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高分子膜材料的研究概况 总被引:2,自引:0,他引:2
介绍高分子膜材料的分类和研究方法,着重从高分子膜的性能、成膜及改性方法、新型膜材料几方面综述高分子膜材料的研究进展情况,同时概要叙述高分子膜材料的应用及今后的发展远景。 相似文献
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聚乙烯醇(PVA)因其良好的化学稳定性、耐酸碱、耐有机溶剂性以及优异的成膜性和生物安全性,成为应用最广泛的亲水性膜材料之一。但亲水性PVA膜力学性能弱和耐水性能差等缺点严重限制其实际应用。近些年,人们通过共混、纳米复合、热处理、化学交联以及协同改性等方法对PVA膜进行了大量的改性研究工作并取得了众多成果。本文总结了不同PVA膜改性方法的特点及存在的问题,重点阐述了性能优异的填料在纳米复合改进PVA膜力学性能上的研究现状,简述了共混、热处理、化学交联对改性PVA膜的作用,强调了协同改性对提高PVA膜综合性能的重要意义,为设计和制备高性能的PVA膜提供一定的参考。指出改性后的PVA膜在水处理和食品包装领域具有良好的应用前景。 相似文献
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新型气液膜接触器是很多具有共同特点膜过程的总称,它使用高分子膜将两流体分隔开,膜孔为两流体提供有效传质的场所,与传统分离器相比具有许多独特的优点,日益成为分离科学研究的热点。简述膜接触器在不同气/液分离体系中的应用,针对膜吸收、膜蒸馏、膜结构填料等三种典型的气/液界面膜接触分离过程,从结构、膜材料、传质、分离效率等方面详细进行了分析和比较。着重介绍了近年来相关领域膜材料学的研究进展,如高分子膜材料、成膜方法以及膜材料的改性方法(等离子体改性法、紫外辐照法和表面涂覆改性法等)等。 相似文献
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壳聚糖及其衍生物具有功能基团丰富、化学活性强、亲水性高、易从可再生资源中获得等优势,是去除水体中杂质的理想材料。由于分子内和分子间的氢键作用、范德华力以及分子的规整性使壳聚糖易成膜,将壳聚糖与膜分离技术结合制备抗污染性能强、选择特异性高、活性吸附位点丰富、稳定性强且具有良好再生能力的壳聚糖膜,并应用在废水处理领域成为国内外学者研究的热点。本文围绕壳聚糖及其改性膜的研究进展及在废水处理上的应用进行综述,分别从壳聚糖作为成膜基质和膜表面修饰材料两个方面进行详细介绍。总结了共混改性、交联改性、印迹改性以及新型的磁性纳米粒子负载改性、表面等离子体改性、MOFs改性等改性方法对壳聚糖膜性能的影响及在水处理中的应用效果,最后对壳聚糖膜在分离领域的发展方向进行了展望。 相似文献
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The technology for generating high quality keratin films has recently advanced and led to their implementation in a variety of applications. As an initial step toward investigating the films as a screening tool for predicting the efficacy of potential hair dyes, CI Acid Orange 7 was applied to a set of opaque and translucent films. Overlaid time‐of‐flight secondary ion mass spectrometry images arising from protein and dye fragments revealed that dye uniformly penetrated both film types. Results also showed that the relative concentration of dye in each film complemented outcomes from ultraviolet‐visible analysis and revealed that the translucent film contained a higher dye concentration. Scanning electron microscopy analysis of film morphology suggested that the observed difference was due to the higher porosity of the opaque film, which facilitated dye desorption during the rinsing step. Consequently, the translucent film was judged to be a better substrate for screening potential new hair dyes. 相似文献
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Surface modification on polytetrafluoroethylene (PTFE) films was performed with sequential hydrogen plasma/ozone treatments and surface-initiated polymerization. C-H groups were introduced to the surface of PTFE films through defluorination and hydrogenation reactions under hydrogen plasma treatment. The C-H groups then served as ozone accessible sites to form peroxide groups under ozone treatment. Grafting polymerization initiating from the peroxide groups was performed on the PTFE film surface with using acrylamide, acrylic acid, glycidyl methacrylate and 2-(2-bromoisobutyryloxy)ethyl acrylate (BIEA) as monomers. With utilizing the isobutylbromide groups on the surface of PTFE-g-PBIEA film as initiators, sodium 4-styrenesulfonate (NaSS) was polymerized onto the PTFE film surface via atom transfer radical polymerization, to bring arborescent macromolecular structure to PTFE film surface. The chemical structures of the macromolecules on PTFE film surfaces were characterized with FTIR-ATR, SEM-EDX and XPS. The surface hydrophilicities of modified PTFE films were significantly enhanced with the modification. 相似文献
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Mild and Effective Polymerization of Dopamine on Keratin Films for Innovative Photoactivable and Biocompatible Coated Materials 下载免费PDF全文
Tamara Posati Claudia Ferroni Annalisa Aluigi Andrea Guerrini Francesca Rossi Francesca Tatini Fulvio Ratto Emanuela Marras Marzia Bruna Gariboldi Anna Sagnella Giampiero Ruani Roberto Zamboni Greta Varchi Giovanna Sotgiu 《大分子材料与工程》2018,303(8)
Mussel‐inspired polydopamine (PD) coating represents a promising route for constructing functional materials and finely tuning or completely changing their surface properties. In this work, a mild and effective method to realize the deposition of PD on keratin‐based films is reported. Reactive oxygen species (ROS), generated by keratin films doped with a photosensitizer, e.g., Azure A (AzA), upon UV–vis and vis‐near IR irradiation, are exploited to obtain the PD coating. Interestingly, the use of vis‐near IR irradiation leads to an increased production of ROS by AzA resulting in a greater PD deposition. Compared to uncoated keratin films, the PD‐keratin coated materials show a granular but homogeneous surface and an increased hydrophilicity, maintaining the ROS generation ability of AzA. This work demonstrates a useful method to effectively and rapidly functionalize with PD materials that are sensitive to temperature, pH and UV light, such as keratin. The proposed strategy allows obtaining new multifunctional biomaterials of potential interest in tissue engineering and drug delivery; in particular, the use of PD‐keratin films for near IR laser bonding of ophthalmic tissue, which is a representative case in wound healing purpose, is shown. 相似文献
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Bioplastic based on 1,8‐octanediol‐plasticized feather keratin: A material for food packaging and biomedical applications 下载免费PDF全文
Keratin without plasticizer produces fragile films. 1,8‐Octanediol (OD) was used as a plasticizer to modify keratin films in this study. Two keratins with different structures were extracted from duck feather, including reduced keratin (RK) and native keratin (NK). Formaldehyde was used as the crosslinking agent for RK to prepare crosslinked keratin (CK) films. The addition of OD toughened the CK and RK films. In particular, the plasticized CK films demonstrated good mechanical properties and had satisfactory water resistance. The water vapor permeability varied between 0.106 and 0.808 g/(m s Pa) for CK films without OD and with 0.30 g OD/g keratin, respectively, and the tensile strength decreased from 12.1 to 8.0 MPa and the elongation at break increased from 2.3% to 11.6%. Cell culture experiments suggest that OD‐plasticized NK films are biocompatible. In general, OD‐plasticized keratin films can find applications in food packaging and biomedical materials. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46516. 相似文献
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Keratin obtained from poultry feathers was modified with glycerol, which acted as a plasticizer. Films were prepared by pressing the modified keratin at temperatures concurrent with typical polymer processing temperatures. The films were completely cohesive as opposed to partially cohesive if pressed under the same conditions without glycerol. The films were “tough” and the mechanical properties show similarities to the properties of commercially available commodity thermoplastics. The keratin films were produced in a few minutes without reducing or oxidizing agents. The keratin films could have potential applications for which environmentally friendly materials are needed, such as food packaging or mulching films. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1644–1651, 2005 相似文献