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以环氧树脂为基体,二甲基苄胺为固化剂,经酸浸、加热和钠离子交换的结构修饰和有机改性的蛭石为增强剂,制备了环氧树脂/蛭石纳米复合材料.测试了环氧树脂/蛭石纳米复合材料的结构、形貌、力学和电学性能.结果表明:环氧树脂、二甲基苄胺和蛭石的混合顺序,二甲基苄胺和蛭石的用量影响蛭石的剥离,进而影响环氧树脂/蛭石纳米复合材料的性能.在蛭石加入量为环氧树脂质量的1%~5%范围内,3%时环氧树脂/蛭石纳米复合材料的抗拉强度、弹性模量和弯曲强度最大,表面电阻最低,体电阻最高. 相似文献
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李珺鹏;齐暑华;曹鹏;谢璠 《中国塑料》2011,25(6):38-41
以聚砜改性环氧树脂为基体,通过高温模压制备了环氧树脂/玻璃纤维/氮化硼复合材料,研究了不同粒径及不同氮化硼导热粒子用量对复合材料导热性能、力学性能和电性能的影响。结果表明,大粒径粒子有利于复合材料力学性能的提高,小粒径有利于导热性能的提高;随着氮化硼用量的增加,复合材料的导热性能升高,力学性能呈现先增后降趋势,当氮化硼用量为10 %(质量分数,下同)时,复合材料的冲击强度和弯曲强度均达到最佳,当氮化硼用量为20 %时,复合材料仍保持较好的电性能。 相似文献
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采用自制松香海松酸接枝聚十二羟基硬脂酸(RA-g-PHS)超分散剂改性聚丙烯(PP)/剑麻纤维素微晶(MCF)木塑复合材料,研究了RA-g-PHS超分散剂用量对PP/MCF木塑复合材料力学性能、熔体流动速率和热性能的影响,并用扫描电子显微镜(SEM)对PP/MCF木塑复合材料冲击断面形貌的微观结构进行分析。结果表明,当RA-g-PHS超分散剂用量为2 %时,PP/MCF木塑复合材料的冲击强度为13.68 kJ/m2,熔体流动速率为2.06 g/10 min,相比未添加RA-g-PHS超分散剂的PP/MCF木塑复合材料分别提升了100 %和34.6 %,且热稳定性最好。 相似文献
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利用E-51环氧树脂(EP)改性MC尼龙,并以碳纤维(CF)粉为增强剂、二硫化钼(MoS2)为润滑剂、炭黑为增容剂,制备了MC尼龙复合材料.分别研究了EP,CF粉及MoS2的用量对MC尼龙复合材料性能的影响,并测试了MC尼龙复合材料与钢及铝合金摩擦时的耐磨损性能.结果表明,当MC尼龙用量为100份、EP为1.5份、CF粉为13份、MoS2为6.5份、炭黑为3.5份时,MC尼龙复合材料具有较好的力学性能和摩擦性能.相对于钢,该MC尼龙复合材料与铝合金摩擦时的耐磨损性能较好. 相似文献
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以丁腈橡胶(NBR)和氯丁橡胶(CR)为主体材料,通过添加云母粉、中空玻璃微珠(HGB)、蒙脱土(MMT)制备隔声阻尼NBR/CR复合材料,并利用正交试验研究NBR/CR并用比、云母粉用量、HGB用量、MMT用量对NBR/CR复合材料阻尼性能和隔声性能的影响,确定NBR/CR复合材料的优化配方组合。结果表明:对于NBR/CR复合材料的最大损耗因子(tanδmax),其影响因素的主次顺序为NBR/CR并用比、HGB用量、云母粉用量、MMT用量;对于NBR/CR复合材料的有效阻尼温域宽度,其影响因素的主次顺序为NBR/CR并用比、云母粉用量、MMT用量、HGB用量;对于NBR/CR复合材料的平均隔声量,其影响因素的主次顺序为HGB用量、云母粉用量、MMT用量、NBR/CR并用比;NBR/CR复合材料的优化配方组合为:NBR/CR并用比 70/30,云母粉用量 10份,HGB用量 12份,MMT用量 10份。 相似文献
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A new ampholytic homopolypeptide, , which has one tertiary amino and two carboxyl groups in the side chain has been derived from a hydrochloride salt of poly(L-lysine). The polymer in aqueous solution seems to be in the coil form with locally extended structure (LES) at neutral pH. In both the acidic and alkaline regions, the molar ellipticity of the polymer changes as a result of change in net charge on the side chain. The conformational changes may be from the coil with LES to other coiled forms. 5–7 M NaClO4 and 80% aqueous methanol induce the α-helix in the polymer at neutral pH. Divalent cations, Cu2+ and Ca2+, do not induce any remarkably ordered structures such as α-helix or β-structure in the polymer in aqueous solution at any pH. Ultraviolet absorption studies show an absorption peak of the polymer-Cu2+ complex near 240 nm. Dependence of the peak intensity on pH at various q values () indicates the two steps of the complex formation. At q less than 0.64, the formation is described only with the first step. An average coordination number for Cu2+ at the first step was calculated to be about 2 by the method of Mandel and Leyte. The association constant of Cu2+ with the residue at the step was determined from the absorption data to be far smaller than that for the Cu2+-EDTA complex. The second step of the formation occurs in the case of large q but the absorption data for the second step cannot be obtained exactly due to precipitation. 相似文献
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Silvia Schicker Daniel E. García Igor Gorlov Rolf Janssen Nils Claussen 《Journal of the American Ceramic Society》1999,82(10):2607-2612
Wet milling of Al2 O3 -aluminide alloy (3A) precursor powders in acetone has been investigated by milling Fe/Al/Al2 O3 and Fe2 O3 /Al/Al2 O3 powder mixtures. The influence of the milling process on the physical and chemical properties of the milled powders has been studied. Particle refinement and homogenization were found not to play a dominant role, whereas plastic deformation of the metal particles leads to the formation of dislocations and a highly disarranged polycrystalline structure. Although no chemical reactions among the powder components in Fe2 O3 /Al/Al2 O3 powder mixtures were observed, the formation of a nanocrystalline, ordered intermetallic FeAl phase in Fe/Al/Al2 O3 powder mixtures caused by mechanical alloying was detected. Chemical reactions of Fe and Al particle surfaces with the atmosphere and the milling media lead to the formation of highly porous hydroxides on the particle surfaces. Hence the specific surface area of the powders increases, while the powder density decreases during milling. The fraction of Fe oxidized during milling was determined to be 0.13. The fraction of Al oxidized during milling strongly depends on the metal content of the powder mixture. It ranges between 0.4 and 0.8. 相似文献
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Sintering kinetics of the system Si3 N4-Y2O3 -Al2 O3 were determined from measurements of the linear shrinkage of pressed disks sintered isothermally at 1500° to 1700°C. Amorphous and crystalline Si3 N4 were studied with additions of 4 to 17 wt% Y2 O3 and 4 wt% A12 O3 . Sintering occurs by a liquid-phase mechanism in which the kinetics exhibit the three stages predicted by Kingery's model. However, the rates during the second stage of the process are higher for all compositions than predicted by the model. X-ray data show the presence of several transient phases which, with sufficient heating, disappear leaving mixtures of β ' -Si3 N4 and glass or β '-Si3 N4 , α '-Si3 N4 , and glass. The compositions and amounts of the residual glassy phases are estimated. 相似文献
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Akira Akimoto 《Polymer》1974,15(4):216-218
The polymerization of vinyl chloride has been investigated using an catalyst system in the presence of various Lewis bases. Effective Lewis bases are γ-butyrolactone, diglyme and diethylenetriamine which are multidentate. The rate of polymerization is dependent not only on the basicity of the Lewis base used but also on a coordination number of one. The latter is the predominant factor. For the effect of polymeric amines, a tentative hypothesis is discussed. 相似文献
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Mats Carlsson Mats Johnsson Mats Nygren 《Journal of the American Ceramic Society》1999,82(8):1969-1976
Ta0.33 Ti0.33 Nb0.33 C and Ta0.33 Ti0.33 Nb0.33 C x N1− x whiskers were synthesized via a carbothermal vapor-liquid-solid growth mechanism in the temperature range 900°-1450°C in Ar or N2 . The optimum temperature was 1250°C. Whiskers were obtained in a yield of 70-90 vol%. The whiskers were 0.5–1 µm in diameter and 10–30 µm in length. The starting materials that produced the highest whisker yield were: TiO2 , Ta2 O5 , Nb2 O5 , C, Ni, and NaCl. C was added to reduce the oxides, and Ni to catalyze whisker growth. NaCl was used as a source of Cl for vapor-phase transportation of Ta and Nb oxochlorides and Ti chlorides to the catalyst. The catalyst metal was recycled several times during the synthesis and was transported as NiCl2 ( g ) according to thermodynamic calculations. The rate of formation and the chemical composition of the whiskers depended on the synthesis temperature, the choice of catalyst, and the atmosphere. At low temperatures, the whiskers were enriched in Nb and Ta, whereas the Ti content increased with increased synthesis temperature. 相似文献