Thermo-mechanical treatments of Sc- and Mg-modified Al–Cu alloy welds

High-strength heat-treatable aluminum alloy AA2219 finds application in aerospace industries. Though it has good weldability, with alternating current–tungsten inert gas welding, the joint efficiency obtained is only 40%, particularly in thicker plates. In the present study, an attempt has been made to improve the weld metal properties by modifying the chemistry of fusion zone and post-weld thermo-mechanical treatments. Fillers were made through casting route by melting conventional 2319 filler with Sc and Mg. Two levels of Sc (0.3% and 0.6%) and four levels of Mg (0.3% to 0.6%) were varied. Compressive deformation was done on the fusion zone of the weld to get three levels of percentage of reduction (4%, 8%, and 12%). As welded specimens and welds after compressive deformation, those were subjected to post-weld aging treatments at 190ºC for different periods up to 100 h. Compressive deformation on the welds made with modified filler of 2319 with Sc and Mg resulted in significant improvement in the weld metal strength.     

Microstructural evolvement and formation of selective laser melting W–Ni–Cu composite powder

W–Ni–Cu alloy (90 wt% W, 7.5 wt% Ni, and 2.5 wt% Cu) parts were successfully fabricated via selective laser melting method. Phases, microstructure, compositions, and laser forming parameters of laser melted samples were investigated. It was found that the W–Ni–Cu powder system was based on the mechanism of liquid solidification. This process was realized through full melting of W, Ni, and Cu particles under high laser energy input. However, using relatively lower energy input, particle bonding was realized through liquid phase sintering with complete melting of Ni–Cu acting as binder and nonmelting of W acting as structure. Due to the Ni–Cu solid solution phase that appeared in a wide range from 1,084 to 1,455 °C, a coherent matrix interface can be observed after solidification. The microhardness of laser-fabricated specimens varied with different powder layer thicknesses, resulting from the laser-treated condition and ability of trapped air in the loose powder bed to escape. The metallurgical mechanisms were also addressed.     

TEM and electron holography analyses of granular and thin layered Cu–Co magnetic materials

The paper shows the examples of application of transmission electron microscopy (TEM) techniques for characterization of two types of copper–cobalt magnetic nanomaterials: Cu-10 wt% Co granular giant magnetoresistance (GMR) thin ribbons and thin nanocrystalline Co films deposited on Cu substrate. Quantitative TEM microstructural analyses were used for determination of Co particle size distributions in GMR ribbons. It was demonstrated that the relative resistivity depends on the mean diameter of the cobalt nanoparticles. For nanocrystalline thin Co layers, off-axis electron holography was used to investigate their magnetic structure. The mean in-plane component of the magnetic field in cobalt was calculated from the phase gradient.     

The influence of Cu addition on precipitation in Fe–Cr–Ni–Al–(Cu) model alloys

Precipitation in Fe–Cr–Ni–Al–(Cu) model alloys was investigated after ageing for 0.25, 3, 10 and 100 h at 798 K. Characterization of nanoscale precipitates was performed using three-dimensional atom probe microscopy and transmission electron microscopy. The precipitates are found to be enriched in Ni and Al (Cu) and depleted in Fe and Cr. After 0.25 h of ageing the number density of precipitates is ∼8×10²⁴ m⁻³, their volume fraction is about 15.5% and they are near-spherical with an average diameter of about 2–3 nm. During further ageing the precipitates in the both alloys grow, but the coarsening behaviour is different for both alloys. The precipitates of the Cu-free alloy grow much faster compared with the Cu-containing alloy and their density decreases. Precipitates in Cu-free alloy change to plate shaped even after 10 h of ageing, whereas those of Cu-containing alloy remain spherical up to 10 h of ageing. The influence of Cu addition on precipitation in these model alloys is discussed with respect to the different coarsening mechanisms.     

Dry Sliding Friction and Wear Properties of Al–25Zn–3Cu–(0–5)Si Alloys in the As-Cast and Heat-Treated Conditions

Dry sliding friction and wear properties of ternary Al–25Zn–3Cu and quaternary Al–25Zn–3Cu–(1–5)Si alloys were investigated using a pin-on-disc test machine after examining their microstructures and mechanical properties. An alloy (Al–25Zn–3Cu–3Si), which exhibited the highest tensile and compressive strengths, was subjected to T7 heat treatment. Surface and subsurface of the wear samples were investigated using scanning electron microscopy (SEM). The hardness and both tensile and compressive strengths of the alloys increased with increasing silicon content, but the trend reversed for the latter ones above 3% Si. It was observed that T7 heat treatment reduced the hardness and both tensile and compressive strengths of the Al–25Zn–3Cu–3Si alloy, but increased its elongation to fracture greatly. Three distinct regions were observed underneath the surface of the wear samples of the Al–25Zn–3Cu–3Si alloy. The formation of these regions was related to the heavy deformation of surface material and mixing, oxidation and smearing of wear material. Al–25Zn-based ternary and quaternary alloys in both as-cast and heat-treated conditions were found to be superior to SAE 660 bronze as far as their mechanical and dry sliding wear properties are concerned.     

Experimental and theoretical analysis of friction stir welding of Al–Cu joints

This paper presents a study of friction stir welding of aluminium and copper using experimental work and theoretical modelling. The 5083-H116 aluminium alloy and pure copper were successfully friction-stir-welded by offsetting the pin to the aluminium side and controlling the FSW parameters. A theoretical analysis is presented along with key findings. The process temperatures are predicted analytically using the inverse heat transfer method and correlated with experimental measurements. The temperature distribution in the immediate surroundings of the weld zone is investigated together with the microstructures and mechanical properties of the joint. This was supported by a finite element analysis using COMSOL Multiphysics. In this study, two rotational speeds were used and a range of offsets was applied to the pin. The microstructure analysis of the joints was undertaken. This revealed some particles of Cu inclusion in the nugget zone. The energy dispersive spectroscopy showed a higher diffusion rate of aluminium towards the interface while copper maintained a straight base line.     

Effects of cold working and heat treatment on microstructure and wear behaviour of Cu–Be alloy C17200

The effects of cold work process between aging and solution heat treatment on the microstructure, hardness and the tribologic behaviour of a copper–beryllium (Cu–Be) alloy C17200 were investigated. The wear behaviour of the alloys was studied using ‘pin on disc’ method under dry conditions. The results show that the formation of fine grained structure and γ phase particles enhances the mechanical properties of the alloy; nonetheless, they do not reduce the wear rate. This is attributed to the capability of the softer specimens to maintain oxygen rich compounds during the dry sliding test.     

Electrical and electrochemical properties of the MEH–PPV and MEH–PPV doped calix[4]arene derivative layers for the detection of Cu and Na ions

A modified ITO electrode based on conducting polymer (MEH–PPV) matrix doped with the calix[4]arene molecules (β-ketoimine calix[4]arene) is deposited by spin coating. The carrier transport mechanism of the MEH–PPV and MEH–PPV:β-ketoiminecalix[4]arene films is investigated by using I–V characteristics measurements. The conduction mechanisms in these thin films are identified to be a space-charge-limited current (SCLC). The dielectric behavior of the MEH–PPV and the composite β-ketoimine calix[4]arene/MEH–PPV thin films are investigated by impedance spectroscopy (IS). The Cole–Cole plots are studied showing single semicircles and the solid interfaces are modeled by an equivalent circuit. The characteristics of chemical sensors based on MEH–PPV and MEH–PPV doped β-ketoimine calix[4]arene thin films for the detection of Cu²⁺ and Na⁺ ions are investigated by electrochemical impedance spectroscopy (EIS). The experimental impedance data of the modified electrodes are modeled by an equivalent circuit using the Z-View software. The inclusion of calixarene molecules into conducting polymer (MEH–PPV) exhibited considerable rise charge transfer resistance and improves sensing properties.     

Effects of Silicon Content on the Mechanical Properties and Lubricated Wear Behaviour of Al–40Zn–3Cu–(0–5)Si Alloys

In this work, one ternary Al–40Zn–3Cu and seven quaternary Al–40Zn–3Cu–(0.25–5)Si alloys were synthesized by permanent mould casting. Their microstructure, mechanical and lubricated wear properties were investigated using appropriate test apparatus and techniques. As the silicon content increased the hardness of the alloys increased, but their elongation to fracture decreased. Tensile strength of the alloys decreased with increasing silicon content following a sharp decrease and a slight increase. Among the silicon-containing quaternary alloys the highest and the lowest tensile strength values (348 and 305 MPa) were obtained with the Al–40Zn–3Cu–2Si and Al–40Zn–3Cu–5Si alloys, respectively, while the base alloy (Al–40Zn–3Cu) exhibited a tensile strength of 390 MPa. However, the volume loss due to wear of the alloys increased with increasing silicon content after showing an initial increase and a sharp decrease. The lowest wear loss was obtained with the alloy containing approximately 2% Si which has the highest tensile strength among the quaternary alloys containing more than 0.25% Si. Wear surfaces of the alloys were characterized mainly by smearing indicating that adhesion is the dominant wear mechanism for the experimental alloys.     

The Microstructure and Wear Characteristics of Cu–Fe Matrix Friction Material with Addition of SiC

The Cu–Fe matrix continuous braking friction materials using SiC as abrasive were fabricated by powder metallurgy technique, and the effect of content and size of SiC were investigated. The tribological properties of friction materials sliding against AISI 1045 steel ring were carried out on a block-on-ring tester at different loads and sliding speeds. The strengthening effect of nano-SiC (55 nm) was superior to that of micro-SiC (70 μm) of the tribological properties for friction materials. The friction coefficients of friction materials increased with increasing nano-SiC content. However, the wear rates decreased with increasing nano-SiC content and then increased when the content of nano-SiC particle exceeded 10 wt%. The specimen contained 10% nano-SiC had the best tribological properties at different testing conditions.     

Multi-response optimization of EDM with Al–Cu–Si–TiC P/M composite electrode

The present study investigates the relationship of process parameters in electro-discharge of CK45 steel with novel tool electrode material such as Al–Cu–Si–TiC composite produced using powder metallurgy (P/M) technique. The central composite second-order rotatable design had been utilized to plan the experiments, and response surface methodology (RSM) was employed for developing experimental models. Analysis on machining characteristics of electrical discharge machining (EDM) die sinking was made based on the developed models. In this study, titanium carbide percent (TiC%), peak current, dielectric flushing pressure, and pulse on-time are considered as input process parameters. The process performances such as material removal rate (MRR) and tool wear rate (TWR) were evaluated. Analysis of variance test had also been carried out to check the adequacy of the developed regression models. Al–Cu–Si–TiC P/M electrodes are found to be more sensitive to peak current and pulse on-time than conventional electrodes. The observed optimal process parameter settings based on composite desirability are TiC percent of 18%, peak current of 6 A, flushing pressure of 1.2 MPa, and pulse on-time of 182 μs for achieving maximum MRR and minimum TWR; finally, the results were experimentally verified. A good agreement is observed between the results based on the RSM model and the actual experimental observations. The error between experimental and predicted values at the optimal combination of parameter settings for MRR and TWR lie within 7.2% and 4.74%, respectively.     

Tribological Properties of a C/C–SiC–Cu Composite Brake Disc

A life-size composite brake disc was produced from Si, carbon–carbon composite, copper, and phenol resin. The disc had an outer radius Ø380, inner radius Ø180, and thickness of 36 mm. Chopped carbon fibers were used to reinforce frictional and structural layers. To obtain a preform of each layer, resin and carbon-fibers were mixed and hot-pressed. The preforms were pyrolyzed, and bonded by hot pressing. Finally Si and Cu infiltration in vacuum atmosphere was carried out to obtain a C/C–SiC–Cu _x Si _y composite brake disc. The density of the disc was 2.17 g/cm³. The bending strength was 61 MPa. The heat transfer coefficients in vertical and horizontal directions were 30.7, and 85.2 W/m-°C at 25°C, respectively. Friction coefficients of the C/C–SiC–Cu _x Si _y brake disc were more stable than those of C/C–SiC brake discs. X-ray diffraction analysis showed that Cu formed a compound, Cu₃Si.     

Improving Dynamic and Tribological Behaviours by Means of a Mn–Cu Damping Alloy with Grooved Surface Features

In this work, the effect of the damping component with/without individual grooved surface features on the friction-induced vibration and noise (FIVN) and surface wear performance is studied experimentally and numerically. The experimental results show that introducing a grooved damping component in the system has a significantly improved capability in suppressing the generation of FIVN. In addition, it is observed that the friction system with a grooved damping component suffers slighter wear. Numerical results show good agreement with the FIVN events observed in the experimental test. Through analysing the deformation behaviour of damping component and the contact behaviour of the friction system during friction process, it is speculated that the deformation behaviour of damping component plays a significant role in affecting the contact pressure and FIVN behaviour. In addition, linking the vibration performance and wear evolution, the connection between damping, and vibration and wear behaviour is discovered, which can further explain why the friction system with a grooved damping component shows improved capability in suppressing the FIVN of friction system.     

Sliding friction and wear of Cu–graphite against 2024, AZ91D and Ti6Al4V at different speeds

Cu–graphite composite fabricated by powder metallurgy art is no longer novel material. However, it might be a versatile self-lubricating material sliding against different metals and alloys. In this connection, understanding towards its tribological behavior and wear mechanism is very important. Sliding tribological behaviors of Cu–graphite composite against different counterparts, specified as 2024 aluminium alloy, AZ91D magnesium alloy, and Ti6Al4V titanium alloy, were investigated over varied sliding speeds at room temperature in air. The friction and wear tests were conducted on a pin-on-disk tribo-meter. Tribological performance of Cu–graphite composite strongly depended on its counterpart materials. Cu–graphite composite could provide friction reduction in sliding against 2024 and Ti6Al4V. Cu–graphite composite was a good self-lubricating material in sliding against AZ91D at low speeds but not at 0.25 and 0.50 m/s. Wear mechanism of Cu–Gr composite was related to the transfer, counter-transfer, mechanical mixing and tribo-oxidation at tribo-interface. Sliding speed had influences on tribo-interface and thereby wear mechanism. Finally, the effects of naturally occurred oxide film and sliding speed were discussed.     

Influence of matrix hardness on honing engine cylinder liner with Cu–Sn–Fe–Ni diamond stones

In this work, three Cu–Sn–Fe–Ni matrices with different hardness were utilized in the diamond honing stones. Structures of the three matrices were investigated by X-ray diffraction, energy dispersive spectroscopy and scanning electron microscopy, and the results showed that the Cu–Sn–Fe–Ni matrices were composed of the pure copper, pure iron and (Cu, Ni)₄₁Sn₁₁. The wear properties of the matrices were estimated by a pin-on-disk wear machine under dry conditions at room temperature in the air. The influences of hardness on the honing performances were studied in terms of the honed surface aspect, the honing efficiency and the throughput of cylinder liners. Among the three stones, the stone with matrix B (HRB 71) reaches the self-sharpening range in terms of the three aspects mentioned above. Compared this stone with a commercially available product, the former has better honing efficiency.     

Wear analysis of Cu–Al coating on Ti–6Al–4V substrate under fretting condition

Fretting behavior of Cu–Al coating on Ti–6Al–4V substrate was investigated with and without fatigue load. Soft and rough Cu–Al coating resulted in abrasive wear and a large amount of debris remained at the contact surface, which caused an increase in tangential force during the fretting test under gross slip condition. Fretting in the partial slip condition also showed the wear of coating. To characterize wear, dissipated energies during fretting were calculated from fretting loops and wear volumes were obtained from worn surface profiles. Energy approach of wear analysis showed a linear relationship between wear volume and accumulated dissipated energy. This relationship was independent of fatigue loading condition and extended from partial slip to gross slip regimes. As an alternate but simple approach for wear analysis, accumulated relative displacement range was correlated with the wear volume. This also resulted in a linear relationship as in the case of accumulated dissipated energy suggesting that the accumulated relative displacement range can be used as an alternative parameter for dissipated energy to characterize the wear. When the maximum wear depth was equal to the thickness of Cu–Al coating, harder Ti–6Al–4V substrate inhibited further increase in wear depth. Only when a considerable energy was supplied through a large value of the applied displacement, wear in the substrate material could occur beyond the thickness of coating.     

Influence of valence electron concentration over the friction behaviors of quasicrystal and B2‐type approximants in Al–Cu–Fe ternary system

Quasicrystals and their approximants are Hume–Rothery compounds having similar valence electron concentration. According to the valence electron concentration criterion for approximants, some B2 superstructures can be regarded as a special group of approximants. The present paper reports on an investigation of dry friction behavior of this group of phases. The results are compared with the data from quasicrystalline and related crystalline phases with similar composition. Specifically, we show that samples containing the B2 structure and its superstructures exhibit friction coefficients that decrease with increasing e/a and reach a minimum at 1.86, the value of the quasicrystal. Therefore, quasicrystals and B2‐based approximants belong to one group of phases whose surface properties are mainly determined by electronic structure characteristics rather than crystal structures. This revised version was published online in July 2006 with corrections to the Cover Date.     

EDM of hybrid Al–SiCp–B4Cp and Al–SiCp–Glassp MMCs

Hybrid metal matrix composites are a class of material system, with two or more discrete particulate reinforcement. Notwithstanding their superior properties, their widespread application is constrained by the difficulty in machining them. Non-conventional processes such as electrical discharge machining can be applied to machine such composites. This work reports on the application of EDM to machine cast aluminum–silicon carbide–boron carbide and cast aluminum–silicon carbide–glass hybrid metal matrix composites and how the metal removal rate and surface finish vary in response to the various EDM parameters     

Effect of Micro-scale Y Addition on the Fracture Properties of Al–Cu–Mn Alloy

Rare earth (RE) elements have positive effects on Al alloy, while most research is focused on microstructure and mechanical properties. As important application indices, toughness and plasticity are properties that are sensitive to alloy fracture characteristics, and few research studies have characterized the fracture properties of Al–Cu–Mn alloy on RE elements. The effect of different contents of Y on the fracture properties of Al–Cu–Mn alloy is investigated. T6 heat treatment (solid solution and artificial aging treatment), optical microscope (OM), scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS) methods are applied to the alloy. Results showed that when Y element is present at 0.1%, the section of the as-cast alloy has smaller sized dimples and the fracture mode presents ductile features. Slight changes in hardness are also observed and maintained at about 60 HV. With increasing content of the RE element Y from 0.1 to 0.5%, the θ phase and Cu atoms in the matrix were reduced and most stopped at Grain boundaries (GBs). Micro-segregation and an enriched zone of Y near the GBs gradually increased. At the same time, the inter-metallic compound AlCuY is aggregated at grain junctions causing deterioration of the micro-structure and fracture properties of the alloy. After T6 treatment, the flatness of the fracture surface was lower than that of all the as-cast alloy showing lots of dimples and teared edges with a significant increase in hardness. When Y content was 0.1%, the strength and hardness of the alloy increased due to refinement of the grain strengthening effect. The content of Y elements segregated in the inter-dendritic zone and GBs is reduced. Plasticity and deformation compatibility also improved, making cracks difficult to form and merge with each other along adjacent grain junctions and providing an increased potential for ductile fracture. This paper proposes the addition of RE Y as an effective and prospective strategy to improve the fracture properties of the Al–Cu–Mn alloy and provide a meaningful reference in terms of improving overall performance.     

Correlation Between Mechanical Properties and Nanofriction of [Ti–Cr/Ti–Cr–N] n and [Ti–Al/Ti–Al–N] n Multilayers

In this work, thin films deposited by pulsed DC magnetron sputtering of [Ti–Al/Ti–Al–N] _n and [Ti–Cr/Ti–Cr–N] _n multilayers of nanometric periods were analyzed by AFM in contact mode to measure values of lateral and normal forces. From these measurements, the coefficient of friction (COF) of these materials in contact with the AFM tip was calculated. Measurements were made with three types of silicon tips, diamond-coated, Pt–Cr-coated, and bare silicon. Significant differences between the tip materials in contact with the samples, which affected the COF, were observed. The effect of the environmental layer of water covering the surface sample and the tip appears as the most important factor affecting the tribology behavior of the tip-sample contact. For diamond-coated and bare silicon tips there is an additional adherence force increasing the normal load. But for tips platinum–chromium-coated there is a repulsive force due to this water layer, which behaves as a lubricant layer before a threshold load.