) indicating little effect of fertilization on P adsorption. The correlation studies indicated that the DTPA-extractable Fe was the most important factor accounting for P adsorption in these soils. Clay and CaCO₃ content were found to be relatively less important factors affecting P adsorption in the soils studied.The capacity of the two extractants and EUF (electro-ultrafiltration) to desorb the adsorbed P followed the order: EUF (400V, 80°C)>sodium bicarbonate>EUF (200V, 20°C)>calcium chloride. The average amounts of P desorbed from the four Vertisols using these methods were 74, 63, 50, and 3% respectively of the adsorbed P. In the Begamganj soil, the amount of P desorbed by EUF (400V, 80°C) exceeded 100%, indicating that all of the adsorbed P was desorbable including some native P.In conclusion the results of our study show that the Vertisols studied have low phosphate adsorption capacity and that the P they adsorbed is easily desorbable.Approved for publication as Journal Article No. 983 by International Crops Research Institute for the Semi-Arid Tropics (ICRISAT).     

Induced phosphorus fixation and the effectiveness of phosphate fertilizers derived from Sukulu Hills phosphate rock

A greenhouse study was conducted with two surface, acidic soils (a Hiwassee loam and a Marvyn loamy sand) to measure the effect of increasing P-fixation capacity, on the relative agronomic effectiveness (RAE) of phosphate fertilizers derived from Sukulu Hills phosphate rock (PR) from Uganda. Prior to fertilizer application, Fe-gel was added to increase P-fixation capacity from 4.4 to 14.3% for the Marvyn soil and from 37.0 to 61.5% for the Hiwassee soil. Phosphate materials included compacted Sukulu Hills concentrate PR + Triple superphosphate (CTSP) at a total P ratio of PR:TSP = 50:50; 50% partially acidulated PR (CPAPR) from Sukulu Hills concentrate PR made with H₂SO₄; and Sukulu Hills concentrate PR (PRC) made by magnetically removing iron oxide from raw PR ore. Triple superphosphate (TSP) was used as a reference fertilizer. After adjusting soil pH to approximately 6, P sources were applied at rates of 0, 50, 150, and 300 mg total P kg^–1 soil. Two successive crops of 5 week old corn seedlings (Zea mays L.) were grown. The results show that the RAE of the phosphate materials measured using dry-matter yield or P uptake generally decreased as P-fixation capacity was increased for both soils. CTSP was more effective in increasing dry-matter yield and P uptake than CPAPR. PRC alone was an ineffective P source. Soil chemical analysis showed that Bray 1 and Mehlich 1 extractants were ineffective on the high P-fixation capacity Fe-gel amended Hiwassee soil. Mehlich 1 was unsuitable for soils treated with PRC since it apparently solubilizes unreactive PR. When all of the soils and P sources were considered together, Pi paper was the most reliable test for estimating plant available P.     

Comparison of the agronomic effectiveness of a phosphate rock and triple superphosphate as phosphate fertilisers for tea (Camellia sinensis L.) on a strongly acidic Ultisol

Phosphorus deficiency is a major problem affecting tea production in the highly weathered acid soils of humid and sub-humid tropics which are known to have high P fixing capacities. As many of these soils are strongly acidic and receive high rainfall, low-cost phosphate rock (PR) may effectively supply the plant P needs and limited preliminary experiments suggest this is so. A long-term glasshouse trial was conducted on 8-month old tea seedlings to compare the agronomic effectiveness of a locally available PR (Eppawala phosphate rock, EPR) with triple superphosphate (TSP) applied to a strongly acidic (pH water 4.55) marginally P deficient Rhodustult from Sri Lanka at six rates ranging from 10 to 60 kg P ha⁻¹. The results showed that TSP or EPR fertiliser at a rate as low as 10 or 20 kg P ha⁻¹ was sufficient to obtain maximun tea yield. The agronomic effectiveness of EPR was equal to that of TSP at the 5- and 10-month samplings. The concentration of soil P extracted by a cation–anion exchange resin membrane (resin-P) was higher in the TSP treated soil at 5 months due to its greater solubility but at 10 months, the EPR produced higher resin-P due to its increased dissolution over time. In the presence of tea plants, 52% of P from the EPR applied at the rate of 10 kg ha⁻¹, was dissolved at 5 months compared to 75% of dissolution at the 10-month sampling. In the absence of plants, the corresponding dissolution figures were 40% at 5 months and 55% at 10 months. The concentration of inorganic P extracted by 0.1 M NaOH (NaOH-P_i) (loosely characterising Fe + Al bound P) was significantly higher in the TSP treated soil and concentration of P extracted by 0.5 M H₂SO₄ (Ca bound P) was higher in the EPR treated soil. The results suggest that the low-cost, locally available EPR may be used profitably as a maintenace P fertiliser for tea plantations in moderately P deficient soils, which need to be confirmed by field studies. This revised version was published online in June 2006 with corrections to the Cover Date.