New Methods for Aquifer Parameters from Slug Test Data

An objective method and a diagnostic curve method are developed for estimating the aquifer parameters (storage coefficient and transmissivity) from slug test data on a fully penetrating well. In the objective method, explicit equations are developed for estimating the aquifer parameters. In the diagnostic curve method, a set of unimodal diagnostic curves is developed along with a guiding straight line. The rise or fall in water level of the well is plotted diagnostically on a double logarithmic graph and matched to one of the diagnostic curves plotted on the same scale with a parallel shift of axes, to estimate the aquifer parameters from the dual coordinates of a selected point on the matched portion of the graphs. The unimodal shape of the diagnostic curves and the guiding straight line facilitate the matching and limit the subjectivity. The proposed methods can easily identify a nonideal condition. The estimates of the aquifer parameters obtained using the proposed methods are more accurate than those obtained using the prior curve matching methods. The proposed methods are also able to identify nonideal conditions. It is hoped that the new methods will be of help to field and practicing engineers.     

Simple Equations for Aquifer Parameters from Drawdowns in Large-Diameter Wells

Simple equations are proposed for estimating storage coefficient and transmissivity of an aquifer from drawdowns in large- diameter wells. The proposed method requires determination of the peak and time to peak of a unimodal curve. Using these values and utilizing the provided set of equations, the aquifer parameters are estimated through an iterative procedure. The proposed method is void of subjectivity involved in the previously proposed curve matching methods. Also, the new method can be used when the conventional curve matching methods cannot be applied to estimate the aquifer parameters. The new method can be used to estimate the aquifer parameters from the drawdown data observed only up to a time so that the peak could be determined.     

Effects of Ethanol versus MTBE on Benzene, Toluene, Ethylbenzene, and Xylene Natural Attenuation in Aquifer Columns

The increased use of ethanol as a replacement for the gasoline oxygenate, methyl tert-butyl ether (MTBE), may lead to indirect impacts related to natural attenuation of benzene, toluene, ethylbenzene, and the three isomers of xylene (BTEX compounds). Ethanol could enhance dissolved BTEX mobility by exerting a cosolvent effect that decreases sorption-related retardation. This effect, however, is concentration dependent and was not observed when ethanol was added continuously (at 1%) with BTEX to sterile aquifer columns. Nevertheless, a significant decrease in BTEX retardation was observed with 50% ethanol, suggesting that neat ethanol spills in bulk terminals could facilitate the migration of pre-existing contamination. MTBE (25 mg/L influent) was not degraded in biologically active columns, and it did not affect BTEX degradation. Ethanol (2 g/L influent), on the other hand, was degraded rapidly and exerted a high demand for nutrients and electron acceptors that could otherwise have been used for BTEX degradation. Ethanol also increased the microbial concentration near the column inlet by one order of magnitude relative to columns fed BTEX alone or with MTBE. However, 16S-ribosomal ribonucleic acid sequence analyses of dominant denaturing gradient gel electrophoresis bands identified fewer species that are known to degrade BTEX when ethanol was present. Overall, the preferential degradation of ethanol and the accompanying depletion of oxygen and other electron acceptors hindered BTEX biodegradation, which suggests that ethanol could increase the length of BTEX plumes.     

Laplace-Domain Solutions for Radial Two-Zone Flow Equations under the Conditions of Constant-Head and Partially Penetrating Well

A mathematical model is presented for a constant-head test performed in a partially penetrating well with a finite-thickness skin. The model uses a no-flow boundary condition for the casing and a constant-head boundary condition for the screen to represent the partially penetrating well. The Laplace-domain solutions for the dimensionless flow rate at the wellbore and the hydraulic heads in the skin and formation zones are derived using the Laplace and finite Fourier cosine transforms. The solutions of hydraulic heads have been shown to satisfy the governing equations, related boundary conditions, and continuity requirements for the pressure head and flow rate at the interface of the skin zone and undisturbed formation. In addition, an efficient algorithm for evaluating those solutions is also presented. The dimensionless flow rates obtained from new solutions have been shown to be better than those of Novakowski’s solutions, especially when the penetration ratio is large.     

Modeling the Transformation of Chromophoric Natural Organic Matter during UV/H2O2 Advanced Oxidation

This research developed a differential kinetic model to predict the partial degradation of natural organic matter (NOM) during ultraviolet plus hydrogen peroxide (UV/H2O2) advanced oxidation treatment. The absorbance of 254?nm UV, representing chromophoric NOM (CNOM) was used as a surrogate to track the degradation of NOM. To obtain reaction rate constants not available in the literature, i.e., reactions between the hydroxyl radical (?OH) and NOM, experiments were conducted with “synthetic” water, using isolated Suwannee River NOM, and parameter estimation was applied to obtain the unknown model parameters. The reaction rate constant for the reaction between ?OH and total organic carbon (TOC), k?OH,TOC, was estimated at 1.14(±0.10)×104??L?mg-1?s-1, and the reaction rate constant between ?OH and CNOM, k?OH,CNOM, was estimated at 3.04(±0.33)×104??L?mol-1?s-1. The model was evaluated on two natural waters to predict the degradation of CNOM and H2O2 during UV/H2O2 treatment. Model predictions of CNOM degradation agreed well with the experimental results for UV/H2O2 treatment of the natural waters, with errors up to 6%. For the natural water with additional alkalinity, the model also predicted well the slower degradation of CNOM during UV/H2O2 treatment, owing to scavenging of ?OH by carbonate species. The model, however, underpredicted the degradation of H2O2, suggesting that, when NOM is present, mechanisms besides the photolysis of H2O2 contribute appreciably to H2O2 degradation.     

Effect of BTEX on Degradation of MTBE and TBA by Mixed Bacterial Consortium

Methyl tert-butyl ether (MTBE) contamination in groundwater often coexists with benzene, toluene, ethylbenzene, and xylene (BTEX) near the source of the plume. Tertiary butyl alcohol (TBA) is a prevalent intermediate of MTBE degradation. Therefore, there is a significant potential for interference of MTBE and TBA degradation by the presence of BTEX whether treatment is in situ or ex situ. In this study, the effect of BTEX on the degradation of MTBE and TBA was examined using a mixed bacterial culture enriched on MTBE and BTEX. In batch studies, the presence of BTEX did not have a significant effect on MTBE degradation, but did have a slight effect on TBA degradation. Under continuous flow conditions, all compounds degraded simultaneously. Normalizing rates to the MTBE loading to the reactor indicates that BTEX may assist in the development of the biomass for TBA and overall MTBE degradation. Using denaturing gradient gel electrophoresis, several diverse organisms were identified, two of which showed very high similarity with PM1, a known MTBE degrader.     

Genesis and Effects of Particles Produced during In Situ Chemical Oxidation Using Permanganate

A research effort was undertaken to investigate the genesis of particles produced during in situ chemical oxidation (ISCO) of trichloroethene (TCE) with permanganate (MnO4?) and to explore the effects of those particles on system permeability and metal mobility. The experimental approach included characterization of soil and groundwater samples from an ISCO field site, batch experiments with a replicated 25 factorial design, and flow-through column experiments. Analyses of intact soil cores from an ISCO field site revealed that MnO2 solids were present in the subsurface near an injection well for NaMnO4 but at low levels (2.3–2.5 mg/g dry wt media) calculated to fill <1% v/v of the aquifer porosity. Batch tests revealed that the mass of filterable solids (>0.45 μm) produced during chemical oxidation with MnO4? was increased at higher TCE concentrations (54 versus 7 mg/L) and in the presence of ambient silt/clay-sized particles in the groundwater (750 versus 7.5 mg/L). Under otherwise comparable conditions, increasing the MnO4? dose markedly increases the oxidant consumption and also increases the solids production. The oxidant form (NaMnO4 versus KMnO4) or reaction time (15 versus 300 min) had little effect on oxidant consumption or filterable solids production. During MnO4? oxidation of higher levels of TCE in a groundwater with ambient silt/clay particles present, there can be substantial increases in filterable solids generated, which are <1 μm in size and consist of MnO2, commingled with other mineral matter. Conceivably, low volumetric fillings of these solids could cause permeability loss. Flow-through column experiments revealed that permeability loss was possible during ISCO but only under conditions with very high MnO2 solids production. On the positive side, the MnO2 solids produced can increase the sorption potential for metals such as cadmium and can represent a mode of immobilization. This research demonstrated that ISCO with permanganate has the potential to yield system permeability loss under some conditions as well as to affect metal mobility. The magnitude of these effects is related to the subsurface conditions, target organic chemical mass, and permanganate dose and delivery method. The production of solids during ISCO needs to be carefully considered during process design and operation to avoid solids-related performance problems while exploiting potential benefits.     

Secondary Benefits of Aquifer Storage and Recovery: Disinfection By-Product Control

The potential of biological processes during aquifer storage to reduce disinfection by-products (DBP), and DBP precursors were examined under controlled conditions. Finished water treated by conventional water treatment practice was pumped into a sand media column for up to 34 days of residence time. Two experiments were conducted where the finished water was chlorinated or ozonated prior to injection. Chlorination of water withdrawn from simulated aquifer storage conditions resulted in reduced formation of trihalomethane (THM) concentrations for all three treated water types. Ozonation of finished water resulted in a 70% decrease in TTHM formation. Aquifer storage of finished water resulted in a 26–28% reduction in TTHM formation and the removal of preformed THM species was as high as 40%. Overall, aquifer storage of chlorinated finished water resulted in a 44% reduction in TTHM formation when additionally chlorinated after withdrawal. Bromate formed during ozonation was reduced by approximately 54%. This study indicates that the sequencing of chlorination or ozonation with respect to aquifer storage and recovery operations can impact DBP formation.     

Allocation of Scarce Water Resources Using Deficit Irrigation in Rotational Systems

On irrigation schemes with rotational irrigation systems in semiarid tropics, the existing rules for water allocation are based on applying a fixed depth of water with every irrigation irrespective of the crops, their growth stages, and soils on which these crops are grown. However, when water resources are scarce, it is necessary to allocate water optimally to different crops grown in the irrigation scheme taking account of different soils in the command area. Allocating water optimally may lead to applying less water to crops than is needed to obtain the maximum yield. In this paper, a three stage approach is proposed for allocating water from a reservoir optimally based on a deficit irrigation approach, using a simulation-optimization model. The allocation results with a deficit irrigation approach are compared for a single crop (wheat) in an irrigation scheme in India, first with full irrigation (irrigation to fill the root zone to field capacity) and second with the existing rule. The full irrigation with a small irrigation interval was equivalent to adequate irrigation (no stress to the crop). It is found that practicing deficit irrigation enables the irrigated area and the total crop production in the irrigation scheme used for the case study to be increased by about 30–45% and 20–40%, respectively, over the existing rule and by 50 and 45%, respectively, over the adequate irrigation. Allocation of resources also varied with soil types.     

Simple Approximation of Well Function for Constant Drawdown Variable Discharge Artesian Wells

A simple approximation of the well function for a constant drawdown is developed. This approximation is used to estimate the storage coefficient and transmissivity of the aquifer from observed unsteady discharge under a constant drawdown condition, using an optimization method. Another simple approximation for calculating the total production volume during a time span is also developed. The developed approximations for the well function and production function are accurate within a maximum error of 0.7% for the practical range of the argument.     

Comparison of Liquid and Gas-Phase Photooxidation of MTBE: Synthetic and Field Samples

The feasibility of photooxidation treatment of methyl tert-butyl ether (MTBE) in water was investigated using two systems: (1) a slurry falling film photoreactor and (2) an integrated air stripping with gas phase photooxidation system. Methyl tert-butyl ether-contaminated synthetic water and field samples from contaminated sites were used for these studies. Using a TiO2 slurry (0.1 g/L; Degussa P25) flowing down at a rate of up to 0.26 L/min over the inner surface of a glass tube surrounding a 1-kW medium pressure mercury lamp, more than 99% of MTBE in the synthetic samples, initially at 1 mg/L, was degraded within 90 min. The major degradation products from MTBE were tert-butyl alcohol, tert-butyl formate, and small amounts of acetone. However, the degradation of MTBE and its byproducts in contaminated groundwater samples was hindered significantly by dissolved metals such as Fe2+, chloride ions, and aromatic organic species. Integrating air stripping with gas-phase photocatalysis is an an effective alternative that would not be affected by the water chemistry. The reaction rates for MTBE degradation in the gas phase are orders of magnitude faster than in aqueous solution.     

Remediation of TCE-Contaminated Groundwater in a Sandy Aquifer Using Pulsed Air Sparging: Laboratory and Numerical Studies

The objective of this study was to investigate, through laboratory and numerical investigations, the effectiveness of a pulsed air sparging system for remediation of groundwater contaminated with trichloroethylene (TCE) in a sandy aquifer. In laboratory experiments, air was pulsed into TCE source zone on a daily basis in order to remediate TCE-contaminated groundwater. Most dissolved TCE was removed at the end of experiments although its concentrations fluctuated due to the air pulsing. The measured gaseous phase TCE concentration increased whereas the aqueous phase TCE concentration decreased during air sparging pulses. Experimental data were assessed by using a numerical code STOMP (subsurface transport over multiphases) with some modification based on the TCE dissolution kinetics. The unmeasured residual TCE mass was predicted through numerical simulations. Results show that aqueous concentrations for TCE are still much higher than the maximum contaminant level in spite of successful removal of 95% of residual TCE. It may imply that it would be more appropriate to apply air sparging combined with other remediation technologies such as bioremediation for remediation of TCE-contaminated groundwater.     

Reduction of Fulvic Acid in Drinking Water by Ferrate

Acting as a powerful oxidant, efficient coagulant, and effective disinfectant, ferrate is a good multifunctional agent for water and wastewater purification. In this study, some of these key aspects were studied for treating water containing fulvic acid, including the reduction efficiency of fulvic acid (FA) in drinking water and the optimum conditions for reducing FA using ferrate prepared in the laboratory. Jar tests and pilot tests were employed in the studies and the results of FA reduction were analyzed spectrophotometrically. Ferrate in these tests exhibited good oxidation capacity on FA. The ultraviolet absorption (UVA) of 2 mg/L FA in water can be reduced about 90% when the weight ratio of ferrate to FA was 12:1. Adsorption to and coprecipitation with Fe(OH)3 precipitate produced by ferrate decomposition can also result in additional FA reduction. In the presence of turbidity, ferrate can oxidize and adsorb simultaneously and over 95% of UVA was reduced with the same weight ratio of 12:1. Combining the application of ferrate and polyaluminum chloride (PAC) or iron chloride (FeCl3) was more effective for FA reduction. The UVA of 2 mg/L FA was reduced 100% in synthetic drinking water by a joint treatment with 8 mg/L ferrate (FeO42? by weight) and 0.8 mg/L PAC (Al by weight) or 6 mg/L ferrate (FeO42? by weight) and 0.8 mg/L Fe3+ (Fe by weight). The pilot test performed more effectively for FA reduction than did the jar test.     

Effect of Substrate Nitrogen/Chemical Oxygen Demand Ratio on the Formation of Aerobic Granules

The effect of the substrate nitrogen/chemical oxygen demand (N/COD) (mg/mg) ratio on the formation and characteristics of aerobic granules for simultaneous organic removal and nitrification were studied in four sequencing batch reactors operated at different substrate N/COD ratios ranging from 5/100 to 30/100. Results showed that aerobic granules formed at the substrate N/COD ratios studied, and both nitrifying and heterotrophic activities of aerobic granules were governed by the substrate N/COD ratio. The nitrifying activity was significantly enhanced with the increase of the substrate N/COD ratio, while the heterotrophic activity decreased. By determining elemental compositions of aerobic granules cultivated at different substrate N/COD ratios, it was revealed that the cell hydrophobicity was inversely related to the ratio of cell oxygen content to cell carbon content of aerobic granule. The production of extracellular polysaccharides showed a decreasing trend as the substrate N/COD ratio increased. This is probably due to enriched nitrifying population with the high N/COD ratios. This study clearly demonstrated that an aerobic granule-based sequencing batch reactor would have a great potential for simultaneous organic oxidation and nitrification.     

Feasibility of Using Natural Zeolites to Remove Sodium from Coal Bed Methane-Produced Water

Coal bed methane (CBM) is naturally occurring methane, contained in coal seams saturated with water. In order to extract the CBM, large quantities of water must be pumped from the coal seams. CBM water, produced in some areas of New Mexico, contains low total dissolved solids, which can potentially be used for rangeland irrigation. The water, however, has a high sodium adsorption ratio, which can result in severe deterioration of soil permeability with repeated irrigation. The St. Cloud zeolites exhibit a low selectivity of Na+ over Ca2+ (Vanselow selectivity coefficients of 0.26 and usable Na+ exchange capacity of 0.1?meq/g) at the ionic strength of Na+-laden CBM waters (0.035?M). Nevertheless, given the availability and low cost of natural zeolites, ion exchange experiments were conducted using packed columns to estimate a treatment cost. The operation and maintenance cost of the zeolite system was estimated to be about $3 per barrel (one barrel = 159 liters) compared with $0.75–$4/bbl for deep well injection (primary management practice) and $0.06–$0.11/bbl for soil amendment. Based on these preliminary experiments, it is evident that the ion exchange process for Na+ removal, with natural zeolites as the media, is not economical due to the low sodium selectivity.     

Verification of Full-Scale Ozone Contactor Inactivation Performance Using Biodosimetry

A biodosimetric technique was used to verify the concentration-contact time (CT) values [CT10, CT integrated disinfection design framework (CT-IDDF), CT segregated flow analysis (CT-SFA)] of the ozone contactors of the DesBaillets water treatment plant (Montreal), using indigenous aerobic spore formers (ASFs) as indicators of disinfection efficiency. ASF measurement in ozonated water was performed using a large water sample concentration method. Four assays, completed over a 6-week period, involved the implementation of biodosimetric calibration curves using an ozone pilot apparatus and followed by full-scale verifications. ASF inactivation kinetics were well described by a simple Chick–Watson model. The most accurate data also indicated that the CT10 underestimates the effective CT (by 1.2–1.9-fold), whereas the CT-IDDF and CT-SFA overestimate it (by 1.0–1.7-fold and 0.9–1.5-fold, respectively). Underestimation from CT10 was more pronounced with increased ozone dose while overestimation from CT-IDDF and CT-SFA is most likely due to the difficulty in obtaining a representative ozone residual profile within the contactor. The use of segregated flow analysis provided the best estimate of disinfection performance. Biodosimetry is useful in measuring the effective CT transferred, in verifying model predictions, and in determining the influence of water quality on microbial inactivation.     

Postcyclic Reconsolidation Strains in Low-Plastic Fraser River Silt due to Dissipation of Excess Pore-Water Pressures

The postcyclic reconsolidation response of low-plastic Fraser River silt was examined using laboratory direct simple shear testing. Specimens of undisturbed and reconstituted natural low-plastic Fraser River silt and reconstituted quartz powder, initially subjected to constant-volume cyclic loading under different cyclic stress ratios (CSRs) and then reconsolidated to their initial effective stresses (σvo′), were specifically investigated. The volumetric strains during postcyclic reconsolidation (εv-ps) were noted to generally increase with the maximum cyclic excess pore-water pressure (Δumax) and maximum cyclic shear strain experienced by the specimens during cyclic loading. The values of εv-ps and maximum cyclic excess pore-water pressure ratio (ru-max) were observed to form a coherent relationship regardless of overconsolidation effects, particle fabric, and initial (precyclic) void ratio of the soil. The specimens with high ru-max suffered significantly higher postcyclic reconsolidation strains; εv-ps ranging between 1.5 and 5% were noted when ru-max>0.8. The observed εv-ps versus ru-max relationship, when used in combination with the observed dependence of cyclic excess pore-water pressure on CSR and number of load cycles, seems to provide a reasonable approach to estimate postcyclic reconsolidation strains of low-plastic silt.     

Estimation of the Maximum Consumption of Permanganate by Aquifer Solids Using a Modified Chemical Oxygen Demand Test

Knowledge of the consumption of permanganate by naturally occurring reduced species associated with aquifer materials is required for site screening and design purposes to support permanganate in situ chemical oxidation (ISCO) applications. It has been established that this consumption is not a singled-valued quantity, but rather is kinetically controlled. Current methods to determine this permanganate natural oxidant demand (NOD) involve the use of well-mixed batch tests, which are time consuming and subject to test variables (e.g., concentration, mass of oxidant to solid ratio, reaction duration, and mixing conditions) that significantly affect the results. In this paper, we propose a modified chemical oxygen demand (COD) test using permanganate, which can be used to determine the maximum permanganate NOD of an aquifer material. As an initial point of comparison, we tested aquifer materials collected from eight potential ISCO sites using this modified or permanganate COD method, the traditional dichromate COD method, and a method based on well-mixed batch reactors. The results from this comparison indicated that there was no statistically significant difference (α = 5%) between the results of the permanganate COD test and the maximum NOD from the well-mixed batch reactors, while on average the dichromate COD test overestimated the maximum NOD by 100%. The permanganate COD test results were highly correlated to the batch-test maximum NOD data (r = 0.996), and to the total organic carbon and amorphous Fe content of the aquifer materials (r = 0.91). A limited sensitivity investigation of this proposed permanganate COD test revealed that the suspected formation of manganese oxides, a reaction byproduct, may lead to increased experimental variability. However, in spite of this concern we recommend that this proposed permanganate COD method is a quick and economical approach for estimating the maximum permanganate NOD for aquifer materials to support permanganate ISCO site screening and initial design purposes.     

Removal of TDS from Cooling Tower Water by Using EDTA-Modified Bagasse Fibers

Modified by ethylenediaminetetraacetic acid (EDTA) salts and unmodified bagasse fibers were tested for the removal of total dissolved solids (TDSs) from cooling tower water. Parameters such as hydrogen ion concentration (pH), particle size of bagasse fibers, and the concentrations of adsorbent and adsorbate were studied to optimize the conditions to be applied on a commercial scale for the decontamination of effluents of cooling tower water. The optimum pH for TDS removal was between 6 and 6.5. The efficiency of TDS removal increased when the size of fiber particles decreased (100?μm) and when the concentration of EDTA salt increased to reach 78 mg/g of modified bagasse fibers. The adsorption parameters were determined using both Langmuir and Freundlich isotherms. The preferential mechanisms for the retention of TDSs are a complexation process between the TDSs and chemical functions present on the surface of fibers, and the chelation process with the EDTA attached to the fibers. The results obtained could be valuable for application to cooling tower water treatment and for the softening of hard drinking water.     

Selection of Superior Tillage and Fertilizer Practices Based on Rainfall and Soil Moisture Effects on Pearl Millet Yield under Semiarid Inceptisols

Based on seven field experiments of pearl millet with nine treatment combinations of tillage and fertilizer nutrients conducted during 2000–2006 in a semiarid inceptisol at Agra, an assessment is made in this paper about sustainability of treatments using rainfall received during the crop growing period and available soil moisture at sowing, 20, 40, and 60?days after sowing (DAS) and harvest. Three practices, each of tillage: conventional tillage+mechanical weed control, low tillage+mechanical weed control, and low tillage+mechanical weed control+herbicide; and fertilizer application of 60?kg?N [farm?yard?manure?(FYM)]+40?kg?P/ha, 30?kg?N (FYM)+30?kg?N (urea)+40?kg?P/ha and 60?kg?N (urea)+40?kg?P/ha were tested in the same site over seven years. The F-test indicated significant soil moisture differences on different DAS and also between different tillage treatments. Significant yield differences were found among treatments of tillage and fertilizer and their interaction in all seasons, except 2001 and 2002. Treatment-wise correlation of yield with monthly rainfall received in June–September and available soil moisture on different DAS indicated that September rainfall had a negative and significant correlation with yield attained by tillage and fertilizer treatments. The soil moisture at 20 DAS had a negative and significant correlation with yield under all treatments except conventional tillage+mechanical weed control. The soil moisture at 60 DAS and harvest had a positive and significant correlation with yield attained under different tillage and fertilizer treatments. Regression models of yield were calibrated for tillage and fertilizer treatments through monthly rainfall during July–September and soil moisture on different DAS. The predictability of yield improved significantly by inclusion of both rainfall and soil moisture variables in the models compared to either of the two groups of variables. Ranks were assigned to tillage and fertilizer treatments for yield attained in individual years and mean yield, prediction error, and sustainable yield index over years. The study indicated that conventional tillage+mechanical weed control among tillage together with 30?kg?N (FYM)+30?kg?N (urea)+40?kg?P/ha was superior with a minimum rank sum compared to other treatments. The treatment gave a maximum sustainable yield of 1,683?kg/ha with a net return of Rs 5,670?ha, benefit–cost ratio of 1.16, and sustainable yield index of 47.2% under semiarid inceptisols of Agra.