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Tuanjie Shen Liumei Teng Yanjie Hu Weifeng Shen 《Frontiers of Chemical Science and Engineering》2023,17(1):34
In the traditional extractive distillation process, organic solvents are often used as entrainers. However, environmental influence and high energy-consumption are significant problems in industrial application. In this study, a systematic screening strategy and innovative energy-saving design for ionic liquid-based extractive distillation process was proposed. The innovative energy-saving design focused on the binary minimum azeotrope mixtures isopropanol and water. Miscibility, environmental impact and physical properties (e.g., melting point and viscosity) of 30 ionic liquids were investigated. 1-Ethyl-3-methyl-imidazolium dicyanamide and 1-butyl-3-methyl-imidazolium dicyanamide were selected as candidate entrainers. Feasibility analysis of these two ionic liquids was further performed via residue curve maps, isovolatility line and temperature profiles. An innovative ionic liquid-based extractive distillation process combining distillation column and stripping column was designed and optimized with the objective function of minimizing the total annualized cost. The results demonstrate that the total annualized cost was reduced by 19.9% with 1-ethyl-3-methyl-imidazolium dicyanamide as the entrainer and by 24.3% with 1-butyl-3-methyl-imidazolium dicyanamide, compared with that of dimethyl sulfoxide. The method proposed in this study is conducive to the green and sustainable development of extractive distillation process. 相似文献
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Filipe Soares Pinto Roger Zemp Megan Jobson Robin Smith 《Chemical engineering science》2011,(13):2920
In this paper a methodology for thermodynamic analysis and distillation column ‘targeting’ is presented, with emphasis on the use of side condensers and side reboilers. Research in the past has been towards the establishment of a heat distribution curve, showing the way in which heat can be added or extracted across the different column sections. One major disadvantage of these profiles is that they refer to reversible columns, and cannot be used effectively to target for modifications in a real column.The main feature of the proposed methodology is the introduction of a minimum driving force, defined in terms of exergy loss distribution of the existing column, to set realisable targets for side reboiling/condensing in real columns, resulting in considerable energy savings. In addition to providing realisable targets, the new approach also provides the design engineer with information about the best location to place a side exchanger, and the required additional column modifications. The methodology can be applied using conventional column models in commercial process simulation programs, but can be significantly simplified by using reboiled and refluxed absorber models in a bespoke program. Simulation results for modified designs set by the new approach, for binary and multicomponent separations, verify the feasibility of the targets. This contrasts with previous approaches, which result in temperature shifts and heat load penalties after placing side reboilers/condensers, thus requiring additional simulation time and experienced judgement. 相似文献
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Xiao-Hong Wang Yu-Gang Li Yang-Dong Hu Ying-Long Wang 《Computers & Chemical Engineering》2008,32(8):1908-1917
This paper addresses the application of Genetic Programming (GP) to the synthesis of heat-integrated complex distillation system and the flowsheet of complex separation can be expressed directly using GP's special hierarchical structure. A series of unique encoding method and solution strategy is proposed and some evolutionary factor is improved based on the domain knowledge of chemical engineering. A shortcut method is applied to calculate all required design parameters. Conventional and complex columns, thermally coupled (linked) side strippers and side rectifiers, fully thermally coupled columns as well as heat integration between any different columns are simultaneously considered. Two illustrating examples are presented to demonstrate the effective computational strategies. 相似文献
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José A. Caballero Ignacio E. Grossmann 《American Institute of Chemical Engineers》2013,59(4):1139-1159
The design of thermally coupled distillation sequences explicitly including the possibility of divided wall columns (DWC) is described. A DWC with a single wall can be considered thermodynamically equivalent to a fully thermally coupled (FTC) subsystem formed by three separation tasks (a Petlyuk configuration in the case of three‐component mixtures). It is shown how to systematically identify all the sequences of separation tasks that can produce configurations that include at least a DWC. Feasible sequences that explicitly include DWCs are enforced through a set of logical relationships in terms of Boolean variables. These logical relationships include as feasible alternatives from conventional columns (each column must have a condenser and a reboiler) to FTC systems (only one reboiler and one condenser in the entire system). A comprehensive disjunctive programming formulation for finding the optimal solution is presented. The model is based on the Fenske, Underwood Gilliland equations. However, the disjunctive formulation allows easily the use of any other shortcut, aggregated or even rigorous model without modifying much the structure of the model. Two illustrative examples illustrate the procedure. © 2012 American Institute of Chemical Engineers AIChE J, 59: 1139–1159, 2013 相似文献
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This paper is concerned with the development of a quantitative criterion based on the total interstage flowrate in a distillation column. This criterion reflects the total optimum cost of a column and can be used for screening simple column sequences. It has been shown that the interstage flowrate measure is compatible with known heuristics and the results have been compared with those obtained from other methods in the literature. 相似文献
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随着电子学的发展和微制造技术的不断进步,微尺度蒸馏技术作为一种有效的化工强化手段,可用于解决蒸馏工艺存在的设备庞大、能量利用效率低以及对于相对挥发度较低的体系分离困难等问题。当尺度减小后,液体通道的深度和传质距离也随之减少,气-液或液-液间的传质效率显著增强。利用微蒸馏设备进行分离具有极低的等板高度;同时,在具有优良控温系统的前提下可以对传热进行更精准地控制,有利于减少热敏体系中副反应的发生。本综述分别介绍了重力微蒸馏、载气微蒸馏、真空微蒸馏、毛细(管)力微蒸馏和离心力微蒸馏五种主要的微尺度蒸馏方法,比较和讨论了每种方法的结构特征及其优缺点,并对微蒸馏设备的加工制造技术进行了系统介绍。微尺度蒸馏技术具有特殊的优势,能够为现代化工蒸馏向着降耗、环保、集约化的目标发展提供新思路。 相似文献
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精馏分离技术研究新进展 总被引:2,自引:0,他引:2
本文在参考大量文献的基础上,着重介绍了各种精馏方法以及国内外发展状况,对萃取精馏和恒沸精馏方法进行比较,并对催化精馏技术的国内外研究进展做了详细介绍. 相似文献
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《Desalination》1987
The Orbital Tube Evaporator (OTE) was inspired 10 years ago by the emerging technology of the horizontal tube evaporator (HTE). Recent market share (1985–June 1986) of H.T.E. for large land based systems is an impressive growth of 10% from its all time total of 3% (3.3 to 1) as against 48% from 28% (1.7 to 1) for all types of membrane systems and the declining position of 42% from 64.5% for the industrial standby, the multi-stage Flush (MSF) type. (Table II)In either the multi-effect boiling (MEB) or the vapor compression (VC) system configurations, O.T.E. plays essentially the same role as the HTE or the Vertical Tube Evaporator (VTE), but with much higher heat transfer coefficient, higher output purity without the need of demister and less tendency to scaling or fouling. Several engineering models were developed to substantiate its various performances and to simplify the mechanical design for practical application.The superior features of the OTE are derived from an inertially coupled whip rod revolving inside each tube to spread the fluid into thin and uniform film to fascilitate the heat transfer, while allowing the main stream of the throughput to flow down the tube freely. This division of the heat transfer and the mass transfer of the fluid permits the reduction of the dwelling time and assures an even temperature distribution of the fluid quite similar to the wiper evaporators, but without their troublesome seals and mechanical drive mechanism inside the evaporation chamber.The excellent showing of the HTE in the desalination market provides a strong encouragement for further development and adaptation of the OTE for desalination systems of various sizes and configurations. In addition, OTE may also be used for the production of pure water for pharmaceutical or electronic chip manufacture, or for the distillation of other kinds of fluids.Furthermore, OTE as a concentrator can be more cost effective than either the wiper type or the falling film type for a number of applications. Since the OTE is quite simple in system configuration, a successful field test in any one of the above applications would facilitate its adaptation to other systems. 相似文献
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催化蒸馏技术的应用进展 总被引:1,自引:0,他引:1
综述了催化蒸馏技术的应用进展情况,介绍了催化蒸馏技术的特点及装填方式,并从醚化、酯化,烷基化、缩合等几个方面简要叙述了近年来催化蒸馏技术的应用与发展。 相似文献
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Flash and distillation systems evolving on the equilibrium manifold possess stable steady states when the molar flows and the boundary conditions are fixed and a vapor and liquid phase is present at all times. The results extend the range of validity of a local stability theorem for linear, constant molar overflow systems due to Acrivos and Amundson. The approach to stability analysis is motivated by the tangent plane method developed by Gibbs to open systems as it takes advantage of the negative curvature of the entropy surface to construct a Lyapunov function. © 2013 American Institute of Chemical Engineers AIChE J, 59: 3322–3332, 2013 相似文献
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Didier Haillot Xavier Py Vincent Goetz Mohamed Benabdelkarim 《Chemical Engineering Research and Design》2008,86(6):612
Composite materials based on expanded natural graphite (CENG) and various phase change materials (PCM) have been developed for low temperature solar applications (323–373 K). The integration of such composite materials directly into the solar collector could allow new storage functionality. A numerical model has been developed to describe the materials behaviour. Composites properties are presented and discussed. 相似文献
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The paper presents stochastic optimisation technology as applied on separation sequencing problems. Simulated annealing is employed along with a synthesis representation in the form of a dynamic vector. Permutations on the vector and perturbations on the current state generate new sequences and layouts that are accessed, accepted and rejected. The approach can handle problems of industrial complexity. Operational variables (pressures, reflux ratios, product composition) can be optimised simultaneously with the structure. The potential of the methodology is illustrated with an FCC example. 相似文献