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1.
Cylindrical test pins of some commercial polymer-based bearing materials (comprising two nylons 6, a filled nylon 6/6, a filled ultra-high molecular weight polyethene (uhmwpe) and three polyurethanes) were rotated, in dry conditions and at constant load and sliding speed, on circular tracks on stationary discs of steel gauze and abrasive paper.Wear against run-in steel gauze was proportional to the sliding time (distance), with the specific wear rate, vsp, (wear volume per unit area per unit sliding distance) varying with the nominal pressure, p, according to vsp = Kpα. Values of K and α are presented enabling comparison of the fatigue wear of the materials at various loads against steel (or a counterface with rounded asperities) in non-transfer film conditions. Nylon 6 showed the least wear and the polyurethanes showed the greatest wear, up to pressures of 3.43 MN m?2 (500 lbf in?2).With abrasive paper, the circular path became progressively clogged with transfer films and wear debris, and the wear volume, ΔW, diminished with time, t, throughout the test duration, following the relationship ΔW = Dtc, where both c and D are functions of the wear path diameter. c appears to be related to the film transfer capability of the polymer. The best overall abrasive wear resistance (in transfer film conditions) was exhibited by the filled uhmwpe, followed by two polyurethanes. Nylon 6 showed relatively poor abrasion resistance under these conditions. The mechanical properties indicate, with one exception, a similar ranking order for non-transfer film conditions  相似文献   

2.
Processing of agglomerated particulate products can lead to attrition by abrasive wear as the agglomerates move relative to one another. In order to investigate this damage mechanism under controlled conditions, bar-shaped silica sand agglomerates of a range of strengths have been formed by addition of appropriate proportions of polyvinylpyrrolidone binder (molecular weight 44 000). These were then tested for wear resistance against various grades of abrasive paper and by rubbing against each other. In common with many materials, it was found that the wear rate is proportional to total sliding distance and to normal load, and independent of relative velocity. A simple Coulombic interlocking wear model is advanced to account for the dependence of wear rate on the size of abrasive particle forming the countersurface. In sustained (multi-pass) sliding, the presence of the debris reduces the attrition rate significantly. This phenomenon has been exploited by various workers who introduced solid lubricants into particle-processing devices in order to reduce attrition. The wear rate of agglomerates of different strengths has been found to be approximately proportional to the reciprocal of Kc, the critical stress intensity factor measured for the same bar agglomerates using the three-point bend test. This relationship between attrition rate and Kc has also been found for attrition in fluidized beds.  相似文献   

3.
Polyimide cylinders are slid under 50 N normal load and 0.3 m/s sliding velocity against carbon steel (Ra=0.2 and 0.05 μm), high-alloy steel (Ra=0.05 μm), diamond-like carbon (DLC, Ra=0.05 μm) and diamond-like nanocomposite (DLN, Ra=0.05 μm). Only for a limited range of test parameters, the friction of polyimide/DLN is lower than for polyimide/steel, while polyimide shows higher wear rates after sliding against DLN compared to steel counterfaces. The DLN coating shows slight wear scratches, although less severe than on DLC-coatings that are worn through thermal degradation. Therefore, also friction against DLC-coatings is high and unstable. Calculated bulk temperatures for steel and DLN under mild sliding conditions remain below the polyimide transition temperature of 180 °C so that other surface characteristics explain low friction on DLN counterfaces, as surface energy, structural compatibility and transfer behaviour. Friction is initially determined through adhesion and it is demonstrated that higher surface energy provides higher friction. After certain sliding time, different polyimide transfer on each counterface governs the tribological performance. Polyimide and amorphous DLC structures are characterised by C–C bonds, showing high structural compatibility and easy adherence of wear debris on the coating. However, it consists of plate-like transfer particles that act as abrasives and deteriorate the polyimide wear resistance. In sliding experiments with high-alloy steel, wear debris is washed out of the contact zone without formation of a transfer film. Transfer consists of island-like particles for smooth carbon steel and it forms a more homogeneous transfer film on rough carbon steel. The latter thick and protective film is favourable for low wear rates; however, it causes higher friction than smooth counterfaces.  相似文献   

4.
The friction and wear properties of the prevailing different solid lubricant coatings (Ion-plated Au, Ion-plated Ag and RF-sputtered PTFE on SUS440C stainless steel) used in the bearings of high-speed cryogenic-turbo-pumps of liquid rocket engines were experimentally evaluated in liquid nitrogen immersed conditions. Also the above experiments were carried out with two newly proposed solid lubricant coatings of sputter-ion-plated MoSTi and a new ion-plated Pb on SUS440C stainless steel. The friction coefficient and wear rates of the coatings of ion-plated Au, ion-plated Ag, RF-sputtered PTFE, the new ion-plated Pb and MoS2Ti-SIP (with coating thickness of 0.7±0.1 μm) on SUS440C steel against SUS440C stainless steel ball in liquid nitrogen were compared. Worn surfaces were examined microscopically with a microscope and a profilometer for understanding the mechanisms of friction and wear and transfer film lubrication in liquid nitrogen. It is found that the newly proposed solid lubricant coatings are showing promising results for their use in liquid nitrogen immersed conditions. The sputter-ion-plated MoSTi coating on SUS 440C steel shows a minimum value of friction coefficient (μ=0.015) and wear rate (wc=0.56 × 10−6 mm3/N m ) in liquid nitrogen.  相似文献   

5.
Jack C. Roberts 《Wear》1982,79(3):363-374
Single- and multiple-pass two-body abrasion tests were run on Nylon 66 + 20% polytetrafluoroethylene (PTFE) and polycarbonate + 10% PTFE sliding dry against 6–50 μm SiC abrasives. A functional relationship was developed between the single-pass wear rate and the abrasive particle size for abrasive particle sizes less than or equal to 10.4 μm. The single-pass abrasive wear rate was 20–40 times greater than the multiple-pass wear rate for each material when it was slid against abrasive grains with a mean size not exceeding 10.4 μm. This was due to the formation of loose polymer fibril wear debris in single-pass sliding and of transferred plateaux of polymer in multiple-pass sliding. The rate of increase in wear with particle size was about 20 times greater for single-pass sliding than for multiple-pass sliding. Above a mean abrasive particle size of 10.4 μm the type of mechanism in both single-pass and multiple-pass sliding was that of ploughing.  相似文献   

6.
A study has been made of the reciprocating dry sliding wear behaviour of polyamide 66 and polycarbonate containing glass fibres, ultra high molecular weight polyethylene (UHMWPE) and polytetrafluoroethylene (PTFE/2% Si oil). Studies have been conducted at sliding loads of 2 kg and 10 kg at an average velocity of 0.33 m s−1 against a hardened stainless steel counterface with a surface roughness of 0.3 μm.It has been shown that additions of 10–15% of filler/reinforcement lead to greatly improved sliding wear behaviour. PTFE/2% Si oil filled polyamide 66 has been shown to have the best overall wear performance whilst the high glass filled variants of polyamide 66 and polycarbonate have the best combination of wear resistance and mechanical strength. These findings are discussed with reference to composite constitution and properties, thermal effects and counterface interactions. Explanations are advanced to account for the differences in behaviour inter alia the composite materials.  相似文献   

7.
The friction and wear properties of Ti6Al4V sliding against AISI52100 steel ball under different lubricative media of surface-capped copper nanoclusters lubricant—Cu nanoparticles capped with O,O′-di-n-octyldithiophosphate (Cu-DTP), rapeseed oil and rapeseed oil containing 1 wt% Cu-DTP was evaluated using an Optimol SRV oscillating friction and wear tester. The wear mechanism was examined using scanning electron microscopy (SEM) and X-ray photoelectron spectrosmeter (XPS). Results indicate that Cu-DTP can act as the best lubricant for Ti6Al4V as compared with rapeseed oil and rapeseed oil containing 1 wt% Cu-DTP. The applied load and sliding frequency obviously affected the friction and wear behavior of Ti6Al4V under Cu-DTP lubricating. The frictional experiment of the Ti6Al4V sliding against AISI52100 cannot continue under the lubricating condition of rapeseed oil or rapeseed oil containing 1 wt% Cu-DTP when the applied load are over 100 N. Surprisingly, the frictional experiment of Ti6Al4V sliding against AISI52100 steel can continue at the applied load of 450 N under Cu-DTP lubricating. The tribochemical reaction film containing S and P is responsible for the good wear resistance and friction reduction of Ti6Al4V under Cu-DTP at the low applied load. However, a conjunct effect of Cu nanoparticle deposited film and tribochemical reaction film containing S and P contributes to the good tribological properties of Ti6Al4V under Cu-DTP at the high-applied load.  相似文献   

8.
The tribological performance of copper-concentrate (CC) mineral deposit as the filler in polyphenylene sulfide (PPS) was studied as a function of the filler proportions and sliding test variables. CC is a complex mixture of CuS, FexOy, SiO2, Al2O3, and other trace materials. The design of experiments based upon L9 (34) orthogonal arrays by Taguchi was used. Sliding tests were performed in the pin-on-disk configuration against a hardened tool steel (55-60 HRC) disk. The improvement in wear resistance of PPS was considerable with the use of fillers. The lowest steady state wear rate of 0.0030 mm3/km was obtained for PPS+20%CC+15%PTFE composition. It was two orders of magnitude lower than that of unfilled PPS. The variations in steady state coefficient of friction with the changes in filler proportions and sliding test variables were small. The transfer film was studied by atomic force microscopy (AFM) and scanning electron microscopy (SEM). X-ray photoelectron microscopy (XPS) was used to detect chemical reactive species developed during sliding, especially in the interface between transfer film and its counterface. Wear particles and the polymer worn surfaces were analyzed by energy dispersive spectroscopy (EDS) for elemental distribution.  相似文献   

9.
The basic regularities of abrasive outwearing for steels of different structural classes are considered. The reliable function bond of steels’ wear resistance with their mechanical characteristics is proved. The correlation of toughness and plasticity with wear resistance is revealed and the new method of steels’ wear resistance definition based on the use of standard mechanical characteristics is offered. The complex criterion for steels’ wear resistance estimation at mechanical outwearing—the product of ultimate strength on relative reduction of area—(σb×ψ) characterizes a nature of steels’ outwearing and is reliable enough for determination of wear resistance in conditions of sliding friction, rolling friction on an abrasive and at erosive outwearing. Using offered complex criterion of steels wear resistance, it is possible to determine or estimate the wear resistances of many steels without running their wear tests. The leading role of metal science in the decision of problem of wear resistance increase for equipment working under abrasive wear conditions is marked.  相似文献   

10.
《Wear》2006,260(4-5):379-386
SiO2, TiO2, and hydroxyapatite (HA) thin films with good biocompatibility were grown on Ti–6Al–4V (coded as TC4) substrate by sol–gel and dip-coating processes from specially formulated sols, followed by annealing at 500 °C The chemical states of some typical elements in the target films were detected by means of X-ray photoelectron spectroscopy (XPS). Atomic force microscopy (AFM) and high-resolution scanning electron microscopy (SEM) are applied to characterize the original unworn films. The tribological properties of thin films sliding against an AISI52100 steel ball were evaluated on a reciprocating friction and wear tester. As the result, the target films composed of nano-particles ranging from 30 nm to 100 nm around were obtained. All the sol–gel ceramic films are superior in resisting wear compared with the TC4 substrate. Among all, HA film shows the best resistance while SiO2 film shows the worst wear resistance both under higher (3 N) and lower load (1 N). TiO2 shows good wear resistance under lower load (1 N). SEM observation of the morphologies of worn surfaces indicates that the wear of TC4 is characteristic of abrasive wear. Differently, abrasion, plastic deformation and micro-fracture dominate the wear of ceramic films. The superior friction reduction and wear resistance of HA film is greatly due to the slight plastic deformation of the film. It is supposed that the deformation of the HA film is closely related to the special arrangement of the nano-particles and microstructure. HA film is recommended for clinical application from the point of wear resistance view.  相似文献   

11.
The friction and wear properties of the polyetheretherketone (PEEK) based composites filled with 5 mass% nanometer or micron Al2O3 with or without 10 mass% polytetrafluroethylene (PTFE) against the medium carbon steel (AISI 1045 steel) ring under the dry sliding condition at Amsler wear tester were examined. A constant sliding velocity of 0.42 m s−1 and a load of 196 N were used in all experiments. The average diameter 250 μm PEEK powders, the 15 or 90 nm Al2O3 nano-particles or 500 nm Al2O3 particles and/or the PTFE fine powders of diameter 50 μm were mechanically mixed in alcohol, and then the block composite specimens were prepared by the heat compression moulding. The homogeneously dispersion of the Al2O3 nano-particles in PEEK matrix of the prepared composites was analyzed by the atomic force microscopy (AFM). The wear testing results showed that nanometer and micron Al2O3 reduced the wear coefficient of PEEK composites without PTFE effectively, but not reduced the friction coefficient. The filling of 10 mass% PTFE into pure PEEK resulted in a decrease of the friction coefficient and the wear coefficient of the filled composite simultaneously. However, when 10 mass% PTFE was filled into Al2O3/ PEEK composites, the friction coefficient was decreased and the wear coefficient increased. The worn scars on the tested composite specimen surfaces and steel ring surfaces were observed by scanning electron microscopy (SEM). A thin, uniform, and tenacious transferred film on the surface of the steel rings against the PEEK composites filled with 5 mass% 15 nm Al2O3 particles but without PTFE was formed. The components of the transferred films were detected by energy dispersive spectrometry (EDS). The results indicated that the nanometer Al2O3 as the filler, together with PEEK matrix, transferred to the counterpart ring surface during the sliding friction and wear. Therefore, the ability of Al2O3 to improve the wear resistant behaviors is closely related to the ability to improve the characteristics of the transfer film.  相似文献   

12.
In order to improve the tribological properties of titanium-based implants, sodium hydroxide (NaOH), hydrogen peroxide (H2O2) solutions, sol–gel hydroxyapatite (HA) film, thermal treatment and combined methods of NaOH solution/HA film, H2O2 solution/HA film are used to modify the surfaces of Ti–6Al–4V (coded TC4). The chemical states of some typical elements in the modified surfaces were detected by means of X-ray photoelectron spectroscopy (XPS). The tribological properties of modified surfaces sliding against an AISI52100 steel ball were evaluated on a reciprocating friction and wear tester. As the results, complex surfaces with varied components are obtained. All the methods are effective in improving the wear resistance of Ti–6Al–4V in different degrees. Among all, the surface modified by the combined method of NaOH solution/HA film gives the best tribological performances. The friction coefficient is also greatly reduced by the modification of NaOH solution. The order of the wear resistance under 3 N is as following: Ti–NaOH–HA>Ti–NaOH>Ti–HA>Ti–H2O2–HA>Ti–H2O2 >Ti–500; under 1 N is Ti–HA, Ti–NaOH–HA>Ti–NaOH. For Ti–H2O2, a very low friction coefficient and long wear life over 2000 passes is obtained under 1 N. SEM observation of the morphologies of worn surfaces indicates that the wear of TC4 is characteristic of abrasive wear. Differently, abrasion, plastic deformation and micro–crack dominate the wear of Ti–HA; slight abrasive wear dominate the wear mechanism of Ti–NaOH and microfracture and abrasive wear for Ti–NaOH–HA and Ti–H2O2–HA, while the sample modified by thermal treatment is characterized by sever fracture. The superior friction reduction and wear resistance of HA films are greatly attributed to the slight plastic deformation of the film. NaOH solution is superior in improving the wear resistance and decreasing the friction coefficient under relative higher load (3 N) and H2O2 is helpful to reduce friction and wear under relatively lower load (1 N). Combined method of Ti–NaOH–HA is suggested to improve the wear resistance of Ti–6Al–4V for medial applications under fretting situations.  相似文献   

13.
5 CrNiMo steel is used traditionally as hot forging die material in China. High temperature wear is a common failure mode of the steel. This paper deals with the sliding wear behavior of the steel in the temperature range 400°C to 600°C. The composition and features of the worn surface were analyzed using SEM, EDS and XRD. The oxidation of 5 CrNiMo steel under sliding wear condition at elevated temperature indicated that the oxide transfer layer formed on the sliding surface consisted of Fe3O4 and Fe2O3. The wear mechanism changed with the test temperature and the oxide transfer layer played an important part in the change in wear mechanism. At lower temperatures, wear was due to abrasive wear. From 500°C to 550°C, the oxide transfer layer presented a relatively compact morphology and the oxidational wear was the principal wear mechanism resulting in low wear rate at 500°C. When the test temperature was at 600°C, adhesive wear was predominant, and the wear rate increased greatly.  相似文献   

14.
Tribological characteristics and wear mechanisms of gas-nitrided layer on a 2Cr13 steel in vacuum were investigated using a pin-on-disk type tribometer under self-mating dry sliding conditions with various normal loads and sliding velocities. The wear mechanisms involved were investigated by microscopic observations of the worn surfaces, the wear debris, and the corresponding cross sections. Experimental results show that for both sliding velocities of 0.2 and 1.6 m s−1, friction forces are relatively stable in the case of lower loads (≤50 N), whereas become unstable and show high fluctuations under higher loads (>50 N). Wear mechanisms of the nitrided layer in vacuum are different for the lower and the higher sliding velocities. In the former case, mild abrasive wear dominates. In the latter case, a transition takes place from mild adhesive wear to severe adhesive or even delamination wear, with increasing normal load from 10 to 90 N.  相似文献   

15.
Dry friction and wear tests were performed with self-mated couples of SiC containing 50% TiC, Si3N4---BN, SiC---TiB2 and Si3N4 with 32% TiN at room temperature and 400°C or 800°C.Under room temperature conditions, the friction coefficient of the couple SiC---TiC/SiC---TiC is only half of that of the couple SiC/SiC and the wear is one order of magnitude smaller. At 400°C, it exceeds the friction coefficient of SiC/SiC except at the highest sliding velocity of 3 m s−1. At lower sliding velocities the wear coefficient of SiC---TiC/SiC---TiC is lower than that of SiC/SiC.The couple Si3N4---TiN/Si3N4---TiN exhibits high friction coefficients under all test conditions. At room temperature the wear volume of the self-mated couples of Si3N4 and Si3N4---TiN after a sliding distance of 1000 m is similar, but Si3N4---TiN shows a running-in behaviour. At 800°C the wear coefficient of Si3N4---TiN/Si3N4---TiN is approximately two orders of magnitude smaller than that of Si3N4/Si3N4, and equal to those at room temperature. At 22°C the addition of BN reduces the friction of Si3N4. The wear coefficient is independent of sliding velocity and the self-mated couples showing running-in. Friction and wear increase with increasing temperature. The wear coefficient of SiC---TiB2 above 0.5 m s−1 at 400°C is advantageously near 10−6 mm3 (Nm)−1. With the other test conditions the wear behaviour is similar to SSiC.  相似文献   

16.
Polyethersulphone (PES), is an amorphous, brittle and high temperature engineering thermoplastic. Two composites of PES containing short glass fibres (GF) and solid lubricants viz. PTFE and MoS2; and two composites containing short carbon fibre (CF) [30% and 40%] were selected for the present studies. Compositional analysis of selected materials was done with various techniques such as gravimetry, solvent extraction and thermal analysis viz. thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). These materials were studied for adhesive and abrasive wear performance by sliding against a mild steel disc and silicon carbide abrasive paper respectively, under different loads. It was observed that GF reinforcement along with incorporation of solid lubricants (PTFE and MoS2) enhanced the wear performance of PES by an order of two. In the case of solid lubricants, PTFE proved to be more beneficial than MoS2. CF reinforcement, however, proved to be the most effective in enhancing wear performance of PES. PES reinforced with 40% CF exhibited a specific wear rate in the order of 10−16m3/Nm which is considered to be very good for the thermoplastic composite. In the case of abrasive wear behaviour, however, incorporation of fibres or solid lubricants deteriorated the performance of the neat matrix. SEM was employed to investigate the wear mechanisms.  相似文献   

17.
The tribological characteristics of a magnesium alloy, AZ91D (die-casting), are investigated in a sliding lubricating system using various amide compounds as lubricating additives on a Timken type tester against a bearing steel (AISI52100) ring. Results indicate that a significant improvement in the tribological performance exists using the amide compounds as additives. The number of amido group (–CONH2) in additive molecules and the molecular structure of amide compounds have significant effect on the tribological characteristics of magnesium alloy. Electromicroscopy reveals that the mild abrasive wear is a predominant wear mechanism of magnesium alloy using an amide additive while the dominated wear mechanism is a severe abrasive wear with severe material deformation using only base oil. Observation shows the formation of boundary film on the magnesium alloy. XPS analysis suggests the occurrence of tribo-chemical reactions between Mg and amide compounds with the formation of chemically stable compound (or complex) of magnesium and amide, as well as the formation of friction polymer.  相似文献   

18.
In tests of PTFE with 2.9% volume content alpha-phase alumina nanoparticles (40 or 80 nm) in sliding reciprocation against polished steel, wear rates of ~10−7 mm3/Nm were measured which is four orders-of-magnitude lower than unfilled PTFE and two orders-of-magnitude lower than with microparticles (0.5 or 20 μm) of more conventional filler size. This was similar to that previously reported in unidirectional sliding, and did not vary greatly with stroke of reciprocation. For a microfilled PTFE, the wear rate gradually increased towards that of unfilled PTFE as filler content was reduced, whereas nanofilled PTFE maintained relatively constant ~10−7 mm3/Nm to filler contents as low as 0.18% before reverting towards the rapid wear rate of unfilled PTFE. Lightly filled nanocomposites depend upon low countersurface roughness to maintain such low wear rate, and with increasing roughness the wear rate was found to transition at a critical value to a wear rate of ~10−5 mm3/Nm. Nanocomposites with higher filler contents were able to retain the low wear rates against rougher countersurfaces, as the critical roughness at which this wear resistance was lost tended to increase with the square of the filler content. Upon encountering extremely high countersurface roughness in the range R a = 6–8 μm, nanocomposites at each filler content eventually increased in wear rate to ~10−4 mm3/Nm. The steel countersurface did not appear to play an important role in the extreme wear resistance of these alumina nanofilled PTFE composites, as comparable performance was also displayed against alumina countersurfaces.  相似文献   

19.
A HfB2-containing Ni-based composite coating was fabricated on Ti substrates by laser cladding, and its microstructure and tribological properties were evaluated during sliding against an AISI-52100 steel ball at different normal loads and sliding speeds. The morphologies of the worn surfaces were analyzed by scanning electron microscopy (SEM) and three-dimensional non-contact surface mapping. The results show that wear resistance of the pure Ti substrate and NiCrBSi coating greatly increased after laser cladding of the HfB2-containing composite coating due to the formation of hard phases in the composite coating. The pure Ti substrate sliding against the AISI-52100 counterpart ball at room temperature displayed predominantly adhesive wear, abrasive wear, and severe plastic deformation, while the HfB2-containing composite coating showed only mild abrasive wear and adhesive wear under the same conditions.  相似文献   

20.
In this experimental study, the dry sliding wear and two-body abrasive wear behaviour of graphite filled carbon fabric reinforced epoxy composites were investigated. Carbon fabric reinforced epoxy composite was used as a reference material. Sliding wear experiments were conducted using a pin-on-disc wear tester under dry contact condition. Mass loss was determined as a function of sliding velocity for loads of 25, 50, 75, and 100 N at a constant sliding distance of 6000 m. Two-body abrasive wear experiments were performed under multi-pass condition using silicon carbide (SiC) of 150 and 320 grit abrasive papers. The effects of abrading distance and different loads have been studied. Abrasive wear volume and specific wear rate as a function of applied normal load and abrading distance were also determined.The results show that in dry sliding wear situations, for increased load and sliding velocity, higher wear loss was recorded. The excellent wear characteristics were obtained with carbon-epoxy containing graphite as filler. Especially, 10 wt.% of graphite in carbon-epoxy gave a low wear rate. A graphite surface film formed on the counterface was confirmed to be effective in improving the wear characteristics of graphite filled carbon-epoxy composites. In case of two-body abrasive wear, the wear volume increases with increasing load/abrading distance. Experimental results showed the type of counterface (hardened steel disc and SiC paper) material greatly influences the wear behaviour of the composites. Wear mechanisms of the composites were investigated using scanning electron microscopy. Wear of carbon-epoxy composite was found to be mainly due to a microcracking and fiber fracture mechanisms. It was found that the microcracking mechanism had been caused by progressive surface damage. Further, it was also noticed that carbon-epoxy composite wear is reduced to a greater extent by addition of the graphite filler, in which wear was dominated by microplowing/microcutting mechanisms instead of microcracking.  相似文献   

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