Linear and nonlinear optical properties of ZnGeP2 crystal for infrared laser device applications: revisited

Measurement of refractive indices in the spectral bands 9-11 microm and 1.32 microm from a cw CO2 laser and a Q-switched Nd:YAG laser, respectively, is reported in a ZnGeP2 crystal. A new set of Sellmeier dispersion relations has been derived from the measured refractive indices data in this crystal. Second-harmonic generation (SHG) of CO2 laser radiation in this crystal is also reported. It is also seen that the previously reported phase-matching data for others experiments in SHG and optical parametric devices is explained satisfactorily with this new set of Sellmeier dispersion relation.     

Nucleation and growth of catalyst-free zinc oxide nanostructures

This paper deals with the investigations on the nucleation and growth of Zinc Oxide (ZnO) nanostructures in a catalyst free synthesis. The ZnO nanostructures have been formed by evaporation of Zn (99.99%) in O2 and Ar atmosphere in single zone furnace under two temperature regions, region A (approximately 1173-1073 K) and region B (approximately 873-773 K). Through application of XRD and TEM techniques, it has been shown that first ZnO is formed which changes to ZnOx through creation of oxygen vacancies. The ZnOx acts as self-catalyst and leads to formation of various nanostructures. Those observed in the present investigation are nanotetrapods (1 D, diameter approximately 70-450 nm, length approximately 2-4.5 approximatelym) nanorods (1 D, diameter approximately 45-95 nm, length approximately 2.5-4.5 microm), nanoflowers(2D, central core diameter approximately 90-185 nm, length of petals/nanorod approximately 1.0-3.5 microm) and nanoparticles (3D, size approximately 0.85-2.5 microm). These nanostructures have been revealed by SEM explorations. Attempts have been made to explain the formation of the various nanostructures in terms of the creation and distribution of the ZnOx, the temperature as well as oxygenation conditions.     

Laser ablation coupled to a flowing atmospheric pressure afterglow for ambient mass spectral imaging

A plasma-based ambient desorption/ionization mass spectrometry (ADI-MS) source was used to perform molecular mass spectral imaging. A small amount of sample material was ablated by focusing 266 nm laser light onto a spot. The resulting aerosol was transferred by a nitrogen stream to the flowing afterglow of a helium atmospheric pressure glow discharge ionization source; the ionized sample material was analyzed by a Leco Unique time-of-flight mass spectrometer. Two-dimensional mass spectral images were generated by scanning the laser beam across a sample surface. The total analysis time for a 6 mm (2) surface, which is limited by the washout of the ablation chamber, was less than 30 min. With this technique, a spatial resolution of approximately 20 microm has been achieved. Additionally, the laser ablation configuration was used to obtain depth information of over 2 mm with a resolution of approximately 40 microm. The combination of laser ablation with the flowing atmospheric pressure afterglow source was used to analyze several sample surfaces for a wide variety of analytes and with high sensitivity (LOD of 5 fmol for caffeine).     

Difference Frequency Generation in AgGaS(2): Sellmeier and Temperature-Dispersion Equations

Two single-mode diode lasers and AgGaS(2) as a nonlinear medium are applied for difference frequency generation (DFG) in the mid-infrared spectral range between 4.9 and 6.5 mum. Phase matching is achieved by either temperature tuning or angle tuning of the crystal. Experimentally measured sets of input wavelengths lambda(s) and lambda(p), the resulting DFG wavelength lambda(i), and corresponding phase-matching temperatures or angles are compared with the calculated values derived by use of different Sellmeier equations and coefficients and temperature-dispersion equations dn/dT. Our results show that only specific combinations of previously published Sellmeier equations, coefficients, and temperature-dispersion equations are suitable for exact calculations of phase-matching parameters. These combinations reproduce our experimentally obtained phase-matching temperatures and angles with an accuracy of better than 5% and are therefore of fundamental interest for the design of a mid-infrared DFG spectrometer with AgGaS(2) as a nonlinear medium.     

Optical properties of Zitex in the infrared to submillimeter

The results of measurements of the refractive index and power attenuation coefficient of Zitex at 290, 77, and 4 K in the spectral region from 1 to 1000 microm are presented. Zitex is a porous Teflon sheet with a filling factor of approximately 50% and is manufactured in several varieties as a filter paper. Zitex is found to be an effective IR block, with thin (200-microm) sheets transmitting less than 1% in the 1-50-microm range while attenuating < or = 10% at wavelengths longer than 200 microm. Some variation in the cutoff wavelength is seen, tending to be a shorter-wavelength cutoff for a smaller pore size. In addition, the thermal conductivity of Zitex at cryogenic temperatures has been measured and is found to be roughly one half that of bulk Teflon. Finally, its dielectric constant has been measured in the submillimeter as n = 1.20, resulting in extremely low dielectric reflection losses. As a result, Zitex is particularly useful as an IR blocking filter in low-noise heterodyne receivers; in the millimeter-wave range (lambda > or = 850 microm or nu < or = 350 GHz) the attenuation of alpha < or = 0.01 cm(-1) for a 3.5-mm thickness filter of Zitex G125 would raise receiver noise temperatures by <1 K.     

Method for preparation of fine TATB (2-5 microm) and its evaluation in plastic bonded explosive (PBX) formulations

There is a need of fine 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) (2-5 microm) for various high explosive formulations to achieve desired mechanical strength, ease in processing and finally, provide better performance of end product. The reprecipitation method for TATB has been developed using concentrated sulfuric acid as a solvent. The reprecipitation parameters of TATB were optimized to achieve required fine TATB of particle size approximately 2-5 microm. The characteristic properties of fine TATB thus obtained have been confirmed by FTIR, DSC and TG-FTIR. The spectroscopic and thermal data obtained for fine TATB were compared with standard coarse TATB and found chemically unchanged during particle size reduction. In the present study, the preparation of fine TATB was also attempted using ultrasonication method. The fine (2-5 microm) TATB has been introduced to study in the bimodal high explosive formulations. High explosive formulations based on coarse (55 microm) and fine TATB ( approximately 2-5 microm) with 10% polyurethane were studied. It was observed that properties like bulk density (1.70 g/cm(3)), mechanical strength/compressed strength (115.9 mg/cm(2)), %elongation (6.36) were improved for fine TATB in comparison with coarse TATB ( approximately 55 microm) alone in high explosive formulations.     

Synthesis of zinc oxide nanotetrapods and nanorods by thermal evaporation without catalysis

ZnO nanotetrapods and nanorods have been synthesized by a simple thermal evaporation of Zn powder (300 mesh, 99.99% purity) under simultaneous flow of oxygen and argon gases in two-zone furnace in two different temperature regions. These ZnO nanostructures have hexagonal structure, which grow along the [001] direction in the form of nanotetrapods (diameter approximately 60-150 nm, length approximately 1-4 microm) and nanorods (diameter approximately 30-60 nm, length approximately 2-5 microm). The morphologies of these ZnO nanostructures have been investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It has been found that growth parameters like temperature, gas flow rate etc., control the diameter of the nanotetrapods and nanorods. These novel structures of ZnO nanorods and nanotetrapods may be attractive for optical and other nanodevices.     

Solid hydrogen Raman shifter for the mid-infrared range (4.4-8 microm)

We developed a pulsed, continuously tunable laboratory laser source for the mid-infrared spectral range of 4.4-8 microm, which is characterized by the spectral linewidth of 0.4 cm(-1). The device is based on the stimulated backward Raman scattering in solid para-hydrogen at T = 4 K. It is pumped by a focused beam obtained from a commercial near-infrared optical parametric oscillator with output energy of approximately 20 mJ (7-ns pulse). Output energies range from 1.7 mJ at 4.4 microm to 120 microJ at 8 microm, which correspond to quantum efficiencies of 0.53 and 0.08, respectively. Spectra of NO, H2O, and CH4 molecules in the mid-infrared were recorded. The operation of the Raman cell pumped with 532-nm radiation was also studied.     

In situ combustion measurements of CO with diode-laser absorption near 2.3 microm

In situ measurements of CO concentration were recorded with tunable diode-laser absorption spectroscopy techniques in both the exhaust and the immediate post-flame regions of an atmospheric-pressure flat-flame burner operating on ethylene air. Two room-temperature cw single-mode InGaAsSb/AlGaAsSb diode lasers operating near 2.3 microm were tuned over individual transitions in the CO first overtone band (v' = 2 <-- v" = 0) to record high-resolution absorption line shapes in the exhaust duct [79 cm above the burner, approximately 470 K; R(15) transition at 4311.96 cm(-1)] and the immediate postflame zone [1.5 cm above the burner, 1820-1975 K; R(30) transition at 4343.81 cm(-1)]. The CO concentration was determined from the measured absorption and the gas temperature, which was monitored with type-S thermocouples. For measurements in the exhaust duct, the noise-equivalent absorbance was approximately 3 x 10(-5) (50-kHz detection bandwidth, 50-sweep average, 0.1-s total measurement time), which corresponds to a CO detection limit of 1.5 ppm m at 470 K. Wavelength modulation spectroscopy techniques were used to improve the detection limit in the exhaust to approximately 0.1 ppm m (approximately 500-Hz detection bandwidth, 20-sweep average, 0.4-s total measurement time). For measurements in the immediate postflame zone, the measured CO concentrations in the fuel-rich flames were in good agreement with chemical equilibrium predictions. These experiments demonstrate the utility of diode-laser absorption sensors operating near 2.3 microm for in situ combustion emission monitoring and combustion diagnostics.     

Continuous-wave laser performance of Nd:LuVO4 crystal operating at 1.34 microm

A laser-diode-array end-pumped Nd:LuVO4 crystal continuous-wave (cw) laser operating at 1.34 microm has been demonstrated. The maximum cw output power of 1.85 W was obtained at the incident pump power of 17 W for a c-cut 0.5 at. % Nd-doped LuVO4 crystal sample, giving the corresponding optical conversion efficiency of 10.88% and a slope efficiency of 13.5%. Laser experiments of Nd3+ concentration of 0.5 and 0.9 at. % a-cut crystal LuVO4 samples were also investigated; due to the strong excited-state absorption of Nd:LuVO4 at 1.34 microm, the output power was limited.     

In-line broadband 270 degrees (3lambda/4) chevron four-reflection wave retarders

The net differential phase shift Delta(t) introduced between the orthogonal p and s linear polarizations after four successive total internal reflections inside an in-line chevron dual-Fresnel-rhomb retarder is a function of the first internal angle of incidence phi and prism refractive index n. Retardance of 3lambda/4 (i.e., Delta(t)=270 degrees) is achieved with minimum angular sensitivity when phi=45 degrees and n=1.900822. Several optical glasses with this refractive index are identified. For Schott glass SF66 the deviation of Delta(t) from 270 degrees is < or = 4 degrees over a wavelength range of 0.55 < or = lambda < or = 1.1 microm in the visible and near-IR spectrum. For a SiC prism, whose totally reflecting surfaces are coated with an optically thick MgF(2) film, Delta(t)=270 degrees at two wavelengths: lambda(1)=0.707 microm and lambda(2)=4.129 microm. This coated prism has a maximum retardance error of approximately 5 degrees over > three octaves (0.5 to 4.5 microm) in the visible, near-, and mid-IR spectral range. Another mid-IR 3lambda/4 retarder uses a Si prism, which is coated by an optically thick silicon oxynitride film of the proper composition, to achieve retardance that differs from 270 degrees by < 0.5 degrees over the 3-5 microm spectral range.     

Efficient continuous-wave radiatively cooled cr(4+):forsterite lasers at room temperature

Results of a detailed experimental investigation aimed at reducing the thermal loading problem in a cw Cr(4+):forsterite laser at elevated temperatures are presented. From a Cr(4+):forsterite crystal with a differential absorption coefficient of 0.57 cm(-1), as much as 900 mW of cw output power has been obtained at 1.26 mum and at a crystal boundary temperature of 15 degrees C with an absorbed pump power of only 4.5 W at 1.06 mum. No chopping of the pump beam was necessary. An efficient radiative cooling technique was further employed to cool the laser and no subsequent power fading was observed. To the author's knowledge, the measured absorbed power slope efficiency of 29.5% represents the highest cw power performance reported to date from a Cr(4+):forsterite laser pumped by a Nd:YAG laser around room temperature. The role of the low differential absorption coefficient in the reduction of thermal loading is further elucidated by presenting comparative cw power performance data with a second Cr(4+):forsterite crystal having a differential absorption coefficient of 1.78 cm(-1) in the temperature range between 12 and 35 degrees C. Finally, some interesting multipulse effects of the laser observed in the millisecond regime during quasi-cw operation at 50% duty cycle are described.     

Measurement of laser-induced refractive index change of inverted ferroelectric domain LiNbO3

Optical nonlinearities of periodically poled LiNbO(3) crystals were investigated by the single beam Z-scan technique with a continuous wave (cw) laser beam at 532 nm. The nonlinear optical absorption coefficient and refractive index change are determined to be 8.1 x 10(-6) cm/W and 2.6 x 10(-4) at 0.5 MW/cm(2) light intensity, respectively. Both sign and magnitude of the measured refractive nonlinearity are considerably different from the Z-scan results in congruent LiNbO(3). The nonlinearities in the periodically poled LiNbO(3) induced by 532 nm continuous waves are believed to be mainly due to the photorefractive effect.     

On-line multicomponent trace-gas analysis with a broadly tunable pulsed difference-frequency laser spectrometer

The design and application of a novel automated room-temperature laser spectrometer are reported. The compact instrument is based on difference-frequency generation in bulk LiNbO(3). The instrument employs a tunable cw external-cavity diode laser (795-825 nm) and a pulsed diode-pumped Nd:YAG laser (1064 nm). The generated mid-IR nanosecond pulses of 50-muW peak power and 6.5-kHz repetition rate, continuously tunable from 3.16 to 3.67 mum, are coupled into a 36-m multipass cell for spectroscopic studies. On-line measurements of methane are performed at concentrations between 200 ppb (parts in 10(9) by mole fraction) and approximately 1%, demonstrating a large dynamic range of 7 orders of magnitude. Furthermore computer-controlled multicomponent analysis of a mixture containing five trace gases and water vapor with an overall response time of 90 s at an averaging time of only approximately 30 s is reported. A minimum detectable absorption coefficient of 1.1 x 10(-7) cm(-1) has been achieved in an averaging time of 60 s, enabling detection limits in the ppb range for many important trace gases, such as CH(4), C(2)H(6), H(2)CO, NO(2), N(2)O, HCl, HBr, CO, and OCS.     

Interferometric analysis of reorientational nonlinear phenomena at 10.6 microm in a nematic liquid crystal

We describe an infrared interferometric technique based on a two-dimensional spatial fringe analysis Fourier method for investigating the characteristic ring diffraction pattern generated by the self-phase-modulation effect induced in nematic liquid crystals (NLCs) by an infrared laser beam and for measuring the nonlinear refractive index of the NLCs. The experimental setup employs a Mach-Zehnder interferometer with a cw CO2 laser emitting at 10.6 microm and a pyroelectric optoelectronic sensor matrix to detect the modulated ring-pattern intensity distribution formed in the far field by a nematic E7 sample. A Fourier-transform-based analysis of the interference fringe pattern allows comparison of the measurements with the theoretical ring-pattern intensity distribution. We show that accurate determination of the nonlinear refractive index can be obtained by analyzing the two-dimensional phase distribution of the modulated ring pattern.     

Wide-beam atmospheric optical communication for aircraft application using semiconductor diodes

Design considerations for atmospheric optical communication systems using wide divergent beams are described. This new approach can eliminate the need for complex gimbaled pointing and tracking mountings. Communicating systems have been designed and built using both infrared LED and cw and pulsed laser diodes operating in the wavelength range of lambda = 0.8-0.9 microm. Both single-channel and multichannel receivers were designed with fields of view (FOVs) ranging from 0.4 to 24 degrees. Receiver performances were compared for a range close to 1 km under various ambient conditions. Laboratory simulation experiments were used to determine the operating margin and expected SNRs resulting from various design considerations. The need for narrow spectral bandwidth and wide-angle FOV interference filters is pointed out. The systems designed in the present work were low data rate (a few kbit/sec) communication systems and are suitable for aircraft-to-aircraft data exchange or voice communication.     

Spectral parameters of inherent optical property models: method for satellite retrieval by matrix inversion of an oceanic radiance model

Inherent optical property (IOP) spectral models for the phytoplankton absorption coefficient, chromophoric dissolved organic matter (CDOM) absorption coefficient, and total constituent backscattering (TCB) coefficient are linear in the reference wavelength IOP and nonlinear in the spectral parameters. For example, the CDOM absorption coefficient IOP a(CDOM)(lambda(i)) = a(CDOM)(lambda(ref))exp[-S(lambda(i)- lambda(ref))] is linear in a(CDOM)(lambda(ref)) and nonlinear in S. Upon linearization by Taylor's series expansion, it is shown that spectral model parameters, such as S, can be concurrently accommodated within the same conventional linear matrix formalism used to retrieve the reference wavelength IOP's. Iteration is used to adjust for errors caused by truncation of the Taylor's series expansion. Employing an iterative linear matrix inversion of a water-leaving radiance model, computer simulations using synthetic data suggest that (a) no instabilities or singularities are introduced by the linearization and subsequent matrix inversion procedures, (b) convergence to the correct value can be expected only if starting values for a model parameter are within certain specific ranges, (c) accurate retrievals of the CDOM slope S (or the phytoplankton Gaussian width g) are generally reached in 3-20 iterations, (d) iterative retrieval of the exponent n of the TCB wavelength ratio spectral model is not recommended because the starting values must be within approximately +/-5% of the correct value to achieve accurate convergence, and (e) concurrent retrieval of S and g (simultaneously with the phytoplankton, CDOM, and TCB coefficient IOP's) can be accomplished in a 5 x 5 iterative matrix inversion if the starting values for S and g are carefully chosen to be slightly higher than the expected final retrieved values.     

Efficient continuous-wave frequency doubling of a tunable CO(2) laser in AgGaSe(2)

Second-harmonic output at 4.6-5.5 mum of the order of 6 mW with a 0.12% external conversion efficiency has been obtained by pumping a AgGaSe(2) crystal with a low-power cw CO(2) laser. The surface damage threshold of AgGaSe(2) for cw radiation was found to be inside the limit of 33-45 kW/cm(2) in the 9.2-10.8-mum wavelength region. Another important limitation of the pump power connected with a thermal lensing effect in crystal was determined experimentally. A comparison was made of AgGaSe(2) and ZnGeP(2) crystals as materials suitable for the efficient generation of the second harmonic of cw CO(2) laser radiation.     

Development of a Tunable, Narrow-Linewidth, CW 2.066-mum Ho:YLF Laser for Remote Sensing of Atmospheric CO(2) and H(2)O

A smoothly tunable, narrow-linewidth, cw, 32-mW, 2.066-mum Ho:YLF laser was constructed and used for the first time in preliminary spectroscopic measurements of atmospheric CO(2) and H(2)O. The laser was constructed with a 4.5-mm-long, TE-cooled, codoped 5% Tm and 0.5% Ho yttrium lithium fluoride crystal (cut at Brewster's angle) pumped by an Ar(+)-pumped 500-mW Ti:sapphire laser operating at 792 nm. Intracavity etalons were used to reduce the laser linewidth to approximately 0.025 cm(-1) (0.75 GHz), and the laser wavelength was continuously and smoothly tunable over approximately 6 cm(-1) (180 GHz). The Ho:YLF laser was used to perform spectroscopic measurements on molecular CO(2) in a laboratory absorption cell and to measure the concentration of CO(2) and water vapor in the atmosphere with an initial accuracy of approximately 5-10%. The measurement uncertainty was found to be due to several noise sources, including the effect of asymmetric intensity of the laser modes within the laser linewidth, fluctuations caused by atmospheric turbulence and laser beam/target movement, and background spectral shifts.     

Injection-seeded pulsed alexandrite laser for differential absorption lidar application

We describe a Q-switched alexandrite laser injection seeded with a cw single-mode titanium-sapphire laser. The reported experimental results show that this system meets the frequency stabilization required for differential absorption lidar measurement of humidity, pressure, and temperature. The emission of the cw titanium-sapphire master oscillator is locked to an atmospheric absorption line by means of a servoloop with derivative spectroscopy. The spectral position is stabilized within ±3.5 × 10(-4) cm(-1) (10 MHz) of the peak of the line over 1 hr. The alexandrite laser emits pulses of 30 mJ in 500 ns, with a spectral linewidth of ≈ 3.3 × 10(-3) cm(-1) (100 MHz). The position of the centroid of the emitted spectrum has a standard deviation of 6 × 10(-4) cm(-1) (18 MHz) and is held within ±1.3 × 10(-3) cm(-1) (40 MHz) of the peak of the absorption line over 1 h.