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通过力学性能测试、氧指数测试研究了聚磷酸铵(APP)对聚丙烯(PP)/聚乙烯(PE)复合材料的力学性能和阻燃性能的影响。结果表明:APP的加入,PP/PE复合材料的拉伸强度开始增加,当添加量超过25%后,其拉伸强度开始降低;冲击强度是先增大后减小,但包覆APP变化的趋势比较大;氧指数逐渐增大.包覆APP的氧指数均好于硅烷处理APP的氧指数。 相似文献
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采用熔融共混与注塑成型的方法制备了聚丙烯/氧化聚乙烯蜡/剑麻纤维(PP/OPE/SF)复合材料,研究了氧化聚乙烯蜡(OPE)对复合材料力学性能的影响.结果表明,OPE显著提高了复合材料的冲击强度,适当添加量的OPE增强了PP/SF的界面键合,提高了复合材料的拉伸强度和拉伸模量. 相似文献
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以聚丙烯(PP)/高密度聚乙烯(HDPE)共混物为基体,六方氮化硼(h-BN)为导热填料,聚丙烯接枝马来酸酐(PP-g-MAH)为相容剂,通过熔融共混法制备PP/HDPE/h-BN和PP/HDPE/h-BN/PP-g-MAH导热复合材料。采用导热系数仪、场发射扫描电镜、万能试验机、热分析仪等测试导热复合材料,研究不同含量的h-BN、PP-g-MAH对复合材料导热性、力学性能、结晶性能和耐热性的影响。结果表明:随着h-BN含量的增加,PP/HDPE/h-BN复合材料的弯曲强度、热导率和耐热性提高。当h-BN含量为20%,复合材料的弯曲强度达到41.02 MPa;当h-BN含量为25%,复合材料热导率达到0.372 1 W/(m·K)。h-BN对PP的结晶具有促进作用,提升PP的结晶速率和结晶温度。PP、HDPE与h-BN质量比为64∶16∶15时,添加5%的PP-g-MAH,增强了h-BN和基体材料的界面相容性,复合材料的弯曲强度达到42.72 MPa,拉伸强度达到26.64 MPa,热导率达到0.356 1 W/(m·K)。 相似文献
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本文对PP/Talc二元复合材料和PP/CPE/Talc三元复合材料的物理机械性能,流变性能,熔体流动性能和形态结构进行初步研究。研究结果表明,CPE作为第三组分加到PP/Talc二元复合材料体系中,对其综合性能并未提高,似乎有下降的趋势。这表明Talc填充PP是一个较为理想的体系,无需再加入CPE这类高分子抗冲改性剂作为第三组分。并从形态结构进行了阐述。 相似文献
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通过力学性能测试、氧指数测试研究了有机包覆和无机包覆红磷对聚丙烯(PP)/聚乙烯(PE)复合材料的力学性能和阻燃性能的影响。结果表明:随着红磷的加入,PP/PE的拉伸强度和冲击强度均得到了提高,极限氧指数(LOI)逐渐增大,添加有机包覆红磷的PP/PE复合材料的LOI均好于同比添加无机包覆红磷复合材料的LOI。 相似文献
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采用熔融共混法制备聚丙烯/聚烯烃弹性体/聚乙烯/马来酸酐接枝聚丙烯(PP/POE/PE/CaCO3/PP-g-MAH)复合材料,并研究其力学性能。结果表明:PP-g-MAH可提高PP与CaCO3的相容性,使复合材料的韧性和拉伸性能得到提高,PE可提高PP与POE的相容性,并有效提高复合材料的韧性,经POE、PE、CaCO3和PP-g-MAH之间的相互协同改性作用可制得综合性能优良的PP复合材料。 相似文献
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Kiril P. Tchomakov Basil D. Favis Michel A. Huneault Michel F. Champagne Florin Tofan 《加拿大化工杂志》2005,83(2):300-309
The ternary blends of high‐density polyethylene (PE), EPDM terpolymer and polypropylene (PP) have been used as a model low interfacial tension system to study encapsulation dynamics in ternary blends and their relation to the blends' mechanical properties. It was found that the modulus, tensile strength and impact resistance can be improved by PE addition if the PE is localized within the EPDM phase. A range of blend morphology was found depending on the PE viscosity and polymer incorporation sequence in the twin‐screw extruder. In the most favorable sequence, PE and EPDM were mixed together prior to their dispersion in the PP matrix. This practice resulted in a 50% increase in impact resistance when compared to mixing the three components in a single‐step. 相似文献
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Three different polyethylene/polypropylene (PE/PP) blends were microcellular foamed and their crystallinities and melt strengths were investigated. The relationship between crystallinity, melt strength, and cellular structure was studied. Experimental results showed that the three blends had similar variation patterns in respect of crystallinity, melt strength, and cellular structure, and these variation patterns were correlative for each blend. For all blends, the melt strength and PP melting point initially heightened and then lowered, the PP crystallinity first decreased, and then increased as the PE content increased. At PE content of 30%, the melt strength and PP melting point were highest and the PP crystallinity was least. The blend with lower PP crystallinity and higher melt strength had better cellular structure and broader microcellular foaming temperature range. So, three blends had best cellular structure at PE content of 30%. Furthermore, when compared with PE/homopolymer (hPP) blend, the PE/copolymer PP (cPP) blend had higher melt strength, better cellular structure, and wider microcellular foaming temperature range, so it was more suited to be microcellular foamed. Whereas LDPE/cPP blend had the broadest microcellular foaming temperature range because of its highest melt strength within three blends. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 4149–4159, 2007 相似文献
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戴建国 《现代塑料加工应用》1999,11(5):52-55
介绍了国内聚乙烯、聚丙烯工业生产、需求和发展状况 ,分析了产品和消费结构、价格走势及其影响因素 ,并在此基础上预测了今后的市场趋势 相似文献
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The mechanical properties of blends of isotactic polypropylene and high-density polyethylene with a postconsumer resin (recycled dairy containers) were investigated over the entire composition range. Modification of these blends with an ethylene/propylene/diene copolymer or an ethylene/vinyl acetate copolymer was also investigated. Isotactic polypropylene/postconsumer resin blends have satisfactory impact and tensile properties at postconsumer resin contents of less than 50% for certain applications. At higher postconsumer resin contents, the tensile properties were adversely affected. The impact properties remained satisfactory. Addition of an ethylene/propylene/diene copolymer improved the mechanical properties of these blends to levels equal to or greater than those for neat isotactic polypropylene. Ethylene/vinyl acetate copolymers were also able to improve the mechanical properties, but not as efficiently as did the ethylene/propylene/diene copolymer. Blends of high-density polyethylene and a postconsumer resin had poor impact and tensile properties. Although the ethylene/propylene/diene copolymer and ethylene/vinyl acetate copolymers were able to improve these properties, the improvement was insufficient for general recycling, except at lower (≤25%) postconsumer resin contents. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 70: 2081–2095, 1998 相似文献
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概述了导电聚合物的特点、分类及相应的导电机理。综述了国内外复合型导电聚合物的最新研究进展、技术成果以及应用领域。 相似文献