Nanostructured Organic–Inorganic Composite Materials by Twin Polymerization of Hybrid Monomers

Forming two structurally different but associated polymer structures in a single step is a possible route for the production of nanostructured materials. By means of twin polymerization of specially constructed monomers consisting of two different covalently bonded building blocks (hybrid monomers), this route is realized. What is important is that two different macromolecular structures are formed from one monomer in a single process. The two polymers formed can be linear, branched, or cross‐linked structures. The molecular composition of the hybrid monomer defines the degree of cross‐linking of the corresponding macromolecular structures that is theoretically possible.     

多孔吸声材料的吸声特性研究

多孔吸声材料具有吸声系数高、吸声频带宽等优点,采用多孔吸声材料的圆管理论模型,并对此进行数学编程计算与分析,结合工程实际,研究多孔材料孔隙率、孔径、厚度以及结构因子对多孔材料吸声性能的影响,对实际的设计有一定参考价值。     

Alignment and Graphene‐Assisted Decoration of Lyotropic Chromonic Liquid Crystals Containing DNA Origami Nanostructures

Composites of DNA origami nanostructures dispersed in a lyotropic chromonic liquid crystal are studied by polarizing optical microscopy. The homogeneous aqueous dispersions can be uniformly aligned by confinement between two glass substrates, either parallel to the substrates owing to uniaxial rubbing or perpendicular to the substrates using ozonized graphene layers. These opportunities of uniform alignment may pave the way for tailored anisometric plasmonic DNA nanostructures to photonic materials. In addition, a decorated texture with nonuniform orientation is observed on substrates coated with pristine graphene. When the water is allowed to evaporate slowly, microscopic crystal needles appear, which are aligned along the local orientation of the director. This decoration method can be used for studying the local orientational order and the defects in chromonic liquid crystals.     

高性能聚氨酯基多孔复合吸声材料的研究

以半硬质聚氨酯泡沫体为吸声骨料,水泥为胶结材料,研制成一种复合吸声材料.水灰比、引气剂含量及孔径大小对材料吸声性能有显著影响.当引气剂含量为0.2%,水灰比为0.5,孔径大小为1.9mm时,材料的吸声性能最佳.采用驻波管法测试材料的吸声系数.结果表明,材料的最大平均吸声系数和降噪系数分别达0.64和0.63,且中低频吸声性能较佳.     

Laser Rewritable Dichroics through Reconfigurable Organic Charge‐Transfer Liquid Crystals

Charge‐transfer materials based on the self‐assembly of aromatic donor–acceptor complexes enable a modular organic‐synthetic approach to develop and fine‐tune electronic and optical properties, and thus these material systems stand to impact a wide range of technologies. Through laser‐induction of temperature gradients, in this study, user‐defined patterning of strongly dichroic and piezoelectric organic thin films composed of donor–acceptor columnar liquid crystals is shown. Fine, reversible control over isotropic versus anisotropic regions in thin films is demonstrated, enabling noncontact writing/rewriting of micropolarizers, bar codes, and charge‐transfer based devices.