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摘 要:本文以Pd79Cu4Au2Si10P5块体非晶合金为研究对象,采用电化学极化曲线和电化学阻抗测试方法研究了剪切带自修复对其在3 wt.% NaCl溶液和1 mol/L HCl溶液中耐蚀性能的影响。通过研究极化曲线中的自腐蚀电位和自腐蚀电流密度得知,修复后样品耐腐蚀性能优于修复前样品,但仍低于原始样品(即未变形样品)。电化学阻抗研究结果显示,在开路电位下阻抗图均有单一容抗弧构成,修复后样品的电化学转移电阻Rt小于原始样品的、但大于修复前样品的,这进一步表明修复提高了材料的耐腐蚀性能,但仍未达到原始样品的耐蚀性。扫描电镜研究发现,合金表面发生明显的点蚀,其中原始样品的点蚀坑密度最少,修复后样品的次之,修复前样品的最多。 相似文献
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通过铜模铸造法制备出了具有异质结构的Zr63Ni16.2Cu15.8Al5和Zr63.4Ni16.2Cu15.4Al5块体非晶合金.利用X射线衍射(XRD)和差示扫描量热法(DSC)研究了两种Zr基块体非晶合金的微观结构和热稳定性,采用动电位极化方法研究了两种Zr基块体非晶合金在NaCl水溶液中的耐腐蚀性能.结果表明,与均匀结构的Zr65Al10Ni10Cu15块体非晶合金相比,异质结构降低了材料的热稳定性以及耐腐蚀性能,耐腐蚀性能低的原因可能是由于微观结构的不均匀使其具有更多的界面引起的. 相似文献
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Microstructure and Wear Resistance of Fe-Based Amorphous Metallic Coatings Prepared by HVOF Thermal Spraying 总被引:2,自引:0,他引:2
Z. Zhou L. Wang D. Y. He F. C. Wang Y. B. Liu 《Journal of Thermal Spray Technology》2010,19(6):1287-1293
Amorphous metallic coatings with a composition of Fe48Cr15Mo14C15B6Y2 were fabricated by means of high velocity oxygen fuel (HVOF) thermal spraying process. The microstructure and wear performance
of the coatings were characterized simultaneously in this article. It is found that the coatings present a dense layered structure
with the porosity below 1.5%. The coatings primarily consist of amorphous matrix and some precipitated nanocrystals, though
a fraction of Fe-rich phases and oxide stringers also formed during deposited process. High thermal stability enables the
amorphous coatings to work below 920 K temperature without crystallization. Depending on the structural advantage, the amorphous
coatings exhibit high average microhardness of 997.3 HV0.2, and excellent wear resistance during dry frictional wear process. The dominant wear mechanism of amorphous coating under
this condition is fatigue wear, leading to partial or entire flaking off of the lamellae. In addition, the appearance of oxidative
wear accelerates the failure of fatigue wear. 相似文献
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为提高严苛海洋环境下金属机件的服役性能,本文通过电沉积方法制备了Ni-W和Ni-W/SiC复合镀层。利用扫描电子显微镜(SEM)、能谱分析(EDS)和X射线衍射(XRD)等技术研究了SiC对Ni-W合金微观结构和性能的影响,采用电化学方法研究了复合镀层在3.5% NaCl溶液中的耐蚀性能,以探讨其海水综合防护性能。研究表明,经表面处理的SiC可诱导形核促进晶体生长,使Ni-W合金晶粒变细,镀层完整致密。SiC纳米颗粒均匀分布在Ni-W/SiC中,可有效提高镀层硬度及耐磨性,同时Ni-W/SiC也具有比Ni-W合金更好的耐蚀性能,在多因素交互作用的海洋环境中将具有更长的防护寿命,具有良好的应用前景 相似文献
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采用铜模吸铸法制备出成分为(Cu50Zr45Al5)100-xYx(x=0,1,2,3,4,5)的合金试样。利用X射线衍射,金相显微镜,差热分析和电化学极化曲线的方法研究了Y对Cu-Zr-Al系非晶合金的结构、玻璃形成能力和腐蚀行为的影响。结果表明,适量Y的添加提高了非晶合金的玻璃形成能力和热稳定性,当Y含量为2%时合金的过冷液相区宽度为ΔTx=Tx-Tg=64K,约化玻璃转变温度Trg=Tg/T1=0.601,玻璃形成能力γ=Tx/(Tg+T1)=0.409(Tg,Tx,T1分别为非晶合金的玻璃转变温度,晶化开始温度和熔化温度)。非晶合金在3.5%的NaCl溶液中的耐蚀性随Y含量的增加而降低。 相似文献
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Yu. A. Skakov 《Metal Science and Heat Treatment》2000,42(9):377-384
The results of x-ray study of amorphous metal alloys are compared with the structural parameters of intermediate phases determined for equilibrium state diagrams and primary products of crystallization upon warming of amorphous alloys and crystal phases (formed at subcritical cooling rates) of the alloys susceptible to amorphization. It is found that susceptibility of the alloys to amorphization depends on the specific chemical interaction of the components which is revealed in the formation of the intermediate crystal phases. This conclusion is proved by the results of studying solid-phase reaction of amorphization. 相似文献
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Despite the economy of material cost and excellent toughness of Cu-based amorphous alloys, especially Cu_(50)Zr_(50), their poor corrosion resistance to a chloride medium limits their widespread applications. In this study, corrosion tests were performed on the Cu_(50)Zr_(50) amorphous alloy with different degrees of short-range order, which were prepared by annealing below the glass transition temperature(T_g). It was found that the corrosion resistance of amorphous alloys is improved to a significant level when the alloys were heated below T_g. Calorimetric studies showed that thermally activated relaxation process of created disorder, which occurs during sub-T_gannealing, is responsible for the improvement in the corrosion resistance. Molecular dynamics simulations performed on the Cu–Zr amorphous alloys demonstrated that the relaxation process of the alloys is associated with the formation of energetically stable icosahedra and icosahedron-like structures. Our study highlights the effects of sub-T_gannealing on the improvement in the corrosion resistance of the amorphous alloys from the viewpoint the relaxation process of the short-range orders. 相似文献
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Gunilla Bökmark Göran Holmbom Per-Olof Persson Jan Sidén Lennart Granlund 《金属精饰学会汇刊》2013,91(3):122-130
This report presents a survey of various surface treatments to improve the wear resistance of aluminium. Over 25 different treatments have been produced and evaluated in laboratory and in application tests. Three plastically formable alloys and one pressure die casting alloy were included.The different coating systems have been characterised with respect to structure and morphology by scanning and transmission electron microscopy. The laboratory wear tests were performed by using Taber abraser and pin on disc as standard methods. As a comparison, a non-standard reciprocating adhesive wear test set-up was used. In addition, a corrosion test by accelerated outdoor exposure (SCAB) was performed. The application tests were a rotating PTFE sealed sleeve, a station chain in a food packing machine and a yarn feeder.The results from the abrasive and adhesive laboratory wear tests have been correlated to the results in the application tests. For some of the evaluated coating systems the correlation between the laboratory and the application tests is reasonably good. However, substantial difference in performance was found for other systems. 相似文献
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医用CoCrMoC合金的组织结构及耐磨损性能 总被引:4,自引:0,他引:4
以铸造CoCrMoC合金(ASTMF 75-82)为研究对象,通过金相观察,XRD,SEM和EDX分析以及磨损试验,研究了该合金在不同热处理条件下的显微结构与耐磨损性能。结果表明:不含C的CoCrMo合金的耐磨损性能几乎不受热处理制度的影响:含C的CoCrMoC合金在1100℃以上温度固溶处理耐磨损性能明显提高,其中1200℃是最佳温度,固溶后时效处理降低合金的耐磨损性能。分析认为,固溶引起的fcc钴基体固溶强化和适当的碳化物分布是提高耐磨损性能的主要原因,而时效引起的基体fcc相→hcp相的等温马氏体相变对耐磨损性能影响不大。 相似文献
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利用铜模吸铸法在水冷坩埚中制备了4种(Zr0.55Al0.1Ni0.05Cu0.3)100-xNdx(x=0,1,2,3)块体非晶合金。采用XRD和DSC检测了所获合金相组成、非晶形成能力及热稳定性,并采用盐酸溶液浸泡腐蚀试验评价了不同合金的腐蚀速率。结果表明,适量添加Nd可提高Zr0.55Al0.1Ni0.05Cu0.3非晶合金的形成能力和热稳定性,但非晶合金在2mol/L HCl溶液中的耐蚀性随Nd含量的增加而降低。该结果对进一步改善和提高非晶合金的性能具有重要的参考价值。 相似文献
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分别采用单辊甩带法和非晶晶化退火法制备出非晶及纳米晶合金Fe73.5Si13.5B9Nb3Cu1;利用DSC、XRD和TEM对该非晶合金的晶化行为进行了分析;并用电化学极化曲线的方法和电化学阻抗技术研究了该非晶合金经不同温度退火后在1mol/LHCl溶液里的电化学腐蚀行为。结果表明,该非晶合金的晶化过程出现2个阶段。当退火温度为500℃时,合金尚未晶化,仍保持非晶态;当温度达到550℃时,出现了晶化衍射峰,晶粒平均直径约13nm;当温度达到600℃时,晶粒平均直径约为15nm。经过退火得到的纳米晶合金的腐蚀电位大于未退火的非晶,且阳极电流密度变得更低,表明纳米晶状态时的耐腐蚀性能比非晶状态的更好。该非晶合金未退火、550℃退火和600℃退火时的EIS均由单一容抗弧构成,具有一时间常数;且随着退火温度升高,电化学反应电荷转移电阻在增大。 相似文献