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实验重点探讨了高含量碳对除尘灰样品中镁、铝、钾、钙、铬、锰、铜、钡、铅、镉、锌等元素测定的影响,并解决了除碳的问题。样品使用马弗炉高温除碳,采用盐酸-硝酸-氢氟酸-高氯酸消解样品灰分,选择了镁、铝、钾、钙、铬、锰、铜、钡、铅、镉、锌等元素的分析谱线和扣背景模式,建立了使用电感耦合等离子体原子发射光谱法(ICP-AES)测定高碳除尘灰中镁、铝、钾、钙、铬、锰、铜、钡、铅、镉、锌等元素的方法。在仪器最佳工作条件下,各元素校准曲线线性相关系数r均大于0.999 5,方法检出限在1.08~26.01 mg/kg之间。方法应用于除尘灰实际样品中镁、铝、钾、钙、铬、锰、铜、钡、铅、镉、锌的测定,结果的相对标准偏差(RSD,n=11)为0.90%~7.1%,目标元素的加标回收率为90%~117%;按照实验方法测定除尘灰中镁、铝、钾、钙、锌,结果与火焰原子吸收光谱法(FAAS)的测定结果相吻合。 相似文献
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采用11种与因瓦合金成分含量相接近的镍基合金标准样品绘制校准曲线,建立了基本不需要样品处理即可对因瓦合金中14种元素(C、Si、Mn、P、S、Ni、Cr、Mo、Cu、Al、Nb、Ti、Co、Fe)同时测定的辉光放电光谱法。确定辉光光谱仪检测因瓦合金的最佳条件:模块电压和相电压分别为8.22 V和3.82 V;功率为70 W;冲洗时间为80 s;积分时间为60 s。以各元素质量分数为横坐标,其对应的光谱强度为纵坐标绘制校准曲线,各元素校准曲线的相关系数均在0.99以上。采用实验方法对因瓦合金实际样品进行分析,结果显示:Cr、Ni、Mo、Ti、Fe的质量分数均大于0.3%,各元素测定值的相对标准偏差(RSD,n=11)均不大于1%;C、Si、Mn、P、S、Cu、Al、Nb、Co的质量分数均小于0.3%,各元素测定值的RSD(n=11)均小于5%。将实验方法应用于对因瓦合金样品中14种元素的测定,测得结果与滴定法测定Ni和Fe、高频燃烧红外吸收法测定C和S、电感耦合等离子体原子发射光谱法测定Si、Mn、P、Cr、Mo、Cu、Al、Nb、Ti和Co元素的结果基本一致。 相似文献
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《不锈(市场与信息)》2009,(24):1-2
国家拟出台进一步加强淘汰落后产能工作的通知,协调发改委、工信部、环保部、国土部、商务部、海关总署、财政部、央行、银监会、质检总局、安监总局、工商总局、电监会、能源局等,以严厉措施,重点完成电力、煤炭、钢铁、水泥、有色、焦炭、造纸、皮革、 相似文献
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BACKGROUND: To assess the efficacy of a single measurement of amniotic fluid optical density deviation at 450 nanometers in predicting fetal anemia in Rhesus-alloimmunization before 27 weeks gestation. METHODS: In this cross-sectional study, fetal blood and amniotic fluid samples from 43 Rhesus-alloimmunized pregnancies at 18 to 26 weeks gestation were obtained under ultrasound guidance. Amniotic fluid samples were scanned by spectrophotometry for optic density at various wavelengths. Deviation at 450 nanometers was calculated between 550 and 365 nanometers. The fetuses were divided into three groups based on their hematocrit levels and the predictive efficacy of optic density zones for anemia was evaluated. RESULTS: A high number of false positive and false negative results were observed when the delta-amniotic fluid optical density of fetuses at risk for anemia was plotted to the zones recently proposed to manage Rhesus-alloimmunized pregnancies. CONCLUSIONS: These data confirm previous results that the diagnosis of fetal anemia in Rhesus-alloimmunized pregnancies before 27 weeks' gestation cannot be accurately made by a single measurement of amniotic fluid optical density at 450 nanometers. 相似文献
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This paper describes laboratory investigations of the motion between two fixed volumes of dense fluid (surge-type gravity currents) with different salt concentrations that interact above an incline in the presence of ambient stratification. The experiments include both large and small density contrasts between the interacting surges. Initially, the propagation of each fluid mass assumes a thermal-like nature, but then the lower density surge is quickly caught up by the denser fluid flow because of its higher velocity. There are two key process regarding the surge interaction. With a large density contrasting the fluid volumes, the denser flow moves to the front of the current as an intrusion with no mixing. With a small density difference, pronounced mixing occurs between the surges with the development of a homogeneous underflow. A simple energy parameterization is developed to evaluate the source conditions under which the different flow dynamics develop. 相似文献
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Management of Fluid Mud in Estuaries, Bays, and Lakes. II: Measurement, Modeling, and Management 总被引:2,自引:0,他引:2
William H. McAnally Allen Teeter David Schoellhamer Carl Friedrichs Douglas Hamilton Earl Hayter Parmeshwar Shrestha Hugo Rodriguez Alexandru Sheremet Robert Kirby 《Canadian Metallurgical Quarterly》2007,133(1):23-38
Techniques for measurement, modeling, and management of fluid mud are available, but research is needed to improve them. Fluid mud can be difficult to detect, measure, or sample, which has led to new instruments and new ways of using existing instruments. Multifrequency acoustic fathometers sense neither density nor viscosity and are, therefore, unreliable in measuring fluid mud. Nuclear density probes, towed sleds, seismic, and drop probes equipped with density meters offer the potential for accurate measurements. Numerical modeling of fluid mud requires solving governing equations for flow velocity, density, pressure, salinity, water surface, plus sediment submodels. A number of such models exist in one-, two-, and three-dimensional form, but they rely on empirical relationships that require substantial site-specific validation to observations. Management of fluid mud techniques can be classified as those that accomplish: Source control, formation control, and removal. Nautical depth, a fourth category, defines the channel bottom as a specific fluid mud density or alternative parameter as safe for navigation. Source control includes watershed management measures to keep fine sediment out of waterways and in-water measures such as structures and traps. Formation control methods include streamlined channels and structures plus other measures to reduce flocculation and structures that train currents. Removal methods include the traditional dredging and transport of dredged material plus agitation that contributes to formation control and/or nautical depth. Conditioning of fluid mud by dredging and aerating offers the possibility of improved navigability. Two examples—the Atchafalaya Bar Channel and Savannah Harbor—illustrate the use of measurements and management of fluid mud. 相似文献
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W Sepulveda R Reid P Nicolaidis O Prendiville RS Chapman NM Fisk 《Canadian Metallurgical Quarterly》1996,174(3):839-842
OBJECTIVE: Our purpose was to determine whether the presence of heme pigments in amniotic fluid is associated with the ultrasonographic findings of increased fetal bowel echogenicity in the second trimester. STUDY DESIGN: Spectrophotometric analysis of amniotic fluid for optical density at 410 nm was prospectively performed to study the presence of heme pigments in (1) 104 pregnancies undergoing second-trimester amniocentesis for routine cytogenetic indications and (2) in 14 pregnancies undergoing amniocentesis for prenatal karyotyping because of fetal strongly echogenic bowel. In the routine amniocentesis group the fetal small bowel echogenicity was assessed immediately before amniocentesis and classified as nonechogenic (n = 64), mildly echogenic (n = 36), or hyperechogenic (n = 4) with the fetal iliac wing and liver used as references. Only amniotic fluid specimens that were obtained at the first attempt and that were not blood-stained were included in this study, with the first milliliter being discarded in all samples. RESULTS: In the routine amniocentesis group abnormal amniotic fluid optical density readings were significantly more frequent in fetuses with increased bowel echogenicity compared with those with nonechogenic bowel (8/40 [20%] vs 3/64 [5%], respectively; p < 0.001). In the hyperchogenic bowel group abnormal amniotic fluid optical density readings were found in four samples (29%). Overall, 12 of 54 fetuses (22%) with increased bowel echogenicity had a detectable peak at 410 nm. Three of the 12 (25%) fetuses with echogenic bowel and positive readings for hemoglobin were chromosomally abnormal. CONCLUSIONS: Fetal small bowel echogenicity is associated with the presence of heme pigments in amniotic fluid as determined by amniotic fluid optical density at 410 nm. Swallowing of amniotic fluid after intraamniotic bleeding seems implicated in the etiology of second-trimester echogenic bowel in both euploid and aneuploid fetuses. 相似文献
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Particle Image Velocimetry Measurements and Numerical Modeling of a Saline Density Current 总被引:1,自引:0,他引:1
Particle image velocimetry scalar measurements were carried out on the body of a stably stratified density current with an inlet Reynolds number of 2,300 and bulk Richardson number of 0.1. These measurements allowed the mass and momentum transport between the current and the less dense ambient fluid to be investigated. Reynolds stress, Reynolds flux, and shear production of turbulent kinetic-energy profiles revealed local maxima at the bed, as well as at the interface with the ambient fluid. Profiles of excess density variance and buoyancy production of turbulent kinetic energy revealed only local maxima at the interface with the ambient. These maxima decreased downstream as the stable density gradient reduced the turbulent intensities, until turbulence collapsed. A two-dimensional, unsteady, Reynolds-averaged Navier-Stokes (2DV-URANS) simulation was also performed on this density current. Good agreement was found between the modeled and measured normalized mean flow profiles. A comparison was also made between the measured and modeled outer flow scales of the density current. 相似文献
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The change in aortic blood density in an in vivo rabbit preparation was measured to assess fluid movement at the pulmonary capillaries caused by infusion of hypertonic solution (NaCl, urea, glucose, sucrose, or raffinose in isotonic saline) into the vena cava over 20 s. The hypertonic disturbance increased the plasma osmotic pressure by =30 mosmol/l. The density change indicates that the fluid extraction from the lung tissue was completed within 10 s. It was followed by a fluid filtration into the lung tissue and then an extraction and filtration from peripheral organs. An exchange model with flow dispersion yields two equations to estimate the osmotic conductance (sigmaK; where sigma is the reflection coefficient of the test solute and K is the filtration coefficient including the total capillary surface area), and the tissue fluid volume from the area and first moment of the measured density change over the extraction phase. The values of sigmaK are 1.40 +/- 0.11, 1.00 +/- 0. 10, 1.71 +/- 0.10, 2.60 +/- 0.23, and 3.73 +/- 0.34 (SE) ml . h-1 . mosmol-1 . l . g-1 for NaCl, urea, glucose, sucrose, and raffinose, respectively. Consistent with the model prediction, the tissue fluid volume (0.28 +/- 0.04 ml/g wet lung tissue) was independent of the solute used. This value suggests that all fluid spaces in the alveolar septa participate in the process of fluid extraction due to an increase in plasma osmotic pressure. 相似文献
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We report a case of large vestibular aqueduct syndrome with a markedly dilated endolymphatic sac bilaterally. The density and signal intensity of the extraosseous portion of the sac were higher than those of cerebrospinal fluid on CT and MR studies. The findings may represent protein-rich and hyperosmolar fluid within the endolymphatic sac. 相似文献
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G Metry G Wegenius B Wikstr?m V K?llskog P Hansell PG Lindgren H Hedenstr?m BG Danielson 《Canadian Metallurgical Quarterly》1997,52(6):1635-1644
The density of the lung reflects the total mass of fluid, air, and dry lung tissue per unit volume of the lung. Lung density can be measured by evaluation of attenuation of an electron beam with computed tomography (CT). This technique has been shown to be sufficiently reliable and sensitive to distinguish normal from abnormal lung water. The aim of this study was to find out whether lung density properly reflects the hydration status in hemodialysis patients in comparison with other standard methods. Fourteen hemodialysis patients, with an ultrafiltration ranging from 0.3 to 4.5 liters per session, underwent CT measurements of lung density, ultrasonographic measurements of the diameter of the inferior vena cava after quiet expiration (IVCe) and quiet inspiration (IVCi), and measurements of the hematocrit and plasma levels of the biochemical hydration markers cyclic guanosine monophosphate (cGMP) and atrial natriuretic peptide (ANP). These measurements were performed before and 3.5 to 4 hours after termination of dialysis. Quantitative estimates of lung density were obtained within pixels with CT numbers ranging between -1000 and -100 Hounsfield Units (HU), and compared with normal data from 18 normal controls. In normal controls, the lung density ranged from -800 to -730 HU. In hemodialysis patients, lung density was significantly higher than normal before dialysis (-678 +/- 96 HU, P < 0.01) and significantly decreased after dialysis (-706 +/- 92 HU, P < 0.05), indicating a decrease in fluid content of the lung. The density was normalized in 5 patients. A significant correlation was found between lung density and IVCe both before and after dialysis (r = 0.8, P < 0.01 for both). Change in density was significantly correlated to amount of ultrafiltration (r = 0.67, P < 0.01) and percent change in blood volume (r = 0.63, P < 0.05), indicating that lung density is greatly affected by changes in the extracellular fluid volume, mainly the intravascular volume. In conclusion, lung water reflects the hydration status in hemodialysis patients and can be monitored by measuring the lung density by CT. Accordingly, normalization of lung density can help to achieve a proper dry weight in these patients. 相似文献
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F. Weinberg 《Metallurgical and Materials Transactions B》1984,15(4):681-684
The penetration of liquid from a low density brine solution into a higher density solution below it has been measured as a
function of vertical flow velocity and the density difference of the two solutions. The flow velocity was produced by a horizontal
disc rotating in the low density liquid. The results show the penetration distance and penetration rate are dependent on flow
velocity and in particular are very sensitive to small changes in the density difference between the two liquids. The observations
are considered in relation to liquid penetration into dendritic arrays, and fluid flow in the pool of ingots and continuously
cast steel billets, during solidification. 相似文献