共查询到20条相似文献,搜索用时 109 毫秒
1.
2.
3.
三叶型345催化剂的工业开发 总被引:3,自引:0,他引:3
三叶型345催化剂(Fe-K-Ce-Mo)具有高活性、高选择性、抗湿防潮性能好、机械强度大、炉前压降低、使用寿命长等特点。可使乙苯转化率大于78%,苯乙烯选择性大于95%,苯乙烯收率大于74%,使用寿命在1.5a以上。 相似文献
4.
开发成功了具有高活性、高选择性、低水同比、高侧压强及抗水性能好等特点的三叶型355催化剂。工业试生产和工业生产结果表明,在反应温度为620℃,流体空速为1.0h,水油比为2.0的条件下,可使乙苯转化率大于80%,苯乙烯收率大于76%,苯乙烯选择性大于95%。 相似文献
5.
6.
美国孟山都环境化学公司是专门从事环境化学工程的一家公司,也是国外生产和供应钒催化剂的主要厂商之一。据资料介绍,该公司生产的钒催化剂产品有7种,目前推广的主要是普通型环状的LP—120、LP—110和Cs—120、Cs—110型含铯环状低温型催化剂。贵溪冶炼厂在近几年的挖潜增产的技术改造中为了增加硫酸产量和满足尾气排放的环保要求,先后采用了技术性能好的日本触媒公司和孟山都公司的催化剂。 相似文献
7.
《化学工业与工程技术》2006,27(6):53-53
日前,报道称采用酸/碱交替沉淀法(AP法)制备了一种新型的低压甲醇合成催化剂。研究了母液pH值和交替次数对催化剂性能的影响。结果表明,pH值为5.0~9.5,交替次数为3时制备的催化剂活性最好。与其他制备方法相比,AP法制备的催化剂具有最高的活性和耐热性,耐热后活性保留率达88%,比其他催化剂高8%~20%,且耐热后活性甚至高于其他催化剂的初活性。 相似文献
8.
9.
乙苯脱氯催化剂的发展动态 总被引:3,自引:0,他引:3
通过对乙苯脱氯制苯乙烯工业催化剂演变过程的分析,认为近年催化剂组成已经历由Fe-K-Cr系列向Fe-K-Ce系列以及由高钾含量向低钾含量的过渡。催化剂制备工艺也有诸多改进,颗粒形状由传统圆柱形由齿轮柱形及三叶柱形等异型颗粒演变。关于催化活性本质的研究渐趋活跃,多数研究者认为活性相是K2Fe2O4,流失是催化剂在正常操作条件下逐渐老化的根本原因。 相似文献
10.
11.
环状GS-05型乙苯脱氢催化剂的研制及工业应用 总被引:2,自引:0,他引:2
本文介绍了一种新型高效的环状GS-05型乙苯脱氢制苯乙烯催化剂的研究开发及工业应用情况,并就其催化性能与圆柱型GS-05型催化剂在实验室100ml等温固定床反应器和工业5000t/a等温脱氢装置上的运转作比较,认为环状GS-05型催化剂能适应等温床反应器。 相似文献
12.
13.
A range of titania supported palladium catalysts modified by the addition of vanadium have been prepared and tested for the total oxidation of short chain hydrocarbons. The addition of vanadium promoted the rates of oxidation at lower temperatures. Vanadium loadings between 0.5 and 3.0 wt.% were investigated and the most active catalyst was 0.5% Pd1.5% V/ TiO2. The addition of vanadium decreased the palladium dispersion, but temperature programmed reduction studies showed that the combination of palladium with vanadium dramatically increased the ease of catalyst reduction. It is proposed that the increased catalyst activity is related to the modified redox properties of the catalysts. 相似文献
14.
Jaana M. Kanervo M. Elina Harlin A. Outi I. Krause Miguel A. Baares 《Catalysis Today》2003,78(1-4):171-180
Alumina-supported vanadium oxide catalysts with vanadium contents of 2, 5 and 11 wt.% were prepared by incipient wetness impregnation and characterised by XRD, Raman spectroscopy and H2-TPR. The catalysts with the low vanadium contents contained vanadium mainly in the well-dispersed phase, but the catalyst with the highest vanadium content contained also some crystalline AlVO4 according to XRD and Raman spectroscopic results. The reduction kinetics of the vanadium catalysts was modelled based on the hydrogen consumption during the TPR. The reduction kinetics could be described with a single-reducible-site random nucleation model for the catalyst containing the lowest amount of vanadium. The reduction kinetic models for the other catalysts required a combination of multiple processes to describe the experiments properly. In the catalyst with 5 wt.% V, a part of vanadium species possibly reduces as a homogeneous random nucleation process, but topochemical reduction by nuclei growth also takes place. In the catalyst with 11 wt.% V, reduction by nuclei growth seems to be the predominant reduction mechanism. The characterisation of the reduced catalysts by XRD and during reduction by Raman spectroscopy enabled the identification of the features of the TPR profiles. 相似文献
15.
《Journal of Catalysis》2005,229(1):1-11
The total oxidation of short-chain hydrocarbons has been studied using a titania-supported palladium catalyst modified with vanadium. A range of catalysts has been prepared by coimpregnation of the titania support with palladium (II) chloride and ammonium metavanadate. The addition of vanadium promoted the rates of oxidation at lower temperatures. Vanadium loadings between 0.5 and 3.0 wt% were investigated and the most active catalyst was 0.5% Pd1.5% V/TiO2. The addition of vanadium decreased the palladium dispersion and the number of surface palladium sites. Microlaser Raman characterisation identified the supported vanadium species and the vanadium loading influenced these. The addition of palladium modified the vanadium species. In particular the presence of palladium increased the concentration of polymeric vanadium species. Temperature-programmed reduction studies showed that the addition of palladium to V/TiO2 significantly increased the ease of catalyst reduction. Characterisation using electron paramagnetic resonance spectroscopy showed that the presence of palladium significantly increased the concentration of V4+ species. It is proposed that the increased catalyst activity is related to the modified redox properties of the catalysts. 相似文献
16.
通过改变老化处理气氛,研究其对催化裂化捕钒剂性能的影响。在水蒸汽和氮气气氛下,含有捕钒组分的催化剂与不含捕钒组分的催化剂催化活性接近,捕钒组分的捕钒效果不显著。在水蒸汽和空气气氛下,随着空气体积分数由0增加到50%,不含捕钒组分的催化剂微反活性由58%升高到69%,重油转化率由68. 82%升高到74. 02%;含有捕钒组分的催化剂微反活性由60%升高到73%,重油转化率由70. 04%升高到77. 10%,焦炭和干气选择性也优于不含捕钒组分样品,体现了捕钒组分的捕钒效果。通过控制老化气氛中SO2质量分数为0或0. 16%,考察SO2对捕钒组分的影响,结果表明,SO2对此捕钒组分的性能影响较小。 相似文献
17.
甲烷水蒸气重整工艺是现阶段最主要的工业制氢技术,催化剂颗粒形状和反应器操作条件是影响重整反应器性能和产物组成的重要因素。首先从颗粒尺度研究催化剂形状对甲烷水蒸气重整反应的影响,在不同的反应温度和压力下,计算并比较了球形、柱形和环形催化剂的效率因子,其大小顺序为:柱形 < 球形 < 环形。其次,将反应器床层的质量、热量和动量传递与环形催化剂颗粒的扩散-反应方程相结合,建立了用于描述甲烷水蒸气重整工业反应器的一维轴向数学模型。计算并分析了反应器进口温度和压力对反应器床层的温度和压力分布、催化剂效率因子以及甲烷转化率和各组分浓度分布的影响,确定了适宜的工业反应器进口温度和压力,分别为773 K和3 MPa。 相似文献
18.
研究了以废钒催化剂为原料,经水浸-还原酸浸-萃取-沉钒等环节制取五氧化二钒、硫酸钾、液体硅酸钠的方法。考察了以三正辛胺(TOA)-仲辛醇-煤油溶液为萃取液提钒的最佳工艺条件: 将废钒催化剂磨碎至
375 μm左右,经过水浸、还原酸浸后,合并其浸出液进行氧化,在水相pH为2.3时,用9%的TOA-3%的仲辛醇-88%(均为质量分数)的煤油溶液萃取, 在浸取时间为2.5 min条件下, 经三级萃取, 钒的萃取率达99%以上;在pH>8、反萃取剂为0.25 mol NaOH+0.25 mol NaCl、反萃时间为3 min条件下, 经三级反萃, 钒的反萃取率达99.4%。在此工艺条件下, 钒、钾的回收率分别达到91.5%和93.8%,产品五氧化二钒、硫酸钾、液体硅酸钠的主要成分含量均达到相应国家标准要求。 相似文献
19.
以柠檬酸处理过的偏钒酸铵为钒源,采用后合成法制备出了V/SBA-15负载型催化剂,研究其在氧化苯乙烯制苯甲醛反应中的催化性能.结果表明,在钒负载量低于15%时,V/SBA-15仍保持SBA-15的高度有序的二维六方孔道结构,且具有较大的比表面积和孔体积,负载的活性组分金属钒氧化物均匀分布在介孔分子筛表面;在优化条件下催化氧化苯乙烯制苯甲醛,苯乙烯转化率达65.62%,苯甲醛的选择性81.21%,且V/SBA-15具有较好的催化剂稳定性. 相似文献
20.
《Journal of Industrial and Engineering Chemistry》2014,20(6):4457-4462
Leached solution, generated by oxalic acid washing of spent residue hydrodesulfurization (RHDS) catalyst, was used for separation and recovery of vanadium. First of all, solvent extraction, using mixture of 20% (v/v) Alamine-336 and 5% (v/v) tri-butyl phosphate (TBP) as a phase modifier, was conducted to extract molybdenum completely at pH 0.50. Then molybdenum-free solution was used for vanadium extraction at pH 1.25 with 20% Alamine-336 and 5% TBP. Stripping of vanadium from loaded organic solution was performed with 1.5 M H2SO4 at O/A phase ratio of 5:1 where more than 99% of vanadium was stripped in two stages. The stripped vanadium solution was further processed by precipitating with ammonium hydroxide to recover ammonium-meta-vanadate which was calcined to obtain vanadium pentoxide. Finally a conceptual process was established for recovery of high purity vanadium pentoxide from oxalic acid leached solution of spent residue hydrodesulfurization (RHDS) catalyst. 相似文献