NiAl—TiC内生复合材料的高温拉伸行为

研究了ＨＰＥＳ法制备的ＮｉＡｌ－ＴｉＣ内生复合材料的高温拉伸行为及ＮｉＡｌ／ＴｉＣ的界面特点，结果表明，内生ＴｉＣ颗粒可大幅度提高ＮｉＡｌ的高温拉伸强度，在ＮｉＡｌ与ＴｉＣ之间存在着一种相互交错的界面，它对提高复合材料的高温拉伸强度具有重要贡献。     

NiAl微晶涂层对NiAl-TiC复合材料高温氧化性能的影响

研究了磁控溅射ＮｉＡｌ微晶涂层对ＮｉＡｌ－ＴｉＣ（２０％,体积分数）复合材料１０００－１１００℃高温氧化性能的影响。结果表明,ＮｉＡｌ微晶涂层大大提高了ＮｉＡｌ－ＴｉＣ复合材料的恒温及循环氧化性能,降低氧化速率几个数量级,对于ＮｉＡｌ－ＴｉＣ复合材料来说,其表面形成以ＴｉＯ２为主的复合氧化物,而施加ＮｉＡｌ微晶涂层后,其表面氧化物主要是Ａｌ２Ｏ３。     

机械合金化制备NiAl—TiC复合材料的组织和力学性能

研究了反应球磨方法制备的ＮｉＡｌ－ＴｉＣ复合材料的组织和力学性能。结果表明,强化相呈两态分布。１０００℃长期退火对材料的组织和显微硬度影响不大。ＮｉＡｌ－ＴｉＣ复合材料的强度远高于铸态ＮｉＡｌ的强度,也比ＸＤ ＮｉＡｌ－ＴｉＢ２复合材料的强度高。高温热等静压后,该复合材料的室温和高温屈服强度都明显下降。材料的高温强度依赖于应变速率,变形受扩散机制控制。     

NiAl－TiC内生复合材料的高温拉伸行为

研究了ＨＰＥＳ法制备的ＮｉＡｌ－ＴｉＣ内生复合材料的高温拉伸行为及ＮｉＡｌ／ＴｉＣ的界面特点．结果表明，内生ＴｉＣ颗粒可大幅度提高ＮｉＡｌ的高温拉伸强度．在ＮｉＡｌ与ＴｉＣ之间存在着一种相互交错的界面，它对提高复合材料的高温拉伸强度具有重要贡献．     

高压原位合成高致密TiCp／Ni3Al复合材料

采用高温高压（１．５－６．５Ｇａ，１０７３－１４７３Ｋ）方法，由Ｔｉ，Ｃ，Ｎｉ，Ａｌ四种元素娄末原料原位合成了ＴｉＣ颗粒增强Ｎｉ３Ａｌ金属间化合物基复合材料，其密度大于９８％理论值。其中ＴｉＣ颗业尺寸为纳米级，并讨论了ＴｉＣ晶粒尺寸与合成压力的关系，及对复合材料显微硬度的影响。     

自生复合材料（Al—TiB2—TiC）的燃烧合成研究

本文研究了Ａｌ－Ｔｉ－Ｂ４Ｃ体系的燃烧合成过程，用粉末（Ａｌ，Ｔｉ，Ｂ４Ｃ）通过燃烧方法，来制备复合材料（Ａｌ－ＴｉＢ２－ＴｉＣ）。采用ＤＴＡ、ＸＲＤ和ＳＥＭ译复合材料的形成和结果进行了分析研究，得到如下结果：分别用８０％Ａｌ＋２０％（３Ｔｉ＋Ｂ４Ｃ），９０％Ａｌ＋１０％（３Ｔｉ＋Ｂ４Ｃ）原料粉末，通过忆热可得到Ａｌ－ＴｉＢ２－ＴｉＣ，在制备过程中会产生少量的ＴｉＡｌ３．     

大块非晶和部分晶化的Nd—Fe—（Al,B）系合金的硬磁性能

块体非晶态合金可以分为非铁基和铁基两大类 ,如下表所列 ,能制取非晶态最大直径 >5ｍｍ的非铁基(有色金属 )合金系有Ｍｇ Ｌｎ (Ｎｉ,Ｃｕ) ,Ｌｎ Ａｌ (Ｎｉ,Ｃｕ) ,Ｚｒ Ａｌ (Ｎｉ,Ｃｕ) ,含有Ｔｉ、Ｎｂ、Ｔａ或Ｐｄ的Ｚｒ Ａｌ (Ｎｉ,Ｃｕ) ,还有Ｚｒ Ｔｉ Ｂｅ Ｎｉ Ｃｕ、Ｐｄ Ｃｕ Ｎｉ Ｐ、Ｐｄ Ｃｕ Ｆｅ Ｐ、Ｔｉ Ｎｉ Ｃｕ Ｓｎ、Ｃｕ Ｚｒ Ｔｉ Ｙ以及Ｃｕ Ｚｒ Ｔｉ Ｂｅ系。另外 ,可形成非晶态最大直径 >2ｍｍ的铁基和钴基合金系 ,主要有Ｆｅ (Ａｌ,Ｇａ) (Ｐ ,Ｃ ,Ｂ) ,含有Ｃｒ、Ｍｏ或Ｎｂ的Ｆｅ (Ａｌ,Ｇａ) (Ｐ ,Ｃ …     

自蔓燃高温合成（SHS）TiC—Al2O3陶瓷

本文采用自蔓燃高温合成（ＳＨＳ）技术结合热压工艺，以ＴｉＯ２粉，Ａｌ粉及石墨粉（Ｃ）为原料制备出了ＴｉＣ－Ａｌ２Ｏ３陶瓷及（ＴｉＣ－Ａｌ２Ｏ３）／Ｎｉ金属陶瓷复合材料，并对其组织结构及性能进行了研究。结果表明，本方法制备的材料性能优于传统方法制备的材料，适于作刀具。     

TiAl合金激光表面合金化涂层的组织与耐磨性

以ＮｉＣｒ－ＷＣ混合料末为原料,对ＴｉＡｌ合金进行激光表面合金化处理,制得了以γ－ＮｉＣｒＡｌＴｉ镍基固溶体为基体,以ＴｉＣ,Ｗ２Ｃ及Ｍ２３Ｃ６为增强相的耐磨复合材料表面改性层。分析了改性层的组织,并测试了其在滑动摩擦试验条件下的耐磨性。实验结果表明,激光表面合金化涂层具有较高的硬度及较好的耐磨性。     

自生TiCW—AlNp／Al复合材料中TiCW相的形成和分布

用固－气－液三态反应方法和合适的冷却条件制备了自生ＴｉＣＷ－ＡｌＮｐ／Ａｌ复合材料。讨论了ＴｉＣＷ晶须的形成机制和强化特点；并用电子显微镜观察了基体被部分腐蚀掉的ＴｉＣＷ－ＡｌＮ／Ａｌ复合材料中ＴｉＣＷ的立体形貌和空间分布特征。     

High-temperature compression behavior of W–10 wt.%Cu composite

Hot deformation behavior of tungsten–copper (W–Cu) composite at elevated temperature was investigated by hot-compression testing using a Gleeble 3500 thermo-mechanical simulator. W–10%Cu composite was fabricated by copper infiltration on porous tungsten skeleton (CIT) method. The porous tungsten skeleton was prepared by powder injection molding (PIM) process using tungsten powders and wax-polymer binder system. The hot deformation equations for W–10%Cu composite were determined through strain–stress relations at elevated temperatures, where the strain rate is related to static stress, deformation temperature and activation energy. The effects of deformation temperature and strain rate on the mechanical properties of W–10 wt.%Cu composite were investigated through flow strain–stress curves at elevated temperatures and its microstructures before and after deformation.     

Al_2O_3sf／LY12复合材料在高温下的流动应力与塑性变形行为

采用固态高温压缩试验、高温金相观察等试验手段，实验研究了Ａｌ２Ｏ３ｓｆ／ＬＹ１２复合材料在高温下的流动应力与塑性变形行为。结果表明，随着变形温度的提高，由于基体的变形抗力以及基体对阻碍其变形的纤维的剪切作用力大大降低，纤维不易产生断裂并易于以偏转的形式调整自己的方位来适应基体的塑性流动，从而显著降低复合材料的流动应力和大大提高其塑性和变形能力，有利于复合材料的成形。     

Effect of deformation temperature on the deformation behaviors of amorphous/crystalline composites

The amorphous/crystalline composite comprising amorphous particles of Cu54Ni6Zr22Ti18 embedded in the crystalline nickel matrix was produced and its temperature dependence of the plastic deformation behavior was studied in the supercooled liquid region (SLR) of the amorphous alloy. The flow stress of the amorphous alloy was quite sensitive to the testing temperature in the SLR. The deformation of the composites was dominated by the flow stress of the amorphous alloy. The deformation behavior of the composite was analyzed by finite element method (FEM) calculations.     

Influence of spherical particles and interfacial stress distribution on viscous flow behavior of Ti‐Cu‐Ni‐Zr‐Sn bulk metallic glass composites

Bulk metallic glass composites containing micro-scale B2 particles are subject to investigation with regards to the influence of B2 particles and interfacial stress and strain distribution on the viscous flow behavior at a super-cooled liquid state. An increased volume fraction of B2 particles leads to an increase of minimum viscosity and influences viscous flow behavior before crystallization. In high temperature deformation, the bulk metallic glass shows homogeneous deformation feature. However, the heterogeneous deformation feature is found in thermoplastically deformed bulk metallic glass composite. The strong stain accumulation and sluggish viscous flow occur around B2 particles, which are caused by the heterogeneous stress distribution linked to stress concentration and shear stress impediment around B2 particles. The sluggish viscous flow of super-cooled liquids around B2 particles during high temperature deformation induces an increase of viscosity and strongly affects the viscous flow behavior of Ti-based bulk metallic glass composites containing micro-scale spherical B2 particles.     

钛铝复合板横向共挤压翘曲变形分析

针对双金属横向共挤压成形过程中钛铝复合板的翘曲变形问题,采用Deform-3D数值分析,进行塑性变形分析和成形工艺参数优化,提出了主变形的铝材挤出翘曲角和界面压力焊合的压应力标准差作为翘曲变形的评价策略.数值模拟结果表明:翘曲角与挤压速度、温度分别呈正相关和负相关的演变规律,即"高温低速"的共挤压制备工艺有助于减小钛铝...     

Effect of deformation temperature on the hot compressive behavior of metal matrix composites with misaligned whiskers

A multi-inclusion cell model is used to investigate the effect of deformation temperature and whisker rotation on the hot compressive behavior of metal matrix composites with misaligned whiskers. Numerical results show that deformation temperature influences the work-hardening behavior of the matrix and the rotation behavior of the whiskers. With increasing temperature, the work hardening rate of the matrix decreases, but the whisker rotation angle increases. Both whisker rotation and the increase of deformation temperature can induce reductions in the load supported by whisker and the load transferred from matrix to whisker. Additionally, it is found that during large strain deformation at higher temperatures, the enhancing of deformation temperature can reduce the effect of whisker rotation. Meanwhile, the stress-strain behavior of the composite is rather sensitive to deformation temperature. At a relatively lower temperature （150℃）, the composite exhibits work hardening due to the matrix work hardening, but at relatively higher temperatures （300℃ and above）, the composite shows strain softening due to whisker rotation. It is also found that during hot compression at higher temperatures, the softening rate of the composite decreases with increasing temperature. The predicted stress-strain behavior of the composite is approximately in agreement with the experimental results.     

35% SiC_p/2024A1复合材料的热变形行为(英文)

采用Gleeble-1500D热模拟试验机,对35%SiCp/2024A1复合材料在温度350~500°C、应变速率0.01~10s-1的条件下进行热压缩试验,研究该复合材料的热变形行为与热加工特征,建立热变形本构方程和加工图。结果表明,35%SiCp/2024A1复合材料的流变应力随着温度的升高而降低,随着应变速率的增大而升高,说明该复合材料是正应变速率敏感材料,其热压缩变形时的流变应力可采用Zener-Hollomon参数的双曲正弦形式来描述;在本实验条件下平均热变形激活能为225.4 kJ/mol。为了证实其潜在的可加工性,对加工图中的稳定区和失稳区进行标识,并通过微观组织得到验证。综合考虑热加工图和显微组织,得到变形温度500°C、应变速率0.1~1 s-1是复合材料适宜的热变形条件。     

Hot Deformation Behavior of 6061 and 7108 Al-SiCp Composites

Hot deformation behavior of Al 6061- and Al 7108-SiC particulated composites (Al-PMMCs), prepared by stir casting with SiC particulates (SiCp) size of 8 and 15 μm and volume fraction from 0 to 20% is studied by uniaxial compression test carried out at temperature range from room temperature to 500 °C. The flow stress, work hardening behavior, and Young’s modulus are determined. Dynamic recrystallization is also studied. Work hardening and Young’s modulus are directly correlated with composite constituents, whereas the flow stress is greatly influenced by the porosity and SiCp agglomeration. The role of the SiCp in increasing the flow stress decreases by increasing the deformation temperature. The dynamic recrystallization process is stimulated by refining the SiCp and increasing their fraction in soft Al matrix. On the other hand, the PMMCs with Al6061 matrix has more potential for strain hardening than that with Al 7108 matrix. The strain hardening rate is influenced by the matrix type more than the SiCp volume fraction and size.     

Influence of extrusion temperature on deformation behavior of Csf/AZ91D composite during semi-solid extrusion

Deformation behavior and formability of C_sf/AZ91D magnesium composite were investigated by semi-solid extrusion between 695 K and 728 K, including temperatures below and above the partial melting temperature. A method of constructing kinematically admissible velocity fields for axisymmetric extrusion based on the theory of flow function was proposed. Flow lines were analyzed in C_sf/AZ91D composite after extrusion at elevated temperatures. Based on an analytic flow function, the deformation field was obtained. The results show that when the composite is extruded in a semi-solid state containing a small volume of liquid, the presence of the liquid reduces deformation resistance by relaxing the stress concentrations, and improves the formability of composites as lubricant. However, the gradient of velocity field is increased and deformation uniformity is aggravated at temperatures greater than partial melting point at 701.3 K. A more uniform deformation field was attained at the temperature close to or slightly below the partial melting temperature.     

原位TiB2颗粒增强7075铝基复合材料的热压缩变形行为和显微组织演变

采用等温热压缩实验研究不同变形条件下(变形温度300～450℃、应变速率0.001～1 s?1)原位TiB2颗粒增强7075铝基复合材料的热成形行为、损伤机制和显微组织演变.结果表明,复合材料在低温和高应变速率下的主要损伤机制是颗粒断裂和界面脱粘,而在高温和低应变速率下主要是基体的韧窝断裂.此外,复合材料在高温、低应变...