Nitrate distribution and accumulation in an Ustochrept soil profile in a long term fertilizer experiment

Distribution and accumulation of NO₃—N, down to 210 cm depth, in the soil profile of a long term fertilizer experiment were studied after 16 cycles of cropping (maize-wheat-fodder cowpea). The application of fertilizer N without P and K or in combination with only P resulted in higher NO₃—N concentration in the soil profile than the application of N with P and K. With an annual application of 320 kg N ha^–1 alone, a peak in NO₃—N accumulation occurred at 135 cm soil depth. However, with the application of NPK, no peak in NO₃—N distribution was discernible and its content at most of the sampling depths was either less than or equal to N and NP treatments. The annual application of 10 tons farm yard manure (FYM) per ha along with NPK resulted in a relatively lower NO₃—N content in the sub soil. The amount of NO₃—N accumulation in the soil profile decreased as the cumulative N uptake by the crops increased. Application of fertilizer amounts greater than that of the recommended (100% NPK) resulted in low percent N recoveries in crops and greater NO₃—N accumulation in the soil profile.     

Crop yield, nitrogen uptake and nitrate-nitrogen accumulation in soil as affected by 23 annual applications of fertilizer and manure in the rainfed region of Northwestern China

Application of chemical fertilizers and farmyard manure affects crop productivity and improves nutrient cycling within soil–plant systems, but the magnitude varies with soil-climatic conditions. A long-term (1982–2004) field experiment was conducted to investigate the effects of nitrogen (N), phosphorus (P), and potassium (K) fertilizers and farmyard swine manure (M) on seed and straw yield, protein concentration, and N uptake in the seed and straw of 19-year winter wheat (Triticum aestivum L.) and four-year oilseed (three-year canola, Brassica napus L. in 1987, 2000 and 2003; one-year flax, Linum usitatisimum L. in 1991), accumulation of nitrate-N (NO₃-N) in the soil profile (0–210 cm), and N balance sheet on a Huangmian soil (calcaric cambisols, FAO) near Tianshui, Gansu, China. The two main plot treatments were without and with farmyard swine manure (M); sub-plot treatments were control (Ck), N, NP, and NPK.␣The average seed yield decreased in the order MNPK ≥ MNP > MN ≥ NPK ≥ NP > M > N > Ck. The average effect of manure and fertilizers on seed yield was in the order M > N > P > K. The seed yield increase was 20.5% for M, 17.8% for N, 14.2% for P, and 2.9 % for K treatment. Seed yield response to fertilizers was much greater for N and P than for K, and it was much greater for no manure than for manure treatment. The response of straw yield to fertilization treatments was usually similar to that of seed yield. The N fertilizer and manure significantly increased protein concentration and N uptake plant. From the standpoint of increasing crop yield and seed quality, MNPK was the best fertilization strategy. Annual applications of N fertilizer and manure for 23 successive years had a marked effect on NO₃-N accumulation in the 0–210 cm soil profile. Accumulation of NO₃-N in the deeper soil layers with application of N fertilizer and manure is regarded as a potential danger, because of pollution of the soil environment and of groundwater. Application of N fertilizer in combination with P and/or K fertilizers reduced residual soil NO₃-N significantly compared with N fertilizer alone in both no manure and manure plots. The findings suggest that integrated and balanced application of N, P, and K fertilizers and␣manure at proper rates is important for protecting soil and groundwater from potential NO₃-N pollution and for maintaining high crop productivity in the rainfed region of Northwestern China.     

Response of dryland wheat to fertilizer nitrogen in relation to stored water,rainfall and residual farm yard manure

Yield response of dryland wheat to fertilizer N application in relation to components of seasonal water (available soil moisture and rainfall) and residual farm yard manure (FYM) was studied for five years (1983–84 to 1987–88) on a maize-wheat sequence on sandy loam soils in Hoshiarpur district of Punjab, India. Four rates of N viz. 0, 40, 60 and 80 kg ha^–1 in wheat were superimposed on two residual FYM treatments viz. no FYM (F₀) and 15 t ha^–1 (F₁₅) to preceding maize. FYM application to maize increased the residual NO₃-N content by 19–30 kg ha^–1 in the 180 cm soil profile. For a given moisture distribution, F₁₅ increased attainable yields. Over the years, F₁₅ increased wheat yield by 230 to 520 kg ha^–1. Response to fertilizer N was lower in FYM amended plots than in unamended plots. Available soil moisture at wheat seeding and amount and distribution of rainfall during the vegetative and the reproductive phases of crop development affected N use efficiency by wheat. Available soil moisture at seeding alone accounted for 50% variation in yield. The residual effect of FYM on wheat yield could be accounted for by considering NO₃-N in 180 cm soil profile at seeding. The NO₃-N and available soil moisture at wheat seeding along with split rainfall for two main phases of crop development and fertilizer N accounted for 96% variation in wheat yield across years and FYM treatments.     

Nitrogen balance and accumulation pattern in three contrasting prairie soils receiving repeated applications of liquid swine and solid cattle manure

The expansion of intensive livestock operations in western Canada has increased concerns about overloading of nutrients in manured lands. The magnitude of nutrient accumulation and its distribution in the soil profile varies with soil-climatic conditions. The objective of this study was to determine loading and distribution of manure-derived nitrogen (N) in the soil profile as influenced by repeated manure applications. Four field experiments were conducted at three sites (Dixon, Melfort and Plenty) in Saskatchewan under longer-term manure management. The four field experiments provide contrasts in soil type, climatic conditions, manure type, application and cropping history to enable the effect of these factors to be evaluated. Liquid hog manure (LHM—Experiment 1) and solid cattle manure (SCM—Experiment 2) treatments were applied annually over 8 years at Dixon (Black Chernozemic loam soil—Udic Boroll in sub-humid climate), while only LHM was applied at Plenty (Dark Brown Chernozemic heavy clay soil—Typic Boroll in semi-arid climate) over 6 years (Experiment 3), and at Melfort (Dark Gray Luvisol silty clay loam soil—Mollic Cryoboralf in humid climate) over 5 years (Experiment 4). Soil samples were collected in the spring and autumn of 2003 and 2004, and were analyzed for organic N, ammonium-N (NH₄⁺-N) and nitrate-N (NO₃⁻-N) concentrations. Plant samples were collected to determine the impact of manure application rate on plant N uptake and crop N removal. The annual application of LHM (37,000 L ha⁻¹ yr⁻¹) and SCM (7.6 Mg ha⁻¹ yr⁻¹) at agronomic rates at Dixon (added N balances crop demand for that year), or larger rates of LHM (111,000 L ha⁻¹) applied once every 3 years (Melfort) did not significantly elevate NO₃⁻-N in soil compared to the unfertilized control. Lower crop removal and reduced leaching of NO₃⁻-N due to drier conditions as occurred at the Plenty site contributed to greater accumulation of nitrate in the top 60 cm at equivalent rates compared to the other two sites. At large manure rates, excess N from the balance estimates could not be accounted for in soil organic N and was assumed to be lost from the soil-plant system. At the Dixon LHM site, deep leaching of NO₃⁻-N was observed at the excessive rate (148,000 L ha⁻¹ yr⁻¹) up to the 150 cm depth, compared to the control. At Dixon, the large annual application rate of SCM (30.4 Mg ha⁻¹ yr⁻¹) did not significantly increase NO₃⁻-N in the 0–60 cm soil compared to the control, which was attributed to lower mineralization of organic N from the SCM. Over the short and medium term, LHM application at large rates every year poses a greater risk for loading and deep migration of NO₃⁻-N in soil than large rates of SCM. Larger single applications made once every 3 years were not associated with accumulation or deep leaching. To prevent loading, rates of applied manure nitrogen should be reduced when crop N removal potential is diminished by high frequency of drought.     

Effect of poultry litter and composts on soil nitrogen and phosphorus availability and corn production

Environmental problems associated with raw manure application might bemitigated by chemically or biologically immobilizing and stabilizing solublephosphorus (P) forms. Composting poultry litter has been suggested as a means tostabilize soluble P biologically. The objectives of this study were to assessthe nutrient (N, P) value of different-age poultry litter (PL) compostsrelativeto raw poultry litter and commercial fertilizer and determine effects ofpoultrylitter and composts on corn (Zea mays) grain yield andnutrient uptake. The research was conducted for two years on Maryland'sEastern Shore. Six soil fertility treatments were applied annually to aMatapeake silt loam soil (Typic Hapludult): (1) a check without fertilizer, (2)NH₄NO₃ fertilizer control (168 kg Nha^–1), (3) raw poultry litter (8.9 Mgha^–1), (4) 15-month old poultry litter compost (68.7Mg ha^–1), (5) 4-month old poultry litter compost(59 Mg ha^–1) and (6) 1-month old poultry littercompost (64 Mg ha^–1). We monitored changes inavailable soil NO₃-N and P over the growing season and post harvest.We measured total aboveground biomass at tasseling and harvest and corn yield.We determined corn N and P uptake at tasseling.Patterns of available soil NO₃-N were similar between raw PL-and NH₄NO₃ fertilizer-amended soils. LittleNO₃-N was released from any of the PL composts in the first year ofstudy. The mature 15-month old compost mineralized significant NO₃-Nonly after the second year of application. In contrast, available soil P washighest in plots amended with 15-month old compost, followed by raw PL-amendedplots. Immature composts immobilized soil P in the first year of study. Cornbiomass and yields were 30% higher in fertilizer and raw PL amendedplotscompared to yields in compost-amended treatments. Yields in compost-amendedplots were greater than those in the no-amendment control plots. Corn N and Puptake mirrored patterns of available soil NO₃-N and P. Corn Puptakewas highest in plots amended with 15-month old compost and raw PL, even thoughother composts contained 1.5–2 times more total P than raw PL. There wasalinear relationship between amount of P added and available soil P, regardlessof source. The similar P availabilities from either raw or composted PL,coupledwith limited crop P uptake at high soil P concentrations, suggest that raw andcomposted PL should be applied to soils based on crop P requirements to avoidbuild-up of available soil P.     

Nitrogen Cycling with Respect to Environmental Load in Farm Systems in Southwest China

In Qibainong, a steep-mountainous karst region in southwestern China, self-sustaining societies have long existed, but increasing socioeconomic liberation has fuelled the recent rapid structural change of its economy. Consequently, environmental deterioration and exhaustion of resources have become problematic issues. We carried out a field survey in Qibainong in southwestern China and used both estimated and measured N flows and N balances from obtained results. Our results are summarized as follows (1) farmers used large amounts of chemical N fertilizers at intensities of 113–1124 kg N ha⁻¹; (2) substantial application of chemical fertilizer in Qibainong has contributed to an increase in potential NO₃-N leaching of 6–511 kg N ha⁻¹, followed by NH₃ volatilization; (3) crop products are largely distributed to feed livestock, the products of which are a major income source; (4) this area has a great requirement for imported food; (5) in addition, unused manure N (up to 191 kg N ha⁻¹) is generated by the increase in manure N production. Chemical fertilizer application, in addition to unused manure can be regarded as a major source of environmental damage. Based on the relationship between the N application rate and the NO₃-N leaching potential, we estimated the critical limit of the N application rate of chemical fertilizer + manure to be 297 kg N ha⁻¹. In Qibainong, unused manure, which is an important nutrient resource, was applicable within the critical limit. We recommend that all manure N produced within the village be used effectively on arable land, and that any shortages be supplemented by chemical N fertilizer up to 297 kg N ha⁻¹ to maintain water resource quality. Further improvement might be achieved through incorporating chemical fertilizers, P and K supplemented manure, and so on.     

Light fraction organic N, ammonium, nitrate and total N in a thin Black Chernozemic soil under bromegrass after 27 annual applications of different N rates

Anadequate supply of N for a crop depends among others on the amounts of N thataremineralized from the soil organic matter plus the supply of ammonium andnitrateN already present in the soil. The objective of this study was to determine thebehaviour of light fraction organic N (LFN), NH₄-N, NO₃-Nand total N (TN) in soil in response to different rates of fertilizer Napplication. The 0–5, 5–10, 10–15 and 15–30cm layers of a thin Black Chernozemic soil under bromegrass(Bromus inermis Leyss) at Crossfield, Alberta, Canada,weresampled after 27 annual applications of ammonium nitrate at rates of 0, 56,112,168, 224 and 336 kg N ha^–1. The concentration andmass of TN and LFN in the soil, and the proportion of LFN mass within the TNmass usually increased with N rates up to 224 kg Nha^–1. The increase in TN mass and LFN mass per unit ofNadded was generally maximum at 56 kg N ha^–1 anddeclined with further increases in the rate of N application. The percentchangein response to N application was much greater for the LFN mass than for the TNmass for all the N rates and all soil depths that were sampled. Mineral N intheform of NH₄-N and NO₃-N did not accumulate in the soil at 112 kg N ha^–1 rates, whereas theiraccumulation increased markedly with rates of 168 kg Nha^–1. In conclusion, long-term annual fertilization at 112 kg N ha^–1 to bromegrass resulted insubstantial increase in the TN and LFN in soil, with no accumulation ofNH₄-N and NO₃-N down the depth. The implication of thesefindings is that grasslands for hay can be managed by appropriate Nfertilization rates to increase the level of organic N in soil.     

Spatial variability of Soil Nutrients and Influencing Factors in a Vegetable Production Area of Hebei Province in China

This study was conducted to determine soil nutrient spatial variability and the factors influencing it in a vegetable production area using traditional statistics and geo-statistics. The study area encompassed 55 ha and consisted of 182 farmer's plots belonging to six production groups in the Yutian county of China. Two hundred and seventeen soil samples were collected on a 50×50-m grid at depths of 0–20 cm prior to the plots being sown for cabbage. Vegetable production history, including varieties, rotation systems and fertilizer use, at the sampling sites was also examined. Soil pH, organic manure (OM), NO₃⁻–N, available P, K, Zn, and other nutrients and particle size were measured. The results showed that N, P, K and Zn were the main limiting nutrient factors in the soil. Distinct semi-variance structures of spatial variability were observed for soil NO₃⁻–N, available P, K and Zn, with the range of spatial correlation being 204–348 m. Significant spatial distribution similarity was found for soil NO₃⁻–N, P, K and Zn, with relatively high contents of all these nutrients in some areas of the study area and relatively low contents in other areas. The correlation of soil NO₃⁻–N, P and K content with vegetable production history and fertilizer application rates (N, P₂O₅ and K₂O) suggested that vegetable variety and history of fertilizer use are important factors to be considered in the development of a soil nutrient management program in the study area.     

Effects of improved drainage and nitrogen source on yields, nutrient uptake and utilization efficiencies by maize (Zea mays L.) on Vertisols in sub-humid environments

Nitrogen is the most limiting plant nutrient in Vertisols in Kenya. Soil properties, climatic conditions and management factors as well as fertilizer characteristics can influence fertilizer nitrogen (N) use efficiency by crops. Vertisols, characterized by low-basic water infiltration rate, are prone to waterlogging under sub-humid and humid conditions. We determined effects of drainage, N source and time of application on yields, nutrient uptake and utilization efficiencies by maize grown on Vertisols in sub-humid environments. Treatments comprised two furrows (40 cm and 60 cm deep) and a check (i.e., no furrow), calcium nitrate to furnish NO₃-N, ammonium sulphate to supply NH₄-N at 100 kg N ha⁻¹, a control (i.e., no fertilizer N), and fertilizer N application at sowing, 40 days after sowing, and split (i.e., half the rate at sowing and half 40 days after sowing). A split-plot design was used in which drainage formed the main plots and N source × time of N application formed the sub-plots. Higher grain and total dry matter yields, harvest index, leaf N content, uptake of N, P and K, as well as N agronomic (NAE) and recovery (NRE) efficiencies were obtained from drained compared to undrained plots. The increase ingrain yields as a result of drainage varied from 31 to 45% for control, 35 to 43% for NO₃-N, and 16 to 21% for NH₄-N treatments. Drainage resulted in total N uptake increases from 50 to 80 kg N ha⁻¹ in control plots, 80 to 130 kg N ha⁻¹ in NO₃-N treated plots, and 90 to 130kg N ha⁻¹ in NH₄-N treated plots. Ammonium-N source was superior to NO₃-N source in terms of higher yields, NAE, and NRE in undrained plots, but the two N sources behaved similarly in drained plots. Delayed or split NO₃-N application gave higher yields, NAE and NRE than when all N was applied at sowing in undrained plots. There was no difference between 40 cm and 60 cm deep furrows in terms of crop yields and nutrient use efficiencies. Thus, draining excess water with furrows at least 40 cm deep is essential for successful crop production in these Vertisols under sub-humid conditions. This revised version was published online in November 2006 with corrections to the Cover Date.     

Evaluation of methods of measurement of nitrogen in poultry and animal manures

Kjeldahl nitrogen (N), total N and forms of inorganic N (ammoniacal (NH₄)-N, nitrate (NO₃)-N and nitrite (NO₂)-N) were measured in a range of animal manures. The manures include fresh samples of poultry manure, sheep manure, horse manure, dairy slurry and pig slurry and composted poultry manure. Kjeldahl N was measured by standard micro-Kjeldahl digestion. For total N measurements, NO₃-N and NO₂-N were recovered during Kjeldahl digestion by pretreatments with various oxidizing and reducing agents. Inorganic forms of N were measured by extraction with 2M KCl solution.Kjeldahl digestion alone allowed measurement only of organic N and NH₄-N. Amongst various modifications to the Kjeldahl, pretreatment with either acidified (H₂SO₄) Zn-CrK(SO₄)₂ or acidified (H₂SO₄) reduced Fe achieved complete recovery of NO₃-N. Nitrite N was only recovered by first oxidising the NO ₂ ^- to NO ₃ ^- with KMnO₄ followed by reduction to NH₄-N with acidified (H₂SO₄) reduced Fe.More than 95% of the total N in fresh animal manure was present as organic N and NH₄-N which were recovered by the standard Kjeldahl digestion. In the case of fresh manures there was no difference between the amount of total N measured by the Kjeldahl digestion and its modified methods. However composting of poultry manure or drying of poultry manure, pig slurry and dairy slurry resulted in an increase in NO₃-N which was not recovered during Kjeldahl digestion alone. Under these conditions the total N could be measured by pretreating the samples with KMnO₄ and reduced Fe prior to Kjeldahl digestion.Drying of animal manures caused a decrease in organic N and NH₄-N, especially in poultry, pig and dairy manures. There was a slight increase in NO₃-N; but most of the decrease in N content with drying was attributed to the volatilization loss of ammonia (NH₃). Amongst various drying methods examined air drying caused maximum loss of N as NH₃ whereas freeze drying caused minimum loss of N. This suggests that fresh animal manures can be freeze dried for analysis of N which causes minimum loss of N.     

The effect of plant residues on plant uptake and leaching of soil and fertilizer nitrogen in a tropical red earth soil

Two field experiments, in which differing amounts and types of plant residues were incorporated into a red earth soil, were conducted at Katherine, N.T., Australia. The aim of the work was to evaluate the effect of the residues on uptake of soil and fertilizer N by a subsequent sorghum crop, on the accumulation and leaching of nitrate, and on losses of N.Stubble of grain sorghum applied at an exceptionally high rate (~ 18 000 kg ha^–1) reduced uptake of N by sorghum by 13% and depressed the accumulation of nitrate under a crop and particularly under a fallow.Loss of fertilizer N, movement of nitrate down the profile, and uptake by the crop was studied in another experiment after application of N as¹⁵NH₄ ¹⁵NO₃ to field microplots. By four weeks after fertilizer application 14% had been lost from the soil-plant system and by crop maturity 36 per cent had been lost. The pattern of¹⁵N distribution in the profile suggested that losses below 150 cm had occurred during crop growth. The recovery of¹⁵N by the crop alone ranged from 16 to 32 per cent. There was an apparent loss of N from the crop between anthesis and maturity. Residue levels common to sorghum crops in the region (~ 2000 kg ha^–1) did not significantly affect uptake by a subsequent sorghum crop, N losses, or distribution of nitrate in the profile.     

Impact of organic residue management on nitrogen use efficiency in an annual rice cropping sequence of lowland Central Thailand

Field experiments were conducted in Central Thailand under a rice–fallow–rice cropping sequence during consecutive dry and wet seasons of 1998 to determine the impact of residue management on fertilizer nitrogen (N) use. Treatments consisted of a combination of broadcast urea (70 kg N ha^–1) with rice straw (C/N 67) and rice hull ash (C/N 76), which were incorporated into the puddled soil 1 week before transplanting at a rate of 5 Mg ha^–1. Nitrogen-15 balance data showed that the dry season rice recovered 10 to 20% of fertilizer N at maturity. Of the applied N, 27 to 36% remained in the soil. Loss of N (unaccounted for) from the soil–plant system ranged from 47 to 54% of applied N. The availability of the residue fertilizer N to a subsequent rice crop was only less than 3% of the initial applied N. During both season fallows NO₃-N remained the dominant form of mineral-N (NO₃+NH₄) in the aerobic soil. In the dry season grain yield response to N application was significant (P=0.05). Organic material sources did not significantly change grain yield and N accumulation in rice. In terms of grain yields and N uptake at maturity, there was no significant residual effect of fertilizer N on the subsequent rice crop. The combined use of organic residues with urea did not improve N use efficiency, reduced N losses nor produced higher yields compared to urea alone. These results suggested that mechanisms such as N loss through gaseous N emissions may account for the low fertilizer N use efficiency from this rice cropping system. Splitting fertilizer N application should be considered on the fertilizer N use from the organic residue amendment.     

Control of nitrate pollution by application of controlled release fertilizer (CRF), compost and an optimized irrigation system

A nitrogenous controlled release fertilizer (Floranid 32) and a treatment of municipal organic waste compost were tested under two irrigation managements (conventional and ET-adjusted irrigation rates) with the aim of assessing risk of nitrate leaching to the aquifer. A check without N fertilizer was introduced. The experiment was carried out at La Poveda Field Station (30 km SE Madrid, Spain) in alluvial soils with water table depth at 4 m and under maize cropping. The experiment was laid out in a randomized complete block design with three replications, allocating 12 plots to each irrigation management. Although N fertilizer rate (150 kg ha^–1) was reduced at half as related to a previous experiment, no difference in grain yields was observed. This result relates to a high content of soil-N. Floranid showed promising results in controlling N-leaching in comparison with urea that exhibited an accelerated rate of N release which finally determines low use of N by the plant and marked NO₃ ^– leaching. Treatment of municipal waste compost showed NO₃ ^– concentrations in the soil water solution of similar values as those of urea at 140 cm. ET-adjusted irrigation showed no drainage during the corn growing season and lower NO₃ ^– concentrations in the soil water solution which could indicate a general lower rate of N solubilization.     

Nitrogen fertigation of greenhouse-grown strawberries

Two greenhouse experiments were conducted with strawberries (Fragaria ananassa) grown in plastic pots filled with 12 kg of soil, and irrigated by drip to evaluate the effect of 3 N levels and 3 N sources. The N levels were 3.6, 7.2 or 10.8 mmol Nl^–1 and the N sources were urea, ammonium nitrate and potassium nitrate for supplying NH₄/NO₃ in mmol Nl^–1 ratios of 7/0, 3.5/3.5 or 0/7, respectively. Both experiments were uniformly supplied with micronutrients and 1.7 and 5.0 mmoll^–1 of P and K, respectively. The fertilizers were supplied through the irrigation stream with every irrigation. The highest yield was obtained with the 7.2 mmol Nl^–1 due to increase in both weight and number of fruits per plant. With this N concentration soil ECe and NO₃-N concentration were kept at low levels. Total N and NO₃-N in laminae and petioles increased with increasing N level. With the N sources the highest yield was obtained with urea due to better fruit setting. The N source had no effect on soil salinity and residual soil NO₃-N; residual NH₄-N in the soils receiving urea and ammonium nitrate were at low levels.     

Reduced nitrate concentrations in shallow ground water under a non-fertilised grass buffer strip

In this paper the suitability of a buffer strip to reduce nitrate concentrations in the upper groundwater was tested for a sandy arable soil in The Netherlands during two consecutive leaching seasons. The bufferstrip was a 3.5 m wide unfertilised grass strip adjacent to a ditch on an arable field. In total 24 groundwater wells were installed in 4 transects perpendicular to the ditch to determine Cl, NO₃ and δ¹⁵N concentrations. Piezometers were installed to assess the groundwater flow, which was in the direction of the ditch with small downward leakage across a peat layer at about 3 m depth. Nitrogen was dominantly present as nitrate (NO₃). The NO₃-N concentrations under the bufferstrip were significantly lower than under the adjacent arable field. The lower concentrations were due to dilution, uptake by grass and denitrification. Nitrate was actively removed in the bufferstrip, since the Cl/NO₃ ratios were higher in the bufferstrip than in the remainder of the field. Furthermore, δ¹⁵N data indicated that denitrification occurred in the groundwater and increased with decreasing distance to the ditch. NO₃-N loads to the ditch were estimated at 8.5 kg ha⁻¹yr⁻¹, which is relatively low for this area. We can, however, not determine whether these relatively low NO₃-N loads were causally related to the reduced NO₃-N concentrations in the bufferstrip. Nevertheless, the results of the present study are promising and justify additional research on the efficiency of bufferstrips to reduce NO₃ concentrations in shallow groundwater, and subsequently reduce NO₃ loading of surface water, under Dutch conditions.     

Nitrogen fertilization and nitrate pollution in groundwater in Japan: Present status and measures for sustainable agriculture

During the last two decades, nitrate nitrogen (NO₃-N) concentrations in groundwater in Japan have increased steadily due to the development of intensive agriculture. In some areas, they have reached or even exceeded the unacceptable level for drinking water, 10 mg l^–1. In 2000, the Environment Agency showed that 5.6% (173 of 3,374) tested wells and 4.7% (64 of 1,362) wells used for drinking water exceeded the standard level in 1999. The highest value of NO₃-N in the wells was 100 mg l^–1. Many researches have shown that NO₃-N pollution of groundwater was widely observed in Japan, except the paddy field regions. Farming practices in Kagamigahara city of Gifu prefecture have been typical ones for reducing NO₃-N pollution in groundwater. In the east district of the city, NO₃-N concentration was low in 1966, but reached 27.5 mg l^–1 in June, 1974. The farmers in this district began to reduce the nitrogen fertilizers in carrot cultivation, going from 256 kg N ha^–1 in 1970 to 153 kg N ha^–1 in 1991. The use of controlled release fertilizer increased fertilizer-nitrogen efficiency compared with common compound fertilizer and NO₃-N concentration in the groundwater began to decrease steadily. It was discussed that in order to decrease the NO₃-N pollution of groundwater, it is necessary to refocus not only agricultural technology but also agricultural policy, toward sustainable agriculture and rural development.     

Detectability of15N-depleted fertilizer N in soil and plant tissue during a corn-rye crop rotation

Use of¹⁵N-depleted fertilizer materials have been primarily limited to fertilizer recovery studies of short duration. The objective of this study was to determine if¹⁵N-depleted fertilizer N could be satisfactorily used as a tracer of residual fertilizer N in plant tissue and various soil N fractions through a corn (Zea mays L.) -winter rye (Secale cereale L.) crop rotation. Nitrogen as¹⁵N-depleted (NH₄)₂SO₄ was applied at five rates (0, 84, 168, 252, and 336 kg N ha^–1) to corn. Immediately following corn harvest a winter rye cover crop treatment was initiated. Residual fertilizer N was easily detected in the soil NO ₃ ^- -N fraction following corn harvest (140-d after application). Low levels of exchangeable NH ₄ ⁺ -N (<2.5 mg kg^–1) did not permit accurate isotope-ratio analysis. Fertilizer-derived N recovered in the soil total N fraction following corn harvest was detectable in the 0 to 30-cm depth at each N rate and in the 30 to 60 and 60 to 90-cm depths at the 336 kg ha^–1 N rate. Atom %¹⁵N concentrations in the nonexchangeable NH ₄ ⁺ -N fraction did not differ from the control at each N rate. Nitrogen recovery by the winter rye cover crop reduced residual soil NO ₃ ^- -N levels below the 10 kg ha^–1 level needed for accurate isotope-ratio analysis. Atom %¹⁵N concentrations in the soil total N fraction (approximately one yr after application) were indistinguishable from the control plots below the 168, 252, and 336 kg ha^–1 N rate at the 0 to 30, 30 to 60, and 60 to 90-cm depths, respectively. Recovery of residual fertilizer N by the winter rye cover crop was verified by measuring significant decreases in atom %¹⁵N concentrations in rye tissue with increasing N rates. The greatest limitation to the use of¹⁵N-depleted fertilizer N as a tracer of residual fertilizer N in a corn-rye crop rotation appears to be its detectibility from native soil N in the total N pool.Research partially supported by grants from the National Fertilizer and Environmental Research Center/TVA and the Virginia Division of Soil and Water Conservation.     

Nitrogen uptake efficiency in maize production using irrigation water high in nitrate

In order to achieve efficient use of nitrogen (N) and minimize pollution potentials, producers of irrigated maize (Zea mays L.) must make the best use of N from all sources. This study was conducted to evaluate crop utilization of nitrate in irrigation water and the effect N fertilizer has on N use efficiencies of this nitrate under irrigated maize production. The study site is representative of a large portion of the Central Platte Valley of Nebraska where ground water nitrate-N (NO₃-N) concentrations over 10 mg L^–1 are common. Microplots were established to accommodate four fertilizer N rates (0, 50, 100, and 150 kg ha^–1) receiving irrigation water containing three levels of NO₃-N (0, 10, 20 mg L^–1). Stable isotope¹⁵N was applied as a tracer in the irrigation water for treatments containing 10 and 20 mg L^–1 NO₃-N. Plots that did not receive nitrate in the irrigation water where tagged with¹⁵N fertilizer as a sidedress treatment. Sidedressed N fertilizer significantly reduced irrigation-N uptake efficiencies. When residual N uptake is added to first year plant usage, total irrigation NO₃-N uptake efficiencies are similar to total sidedress N fertilizer uptake efficiencies for our cropping system over the two year period. Efficiency of irrigation-N use depends on crop needs and availability of N from other sources during the irrigation season.     

Leaching losses from Kenyan maize cropland receiving different rates of nitrogen fertilizer

Meeting food security requirements in sub-Saharan Africa (SSA) will require increasing fertilizer use to improve crop yields, however excess fertilization can cause environmental and public health problems in surface and groundwater. Determining the threshold of reasonable fertilizer application in SSA requires an understanding of flow dynamics and nutrient transport in under-studied, tropical soils experiencing seasonal rainfall. We estimated leaching flux in Yala, Kenya on a maize field that received from 0 to 200 kg ha^?1 of nitrogen (N) fertilizer. Soil pore water concentration measurements during two growing seasons were coupled with results from a numerical fluid flow model to calculate the daily flux of nitrate-nitrogen (NO₃ ^?-N). Modeled NO₃ ^?-N losses to below 200 cm for 1 year ranged from 40 kg N ha^?1 year^?1 in the 75 kg N ha^?1 year^?1 treatment to 81 kg N ha^?1 year^?1 in the 200 kg N ha^?1 treatment. The highest soil pore water NO₃ ^?-N concentrations and NO₃ ^?-N leaching fluxes occurred on the highest N application plots, however there was a poor correlation between N application rate and NO₃ ^?-N leaching for the remaining N application rates. The drought in the second study year resulted in higher pore water NO₃ ^?-N concentrations, while NO₃ ^?-N leaching was disproportionately smaller than the decrease in precipitation. The lack of a strong correlation between NO₃ ^?-N leaching and N application rate, and a large decrease in flux between 120 and 200 cm suggest processes that influence NO₃ ^?-N retention in soils below 200 cm will ultimately control NO₃ ^?-N leaching at the watershed scale.     

Dryland wheat yield dependence on rainfall,applied N and mulching in preceding maize

To evaluate the response of dryland wheat (Triticum aestivum L.) to mulching in preceding maize and fertilizer N application field experiments were conducted for six years (1980–86) with maize-wheat sequence on a sandy loam soil in northern India. Four rates of N application viz. 0, 40, 60 and 80 kg N ha^–1 in wheat were combined with three mulch treatments viz. no mulch (M₀), paddy straw mulch (M_p) and basooti (Premma mucronate) mulch (M_b) applied at the rate of 4 tons ha^–1 on dry weight basis applied three weeks before harvest of maize. Mulching (M_p and M_b) increased (profile) stored moisture at wheat seedling by 31 to 88 mm. M_b also increased NO₃-N content by 33 to 42 kg ha^–1 in 0–120 cm profile over M₀ and M_p. Over the years, M_p increased wheat yield by 11 to 515 kg ha^–1 and M_b by 761 to 879 kg ha^–1. Wheat yield response to mulching was related to rainfall pattern during its growth season. Significant response to mulching was obtained only in years when rainfall during vegetative phase of the crop was low. Amount and distribution of rainfall during two main phases of crop development affected the N use efficiency by wheat. On an average, each cm of rain substituted for 3.5, 4.6 and 6.5 kg of applied N ha^–1 under M₀, M_p and M_b, respectively. Split rainfall for two main phases of crop growth, available stored water at seeding, fertilizer N and profile NO₃-N content accounted for 89 per cent variability in wheat yield across years and mulching treatments.