Effect of hydrocolloids on gluten‐free batter properties and bread quality

The objectives of this study were to assess the effect of the addition of different hydrocolloids on gluten‐free batter properties and bread quality and to obtain information about the relationship between dough consistency and bread quality. Breads were made of rice, corn and soy flours and 158% water. Following hydrocolloids were added: carrageenan (C), alginate (Al), xanthan gum (XG), carboxymethylcellulose (CMC) and gelatine (Gel). Batter consistency, bread specific volume (SV), crumb analysis, crust colour, crumb hardness and staling rate were determined. Hydrocolloids increased batter consistencies: the highest value was obtained with XG, which doubled that of control batter, followed by CMC. Breads with hydrocolloid presented higher SV than control, especially with XG whose SV was 18.3% higher than that of control bread. A positive correlation was found between SV and batter consistency (r = 0.94; P < 0.05). Crumbs with Gel, XG and CMC presented higher cell average size. XG and CMC crumbs looked spongier. Breads containing hydrocolloid evidenced lighter crusts. Crumb firmness was decreased by XG and CMC addition, and staling rate was slower. Overall, XG was the hydrocolloid that most improved gluten‐free bread quality. These results show that, in formulations with high water content, batter consistency is strongly associated with bread volume.     

Application of decolourised hsian‐tsao leaf gum to low‐fat salad dressing model emulsions: a rheological study

The effects of mixed gums, including decolourised hsian‐tsao leaf gum (dHG) mixed with propylene glycol alginate (PGA) or xanthan gum (XG), and egg yolk concentration on the rheological properties of low‐fat salad dressing model emulsions were studied. All model emulsions showed pseudoplastic flow behaviour. Model emulsions with PGA addition showed the lowest pseudoplasticity, followed by those with dHG and then XG addition. Increasing the PGA level in the dHG/PGA system reduced the pseudoplasticity. Increasing the XG level in the dHG/XG system did not change the pseudoplasticity significantly but imparted a significant increase in viscosity. Dynamic viscoelasticity measurements indicated that model emulsions with dHG or XG addition could be classified as elastic gels. However, model emulsions with PGA addition essentially belonged to the class of either dilute or concentrated solutions rheologically, depending on the egg yolk concentration. The rheological characteristics of individual gums were found to be confounded in generating the rheological characteristics of model emulsions containing them. Copyright © 2004 Society of Chemical Industry     

Quality characteristics improvement of low‐phenylalanine toast bread

This study was designed to prepare and evaluate low‐phenylalanine toast bread made from gliadin‐free wheat flour and hydrocolloids. Wheat protein fraction (gliadin) rich in phenylalanine was extracted using aqueous alcohol solution for the production of low‐phenylalanine wheat flour. Pectin, gum arabic and carboxymethylcellulose (CMC) were used separately to improve the quality of bread at levels of 1, 2 and 3%. Chemical, rheological, organoleptic, baking, staling and microstructure of bread were studied. Phenylalanine content of gliadin‐free bread samples reduced by 43.2% compared with control. Separation of gliadin negatively affected the rheological properties of dough and baking quality of bread, while rheological properties, baking quality and staling were improved upon hydrocolloids addition. Microscopic examination of crumb structure revealed remarkable differences in control and treated breads. It was found that acceptable bread could be produced using gliadin‐free wheat flour with the addition of pectin or CMC up to 2 and 3%, respectively.     

Functional effects of xanthan gum on composite cassava-wheat dough and bread

The use of composite flour for bread making is gradually gaining prominence worldwide due to some economic and nutritional reasons. However, studies on the application of functional ingredients purposely to improve composite bread quality are very few. This paper examines the functional role of xanthan gum (XG) on the properties of dough and bread from composite cassava-wheat flour. The viscoelastic properties of dough and gas retention characteristics of batter as well as the fresh and storage properties of bread from the composite flour (90% wheat plus 10% cassava) were studied. The crumb cell structure was also studied using digital image analysis technique. Inclusion of XG had significant effects on the dough tenacity and extensibility and sensory acceptability of fresh composite bread. The oven spring, specific volumes of bread loaf and crumb softness were higher at 1% XG content. Also, addition of XG made the composite bread samples had more open crumb structure and better sensory acceptability. However, moisture loss and crumb firming during bread storage were best reduced when 1% XG was added to bread formulation.     

Effects of methylcellulose,xanthan gum and carboxymethylcellulose on thermal properties of batter systems formulated with different flour combinations

The functionalities of hydrocolloid–flour mixtures in terms of the thermal properties of their resulting batter systems were investigated, and the effects of different thermal processes such as cooking–freezing–thawing (CFT) and freezing–cooking (FC) on thermal properties of the various batter systems were determined in this study. Differential scanning calorimetry (DSC) was used to determine thermal property parameters including gelatinization temperature (T_G), total enthalpies of gelatinization (ΔH_G), glass transition temperature (T_g), melting peak temperature (T_m), and total melting enthalpies (ΔH_m). The different thermal processes did not significantly affect either T_G or ΔH_G of batter systems, but they influenced the glass transition behavior and the ΔH_m of batter systems. The thermal processes also showed different effects on the batter systems containing different hydrocolloids such as methylcellulose (MC), carboxymethylcellulose (CMC), and xanthan gum (XG). The hydrocolloids shifted T_G upwards, depressed T_g, and increased T_m of batters. The effect of these hydrocolloids on glass transition temperature was more pronounced in raw samples (FC process) than in cooked samples and increased with increasing levels of CMC and MC used in the formulations. Batters with MC showed increased ΔH_m for all the thermal processes. CMC only showed significant effect on ΔH_m for cooked samples (CFT process). MC and CMC showed more pronounced effects on T_g for raw uncooked rice- and corn flour-based batters than on raw uncooked wheat flour-based batters. However, this special effect was not obvious in the batters containing 0.2% XG.     

Incorporation of several additives into gluten free breads: Effect on dough properties and bread quality

The objective of this work was to assess the effect of emulsifiers, hydrocolloids and enzymes on gluten-free dough rheology and thermal properties and bread quality, while relating dough properties parameters to bread technological quality. Breads were based on rice flour, cassava starch and full-fat active soy flour, with 65% or 75% (flour-starch basis) of water incorporation. Additives used were emulsifiers (diacetyl tartaric acid ester of monoglycerides – DATEM and sodium stearoyl lactylate – SSL), enzymes (glucose oxidase and α-amylase) and hydrocolloids (xanthan gum, carboxymethylcellulose, alginate and carrageenan). Results showed that additive incorporation modified dough behavior, evidenced by different calorimetric and rheological properties. Besides, the electrophoretic pattern of dough extracted proteins changed with glucose oxidase addition. These modifications resulted in breads with different characteristics, such as specific volume, firmness and firming rate, and crumb structure. Nonetheless, they did not necessarily show better quality parameters than the control bread. The control dough displayed good performance for obtaining gluten-free breads of acceptable volume, crumb structure and, principally, with lower hardening rate during storage. Contrary to widespread opinion, this work shows that the presence of additives is not essential for gluten-free bread production. This fact provides new perspectives to the gluten free market at the moment of selecting raw materials and technological parameters, reducing production costs and facilitating gluten free products development.     

Effect of common and new gums on the quality,physical, and textural properties of bakery products: A review

Hydrocolloids (gums) have a good functional characteristic such as emulsifying, gelling, solubility, and textural improvement. In the bakery products, hydrocolloids were used to improving dough performance, bread and cake characteristics, sensorial quality, and extension the products shelf life. Several studies reported the potential use of hydrocolloids in breads, biscuits, cakes, and pasta formulation. The present review summarized the effect of the most common and new hydrocolloids (xanthan, guar, Arabic, carrageenan, karaya, alginate, acacia, methylcellulose, carboxy methyl cellulose, hydroxyl propyl methyl cellulose, locust bean, balangu seed, wild sage seed, basil seed, and cress seed gums) on the rheological, physicochemical, textural, and quality characteristics of bakery products. Gums addition improved volume and porosity of the breads and cakes. Gums influence on the gelatinization and retrogradation of starch and decreased the retrogradation of starch. In the bakery products, hydrocolloids were used to improving mixing and increasing the shelf life of the products through moisture preservation and avoidance of syneresis in some frozen foods. This study summarized the influence of the most common and new hydrocolloids on the rheological, physicochemical, textural, and quality characteristics of bakery products. Addition of seeds gum to the breads, biscuits, cakes, and pasta formula led to an increase in the viscosity of the batter. Also, the firmness of bakery products showed that they became softer with increasing gum levels.     

Rheological Properties of Solutions and Emulsions Stabilized with Xanthan Gum and Propylene Glycol Alginate

The rheological effects of propylene glycol alginate (PGA) added to solutions and model emulsions containing xanthan gum (XG) were studied using controlled stress rheometry with concentrations appropriate for salad dressings. For samples with XG and XG + PGA blends, solutions and emulsions showed a Newtonian plateau at low shear stresses. The Newtonian plateau of a solution accurately predicted (r²= 1.00) the Newtonian plateau for an emulsion of equivalent gum concentration. Addition of PGA to constant levels of XG showed a more than additive increase in the Newtonian plateau viscosity for solutions and emulsions. For XG aqueous solutions, pseudoplasticity decreased upon addition of PGA. Storage and loss moduli increased with addition of PGA to XG for solutions and emulsions, although G’ for solutions of PGA alone were negligible.     

Rheological properties of batter systems containing different combinations of flours and hydrocolloids

The rheological properties of batters formulated using different combinations of wheat, corn, and rice flours with two types of hydrocolloids, namely methylcellulose (0.5%, 1% and 1.5%) or xanthan gum (0.2%), were studied. Control samples were formulated with combinations of flours without the added hydrocolloids. The effects of hydrocolloids on rheological characteristics of the batter systems were measured using a controlled stress rheometer at a temperature of 15 °C. The effects of hydrocolloids on dynamic viscoelastic parameters as functions of temperatures were evaluated. All the batters showed shear thinning behaviour with flow behaviour indices in the range 0.34–0.67. Addition of xanthan gum lowered the flow index values, imparting a higher degree of pseudoplasticity to the batter samples compared to methylcellulose. The consistency index of the control batter samples varied from 0.46 to 69.2 Pa sⁿ. Addition of xanthan gum or methylcellulose significantly increased the batter consistency index value. The gums changed the onset temperature of structure development, and the storage (G′_max) and loss moduli (G″_max) of the batter systems. However, no statistically significant effects were observed on the peak temperature of batter systems in which the G′ reached a maximum value. Xanthan gum increased both G′_max and G″_max, whereas at higher concentrations methylcellulose increased G′_max but lowered G″_max. Copyright © 2007 Society of Chemical Industry     

Physical properties of breads containing hydrocolloids stored at low temperature. I. Effect of chilling

Different bread types, some of them containing also hydrocolloid stabilizers, were cold stored for evaluating the final quality of breads after storage. Dough (DB), semi-baked products (SB) and full-baked (FB) breads were used. After storage their physical characteristics were measured, data grouping was performed using PCA analysis and correlations among the properties measured were found. Fresh samples presented some similarities to DB or SB breads, but FB breads had a completely different behaviour. Crust characteristics were found to be important for the quality characterization of breads, as crust textural characteristics; its colour and moisture content were correlated to other properties. Furthermore, crust viscoelastic characteristics gave an indication of bread staling. Porosity was the only physical property not correlated to other bread characteristics. Differences were noticed according to the bread type before storage and the hydrocolloid used, but the main differences were determined by the baking stage before storage. Furthermore, hydrocolloids addition could result in different final bread properties according to the baking stage before storage. The crumb of FB breads was relatively viscous despite of hydrocolloid addition. Hydrocolloids seem to be more effective as stabilizers in DB and SB breads.     

Batter rheology and bread texture of sorghum‐based gluten‐free formulations modified with native or pregelatinised cassava starch and α‐amylase

The influence of α‐amylase (0–0.3 U g^?1) on the crumb properties of gluten‐free sorghum batter and bread, respectively, was investigated. The formulations were modified using native or pregelatinised cassava starch (i.e. batter A – 17% pregelatinised starch, 83% sorghum, 100% water fwb; batter B – 17% native starch, 83% sorghum, 100% water fwb; and batter C – 30% native starch, 70% sorghum, 80% water fwb). The batters had solid viscoelastic character with the storage modulus predominant over the loss modulus. Storage moduli of batter A decreased with increasing angular frequency, whereas the moduli of batters B and C were independent from the angular frequency. Increasing enzyme concentration did not affect the loss factors of the batters. Batters’ resistance to deformation, from highest to lowest, followed the order C > A > B. Increasing enzyme concentration decreased crumb firmness, cohesiveness, springiness, resilience and chewiness but increased adhesiveness. Overall, breads containing native starch had better crumb properties (i.e. springier and less firm, chewy and adhesive) than breads containing pregelatinised starch.     

Impact of emulsifiers on the quality and rheological properties of gluten-free breads and batters

The effects of the emulsifiers lecithin (LC), di-acetyl tartaric ester of monoglycerides (DATEM), distilled monoglycerides (DM) or sodium stearoyl lactylate (SSL) were studied in a gluten-free (GF) batter and bread formulation. Three different levels, i.e. low, medium, and high, were evaluated and compared to a control bread with no emulsifier. The rheological properties of the emulsifiers at their optimum level as well as their effect on starch retrogradation were investigated. Standard baking tests were carried out and the breads were tested over 5 days of storage. Rheological tests suggested that LC reduced the elasticity of the batter and increased the batter consistency during gelatinisation (P < 0.05). A significant increase in the specific volume was found with the addition of the various emulsifiers (P < 0.05). Higher volumes were found for breads with DM whereas lower specific volumes were obtained for the breads with DATEM. With regards to cell size and distribution, significant differences were found across the emulsifiers and the levels used (P < 0.05). Crumb staling revealed significant time effects as well as an increase in the shelf-life by the addition of high levels of DM and SSL. The retrogradation of starch over 5-days did not seem to be affected by the addition of emulsifiers. Overall this study demonstrated that the addition of emulsifiers at their respective optimum level enhanced the quality of the GF breads.     

Physical properties of breads containing hydrocolloids stored at low temperature: II—Effect of freezing

Bread types such as dough samples (DB), semi-baked (SB) and full-baked (FB) breads were frozen stored for a week and further baked (DB or SB). Structure stabilizers such as xanthan (X), hydroxypropylmethylcellulose (HPMC), guar gum (GG) or locust bean gum (LB) were also added to the dough. Baking stage is important for bread quality after storage; additionally hydrocolloids provide stability in many frozen foods. Fresh bread samples were prepared for comparison. Yield in baked product, dough characteristics, specific volume, porosity, textural properties of both crumb/crust, moisture content of crumb/crust and finally crust thickness and colour were measured. Data grouping was performed using PCA analysis and correlations among the properties measured were found. X and LB addition resulted in the most stable dough, since strength and dough extensibility change during storage was low. Hydrocolloid stabilizers’ (HS) influence on final bread characteristics was more pronounced in DB and SB breads. Crust moisture content was higher in SB breads, and it reached values 11–19% higher in control and galactomannan-containing breads than in DB respective samples. Bread specific volume was highly correlated to the crumb moisture content, to the crumb/crust textural characteristics and to the yield in the baked product. It was not correlated to crust moisture content and thickness. Porosity and bread colour were not correlated to any of the other properties. Bread type and HS selection are important factors for improving stability during storage.     

Physicochemical and nutritional properties of reduced-caloric density high-fibre breads

The influence of some physicochemical properties (chemical and nutritional composition, particle size, colour, dynamic viscosity, viscoelastic moduli) of associated binary mixtures of structuring hydrocolloids (cellulose derivatives, galactomannans) and prebiotic oligosaccharides (fructo- and gluco-oligosaccharides) in diluted hydrated wheat flour matrixes is discussed in terms of nutritional (higher resistant starch, lower digestible starch and lower in vitro Glycaemic Index) and technological functional profiles (higher sensory scores and longer keepability) of reduced-caloric density (−20%) high-fibre (>6 g/100 g) breads. Few technological functional (sensory firmness and overall acceptability) and most nutritional bread properties (protein digestibility, rapidly digestible starch, slowly digestible starch, in vitro expected Glycaemic Index, total digestible starch and resistant starch) were found to depend on dietary fibre molecular characteristics (mean particle diameter (D[4, 3]), storage modulus (G′), loss modulus (G″), complex viscosity (η*), and lactic acid solvent retention capacity. Dietary fibres with larger particle size resulted in highly sensory acceptable breads with higher amounts of resistant starch and slightly lower protein digestibility. Fibres exhibiting high viscoelasticity -G′, G″- and complex viscosity -η*- in concentrated solutions yielded breads with better sensory perception, lower digestible starch and higher resistant starch contents bringing to lower in vitro expected Glycaemic Index.     

Evaluation of the effects of fat replacers on the quality of wheat bread

The performance of different fat replacers at various levels (Inulin powder, Inulin gel and Simplesse) in wheat bread and dough compared to a control containing block fat was examined. Empirical and fundamental rheological tests were carried out on the doughs. Volume yield, crumb texture, crust colour and crumb image characteristics were measured for the baked loaves. The addition of inulin gel was found to increase water absorption. Dough complex modulus for doughs containing fat was significantly lower (P<0.01) than the doughs containing the replacers. The addition of simplesse and inulin increased the complex modulus (P<0.01). Loaves containing the control fat and inulin gel had similar volume yields, significantly higher (P<0.01) than loaves containing simplesse or inulin powder. Inulin powder and simplesse had adverse effects on crumb hardness, producing slices significantly harder (P<0.01) than slices with the control fat or inulin gel. Overall it was found that breads containing the inulin gel were similar in quality characteristics to the control breads containing fat.     

Gelatinization and rheological properties of rice starch/xanthan mixtures: Effects of molecular weight of xanthan and different salts

Effects of molecular weight (M_w) of xanthan (XG) and salts (0.1 M NaCl or CaCl₂) on the pasting, thermal, and rheological properties of rice starch (RS) were studied. A series of five XG samples, having various M_w, was prepared by homogenization of native XG solutions in the presence or absence of salts. The presence of salts greatly reduced the intrinsic viscosities, [η], of all XG solutions. Rapid visco-analysis (RVA) data showed that XG addition increased the peak, breakdown, final, and setback viscosities of RS, either in the presence or absence of salts, whereas the pasting temperatures were unaffected. Differential scanning calorimetry (DSC) demonstrated that the gelatinization temperatures of RS were unaffected by XG addition but slightly increased by CaCl₂ addition, whereas the gelatinization enthalpies (ΔH) were significantly decreased by additions of XG and salts. Dynamic shear data revealed weak gel-like behaviour in all paste samples in which their rigidity was decreased by XG addition. Flow tests showed that all pastes exhibited time-dependent shear-thinning (thixotropic) with yield stress behaviour in which the hysteresis loop areas were significantly decreased by XG addition, whereas the other rheological parameters varied differently among the samples, with and without added salt. In general, the effects of XG addition on the pasting and rheological properties of RS were more pronounced with increasing M_w of XG and these effects depended on salts added.     

Extensional flow,viscoelasticity and baking performance of gluten-free zein-starch doughs supplemented with hydrocolloids

Viscoelastic doughs of zein and starch were prepared at 40 °C, above the glass transition temperature of zein. The effects of hydrocolloid supplementation with hydroxypropyl methylcellulose (HPMC) or oat bran with a high content of β-glucan (28%) were investigated by dynamic measurements in shear, confocal laser scanning microscopy (CLSM) and Hyperbolic Contraction Flow. Zein-starch dough without hydrocolloids exhibited rapid age-related stiffening, believed to be caused by cross-links between peptide chains. A prolonged softness was attributed to doughs containing hydrocolloids, with the oat bran exhibiting the most pronounced reduction in age-related stiffening. Moreover, CLSM-images of dough microstructure revealed that a finer fibre network may be formed by increased shearing through an addition of viscosity-increasing hydrocolloids, a reduction in water content in the dough or the use of appropriate mixing equipment. The Hyperbolic Contraction Flow measurements showed that doughs containing hydrocolloids had high extensional viscosities and strain hardening, suggesting appropriate rheological properties for bread making. Zein-starch dough without hydrocolloids showed poor bread making performance while hydrocolloid additions significantly improved bread volume and height. Although the hydrocolloid supplemented doughs had similar extensional rheological properties and microstructures, a fine crumb structure was attributed only to bread containing HPMC, marking the importance of surface active components in the liquid-gas interface of dough bubble walls. Zein could not mimic the properties of gluten on its own, but hydrocolloids did positively affect the structural and rheological properties of zein, which yielded dough similar to wheat dough and bread with increased volume.     

Effect of hydrocolloids and emulsifiers on the rheological,microstructural and quality characteristics of eggless cake

Effect of hydrocolloids like Arabic (AR), guar (GR), xanthan (XN), carrageenan (CG) and hydroxypropylmethylcellulose (HPMC) in combination with emulsifiers such as glycerol monostearate (GMS) and sodium stearoyl-2-lactylate (SSL) on the rheological, microstructural and quality characteristics of eggless cake was studied. Addition of GR to wheat flour in the presence of SSL increased peak viscosity, while in the presence of GMS all hydrocolloids excepting XN increased the peak viscosity. The set back value decreased with the addition of hydrocolloids. Addition of hydrocolloids to wheat flour as well as in the presence of GMS and SSL increased the eggless cake batter viscosity, specific gravity, and XN showed the highest value. Among different hydrocolloids tried, only HPMC improved the eggless cake making characteristics of wheat flour. Use of HPMC increased the overall quality score of eggless cake with GMS to the maximum extent followed in decreasing order by CG and XN. Addition of all the hydrocolloids increased the overall quality of eggless cake with SSL and highest improvement was brought about by HPMC. Microstructure studies of eggless cake crumb with hydrocolloids showed that the starch granules appeared wrapped by XN and HPMC. In eggless cake with combination of HPMC and SSL the protein matrix appeared more uniform.     

Mouthfeel and flavour of fermented whey with added hydrocolloids

High-methoxy pectin (HMP), propylene glycol alginate (PGA), carboxymethyl cellulose (CMC) and xanthan gum (XG) were added separately to whey fermented by a yoghurt starter culture at concentrations that yielded a viscosity similar to that of commercial fermented milk beverages. Mouthfeel and flavour of the samples were assessed by a highly trained panel, and volatile analysis was performed by proton-transfer reaction mass spectrometry to determine the effect of hydrocolloids on the partition of flavour compounds in the headspace. CMC and HMP produced significantly higher thickness than PGA and XG; PGA caused a ‘gritty’ mouthfeel. The yoghurt aroma of the samples containing CMC and PGA was perceived as less intense compared with the control, consistent with a reduced concentration of key volatile compounds in the headspace of these samples.     

Gluten-Free Bread Making Trials from Cassava (Manihot Esculenta Crantz) Flour and Sensory Evaluation of the Final Product

The aim of this work was to evaluate the effectiveness of the use of cassava flour in bread making, and the sensory acceptability of the final product. Different baking trials were carried out by using egg white and extra-virgin olive oil, in consideration of their high nutritional value with respect to other food additives (i.e., hydrocolloids). Significant (p < 0.05) improvements of loaf specific volume (from 2.24 to 3.93 mL/g) and crumb firmness (from 9.14 to 4.67 N) were achieved by contemporarily including egg white and extra-virgin olive oil in the formulation. Cassava breads containing both these ingredients obtained the best scores from panelists for all the test breads examined and resulted attractive as the wheat bread prepared as reference.