Normal-incidence efficiencies of 4800-grooves/mm-ruled replica gratings with multilayer and gold coatings in the 125-325-A wavelength region

The normal-incidence efficiencies of two 4800-grooves/mm ruled replica gratings, one with a dual-bandpass molybdenum/silicon multilayer coating and the other with a gold coating, were measured by use of synchrotron radiation in the 125-325-A wavelength region. The peak reflectance of the multilayer coating was 22% in the first Bragg order near 235 A and 28% in the second Bragg order near 126 A. The peak efficiency of the multilayer grating was 2.6% in the first diffraction order near 225 A and 0.3% in the second diffraction order near 125 A. The efficiencies of the multilayer grating were much higher than the corresponding efficiencies of the gold grating. The characterization of the surfaces of the gratings by atomic force microscopy indicated rms microroughness values in the 5-18-mum(-1) frequency range of 12-20 A for the multilayer grating and 22-32 A for the gold grating. Both gratings had bumpy surface features larger than the nominal groove height. The rather large surface roughness and groove irregularities had a detrimental effect on the grating efficiencies.     

Skylab 3600 groove/mm replica grating with a scandium-silicon multilayer coating and high normal-incidence efficiency at 38-nm wavelength

A Sc-Si multilayer coating was applied to a replica of the 3600 groove/mm grating, developed for the SO82A spectroheliograph that flew on the Skylab mission, for the purpose of enhancing the normal-incidence efficiency in the extreme-ultraviolet region. The efficiency, measured at an angle of incidence of 6 degrees with synchrotron radiation, had a maximum value of 7.2% at a wavelength of 38 nm and was a factor of 3 higher than the efficiency of the gold-coated Skylab grating. The measured efficiency of the Sc-Si grating was in good agreement with the efficiency calculated by use of the modified integral method.     

Multilayer-coated laminar grating with 16% normal-incidence efficiency in the 150-A wavelength region

We characterized a laminar grating with a Mo/Si multilayer coating by using synchrotron radiation and atomic force microscopy. The grating substrate had 2400 grooves/mm, 40-A groove depth, and 2080-A groove width. The microroughness of the grating substrate was 5 A rms. The multilayer coating was optimized to have peak normal-incidence reflectance at a wavelength near 150 A. For an angle of incidence of 10 degrees the peak grating efficiency was 16.3% in the +1 order and 15.0% in the -1 order. The efficiency in the zero order was lower by a factor of 40 owing to the excellent matching of the groove depth and groove width to the wavelength of the incident radiation. By dividing the grating efficiencies by the measured reflectance of the multilayer coating, we obtained inferred groove efficiencies of 34% and 32% in the +1 and -1 orders, respectively.     

Thin-film interference effects on the efficiency of a normal-incidence grating in the 100-350-A wavelength region

Thin-film interference effects were observed in the normal-incidence efficiency of a 2400-groove/mm replica grating. The efficiency was measured in the 100-350-A wavelength range and had an oscillatory behavior that resulted from the presence of a thin SiO(2) coating. The thicknesses of the SiO(2) and the underlying oxidized aluminum layers were inferred from computer modeling of the zero-order efficiency. The efficiencies in the diffracted orders were calculated with the modified integral approach and accounting for the multilayer coating and the groove profile derived from atomic force microscopy. The calculated and measured efficiencies were in good agreement.     

Comparison of the calculated and the measured efficiencies of a normal-incidence grating in the 125-225- A wavelength range

The efficiency of a diffraction grating was measured near normal incidence in the 125-225-A wavelength range with synchrotron radiation. The grating pattern had 2400 grooves/mm and was recorded on a concave fused-silica blank by a holographic technique. The grooves were shaped by ion-beam etching to provide a facet with a blaze angle of 2.5 degrees as determined by atomic force microscopy. Because of the characteristics of the etching process the groove profile was approximately triangular, with the other facet inclined at an angle of 5.5 degrees to the surface. The measured efficiency was compared with the efficiency calculated by a computer program, small enough to run on a personal computer, that solved the periodic boundary-value problem corresponding to electromagnetic radiation incident on a diffraction grating with finite conductivity. The calculation was based on the nominal groove profile that was determined by atomic force microscopy. The measured and the calculated efficiencies were in good agreement. This investigation indicates that the diffraction efficiency of a normal-incidence grating can be calculated in the soft-x-ray region with a personal computer.     

Efficiency and polarization performance of a multilayer-coated laminar grating in the 6.5-6.9-nm wavelength region

We applied a Mo/B4C multilayer coating to a laminar holographic grating with 2400 grooves/mm and a 1-m radius of curvature. By use of synchrotron soft x rays the multilayer-coated grating was evaluated to have diffraction efficiencies of 3.1% and 0.017% for s- and p-polarized radiation, respectively, at a 6.7-nm wavelength at a 45.35 degrees grazing angle of incidence in the +1 (inside) grating order. Thus the polarizance was estimated to be 98.9% at least. The zero-order peak was suppressed by the destructive interference caused by the groove profile.     

Development of multilayer laminar-type diffraction gratings to achieve high diffraction efficiencies in the 1-8 keV energy region

W/C and Co/SiO(2) multilayer gratings have been fabricated by depositing a multilayer coating on the surface of laminar-type holographic master gratings. The diffraction efficiency was measured by reflectometers in the energy region of 0.6-8.0 keV at synchrotron radiation facilities as well as with an x-ray diffractometer at 8.05 keV. The Co/SiO(2) and W/C multilayer gratings showed peak diffraction efficiencies of 0.47 and 0.38 at 6.0 and 8.0 keV, respectively. To our knowledge, the peak efficiency of the W/C multilayer grating is the highest measured with hard x rays. The diffraction efficiency of the Co/SiO(2) multilayer gratings was higher than that of the W/C multilayer grating in the energy range of 2.5-6.0 keV. However, it decreased significantly in the energy above the K absorption edge of Co (7.71 keV). For the Co/SiO(2) multilayer grating, the measured diffraction efficiencies agreed with the calculated curves assuming a rms roughness of approximately 1 nm.     

Survey of Ti-, B-, and Y-based soft x-ray-extreme ultraviolet multilayer mirrors for the 2- to 12-nm wavelength region

We have performed an experimental investigation of Ti-, B(4)C-, B-, and Y-based multilayer mirrors for the soft x-ray?extreme ultraviolet (XUV) wavelength region between 2.0 and 12.0 nm. Eleven different material pairs were studied: Ti/Ni, Ti/Co, Ti/Cu, Ti/W, B(4)C/Pd, B/Mo, Y/Pd, Y/Ag, Y/Mo, Y/Nb, and Y/C. The multilayers were sputter deposited and were characterized with a number of techniques, including low-angle x-ray diffraction and normal incidence XUV reflectometry. Among the Ti-based multilayers the best results were obtained with Ti/W, with peak reflectances up to 5.2% at 2.79 nm at 61° from normal incidence. The B(4)C/Pd and B/Mo multilayer mirrors had near-normal incidence (5°) peak reflectances of 11.5% at 8.46 nm and 9.4% at 6.67 nm, respectively, whereas a Y/Mo multilayer mirror had a maximum peak reflectance of 25.6% at 11.30 nm at the same angle. The factors limiting the peak reflectance of these different multilayer mirrors are discussed.     

Fabrication and evaluation of a wideband multilayer laminar-type holographic grating for use with a soft-x-ray flat-field spectrograph in the region of 1.7 keV

A multilayer laminar-type holographic grating having an average groove density of 2400 lines/mm is designed and fabricated for use with a soft-x-ray flat-field spectrograph covering the 0.70-0.75 nm region. A varied-line-spaced groove pattern is generated by the use of an aspheric wavefront recording system, and laminar-type grooves are formed by a reactive ion-etching method. Mo/SiO2 multilayers optimized for the emission lines of Hf-M, Si-K, and W-M are deposited on one of the three designated areas on the grating surface in tandem. The measured first-order diffraction efficiencies at the respective centers of the areas are 18%-20%. The flat-field spectrograph equipped with the grating indicates a spectral linewidth of 8-14 eV for the emission spectra generated from electron-impact x-ray sources.     

Thermal stability of the peak emission wavelength in multilayer InAs/GaAs QDs capped with a combination capping of InAlGaAs and GaAs

The effect of rapid thermal annealing (RTA) on the optical properties of a 10 layer stacked InAs/GaAs quantum dot (QD) heterostructure where the QDs are overgrown with a combination of quaternary InAlGaAs and GaAs capping have been investigated. TEM micrographs showed that the shape of the QDs is preserved for annealing temperatures up to 800 degrees C. The peak emission wavelength of the investigated heterostructures remains stable on annealing at temperatures upto 750 degrees C, which is unusual in QD samples. This phenomenon is attributed due to the suppression of the strain-enhanced intermixing in such structures. One of the reasons behind such suppression is the strain driven phase separation of Indium from the overgrown quaternary alloy, which maintains an In rich region across the QD periphery thereby checking the out-diffusion of Indium from the dots. The overlapping vertical strain from the under lying dot layers in the QD stack also maintains a strain relaxed state at the QD base, thereby preventing the material mixing at the base of the pyramidal QDs. This stability of wavelength is of paramount importance in optoelectronic devices where the design is based on the emission wavelength of the active region.     

Isotope 18O/16O ratio measurements of water vapor by use of the 950-nm wavelength region with cavity ring-down and photoacoustic spectroscopic techniques

Two optical methods, cavity ring-down spectroscopy and photoacoustic spectroscopy, are applied to the measurement of the isotope ratio 18O/16O in water-vapor samples with a Nd3+:YAG pumped-dye laser. The combination band of (2v1 + v3) in the 960-nm region of water molecules is investigated for two standard water samples, the Vienna Standard Mean Ocean Water and the Standard Light Antarctic Precipitation. The results demonstrate that the two methods have the potential of compact systems for in-situ measurements of H2O isotope ratio in the environment.     

Aging and thermal stability of Mg/SiC and Mg/Y2O3 reflection multilayers in the 25-35 nm region

Reflection measurements in the 25-35 nm region were made for Mg/SiC and Mg/Y2O3 multilayers kept in a low-humidity atmosphere for 4 or 5 years. Aged Mg/SiC multilayers keep their reflectances, and the reflectance value at 31.2 nm is 0.44 at 10 degrees of the normal angle of incidence. Aged Mg/Y2O3 multilayers change reflectance as top layer materials, and the best value at 30.1 nm is 0.40 at 10 degrees. Reflection measurements are also made for Mg-based multilayers that are annealed from room temperature to 400 degrees C at 50 degrees C intervals. Both multilayers keep their reflectance at annealing temperatures of 200 degrees C. These results suggest that both Mg-based multilayers can be applied to practical optics.     

Experimental study on the evaporative heat transfer and pressure drop of CO2 flowing upward in vertical smooth and micro-fin tubes with the diameter of 5 mm

Because of the ozone layer depletion and global warming, new alternative refrigerants are being developed. In this study, evaporation heat transfer characteristic and pressure drop of carbon dioxide flowing upward in vertical smooth and micro-fin tubes were investigated by experiment with regard to evaporating temperature, mass flux and heat flux. The vertical smooth and micro-fin tubes with outer diameter (OD) of 5 mm and length of 1.44 m were selected as a test section to measure the evaporative heat transfer coefficient. The tests were conducted at mass fluxes from 212 to 530 kg/(m² s), saturation temperatures from −5 to 20 °C and heat fluxes from 15 to 45 kW/m², where the test section was heated by a direct heating method. The differences of heat transfer characteristics between the smooth and the micro-fin tubes were analyzed with respect to enhancement factor (EF) and penalty factor (PF). Average evaporation heat transfer coefficients for the micro-fin tube were approximately 111–207% higher than those for the smooth tube at the same test conditions, and PF was increased from 106 to 123%.     

Effects of gold nanoparticles in the green and red emissions of TeO2–PbO–GeO2 glasses doped with Er–Yb

In the present work it is reported for the first time the effects of gold nanoparticles in the infrared-to-visible frequency upconversion of Er³⁺–Yb³⁺ co-doped TeO₂–PbO–GeO₂ glasses. Intense emission bands at 527, 550, and 660 nm were observed corresponding to the Er³⁺ transitions. It is shown that the combined effects of gold nanoparticles and the efficient Yb³⁺ → Er⁺³ energy transfer mechanism change the upconversion visible spectrum. It is then demonstrated that the enhanced local field contribution due to gold nanoparticles and the energy transfer processes between two different rare-earth ions can be used to control and improve the efficiency of luminescent glasses.     

Microscopic examination of the interface region in AC8A/Al18B4O33w composites reinforced with as-received and artificial nitrided Al18B4O33 whiskers

Aimed to control the interfacial reaction in Al₁₈B₄O₃₃/Al composites, the artificial nitridation process is proposed based on thermodynamic calculations, which leads to a 50-nm thick artificial nitrided coating surrounding a Al₁₈B₄O₃₃ whisker. Aluminum (AC8A) matrix composites reinforced with different Al₁₈B₄O₃₃ whiskers were processed and Al₁₈B₄O₃₃ whiskers were used in their as-received form and after artificial nitridation. The interface region between the aluminum matrix and Al₁₈B₄O₃₃ was charactered using transmission electron microscopy. Results show that extensive reaction takes place during the incorporation process between the as-received Al₁₈B₄O₃₃ whiskers and the aluminum matrix and Mg in the base alloy forms MgAl₂O₄ spinel phases. Such interfacial reaction is enhanced after T6 heat treatment. In the case of artificially nitrided Al₁₈B₄O₃₃ whiskers, even though the artificial nitrided coating surrounds the Al₁₈B₄O₃₃ whisker, it can react with the AC8A alloy to produce MgAl₂O₄, but the degree of the interfacial reaction is reduced. The interfacial reaction only consumes the artificial nitrided coating instead of the reinforcement whiskers and the integrity of the whisker is preserved.