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1.
Andrew C. Lawson Joyce A. Roberts Barbara Martinez Hassel Ledbetter Albert Migliori James W. Richardson 《JOM Journal of the Minerals, Metals and Materials Society》2003,55(9):31-33
This article describes the authors’ use of the Weiss two-state model for Fe-Ni invar alloys to understand the anomalous thermal
expansion of Pu-Ga alloys. Studies on thermal expansion of Pu-Ga are reviewed briefly, and the two-state invar model is described.
The authors fit the available neutron-diffraction data for Pu-Ga alloys to the invar model and discuss the consequences.
For more information, contact Andrew C. Lawson, Structure and Properties Group: MST-8, MS H-805, Los Alamos National Laboratory,
Los Alamos, New Mexico 87545; (505) 667-8844; fax (505) 665-2676; e-mail lawson@lanl.gov. 相似文献
2.
In this study, a semi-empirical Lennard-Jones/embedded atom method model is used to capture real materials behavior through
the introduction of many-body forces. By means of molecular dynamics calculations, the model is used to study the dependence
of the solid-liquid interface velocity on temperature for two alloy compositions.
For more information contact M.I. Baskes, Los Alamos National Laboratory, PO Box 1663, MS-G755, Los Alamos, NM 87545, USA;
(505) 667-1238; fax (505) 667-8021; baskes@lanl.gov. 相似文献
3.
T. G. Zocco A. J. Schwartz 《JOM Journal of the Minerals, Metals and Materials Society》2003,55(9):24-27
Transmission electron microscopy (TEM) has proven to be a useful tool to investigate the morphological and crystallographic
nature of plutonium metal and alloys. Its unique ability to provide direct visual as well as crystallographic information
on a very fine scale has given new insight into the complex nature of plutonium. Because of the limited number of TEM observations
performed to date, there is little doubt that this metal’s most intriguing microstructural secrets are yet to be revealed.
For more information, contact T.G. Zocco, Los Alamos National Laboratory, NMT-10, Manufacturing Process Science and Technology
Group, P.O. Box 1663, Mail Stop E506, Los Alamos, NM 87545; (505) 667-4481; fax (505) 667-8528; e-mail zocco@lanl.gov. 相似文献
4.
Terry C. Lowe Ruslan Z. Valiev 《JOM Journal of the Minerals, Metals and Materials Society》2004,56(10):64-68
Severe plastic deformation (SPD) has emerged as a promising method to produce ultrafine-grained materials with attractive
properties. Today, SPD techniques are rapidly developing and are on the verge of moving from lab-scale research into commercial
production. This paper discusses new trends in the development of SPD techniques suchas high-pressure torsion and equal-channel
angle pressing, as well as new alternative techniques for introducing SPD. The paper also contains a comparative analysis
of SPD techniques in terms of their relative capabilities for grain refinement, enhancement of properties, and potential to
economically produce ultrafine-grained metals and alloys.
For more information, contact Terry C. Lowe, Science and Technology Base Programs, Los Alamos National Laboratory, Los Alamos,
NM 87545; (505) 667-7824; fax (505) 665-3199; e-mail tlowe@lanl.gov. 相似文献
5.
The fundamentals of nanostructured materials processed by severe plastic deformation 总被引:3,自引:0,他引:3
Yuntian T. Zhu Terence G. Langdon 《JOM Journal of the Minerals, Metals and Materials Society》2004,56(10):58-63
Nanostructured materials produced by severe plastic deformation (SPD) are 100% dense, contamination-free, and sufficiently
large for use in real commercial structural applications. These materials are found to have high strength, good ductility,
superior superplasticity, a low friction coefficient, high wear resistance, enhanced high-cycle fatigue life, and good corrosion
resistance. This article reviews the structures and properties of nanostructured materials produced by SPD and reports recent
progress in determining the deformation mechanisms that lead to these superior mechanical properties.
For more information, contact Yuntian T. Zhu, Los Alamos National Laboratory, Materials Science and Technology Division, Los
Alamos, NM 87545; (505) 667-4029; fax (505) 667-2264; e-mail yzhu@lanl.gov. 相似文献
6.
Plutonium is unstable with time because of its radioactive decay, but it is the peculiar nature of its electronic structure
that gives rise to phase instability with temperature, pressure, and chemical additions, making engineering applications particularly
challenging. This instability leads to an interesting array of phase transformations and microstructures.
For more information, contact Siegfried S. Hecker at the Los Alamos National Laboratory, Materials Science and Technology
Division, MS G754, Los Alamos, NM 87545; (505) 665-6601; fax (505) 665-4584; e-mail sh@lanl.gov. 相似文献
7.
J. L. Sarrao L. A. Morales J. D. Thompson 《JOM Journal of the Minerals, Metals and Materials Society》2003,55(9):38-40
Superconductivity has recently been discovered in a plutonium intermetallic compound (PuCoGa5) at the surprisingly high temperature of 18.5 K. This article discusses the motivation that led to this discovery as well
as what it implies for the understanding of both unconventional superconductivity and the metallurgy of plutonium.
For more information, contact J.L. Sarrao, Los Alamos National Laboratory, MST-10: Condensed Matter & Thermal Physics, Mail
Stop K764, Los Alamos, NM 87545; (505) 665-0481; fax (505) 665-7652; e-mail sarrao@lanl.gov. 相似文献
8.
R. Z. Valiev T. C. Lowe A. K. Mukherjee 《JOM Journal of the Minerals, Metals and Materials Society》2000,52(4):37-40
Refining microstructure by severe plastic deformation to a nanometer range changes fundamental properties, such as the Curie
and Debye temperatures, and engineering properties of pragmatic significance, such as strength and ductility. These enhancements
originate in the combination of very small grain sizes coupled with specific defect structures. Ongoing research is rapidly
advancing the understanding of severe plastic deformation-induced microstructures, leading toward the commercialization of
these materials.
For more information, contact T.C. Lowe, Los Alamos National Laboratory, Materials Science and Technology Division, MD G754,
Los Alamos, New Mexico 87545; (505) 665-1131; fax (505) 665-4584; e-mail tlowe@lanl.gov.
Authors’ Note: All compositions are given in weight per cent. 相似文献
9.
Joseph C. Martz Adam J. Schwartz 《JOM Journal of the Minerals, Metals and Materials Society》2003,55(9):19-23
Planning for future refurbishment and manufacturing needs of the U.S. nuclear weapons complex critically depends on credible
estimates for component lifetimes. One of the most important of these components is the pit, that portion of the weapon that
contains the fissile element plutonium. The U.S. government has proposed construction of a new Modern Pit Facility, and a
key variable in planning both the size and schedule for this facility is the minimum estimated lifetime for stockpile pits.
This article describes the current understanding of aging effects in plutonium, provides a lifetime estimate range, and outlines
in some detail methodology that will improve this estimate over the next few years.
For more information, contact J.C. Martz, Los Alamos National Laboratory, Enhanced Surveillance, MST-DO, Los Alamos, New Mexico
87545; (505) 667-2323; e-mail jmartz@lanl.gov.
Editor’s Note: A hypertext-enhanced version of this article is available on-line at www.tms.org/pubs/journals/JOM/0309/Martz-0309.html 相似文献
10.
Daniel S. Schwartz Jeremy N. Mitchell Douglas V. Pete Michael Ramos 《JOM Journal of the Minerals, Metals and Materials Society》2003,55(9):28-30
The α′→δ reversion transformation in stabilized δ phase Pu-Ga alloys containing 0.5 wt.% and 0.6 wt.% Ga was studied using
dilatometry and differential scanning calorimetry. The α′→δ reversion was observed to occur as a series of transformation
bursts spread over a 20°C to 40°C temperature range. The enthalpy of the endothermic α′→δ reversion transformation was estimated
to be approximately 0.56 J/g for the 0.6 wt.% Ga alloy. Lower gallium was found to raise the α′→δ reversion temperature in
specimens cooled to −155°C from 44–48°C for 0.6 wt.% Ga to 92°C for 0.5 wt.% Ga. Repeated cycling to −155°C caused the reversion
onset temperature to decrease by ∼10°C. Raising the minimum hold temperature from −150°C to −125°C caused the reversion onset
temperature to decrease by 5–10°C. Annealing at 300–400°C was required to erase all traces of the effects of cold exposure;
material heated to only 200°C after thermal cycling displayed decreased reversion onset temperatures during subsequent thermal
cycling.
For more information, contact D.S. Schwartz, Los Alamos National Laboratory, NMT Division, Los Alamos, New Mexico 87545. 相似文献
11.
Corbett C. Battaile Jeffrey J. Hoyt 《JOM Journal of the Minerals, Metals and Materials Society》2005,57(9):71-73
The Atomic Kinetic Lattice Monte Carlo method was used to model the effects of a clustering impurity species on the deposition
of nanocrystalline nickel films onto (001) copper. The deposition model was partly parameterized by physical inputs from atomistic
calculations of copper-nickel alloys. The grain size and shape is shown to depend on the concentration of impurities in the
deposited film. Low concentrations yield elongated columnar grains, while higher concentrations produce much smaller and more
equiaxed grains.
For more information, contact Corbett C. Battaile, Sandia National Laboratories, P.O. Box 5800, MS 1411, Albuquerque, NM 87111,
USA; (505) 844-7039; fax (505) 844-9781; e-mail ccbatta@sandia.gov. 相似文献
12.
Zr
100-xA1x (x ≤ 40) metastable alloys were synthesized by high- energy ball milling of elemental Zr and Al powders: supersaturated
substitutional cph solid solution for x ≤ 15 and an amorphous phase for x ≥ 17.5. We performed a calorimetric study of the
thermodynamics and kinetics of the metastable- to- equilibrium transformations of these phases. Their stability range (temperature/composition),
as well as the apparent activation energies associated with the transformations, were determined. The transformation enthalpies
were measured and used to determine the enthalpy of formation for these metastable phases. For both as- milled and relaxed
amorphous phases, the measured enthalpy of crystallization is compared with those estimated for an undercooled liquid. Different
amounts of retained entropy at the glass transition temperature were used to estimate the enthalpy loss upon undercooling
due to the excess specific heat.
This paper was presented at the Thermodynamics and Phase Equilibria of Metastable Phases Symposium at the Spring TMS Meeting,
March 1-4,1992, in San Diego. The symposium was organized by Philip Nash, Illinois Institute of Technology, and Ricardo Schwarz,
Los Alamos National Laboratory. 相似文献
13.
Charles Farrar Francois Hemez Gyuhae Park Hoon Sohn Amy Robertson Todd Williams 《JOM Journal of the Minerals, Metals and Materials Society》2004,56(3):40-42
An approach to developing a damage prognosis solution that integrates advanced sensing technology, data interrogation procedures
for damage detection, novel model validation and uncertainty quantification techniques, and reliability-based decision-making
algorithms is summarized in this article. In parallel, experimental efforts are underway to deliver a proof-of-principle technology
demonstration by assessing impact damage and predicting the subsequent fatigue damage accumulation in a composite plate. This
article provides an overview of the various technologies that are being integrated to address this damage prognosis problem.
Editor’s Note: Presentation of this paper is supported by the Air Force Research Laboratory, under agreement number F33615-01-D-5801. The
U.S. Government is authorized to reproduce and distribute reprints for governmental purposes notwithstanding any copyright
notation thereon. The views and conclusions contained herein are those of the authors and should not be interpreted as necessarily
representing the official policies or endorsements, either expressed or implied, of the Air Force Research Laboratory or the
U.S. Government.
For more information, contact Charles Farrar, Los Alamos National Laboratory, MST-006, Los Alamos, NM 87545; e-mail farrar@lanl.gov. 相似文献
14.
J. J. Hoyt Alain Karma M. A. Asta D. Y. Sun 《JOM Journal of the Minerals, Metals and Materials Society》2004,56(4):49-54
Dendritic microstructures control the properties of a wide range of advanced materials ranging from nickel-based superalloys
used in turbine blades to lightweight aluminum-based alloys for the automotive industry. This article reviews recent progress
in quantitative modeling dendritic growth through the combination of state-of-the-art atomistic and phase field simulations.
Also shown is how the combination of these two distinct length-scale modeling approaches can yield a parameter-free prediction
of the dendrite growth velocity as a function of undercooling for deeply undercooled nickel melts.
For more information, contact J.J. Hoyt, Sandia National Laboratories, P.O. Box 5800, MS 1411, Albuquerque, NM 87185-1411;
(505) 284-5391; fax (505) 844-9781; e-mail jjhoyt@sandia.gov. 相似文献
15.
R. Scott Lillard Darryl P. Butt 《JOM Journal of the Minerals, Metals and Materials Society》1998,50(12):56-59
Efforts to measure the real-time corrosion rates of alloy 718 during 800 MeV proton radiation at currents up to 1 mA are reported.
Specially designed corrosion probes, which incorporate ceramic seals, were mounted in a water manifold that allowed samples
to be directly exposed to the proton beam at the Los Alamos Neutron Science Center. The water system that supplied the manifold
provided a means for controlling water chemistry, measuring dissolved hydrogen concentration, and measuring the effects of
water radiolysis and water quality on corrosion rate. Real-time corrosion rate measurements during proton irradiation showed
an exponential increase in corrosion rate with proton-beam current. These results are discussed within the context of water
radiolysis at the diffusion boundary layer/beam-spot interface. However, additional factors that may influence these parameters,
such as oxide spallation and charge build-up in the passive film, are not ruled out.
Scott Lillard earned his Ph.D. in materials science and engineering from Johns Hopkins University in 1992. He is currently a technical
staff member at the Materials Corrosion and Environmental Effects Laboratory, Los Alamos National Laboratory.
Darryl P. Butt earned his Ph.D. in ceramic science from Pennsylvania State University in 1991. He is currently a technical staff member
at the Non-Proliferation and International Security Division, Los Alamos National Laboratory. 相似文献
16.
The recrystallization textures of aluminum alloys can be explained by a growth selection of grains with an approximate 40°
〈111〉 orientation relationship out of a limited spectrum of preferentially formed nucleus orientations. Accordingly, recrystallization
textures can be modeled by the multiplication of a function f(g)nucl describing the probability of nucleation of the various orientations with a function f(g)grow representing their growth probability. Whereas the growth probability can be accounted for by a 40° 〈111〉 transformation
of the rolling texture, the nucleation probability of the respective grains is given by the distribution of potential nucleus
orientations, which is known from local texture analysis of rolled aluminum alloys to be cube bands, grain boundaries, and
second-phase particles. The contributions of these nucleation sites are determined according to an approach to calculate the
number of nuclei forming at each site, which is based on microstructural investigations of the evolution of the various nucleation
sites during deformation. This article describes the model for recrystallization texture simulation in aluminum alloys and
gives examples of recrystallization textures of AA3004 deformed in plane-strain compression at different deformation temperatures
and strain rates.
O. Engler earned his Ph.D. in physical metallurgy at the University of Technology at Aachen, Germany, in 1990. He is currently a long-term
visiting staff member at Los Alamos National Laboratory. Dr. Engler is a member of TMS.
H.E. Vatne earned his Ph.D. in physical metallurgy at the Norwegian Institute for Science and Technology, Trondheim, in 1995. He is
currently a research scientist at Hydro Aluminum. 相似文献
17.
N. Missert J. C. Barbour R. G. Copeland J. E. Mikkalson 《JOM Journal of the Minerals, Metals and Materials Society》2001,53(7):34-36
Arrays of engineered copper islands on an aluminum thin-film matrix have been employed to investigate the role of copper in
localized corrosion of Al-Cu alloys. When exposed to dilute NaCl solutions, the engineered samples corrode with a morphology
similar to that observed in second-phase particles in real alloys. In-situ fluorescence microscopy allows the observation
of oxygen reduction at copper islands during corrosion of the underlying aluminum thin-film matrix. The spacing between engineered
copper islands was found to strongly influence the corrosion rate of the surrounding matrix.
For more information, contact N. Missert, Department of Nanostructure and Semiconductor Physics, MS 1415, P.O. Box 5800, Albuquerque,
New Mexico 87185-1415; (505) 844-2234; fax (505) 844-1197; e-mail namisse@sandia.gov. 相似文献
18.
K.A. Gschneidner Jr. 《Journal of Alloys and Compounds》1992,180(1-2):1-13
Research highlights on rare earth materials are described from the earliest days as a graduate student during the mid 1950s, through the six years at Los Alamos, to the last 28 at Iowa State University. The early work was concerned with the rare earth carbides which led to an appreciation of systematics of the properties of rare earth materials. Use of the systematic variation of properties and behaviors is a powerful tool in understanding the nature of certain phenomena - in particular solid solution formation and the role of 4f electrons in bonding (4f hybridization). Some of the anomalous 4f properties of cerium metal and cerium compounds, and the quenching of spin fluctuations in exchanged enhanced materials, are also discussed. 相似文献
19.
Engineering Applications of Time-of-Flight Neutron Diffraction 总被引:1,自引:0,他引:1
Bj?rn Clausen Donald W. Brown I. C. Noyan 《JOM Journal of the Minerals, Metals and Materials Society》2012,64(1):117-126
Time-of-flight neutron diffraction is widely used in characterizing the microstructure and mechanical response of heterogeneous
systems. Microstructural characterization techniques include spatial or temporal mapping of the phases and determination of
grain size, dislocation structure, and grain orientations (texture) within these phases. Mechanical response analysis utilizes
the crystallographic selectivity of the diffraction process to measure the partitioning of strain within the system. The microstructural
and mechanical response information is then used to develop more realistic constitutive models. In this article we review
some examples of such measurements, based on our experiences at the Lujan Center of Los Alamos National Laboratory. 相似文献
20.
A chemical bonding model that provides a method of predicting thermodynamic properties of metastable structures of the solid
elements is presented. The method involves a Born-Haber-type cycle to calculate the difference in bonding energies between
the room temperature stable structures and metastable structures. To carry out the calculations, spectroscopic data are used
to determine the promotion energies from the ground state of the gaseous atom to the valence state corresponding to each structure.
Such data are available for most elements, but in cases where experimental data are lacking, they are derived using predictive
models. Combinations of promotion energies and heats of sublimation are used to determine bonding enthalpies. The contribution
of the outer-shell s and p-electrons and the inner-shell d and f electrons to the bonding energies are considered taking into
account the crystal field effect upon the bonding abilities of different d and f orbitals
This paper was presented at the Thermodynamics and Phase Equilibria of Metastable Phases Symposium at the Spring TMS Meeting,
March 1-4, 1992, in San Diego.
The symposium was organized by Philip Nash, Illinois Institute of Technology, and Ricardo Schwarz,Los Alamos National Laboratory. 相似文献