基于两种丁腈橡胶复合填料的高性能离合器摩擦材料

本文提出了以丁腈乳胶改性水基酚醛树脂作粘合剂,分别以玻璃纤维和复合包芯纱纤维作为增强材料。采用两种新型丁腈复合填料作主要填料制备高性能离合器摩擦材料的试验方法。两种新型复合填料分别为含9％硫化丁腈橡胶和含20％未硫化丁腈橡胶。试验表明：当两种新型复合填料按1：1的比例加入,即丁腈橡胶含量在16％左右时,制备出的摩擦材料具有良好的摩擦磨损性能、适中的硬度、良好的冲击强度及较低的噪音。     

基于两种丁腈橡胶复合填料的高性能离合器摩擦材料的研究

以丁腈胶乳改性水基酚醛树脂为胶粘剂,分别以玻璃纤维和复合包芯纱纤维为增强材料,采用两种新型丁腈复合填料[含9%硫化丁腈橡胶(NBR)和含20%未硫化NBR]为主要填料制备高性能离合器摩擦材料。实验结果表明,当m(9%硫化NBR)∶m(20%未硫化NBR)=1∶1[即W(NBR)≈16%]时,制取的摩擦材料具有良好的摩擦磨损性能、适中的硬度、良好的冲击强度和较低的噪音。     

ZrSiO_4和Al_2O_3粒度对制动摩擦材料摩擦磨损性能的影响

采用热压成型法制备有机制动摩擦材料,对所制备的摩擦材料进行摩擦磨损测试。研究填料硅酸锆和氧化铝的粒度对多纤维增强树脂基制动摩擦材料摩擦磨损性能的影响。研究结果表明,硅酸锆和氧化铝的加入可起到良好的增摩效果,随着填料粒度的细化,摩擦系数减小,但稳定性在粒度居中时最好,同时对磨损率也有一定影响。通过观察试样磨损后表面形貌探讨摩擦磨损机理。     

无石棉纤维膨化复合纱线生产工艺及其性能

采用膨化复合工艺生产的新型无石棉纤维复合纱线作为增强材料的汽车离合器面片技术参数稳定,性能良好。同时,膨化复合工艺能够缩短汽车离合器面片增强用复合纱线的生产流程,降低生产成本,改善生产环境和提高生产效率。     

聚合填充型填料A／超高分子量聚乙烯复合料的研究

本文采用一种新工艺－－聚合填充法制备了填料A／超高分子量聚乙烯合料,研究了填料A的矿化温度、活化剂的用量、聚合、聚合压力、填料粒度、氢调等条件对填料A进行聚合填充反应的影响,找出了聚合规律,得到了性能的新型超高分子量聚乙烯复合料,并与传统的共混工艺制备的填料A／超高分子量聚乙烯复合料的性能进行了对比。     

环氧复合涂层的摩擦磨损性能研究

综述了环氧复合涂层摩擦磨损性能的研究进展,阐述了不同填料单一填充和复合填充改性对环氧复合涂层摩擦磨损性能的影响,分析了不同填料改性环氧复合涂层的摩擦磨损机制。多种填料之间存在性能互补性,易产生协同效应,多种填料复合填充可提高环氧复合涂层的减摩耐磨性能,使环氧复合涂层具有更优异的摩擦磨损性能。     

刹车片摩擦材料的研究现状与发展趋势

作为车辆和机械离合器总成及制动器中的关键性安全部件,高性能刹车片摩擦材料的研究广泛受到各科研机构和主机厂的关注。本文介绍了刹车片摩擦材料的可压缩性、内剪切强度、热膨胀量等主要性能,同时从粘结剂、增强纤维、填料和摩擦性能调节剂等方面概述了主要影响刹车片摩擦材料性能的研究现状,并归纳了正交试验设计与模糊综合评价法、黄金分割法与灰色相关度分析、人工神经网络等摩擦材料配方设计及优化方法的应用情况,进一步探索了刹车片摩擦材料的未来发展趋势,指出摩擦材料各组分之间的耦合机理及对性能影响的研究是未来的热点,多种优化方法的融合将有利于新型刹车片摩擦材料的开发应用。     

耐高温改性酚醛树脂基复合摩擦材料研究进展

针对酚醛树脂(PF)基复合摩擦材料存在抗热衰退性及恢复性较差、耐久性不足等缺陷,从PF基体改性、增强体、填料及摩擦性能调节剂三个方面,综述了国内外近年来耐高温改性PF基复合摩擦材料的研究进展,并分析了其今后的发展趋势。     

工程用聚合物基复合材料摩擦行为研究进展

综述了复合改性聚合物材料摩擦磨损性能研究发展 ,主要分析了纤维、金属及其化合物、无机非金属化合物及聚合物填料对材料摩擦性能的影响和作用机理 ,以及工况条件及摩擦磨损形式对材料摩擦行为的影响 ,简述了复合材料摩擦行为模拟及预测的研究现状及研究中存在的问题 ,进一步探讨了材料摩擦行为模拟和预测的可能性。     

微粉石墨在玻璃钢风机叶片表面胶衣中的应用

以鳞片状微粉石墨在冷却塔玻璃钢风机叶片的表面胶衣树脂中作为功能填料,选用合理的粒度、配方、掺杂工艺,使表面胶衣树脂的力学、摩擦性能、电性能等方面性能得到提升,进一步提高整个玻璃钢风机叶片的性能。     

Friction properties of graphene reinforced nitrile rubber composites after thermal oxidation aging: Experiment and molecular dynamics simulation

We established friction models for pure NBR, GNS/NBR, and GO/NBR composites through molecular dynamics (MD) simulation. Our study focused on the impact of GNS and GO on the friction properties of nitrile rubber (NBR) composite materials after undergoing thermal oxygen aging. Based on the simulation results, it can be observed that the GNS/NBR and GO/NBR composites' coefficient of friction (COF) decreases by 20.8% and 24.8%, respectively, at 348 K. Additionally, the abrasion rate is reduced by 17.4% and 25.7%, respectively, for the same composites. Adding GNS and GO can effectively improve the friction performance of the NBR composite system, and compared with GNS, GO shows a better enhancement effect. Pure NBR and GO/NBR composite materials were prepared by mechanical blending method, and the friction properties of GO-enhanced NBR composite materials were studied. The experimental results show that the GO/NBR composite material can maintain a low friction and wear coefficient after thermal and oxygen aging. It shows that adding GO can effectively improve the friction properties of NBR composite systems and slow down the weakening effect of aging on the friction properties of NBR composite materials. This is because the GO surface contains wealthy functional groups such as epoxy groups, which enhances the binding strength between the GO and NBR interface so that the GO/NBR composite material exhibits better friction properties and thermal oxygen aging resistance. In addition, the wear surface was characterized by scanning electron microscopy (SEM), revealing the damage mechanism of friction and wear of NBR composite materials.     

Influence of graphite particle size and shape on the properties of NBR

Four graphite powder fillers with different form and size were mixed with acrylonitrile butadiene rubber (NBR, acrylonitrile content at 26%) at 20, 40 and 60 phr of the filler loadings, and the obtained compounds were characterized by SEM, tensile test, friction and wear test. Through the SEM observation, it was found that the expanded graphite could not be broken down to small particles uniformly when blended with rubber on the twin‐roller. In the tensile test, the graphite with the smallest size possessed the best reinforcement ability as expected. The tribological properties of the rubber were improved when adding more graphite. The largest graphite particles imparted the lowest friction coefficient of the composites among four fillers, but the submicrometer graphite provided the best wear property to NBR. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4007–4015, 2006     

Mechanical and tribological performance of acrylonitrile-butadiene rubber/carbon black/cryptocrystalline graphite composites

In this study, cryptocrystalline graphite (CG) was investigated as a novel functional filler for acrylonitrile-butadiene rubber (NBR)/carbon black (CB) composites. NBR/CB/CG composites are characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) as well as differential scanning calorimetry (DSC). The results showed that NBR/CB/CG-10 increased by 18.2%, 11.0%, and 10.0% in tensile strength, 300% tensile modulus and tear strength, respectively compared with NBR/CB. Uniform filler dispersion and stronger interfacial interaction contributed to enhancing the mechanical property of NBR/CB/CG composites. It was revealed that the small particle size, rough surface, and defective structure of CG facilitated its exfoliation and intercalation. In addition, the tribological performance of NBR/CB/CG composites was tested on a ring-on-block wear tester under dry sliding conditions. The friction coefficient and specific wear rate of NBR/CB/CG-5 reduced by 50.3% and 51.4%, respectively through the formation of fine lubrication and transfer films. CG enhanced the thermal stability, mechanical, and tribological performance of NBR composites simultaneously and the results of this work proved that CG would be a cost-effective and resource-available functional filler especially suitable for rubber seal application.     

温度对酚醛树脂/丁腈橡胶复合材料摩擦学性能的影响

采用机械共混法将酚醛树脂（PF）与丁腈橡胶（NBR）进行混合而制得PF/NBR复合材料,研究了PF用量对NBR的拉伸性能、撕裂性能及硬度的影响,使用多功能材料表面性能综合测试仪、三维表面形貌仪和扫描电子显微镜对力学性能最优的PF/NBR复合材料试样A 2（添加5份PF）在不同温度下的摩擦性能进行了探究,并与未添加PF的试样A 0进行了对比,此外还对PF/NBR复合材料的磨损机理进行了初步分析。结果表明,当温度超过75 ℃时,试样A 0的摩擦系数曲线整体呈持续上升的趋势,同时其表面有较多孔洞,分子间结合力下降,耐磨性变差,而试样A 2的摩擦系数则基本保持稳定,磨损行为表明其磨损机理由磨粒磨损逐渐转变为黏着磨损;相对于试样A 0而言,试样A 2在高温下仍能保持较好的摩擦性能。     

酸性活性修饰剂对白泥/丁腈橡胶复合材料力学性能的影响

利用丙烯酸和对乙烯苯磺酸作为白泥的修饰剂,对白泥进行湿法修饰,而后利用石蜡对白泥进行二次包覆制备了有机修饰活性白泥,并将其作为橡胶填料填充到丁腈橡胶(NBR)中制备了修饰白泥/NBR(400:100)母胶,而后将母胶填充到NBR中制备了不同白泥含量的白泥/NBR复合材料。考察了不同修饰量制备的母胶对复合材料硫化性能的影响、母胶及用量对NBR复合材料的性能影响。实验结果表明:当加入修饰剂的用量逐步增加(以干白泥质量计算)时,母胶填充的白泥/NBR复合材料的力学性能呈现先增大后减小的趋势。酸性活性剂用量为白泥2%的母胶且母胶份数为100phr时其白泥/NBR复合材料的力学性能达到最佳值。但是两种活性修饰剂修饰的白泥母胶在改性NBR性能上存在差异:丙烯酸修饰白泥母胶制备的白泥/NBR复合材料的力学性能为拉伸强度8.3MPa、扯断伸长率386%、300%定伸应力3.7MPa、硬度79;乙烯苯磺酸修饰白泥母胶的力学性能为拉伸强度9.8MPa、扯断伸长率652%、300%定伸应力4.2MPa、硬度78。研究表明:利用丙烯酸、对乙烯苯磺酸作为白泥的修饰剂并制备橡胶母胶可大幅度提高橡胶材料的力学性能,可作为白泥综合利用的一种有效方法。     

Properties of silica‐filled styrene‐butadiene rubber compounds containing acrylonitrile‐butadiene rubber: The influence of the acrylonitrile‐butadiene rubber type

Because silica has strong filler‐filler interactions and adsorbs polar materials, a silica‐filled rubber compound exhibits poor dispersion of the filler and poor cure characteristics in comparison with those of a carbon black‐filled rubber compound. Acrylonitrile‐butadiene rubber (NBR) improves filler dispersion in silica‐filled styrene‐butadiene rubber (SBR) compounds. The influence of the NBR type on the properties of silica‐filled SBR compounds containing NBR was studied with NBRs of various acrylonitrile contents. The composition of the bound rubber was different from that of the compounded rubber. The NBR content of the bound rubber was higher than that of the compounded rubber; this became clearer for NBR with a higher acrylonitrile content. The Mooney scorch time and cure rate became faster as the acrylonitrile content in NBR increased. The modulus increased with an increase in the acrylonitrile content of NBR because the crosslink density increased. The experimental results could be explained by interactions of the nitrile group of NBR with silica. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 385–393, 2002     

叶腊石/白炭黑/NBR复合材料的结构与性能研究

利用机械共混法制备了叶腊石/白炭黑/NBR复合材料,采用RPA2000、SEM、DMA等实验方法研究改性剂的种类、增塑剂DOP用量对复合材料性能的影响。结果表明,偶联剂Si-69不仅可以改善复合填料的分散性,而且可以提高复合填料与NBR之间的相互作用,其改性效果最佳。增塑剂DOP可以改善NBR胶料的加工性能,提高NBR复合材料的耐溶剂性能、回弹性及耐低温性能,对NBR复合材料的补强及耐热空气老化性能不利,但可以降低胶料成本。     

Preparation and properties of nitrile rubber/superfine down powder composites

The purpose of this study was to improve utilization rate of waste protein materials. In this article, down fiber was ground into superfine down powder (SDP) and then filled into nitrile rubber (NBR) directly. The cure‐curve, dynamic rheological behavior, morphology, tensile property, and thermal properties of NBR/SDP composites were studied. The results showed that SDP formed a developed but weak filler–filler network, which resulted in obvious “Payne effect,” the increased storage modulus, loss tangent and complex viscosity of the NBR/SDP composites. SDP could be distributed uniformity in the NBR matrix, but the large sizes of most SDP weaken the interaction between the particles and NBR matrix. The tensile property was improved by high SDP load. The SDP decreased the temperature at 5% weight loss of the NBR/SDP composites, but not apparently affected the maximum weight loss rate of the NBR. At last, the results of this study suggested that SDP was potential to be one of the available additives fillers in rubber industry, as long as the smaller size of SDP was achieved. POLYM. COMPOS., 34:1136–1143, 2013. © 2013 Society of Plastics Engineers     

Improvement of properties of silica‐filled styrene–butadiene rubber compounds using acrylonitrile–butadiene rubber

Since silica has strong filler–filler interactions and adsorbs polar materials, a silica‐filled rubber compound has a poor dispersion of the filler and poor cure characteristics. Improvement of the properties of silica‐filled styrene–butadiene rubber (SBR) compounds was studied using acrylonitrile–butadiene rubber (NBR). Viscosities and bound rubber contents of the compounds became lower by adding NBR to the compound. Cure characteristics of the compounds were improved by adding NBR. Physical properties such as modulus, tensile strength, heat buildup, abrasion, and crack resistance were also improved by adding NBR. Both wet traction and rolling resistance of the vulcanizates containing NBR were better than were those of the vulcanizate without NBR. The NBR effects in the silica‐filled SBR compounds were compared with the carbon black‐filled compounds. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 79: 1127–1133, 2001