热塑性树脂基体对超高分子量聚乙烯纤维复合材料力学性能和抗弹道侵彻性能的影响

选用热塑性的水性橡胶、水性聚酯、水性聚氨酯作为基体树脂,超高分子量聚乙烯(UHMWPE)纤维作为增强纤维,采用热压工艺制备单向正交结构的防弹先进复合材料层压板.基于弹道侵彻试验和力学试验研究热塑性树脂基体对防弹先进复合材料弹道响应及力学行为的影响.研究结果显示:相比单一的热塑性树脂体系,以热塑性树脂混合体系作为基体制备...     

超高分子量聚乙烯纤维增强防弹复合材料研究进展

介绍了超高分子量聚乙烯(UHMWPE)纤维的特点、种类及编织结构,分析了UHMWPE纤维复合材料的防弹机理,总结了UHMWPE纤维的编织结构、树脂基体性能、界面性能等因素对防弹性能的影响,归纳了UHMWPE纤维防弹复合材料的优缺点,并对UHMWPE纤维复合材料的发展进行了展望。     

界面对纤维增强陶瓷基复合材料拉伸性能的影响

建立了桥联纤维细观力学模型, 研究了界面对纤维增强陶瓷基复合材料拉伸模量及强度的影响。分别引入纤维应力均匀系数和界面脱粘率作为界面完全脱粘和局部脱粘条件下界面性能的表征参数。研究表明, 应力均匀系数及界面脱粘率越大, 材料模量越低, 而断裂时纤维所承担的应力越高。基于混合率给出了拉伸强度表达式, 同时也分析了基体裂纹分布、界面脱粘和纤维拔出对强度的影响。计算结果表明, 本文强度模型给出的预测值与试验值吻合较好。      

有缺陷纤维增强复合材料的细观力学

本文沿着细观力学从各向同性到各向异性，从平面问题到三维问题，从线弹性到弹塑性的发展历程，对有缺陷复合材料的细观力学的主要研究领域进行了总结和评述。     

双向玻纤织物复合材料双轴拉伸载荷下的力学行为

为研究双向玻纤织物复合材料在复杂应力状态下的力学行为,设计双轴加载十字型试样,对其进行不同载荷比的双轴拉伸实验,对比分析了材料在双轴拉伸载荷下的拉伸模量、拉伸强度及失效模式。结果表明:双向玻纤织物复合材料单轴拉伸行为表现为后期非线性、脆性断裂,双轴拉伸载荷下非线性现象更为显著;双轴拉伸模量随载荷的增大而增加,双轴拉伸载荷对材料的拉伸模量具有一定的强化作用;材料的双轴拉伸强度存在双向弱化效应,等比例双轴拉伸时,双轴拉伸强度最低,仅为单轴强度的60.5%;试样破坏发生于中心实验区域,材料不同载荷比的破坏形式有所不同,分别主要表现为纤维断裂、基体失效和玻纤布分层。     

纤维增强热塑性树脂基复合材料界面研究进展

纤维增强热塑性树脂基复合材料具有优良的耐化学药品性、生产周期短、可二次加工等特点,克服了热固性树脂基复合材料韧性差,断裂延伸率低,易发生早期应力开裂等缺点,可在使用环境苛刻,承载能力要求高的场合得到应用.本文从复合材料界面设计思想入手,评述了纤维/热塑性复合材料界面的最新研究进展,并结合剪滞法对微复合材料的界面测试方法进行了分析讨论.     

连续石墨纤维增强铝基复合材料准静态拉伸损伤演化与断裂力学行为

针对连续石墨纤维增强铝基(CF/Al)复合材料,采用三种纤维排布方式的代表体积单元(RVE)建立了其细观力学有限元模型,采用准静态拉伸试验与数值模拟结合的方法,研究了其在轴向拉伸载荷下的渐进损伤与断裂力学行为。结果表明,采用基体合金和纤维原位力学性能建立的细观力学有限元模型,对轴向拉伸弹性模量和极限强度的计算结果与实验结果吻合良好,而断裂应变计算值较实验结果偏低。轴向拉伸变形中首先出现界面和基体合金损伤现象,随应变增加界面发生失效并诱发基体合金的局部失效,最后复合材料因纤维发生失效而破坏,从而出现界面脱粘后纤维拔出与基体合金撕裂共存的微观形貌。细观力学有限元分析结果表明,在复合材料制备后纤维性能衰减而强度较低条件下,改变界面强度和刚度对复合材料轴向拉伸弹塑性力学行为的影响较小,复合材料中纤维强度水平是决定该复合材料轴向拉伸力学性能的主要因素。     

有缺陷纤维增强复合材料的细观力学

本文沿着细观力学从各向同性到各向异性，从平面问题到三维问题，从线弹性到弹塑性的发展历程，对有缺陷复合材料的细观力学的主要研究领域进行了总结和评述。     

超高分子量聚乙烯复合材料的流变行为

聚合填充法制备的UHMWPE/Kaolin复合材料具有特殊的流变行为。一般情况下填料的加入使聚合物熔体粘度,动态模量升高。与此相反,由填充复合法制备的UHWMPE/Kaolin复合材料的表观粘度、复数粘度、动态模量均随Kaolin填充量呈下降趋势,其加工性得到改善。文中对此现象的实验结果进行了报道,并探讨了流变行为与聚合填充法赋予复合材料的独特结构的关系。      

Three kinds of charcoal powder reinforced ultra-high molecular weight polyethylene composites with excellent mechanical and electrical properties

Highly filled charcoal powder reinforced ultra-high molecular weight polyethylene (UHMWPE) composites with tunable electrical conductivity and good mechanical properties were prepared using extrusion and hot-compression techniques. Three kinds of charcoal carbonized under various temperatures were used in this study. The scanning electron microscopy showed that charcoal powder was dispersed uniformly in the UHMWPE matrix and strong interfacial interaction was achieved. The tensile test results showed that with the incorporation of charcoal powder, the tensile strength increased by 325%, 262% and 203% respectively compared to neat UHMWPE. Furthermore, the composites containing 70 wt.% charcoal powder (above 700 °C) exhibited good electrical conductivity, which is adequate for many electrical applications. It was obvious that the storage modulus of all the composites increased remarkably with the incorporation of charcoal powder, E′ reached 30.2, 26.8 and 25.9 GPa for samples PC1100/UHMWPE, AC1100/UHMWPE and BC1100/UHMWPE at − 150 °C respectively.     

超高分子量聚乙烯纤维复合表面改性及其橡胶基复合材料的力学性能

针对超高分子量聚乙烯(UHMWPE)纤维与基体之间界面结合强度低的问题,采用超声波结合铬酸溶液氧化的复合工艺对UHMWPE纤维进行表面处理,并将处理后的纤维加入到天然橡胶(NR)中制备短切UHMWPE纤维/NR复合材料。结果表明:复合改性工艺可有效增加纤维表面粗糙度及表面含氧官能团含量,最佳改性工艺条件为:按照重铬酸钾、水及浓硫酸的质量比7∶12∶150配置铬酸溶液,将含有一定质量UHMWPE纤维的铬酸溶液放入35℃的超声波清洗仪中氧化5min,其中超声波频率为100kHz。与纯NR样品相比,在UHMWPE纤维与NR的质量比为0~6∶100范围内,随着处理后短纤维含量的增加,复合材料的拉伸强度逐渐减小,最大损失量达到50%;复合材料的硬度不断增大,最大增加量达到96%;复合材料的撕裂强度先增大后减小,在UHMWPE纤维与NR的质量比为5∶100时达到最大值,最大增加量达到49%。     

Improving the ballistic performance of ultra high molecular weight polyethylene fiber reinforced composites using conch particles

A new method was proposed to improve ballistic impact performance of unidirectional ultra high molecular weight polyethylene (UHMWPE) fiber plate (UD plate) by adding shell particles in matrix. The complex micro-laminate structure of these bio-composite materials was studied. It was revealed by Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FT-IR) spectra that modified shell particles were uniformly dispersed in the matrix. The results of ballistic tests and temperature adaptation tests demonstrated that the bulletproof property of the modified UD plate was improved by 20%.     

A methodology for hydrocode analysis of ultra-high molecular weight polyethylene composite under ballistic impact

Ballistic performance analysis of ultra-high molecular weight polyethylene (UHMW-PE) is critical for the design of armour systems against ballistic threats. However, no validated modelling strategy has been published in literature for UHMW-PE composite that captures the penetration and damage mechanisms of thick targets impacted between 900 m/s and 2000 m/s. Here we propose a mechanistically-based and extensively validated methodology for the ballistic impact analysis of thick UHMW-PE composite. The methodology uses a non-linear orthotropic continuum model that describes the composite response using a non-linear equation of state (EoS), orthotropic elastic–plastic strength with directional hardening and orthotropic failure criteria. A new sub-laminate discretisation approach is proposed that allows the model to more accurately capture out-of-plane failure. The model is extensively validated using experimental ballistic data for a wide range of UHMW-PE target thicknesses up to 102 mm against 12.7 mm and 20 mm calibre fragment simulating projectiles (FSPs) with impact velocities between 400 m/s and 2000 m/s. Very good overall agreement with experimental results is seen for depth of penetration, ballistic limit and residual velocity, while the penetration mechanisms and target bulge behaviour are accurately predicted. The model can be used to reduce the volume of testing typically required to design and assess thick UHMW-PE composite in ballistic impact applications.     

热塑性酚醛树脂对碳纤维环氧树脂基复合材料性能的影响

利用热重分析(TGA)、扫描电镜(SEM)和三点短梁法对添加不同含量的热塑性酚醛树脂(PF)的复合材料体系改性效果进行了研究,考察了不同含量的酚醛树脂对固化体系力学性能及热性能的影响.结果表明,随着酚醛树脂含量的增加,碳纤维环氧树脂基复合材料(CFRP)的弯曲强度和弯曲弹性模量呈递减趋势;层间剪切强度(ILSS)呈现先增加后减小的趋势,当酚醛树脂的含量为20%时,层间剪切强度达到111.31MPa,提高约7%;热稳定性较其它含量时高,复合材料体系的综合性能最好.     

Electrical properties of graphene nanoplatelets/ultra-high molecular weight polyethylene composites

Graphene nanoplatelets (GNPs)/ultra-high molecular weight polyethylene (UHMWPE) composites with a segregated structure had been fabricated using ethanol-assisted dispersion and hot compression at 180 °C. A percolation threshold of 3.5 wt% was achieved because of the formation conductive network. The positive temperature coefficient (PTC) and the negative temperature coefficient (NTC) effects of GNPs/UHMWPE composites had been investigated. The PTC behavior enhanced with increasing GNPs content but this was not always the case. The maximum PTC effect was observed in GNPs/UHMWPE composites (GNPs, 3.8 wt%) with the relatively low room temperature resistivity and the relatively high peak resistivity. The structure for GNPs/UHMWPE composites was examined by the SEM. The fact revealed that the slight interaction between GNPs and UHMWPE matrix may be changed by thermal cycles, and this can explain why thermal cycles could increase PTC and NTC intensity.     

超高分子量聚乙烯纤维/环氧复合材料的吸湿行为及吸湿应力分析

为了揭示超高分子量聚乙烯(UHMWPE)纤维增强环氧树脂基复合材料的吸湿机制,利用ABAQUS有限元软件,建立二维模型,对此类复合材料的吸湿行为及吸湿应力进行研究。模拟计算了两种不同纤维分布模型内部的水分浓度场分布; 根据获得的水分浓度场,对两种模型随温度及时间变化的吸湿应力场进行了分析。结果表明: 水分在两种模型中的扩散都符合Fick扩散定律,纤维按正六边形分布模型比纤维随机分布模型更早达到吸湿平衡,但后者更符合实际情况,也与实验结果比较吻合; 长时间的吸湿会导致材料内部吸湿应力达到很高的水平(>60 MPa),温度越高,越早达到吸湿平衡,应力越大,最大的吸湿应力出现在纤维聚集最密集的基体区域,纤维随机分布模型的吸湿应力水平高于纤维按正六边形分布模型。     

Tribological behavior of ultra-high molecular weight polyethylene in a hip joint simulator

In this paper effects of various injection molding parameters on tribological properties of ultra-high molecular weight polyethylene (UHMWPE) were investigated. The tribological properties like coefficient of friction and wear rate were obtained from the experimental results of hip simulator which was designed and fabricated in the laboratory. Bovine serum was used as a lubricant in this study. In addition, the hardness of the specimen was also investigated as well. The injection molding parameters that varied for this study are melt temperature, injection velocity and compaction time. The results show that contact loads and melt temperature were mostly influenced the tribological behavior of UHMWPE. A wear mechanism map was developed to study the dominant wear mechanism that influences the wear behavior of UHMWPE. SEM was employed to study the worn out morphologies of UHMWPE. The dominant wear mechanisms that are dominated through our study are ironing, scratching, ploughing, plastic deformation, and fatigue wear.     

石墨烯纳米片增强铝基复合材料的动态力学行为

采用压制-烧结-热挤压工艺制备石墨烯纳米片(GNFs)增强铝基(Al)复合材料,并对其进行压缩性能测试。结果表明:GNFs/Al复合材料是应变率敏感材料,当应变率从10^-3s^-1提高至3×10~3s^-1时,复合材料的强度明显提高;而当应变率继续提高至5×10~3s^-1时,由于材料内部发生热软化,复合材料的强度反而表现出少许下降。动态压缩后复合材料中铝基体发生动态再结晶,且应变率越高,动态再结晶越显著;增强相GNFs则发生扭曲变形后仍保持完整结构且与基体间保持原子间结合。因此,GNFs/Al复合材料具有良好的动态压缩塑性。