共查询到19条相似文献,搜索用时 586 毫秒
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介绍了氧化锆的性质、制备方法及国内外研究现状,概述了掺杂氧化锆的研究进展,并对氧化锆及掺杂氧化锆的发展方向进行了分析和讨论。 相似文献
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介绍中孔氧化锆的合成机理及国内外研究现状,讨论了影响合成中孔氧化锆的一些因素,特别是对掺杂中孔氧化锆合成的影响。概述了掺杂中孔氧化锆的应用并展望了其发展方向。 相似文献
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金属共掺杂对树脂炭结构及抗氧化性能的影响 总被引:1,自引:0,他引:1
以热固性酚醛树脂和金属铝粉为原料、纳米镍为催化剂,采用机械搅拌法制备了金属铝和纳米镍共掺杂酚醛树脂,研究了金属铝和纳米镍共掺杂对树脂炭结构及其抗氧化性能的影响。结果表明:在埋炭气氛下,树脂材料内部CO分压较高而无氮化物存在,体系属于Al-C-O系统;随着温度的升高,氧分压增大,Al2O3(s)相的稳定区间增大。900℃炭化后体系中生成纳米碳管和Al3C4晶须,1 000℃处理后有Al3C4晶须和Al2O3颗粒同时存在。当温度升高到1 200℃时,Al3C4相消失,Al2O3晶须生成量增加。随着热处理温度升高,纳米碳管的直径从60 nm增大到100 nm。添加金属铝粉和纳米镍后,掺杂改性树脂炭化后炭产物的氧化峰值为664.6℃,相比单一掺杂,氧化峰值温度提高了约122℃,增幅达到22%。 相似文献
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以板状刚玉、活性α—氧化铝、氧化锆(PSZ)、碳黑为主要原料,以金属硅和碳化硼作为添加剂,以热固性酚醛树脂作为结合剂,制备了ZrO2基Al2O3-ZrO2-C质材料。实验证明添加稳定氧化锆的Al2O3-ZrO2-C质高温陶瓷材料的抗渣性能优于添加单斜氧化锆、纳米氧化锆、金属铝的Al2O3-ZrO2-C质高温陶瓷材料。 相似文献
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以水热法自制的纳米氧化锆为原料,用油酸对其进行表面改性。考查了改性温度、油酸用量对改性粉体的分散性的影响。用TEM、SEM对改性粉体进行表征。结果表明,改性后氧化锆从亲水性明显转变为亲油性,在弱极性溶剂中分散效果良好,改性效果明显。 相似文献
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Yoshiaki Kinemuchi Hiroshi Mouri Tsuneo Suzuki Hisayuki Suematsu Weihua Jiang Kiyoshi Yatsui 《Journal of the American Ceramic Society》2003,86(9):1522-1526
Activated alumina powders have been synthesized by using a novel dry process of pulsed wire discharge. The temperature of phase transition from activated alumina to α-alumina and its variation caused by adding zirconia have been investigated. A mixture of activated alumina and zirconia was formed by mixing zirconium plasma with aluminum plasma and cooling together in an oxygen atmosphere. It was found that the transition temperature increased when the zirconia content ratio was increased. On the other hand, results of X-ray diffraction and X-ray photoelectron spectroscopy analysis indicated no substitution of zirconium in an alumina lattice. Thus, most of the zirconium atoms were located in zirconia particles on the surface and/or the grain boundary of alumina grains. Thus, it appears that the increase in the phase transition was caused by retardation of atomic diffusion at zirconia particles. 相似文献
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Zhiyong Wang Mohammed A. Al-Daous Elizabeth R. Kiesel Fan Li Andreas Stein 《Microporous and mesoporous materials》2009,120(3):351-358
Zeolite NaY nanocrystals (20−50 nm) were hydrothermally grown on polyelectrolyte-coated three-dimensionally ordered macroporous (3DOM) activated zirconia. The zeolite nanocrystallites uniformly coated the macropore walls of 3DOM sulfated zirconia, but sulfate groups were lost during the hydrothermal reaction. 3DOM tungstated zirconia was found to be more stable in the strong basic environment of the zeolite precursor solution. Further, ion-exchange of zeolite NaY with ruthenium followed by hydrogen-reduction formed a composite of RuNaY and 3DOM activated zirconia. The presence of ruthenium was confirmed by X-ray photoelectron spectroscopy and the external shape of zeolite nanoparticles was maintained after ion-exchange, but the zeolite lattice fringes could not be observed by transmission electron microscopy after incorporation of reduced ruthenium. Although the catalytic activity of the materials has not yet been tested, these hierarchical nano- and microstructures bring multiple catalyst components (modified zeolite Y, a typical Fischer–Tropsch catalyst, and activated zirconia, an isomerization catalyst) together in intimate contact for potential multi-reaction processes. 相似文献
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《Journal of the European Ceramic Society》2000,20(9):1289-1295
Nanocrystals of pure zirconia and yttria stabilized zirconia (YSZ) are obtained by a simple chemical synthesis route using sucrose, polyvinyl alcohol (PVA) and metal nitrates. The reaction mixture on pyrolysis and calcination gives nanocrystals. These are characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The size of the nanocrystallites for pure zirconia is in the range of about 7.0–45.0 nm and for yttria stabilized zirconia, is in the range of about 5.0–24.0 nm at 200°C and above, according to the preparative condition. At 200°C, pure zirconia forms cubic phase and this cubic phase is stable up to 600°C and then slowly transformed into monoclinic form. For yttria stabilized zirconia, the crystals are tetragonal in the temperature range from 200 to 1200°C. 相似文献
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Hongliang Zhu Deren Yang Zhenqiang Xi Luming Zhu 《Journal of the American Ceramic Society》2007,90(4):1334-1338
This work focuses on the synthesis of tetragonal zirconia (ZrO2 ) nanocrystallites with diameters of 5 nm by a simple hydrothermal process in the presence of hydrazine hydrate. Structural characterization of the ZrO2 products using X-ray diffraction and Raman spectroscopy revealed that the predominant crystal phase was the tetragonal phase. High-resolution transmission electron microscopy images further showed that that the diameter of the majority of the tetragonal ZrO2 nanocrystallites was <5 nm. Furthermore, we discussed the mechanism of the hydrothermal process and the critical roles of hydrazine hydrate in the hydrothermal formation of the small-sized ZrO2 nanocrystallites. 相似文献
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Mahshid Mohammadi Mohammad Hashem Sedghkerdar Mohsen Abbasi Ali Izadbakhsh Davood Karami 《加拿大化工杂志》2023,101(5):2548-2555
Calcium looping process is a promising approach for CO2 capture from the flue gas of fossil fuel power plants and the cement industry. Even though the advantages of calcium-based sorbents are low cost and high uptake capacity, they suffer from low durability during cycles. Modified sorbents were fabricated by adding alumina and zirconia and the mixture of alumina and zirconia to calcium oxide via the co-precipitation method. The performance of synthesized sorbents in terms of stability and CO2 capture capacity were evaluated using a fixed bed reactor in various CO2 sorption/desorption cycles. The sorbents were fabricated by a co-precipitation methodology using 10% binders (alumina and/or silica). X-ray diffraction (XRD), BET/BJH, and scanning electron microscopy (SEM) were conducted for characterization of synthesized sorbents. CaO-10% ZrO2 showed the best performance among the fabricated sorbents in terms of stability during 5 cycles and CO2 capacity (14 mmol CO2/g sorbent). The formation of CaZrO3 with a perovskite structure and high-temperature resistance could be attributed to well performance of zirconia-supported sorbent. On the other hand, no sign of aluminum zirconate formation was approved in XRD analysis for the fabricated sorbent using mixed binders of zirconia and alumina to enhance its stability during cycles. 相似文献
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Carbon nanospheres (CNSs) with the diameters of 50–250 nm were synthesized through a one-step solvothermal method at about 300 °C. In this process, benzene and hexachloroethane (C2Cl6) served as carbon source for the CNSs. The results showed that the CNSs were composed of a mixture of graphitic nanocrystallites and amorphous carbon. It is believed that they formed through intermolecular Friedel–Crafts alkylation and dehydrogenation reactions in the presence of anhydrous aluminum chloride (AlCl3). The mechanism of carbonization and the effect of Al particles on the morphology of carbon products are discussed. 相似文献
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Hongwei Che Shuhua Han Wanguo Hou Aifeng Liu Shasha Wang Yuanyuan Sun Xiaoyan Cui 《Journal of Porous Materials》2011,18(1):57-67
A novel strategy involving the combination of soft-templating and solid–liquid method (CSSL) is presented to synthesize mesoporous
nanocrystalline zirconia with high specific surface area, that is, the mesostructured zirconia hybrid is firstly synthesized via cooperative assembly between zirconium sulphate as inorganic
precursor and 1-hexadecyl-3-methylimidazolium bromide (C16mim+Br−) as the structure-directing agent, and subsequently ground with solid magnesium nitrate salt followed by heat-treatment in
air. The resulting zirconia material after calcination at 600 °C possesses a wormlike arrangement of mesopores surrounded
by tetragonal ZrO2 nanocrystallites of ca. 2.3 nm. The BET surface area is 255 m2/g and the pore size is ca. 4.3 nm. However, no mesoporous structure exists in the obtained zirconia material via the simple soft-templating method at
the same calcination temperature. Photoluminescence (PL) spectra of the obtained mesoporous nanocrystalline ZrO2 show a strong emission peak at ca. 394 nm under UV excitation of 250 nm wavelength. 相似文献
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N. V. Meshalkina V. I. Strakhov V. E. Levinok 《Refractories and Industrial Ceramics》1976,17(7-8):493-496
Conclusions An investigation of the wettability of zirconia refractories with molten aluminum and iron showed that regardless of the amount of stabilizing oxide in the material the refractories are wetted more rapidly with the molten iron. Aluminum and iron melts both wet the refractory more rapidly when the latter is produced from a cubic solid solution containing a large amount of stabilizing oxide.When wetted with the melts of aluminum and iron a zirconia refractory acquires a zonal structure, the ZrO2 in the reaction zone being partly destabilized.Translated from Ogneupory, No. 8, pp. 35–38, August, 1976. 相似文献