基于PVD-TiN和TiSiN涂层的Al2O3/TiCN陶瓷刀具及其切削性能研究

采用物理气相沉积(Physical vapor deposition, PVD)工艺在Al₂O₃/TiCN陶瓷刀具表面分别沉积了TiN和TiSiN涂层。通过扫描电子显微镜(SEM)观察涂层微观结构, 采用显微硬度计和划痕仪分别表征涂层硬度和测量涂层与基体的结合强度。通过对涂层刀具进行连续干切削灰铸铁实验, 研究TiN和TiSiN涂层对刀具磨损特征的影响并探讨其磨损机理, 同时研究了涂层对工件加工表面质量的影响。结果表明: PVD涂层可显著提高Al₂O₃/TiCN陶瓷的刀具硬度。TiN涂层和TiSiN涂层可分别提高刀具表面硬度25%和65%, 从而增加刀具耐磨性。两种涂层刀具在连续切削灰铸铁实验中主要的失效机理均是挤压变形下的磨粒磨损, 其中TiN涂层刀具还伴随有粘结磨损; 刀具上的PVD-TiN和TiSiN涂层可以有效保护Al₂O₃/TiCN陶瓷刀具基体, 防止崩刃, 进而改善工件表面加工质量。     

Machining of high performance workpiece materials with CBN coated cutting tools

The machining of high performance workpiece materials requires significantly harder cutting materials. In hard machining, the early tool wear occurs due to high process forces and temperatures. The hardest known material is the diamond, but steel materials cannot be machined with diamond tools because of the reactivity of iron with carbon. Cubic boron nitride (cBN) is the second hardest of all known materials. The supply of such PcBN indexable inserts, which are only geometrically simple and available, requires several work procedures and is cost-intensive. The development of a cBN coating for cutting tools, combine the advantages of a thin film system and of cBN. Flexible cemented carbide tools, in respect to the geometry can be coated. The cBN films with a thickness of up to 2 µm on cemented carbide substrates show excellent mechanical and physical properties. This paper describes the results of the machining of various workpiece materials in turning and milling operations regarding the tool life, resultant cutting force components and workpiece surface roughness. In turning tests of Inconel 718 and milling tests of chrome steel the high potential of cBN coatings for dry machining was proven. The results of the experiments were compared with common used tool coatings for the hard machining. Additionally, the wear mechanisms adhesion, abrasion, surface fatigue and tribo-oxidation were researched in model wear experiments.     

Boron containing combination tool coatings—characterization and application tests

The requirements for durable tool coatings continuously increase. In many cases, tool coatings combining different phases or several layers could provide an improvement in tool life. The broad range of mechanical properties of materials in the B–C–N and Ti–B–N ternary systems, from very soft to superhard, presents many possibilities to generate various combination coatings. Such coatings were prepared using reactive sputter techniques with different target materials. An outstanding example is a superhard 3 μm thick coating system with a 0.5 to 0.8 μm thick cBN top layer deposited on cutting inserts. Soft coatings like hexagonal boron nitride were found to be essential for machining operations under dry conditions. The coatings were characterized with respect to hardness, abrasive wear rate and friction coefficients. The correlation between properties and composition was revealed. Application test results of B–C–N and Ti–B–N coating systems on tools obtained under near production conditions will be reported. Specifically, turning tests performed with cemented carbide cutting inserts coated with a superhard coating system with a cBN top layer will be discussed.     

不同后处理对MT-TiCN涂层刀具组织与切削性能的影响

目的研究不同后处理工艺(包括热处理、湿喷砂和刃口处理)对MT-TiCN涂层组织与刀片切削性能的影响。方法采用中温化学气相沉积技术在硬质合金刀片上制备TiCN涂层;利用光学显微镜(OM)、扫描电子显微镜(SEM)、X射线衍射仪(XRD)、纳米压痕仪分析MT-TiCN涂层的组织形貌、相结构、硬度和弹性模量;在AISI 4340合金钢上进行车削试验。结果 MT-TiCN涂层呈柱状晶结构,涂层沿(422)晶面方向择优生长,且织构系数达5.5;涂层表面和断口平均硬度分别为26.6 GPa和30.7~31.8 GPa,平均弹性模量分别为528.6 GPa和467.7~494.4 GPa;在连续车削条件下,经湿喷砂处理的涂层刀片切削性能最佳;在低切深、低进给断续车削工况下,湿喷砂后又经热处理和刃口处理的涂层刀片使用寿命最长;湿喷砂后再进行热处理,对刀具的切削性能影响较小。结论湿喷砂和热处理对MT-TiCN涂层组织的影响较小;不同后处理工艺对涂层刀具切削性能的影响较大,这主要是因为刃口处理会减小涂层厚度同时提高涂层韧性。     

Investigation on Some Machinability Aspects of Inconel 825 During Dry Turning

In the current study, attempt has been made to investigate the influence of cutting speed (Vc) (51, 84, and 124 m/min) on various machining characteristics like chip morphology, chip thickness ratio, tool wear, surface, and sub-surface integrity during dry turning of Inconel 825. Comparable study was carried out using uncoated and commercially available chemical vapor deposition multilayer coated (TiN/TiCN/Al₂O₃/ZrCN) cemented carbide (ISO P30 grade) insert. Chip morphology consists of chip forms obtained at different cutting conditions. Serrated chips were observed when machining Inconel 825 with both types of tool with more serration in case of uncoated insert. The chip thickness ratio increased as cutting speed was increased. Use of multilayer coated tool also resulted in increase in chip thickness ratio. Rake and flank surfaces were examined with scanning electron microscope and optical microscope. Abrasion, adhesion, and diffusion wears were found to be dominating tool wear mechanism during dry machining of Inconel 825. The beneficial effect of coated tool over its uncoated counterpart was most prominent during machining at high cutting speed (Vc = 124 m/min). The surface and sub-surface integrity obtained with coated tool were superior to that while machining Inconel 825 with uncoated tool.     

A comparative evaluation of HfN,Al2O3, TiC and TiN coatings on cemented carbide tools

Cemented carbide cutting tools coated with HfN, Al₂O₃, TiC and TiN were evaluated in continuous and interrupted turning of alloy steel and cast iron in the range from 600 to 1000 surface ft min^-1. The results showed that HfN was the most effective coating in prolonging tool life over the widest range of cutting conditions.     

Comparative assessment of coated and uncoated ceramic tools on cutting force components and tool wear in hard turning of AISI H11 steel using Taguchi plan and RMS

This study investigated the cutting performance of coated CC6050 and uncoated CC650 mixed ceramics in hard turning of hardened steel. The cutting performance was mainly evaluated by cutting force components and tool wear. The planning of experiments was based on Taguchi’s L₃₆ orthogonal array. The response surface methodology and analysis of variance were used to check the validity of multiple linear regression models and to determine the significant parameter affecting the cutting force components. Tool wear progressions and, hence, tool life, different tool wear forms and wear mechanisms observed for tools coated with TiN and uncoated mixed ceramics are presented along with the images captured by digital and electron microscope. Experimental observations indicate higher tool life with uncoated ceramic tools, which shows encouraging potential of these tools to hard turning of AISI H11 (50 HRC). Finally, tool performance indices are based on units which characterise machined cutting force components and wear when hard turning.     

A study of the tool life of TiC and TiC plus Al2O3 chemical vapour deposited tungsten carbide tools

Tool life characteristics were investigated for tungsten carbide cutting tools coated with TiC and with TiC plus Al₂O₃. A low carbon steel workpiece was turned on a lathe at a feed rate of 0.206 to 0.410 mm rev^–1 and a depth of cut of 0.1 to 0.5 mm for cutting velocities between 100 and 250 m min^–1. Data were analysed using both Taylor's tool life equation and Wu's tool life method. Results were similar for both methods but Wu's method seemed to give more consistent results. Compared to an uncoated tungsten carbide tool, the tool life of both the coated tools were from 5 to 7 times longer and the improvement was greater at higher cutting speeds. The TiC plus Al₂O₃ coated tool was slightly superior to the TiC coated tool. The wear mechanism and a possible explanation of increased tool life for the coated tools are discussed.     

The effect of the martensitic packet size on the machinability of modified AISI P20 prehardened mold steel

The effect of martensitic packet size on the machinability of prehardened mold steel at a hardness of ~40 HRC (typical hardness for prehardened mold steels) was studied in terms of cutting force and tool life. The machinability tests were performed in end milling using coated, cemented carbide tools at three different cutting speeds. The results showed that an increase in the martensite packet size led to higher cutting force and shorter tool life. The increase in cutting force was related to the increase of work hardening. The work material with a coarser martensite packet size showed a higher amount of work hardening that can explain the higher cutting force. The longer tool life in the workpieces with finer structure was correlated to smaller amplitude of the variation in cutting force.     

Nanocomposite‐Beschichtungen auf CBN‐Werkzeugen

Nanocomposite coatings on CBN‐tools CBN (cubic boron nitride) cutting materials are often used to improve the properties of cutting tools. This allows new applications and processes, which are not possible with common cutting materials (e.g. hard metals). Today CBN cutting materials are mostly coated to estimate the wear by an optical evaluation. Coatings on CBN cutting materials for enhancement of the tribological properties are normally not used. For improvement of the properties of used CBN tools during the cutting process a coating technology was developed. This technology combines the advantages of CBN cutting materials with the excellent properties (e.g. hardness, temperature stability) of nanostructured materials. Investigations with different coating systems and pre‐treatment processes were done to test the CBN cutting tools. These investigations have been shown, that nanocomposite coatings can be used to enhance the tool life of CBN cutting tools. Important for an increase in the tool life is a very good coating adhesion, which can be reached by special adhesion layers and an optimized coating structure.     

Effect of microarc oxidised layer thickness on plain fatigue and fretting fatigue behaviour of Al–Mg–Si alloy

The objective of this work was to investigate the performance of microarc oxide coatings of two different thicknesses (40 and 100 μm) on Al–Mg–Si alloy samples under plain fatigue and fretting fatigue loadings. Tensile residual stress present in the substrate of 40 μm thick coated samples induced early crack initiation in the substrate and so their plain fatigue lives were shorter than those of untreated specimens. Presence of more pores and tensile surface residual stress in 100 μm thick coated samples caused early crack initiation at the surface leading to their inferior plain fatigue lives compared with 40 μm thick coated samples. While the differences between the lives of coated and uncoated specimens were significant under plain fatigue loading, this was not the case under fretting fatigue loading. This may be attributed to relatively higher surface hardness of coated specimens. The performance of 40 μm thick coated samples was better than that of 100 μm thick coated specimens under both plain fatigue and fretting fatigue loadings.     

Tool life and surface integrity when milling inconel 718 with coated cemented carbide tools

Abstract

This paper presents a study of tool life and surface integrity while machining superalloy Inconel 718 using coated cemented carbide tools. In the machining of heat resistant superalloys used in aeronautical applications and classified as difficult‐to‐machine, tool life is an important parameter in evaluating the performance of the cutting tools. Surface quality of the workpiece is one of the important criteria in determining tool life. Our tests have been done under various combinations of speed, feed rate, and depth of cut to verify the change in surface roughness due to increasing tool wear. The behavior of the uncoated, TiN, and TiCN layers using various cutting conditions was analyzed. At the end, a choice of coating and optimization of the cutting conditions has been proposed.     

基于TiC_(0.5)N_(0.5)/Si_3N_4复相陶瓷基体的PVD及CVD涂层刀具性能

首先,以15vol%或25vol%的TiC0.5N0.5粉体为导电第二相,利用热压烧结法制备了TiC0.5N0.5/Si3N4复相陶瓷;然后,分别通过物理气相沉积(PVD)和化学气相沉积(CVD)技术在TiC0.5N0.5/Si3N4陶瓷刀具表面沉积了CrAlN和TiN/Al2O3/TiN涂层;最后,通过对TiC0.5N0.5/Si3N4刀具进行连续切削灰铸铁实验,研究了TiC0.5N0.5含量和涂层类型对刀具磨损特征的影响,并探讨了刀具的磨损机制。结果表明:TiC0.5N0.5含量的增加有利于提高TiC0.5N0.5/Si3N4复相陶瓷刀具基体的硬度和电导率,但对耐磨性和切削寿命的影响较小;采用PVD技术沉积CrAlN涂层时,随着TiC0.5N0.5含量的增加,涂层的厚度、结合强度和硬度都得到提高,涂层刀具的磨损性能显著提高,切削寿命也明显延长;而采用CVD技术沉积TiN/Al2O3/TiN涂层时,TiC0.5N0.5含量的变化对涂层的厚度、结合强度和硬度基本没有影响,TiN/Al2O3/TiN涂层刀具整体切削性能变化不大。CrAlN涂层和TiN/Al2O3/TiN涂层都可明显改善TiC0.5N0.5/Si3N4复相陶瓷刀具的耐磨性和切削寿命;相对于TiN/Al2O3/TiN涂层,CrAlN涂层具有更高的涂层硬度和粘着强度,但TiN/Al2O3/TiN涂层具有较大的涂层厚度,TiN/Al2O3/TiN涂层刀具表现出更加优异的耐磨性和切削寿命。TiC0.5N0.5/Si3N4复相陶瓷刀具的磨损机制以机械摩擦导致的磨粒磨损为主,伴随有少量的粘结磨损。     

Effect of cutting speed on the performance of Al2O3 based ceramic tools in turning nodular cast iron

This paper presents the results of an experimental investigation on the effect of cutting speed in turning nodular cast iron with alumina (Al₂O₃) based ceramic tools. Three different alumina based ceramic cutting tools were used, namely TiN coated Al₂O₃ + TiCN mixed ceramic, SiC whisker reinforced Al₂O₃ and uncoated Al₂O₃ + TiCN mixed ceramic tool. Turning experiments were carried out at four different cutting speeds, which were 300, 450, 600 and 750 m/min. Depth of cut and feed rate were kept constant at 1 mm and 0.1 mm/rev, respectively, throughout the experiments. Tool performance was evaluated with respect to tool wear, surface finish produced and cutting forces generated during turning. Uncoated Al₂O₃ + TiCN mixed ceramic was the worst performing tool with respect to tool wear and was the best with respect to surface finish. SiC whisker reinforced Al₂O₃ exhibited the worst performance with respect to cutting forces. If tool wear, surface finish and cutting force results are considered together, among the three tools studied, TiN coated Al₂O₃ + TiCN mixed ceramic tool is the most suitable one for turning nodular cast iron, especially at high cutting speeds (V_c > 600 m/min).     

Tool life model for Al2O3 particle reinforced MMCs using genetic expression programming

Abstract

In the present work, the wear of cutting tools in the machining of 7075Al alloy composites reinforced with 10 and 25 wt-% and 16 μm average size Al₂O₃ particles was investigated. Machining tests were performed on both as cast and heat treated composites by turning process using a physical vapour deposition coated carbide tool CP500 at different cutting conditions. A new model was developed to predict the tool life by genetic expression programming. The training and validation data sets were obtained from the well established machining test results. The weight fraction of particle P_w, cutting speed V, feedrate f and heat treatment Ht were used as independent input variables, while tool life T was used as a dependent output variable. Different models for tool life were predicted on the basis of the training data set using genetic programming, and the accuracy of the best model was proved with validation data set. The test results showed that the genetic expression programming model has produced correlation coefficient R values of ～0·958 for the training data and 0·952 for the validation data. The predicted tool life results were compared with experimental results and found to be in good agreement with the experimentally observed ones.     

Development of diamond coated tool and its performance in machining Al-11% Si alloy

An attempt has been made to deposit CVD diamond coating on conventional carbide tool using hot filament CVD process. ISO grade K10 turning inserts with SPGN 120308 geometry were used to deposit diamond coating. This diamond coating well covering the rake surface, cutting edges and flank surfaces could be successfully deposited. The coatings were characterized by SEM, XRD and Raman spectroscopy for coating quality, morphology etc. Performance of diamond coated tool relative to that of uncoated carbide tool was evaluated in turning Al-11% Si alloy under dry environment. The diamond coated tool outperformed the uncoated carbide tool which severely suffered from sizeable built-up edge formation leading not only to escalation of cutting forces but also poorer surface finish. In contrast, the diamond coated tool, owing to chemical inertness of diamond coating towards the work material, did not show any trace of edge built-up even in dry environment and could maintain low level of cutting forces and remarkably improved surface finish. It has been further revealed that success of the diamond coated tool depends primarily on adhesion of the diamond coating with the carbide substrate and this is strongly influenced by the pre-treatment of the carbide substrate surface before coating.     

Special features of the applications of cutting tools from polycrystalline cubic boron nitride with protective coatings

The results of the investigations on the efficiency of cutting tools from polycrystalline superhard materials based on cubic boron nitride with a protective coating. A hypothesis is proposed for the increase of the cutting tool life in turning hardened steel due to a decrease of the temperature in the cutting zone and a complex of physico-mechanical properties of the protective coating required for this is analyzed. A protective coating of boron nitride is considered in the amorphous state that plays a role of a solid lubricant in the zone of the tool contact with cutting chips, decreases the temperature in the contact zone through the reduction of the contact length and cutting force, ensures an increase of the tool life and reliability, especially at the stage of the run-in.     

Investigation on diamond tool wear in ultrasonic vibration-assisted turning die steels

This paper presents comprehensive theoretical analyses and experimental investigations for evaluating the ultrasonic vibration-assisted turning (UVAT) of die steels with single-crystal diamond tools. The diamond tool wear was found to rely heavily on the feed rate and the cutting speed while being insensitive to the depth of cut and the tool relief angle under the cutting conditions used in the tests. The tool wear characteristics were further studied based on the observation of wear zone using Raman spectral analysis and energy-dispersive X-ray (EDX) analysis. The detection results of the tool worn topography, the phase transformation and the carbon diffusion of diamond crystals revealed that tool wear mainly occurred on the tool flank face due to the graphitization and the diffusion of the diamond tool. Analytical results of the function mechanisms of the ultrasonic turning indicated that the friction force between the tool flank face and the machined surface, which depended mainly on the ratio of the cutting speed and the vibration speed, could be effectively reduced in ultrasonic turning process. The analytical and experimental results indicated that compared with conventional turning (CT), the cutting performance, in terms of the tool life, was markedly improved by applying ultrasonic vibration to the cutting tool.     

Influence of Tool Coating,Tool Material,and Cutting Speed on the Machinability of Low-Leaded Brass Alloys in Turning

The influence of tool coating and material on the machinability of low-leaded brass alloys (Pb < 0.2%) was analyzed in external turning. Carbide tools with various coatings as well as polycrystalline diamond (PCD) tools were applied. As workpiece materials, three low-leaded brass alloys CuZn38As, CuZn42, and CuZn21Si3P were used. Their machining behavior was compared to the leaded (Pb < 3.32%) brass CuZn39Pb3. CuZn38As showed the worst machinability in terms of process forces, chip formation, and workpiece quality. This is due to the high volume fraction of α-phase with face-centered cubic lattice structure. The machining problems were reduced by the use of tool coatings, in particular by a diamond-like carbon coating. The latter is characterized by high hardness, diamond-like cubic-crystalline lattice structure, and low chemical affinity to brass, which reduced friction in the secondary shear zone. CuZn42 exhibited an improved machinability compared to CuZn38As due to the lower volume fraction of α-phase. The positive influence of the tool coating was similar to CuZn38As. Main machining problem of CuZn21Si3P is tool wear because of the hard silicon-rich κ-phase. In tool life tests, PCD showed higher performance than uncoated and coated carbide tools due to its high abrasive wear resistance and low adhesion tendency.     

Aquesons Films Coating Stuied of Sustabined Release Niciotine Acid Fellets: An In-Vitro Evalutiion

Numerous batches of nicotinic acid (niacin) pellets were coated to determine the optimum level of Surelease® coating which would exhibit in-vitro release patterns suitable for BID dosing. Various levels of Surelease, with and without the incorporation of a hydrophilic material, were studied. It was expected that a significantly high level of Surelease would be needed to obtain the desired in-vitro dissolution release rate for the water soluble drug. However, a coating level of 1.2% Surelease coating was found to have an in-vitro dissolution profile approximating that of a BID product. Scanning electron microscopic examination has shown that the surface of coating is smooth and uniform with the coating thickness of about 2 μm. The 2 months stability data showed no significant changes in the dissolution profiles.