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1.
采用无金属催化剂的简单热蒸发法,在Si(100)衬底上不同生长温度下成功地制备了高密度和大长径比的单晶ZnO纳米线。分别利用X射线衍射仪(XRD)、扫描电子显微镜(SEM-EDS)、透射电子显微镜(TEM)及荧光光谱仪表征样品的结构和发光性质。XRD和TEM研究表明,所制备的样品为沿c轴择优取向生长的单晶ZnO纳米线,具有六方纤锌矿结构。SEM和TEM研究表明,生长温度对ZnO纳米线的形貌及长径比的影响较大。当生长温度为700℃时,制备得到长径比为300(长度约为15μm,直径约为50nm)的ZnO纳米线;低于600℃时,形成花状ZnO纳米锥或纳米棒;高于700℃时,形成小长径比的ZnO纳米棒。此外,室温光致发光(PL)谱上出现一个强而尖锐的紫外发射峰以及一个弱而宽泛的蓝光发射峰。采用的热蒸发法制备ZnO纳米线基于气-固(VS)生长机理且该生长方法可用于大规模、低成本制备高纯度的单晶ZnO纳米材料。  相似文献   

2.
程文德  吴萍  鄢剑  陈蓓  肖潭 《功能材料》2007,38(6):882-884
将锌粉、炭粉和氧化锌粉末混合,用简单的热蒸发方法一步就合成了大量的尖锥状纳米ZnO阵列,该方法克服了其它制备方法需要先单独制备催化剂再合成ZnO的缺点而且得到产物不含杂质.用SEM、EDX、XRD和PL对样品进行了形貌、结构和发光特性分析.结果表明,生成的锥状阵列纳米ZnO为六方纤锌矿结构,产物中氧的含量不足,初步探讨了阵列纳米ZnO结构的生长机理和光致发光性质.  相似文献   

3.
采用无金属催化剂的简单热蒸发法,在Si(100)衬底上不同生长温度下成功地制备了高密度和大长径比的单晶ZnO纳米线。分别利用X射线衍射仪(XRD)、扫描电子显微镜(SEM-EDS)、透射电子显微镜(TEM)及荧光光谱仪表征样品的结构和发光性质。XRD和TEM研究表明,所制备的样品为沿C轴择优取向生长的单晶ZnO纳米线,具有六方纤锌矿结构。SEM和TEM研究表明,生长温度对ZnO纳米线的形貌及长径比的影响较大。当生长温度为700℃时,制备得到长径比为300(长度约为15μm,直径约为50nm)的ZnO纳米线。低于600℃时,形成花状ZnO纳米锥或 纳 米 棒。高 于700℃时,形 成 小 长 径 比 的ZnO纳米棒。此外,室温光致发光(PL)谱上出现一个强而尖锐的紫外发射峰以及一个弱而宽泛的蓝光发射峰。采用的热蒸发法制备ZnO纳米线基于气-固(VS)生长机理且该生长方法可用于大规模、低成本制备高纯度的单晶ZnO纳米材料。  相似文献   

4.
研究发现,热蒸发铜粉即可在硅衬底上直接生长出硅纳米线.场发射电子扫描电镜和透射电镜分析表明,纳米线的形貌、结构及生长机制,随沉积区域的不同而变化.在高温沉积区,硅纳米线高度弯曲且相互缠绕,按气-液-固机制生长;在低温沉积区,高度定向生长的直硅纳米线,规整地排列在硅衬底表面,其生长机制是氧化辅助生长机制.  相似文献   

5.
氧化锌纳米棒有序阵列的制备及表征   总被引:2,自引:0,他引:2  
俞有幸  郝维昌  杜轶  王春忠  王天民 《功能材料》2007,38(8):1370-1372,1376
氧化锌是一种重要的化合物半导体,其低维结构在微电子器件领域具有潜在的应用前景.在温和的条件下利用软化学方法在沉积了单层ZnO颗粒膜的玻璃衬底上制备了直径为70~300nm,长约1μm的氧化锌纳米棒有序阵列,讨论了颗粒膜对阵列生长的作用以及水浴温度对晶体结构和形貌的影响.结果表明,产物为纤锌矿结构;ZnO颗粒膜为阵列的生长提供了分布均匀且固定的形核中心,对阵列的有序生长起诱导作用;随着反应温度的升高,阵列直径变小且排列更加有序,但过高的温度会抑制ZnO晶体内部的c轴择优取向作用.研究了ZnO阵列的光致发光特性,初步讨论了其发光机理.  相似文献   

6.
热蒸发锌粉法制备半导体氧化锌纳米线的研究   总被引:8,自引:0,他引:8  
采用热蒸发锌(Zn)粉的方法,制备出高产量的由半导体氧化锌纳米线组成的蒲公英花状和四角锥状纳米结构.利用SEM、TEM和X射线衍射对产物的形貌及结构进行了分析.结果表明,所生成的是具有六方结构的单晶ZnO纳米线.纳米线长约5-10μm,根部直径较粗,约110-120nm;梢部较细,约25-30nm,其生长机制为气-固(VS)机制.  相似文献   

7.
钟明龙 《功能材料》2015,(3):3139-3143
采用简单热氧化蒸发沉积法在ITO玻璃基片上制备了大面积MoO3微纳米片。制备出的微纳米片具有良好晶体结构,其长度、宽度和片层厚度分别可达100,1~5μm和约100nm;微纳米片沿[001]方向生长,这是因为晶体各方向键合能的不同而具有不同的生长速度,其形成过程遵循气-固生长机制。光致发光谱显示室温下MoO3微纳米片同时具有紫光发射峰、蓝光发射峰和绿光发光带,发射光强度随氧化沉积温度升高而增大,这是由于温度升高,微纳米片缺陷增加导致的。  相似文献   

8.
梳状氧化锌纳米材料的制备及结构、性能的表征   总被引:1,自引:1,他引:1  
通过纯锌粉蒸发,在600-650℃无催化条件下成功制备了高质量的梳状ZnO纳米结构。通过扫描电镜(SEM)及高分辨透射电镜(HRTEM)观察,所制备的梳状ZnO纳米结构具有两种典型形貌,且皆为单晶结构,分析表明其生长由气-固生长机理控制。室温光致发光谱显示,梳状ZnO纳米结构在385nm附近形成紫外发射峰;在以495nm为中心的范围内,形成较宽的绿光发射峰。  相似文献   

9.
采用热蒸发的方法在ZnO薄膜缓冲层上成功制备了高密度的ZnO纳米棒阵列,其中ZnO薄膜缓冲层是通过PLD(Pulsed Laser Deposition)的方法制得。与已有的报道不同,该方法未使用任何金属催化剂。X射线衍射仪(XRD)以及场发射扫描电子显微镜(FE-SEM)的结果表明,实验得到的ZnO纳米棒阵列整齐垂直排列在衬底上.此外,在常温下测量得到的光致发光(PL)谱和透射电子显微镜显示该ZnO纳米棒阵列结晶较好,无明显的缺陷,研究结果表明纳米棒阵列的形成主要归因于ZnO纳米棒和薄膜之间完美的晶格匹配。  相似文献   

10.
采用热蒸发法制备了单晶Sn掺杂ZnO纳米带,其中Sn的掺杂含量约为5%(原子分数).X射线衍射(XRD)结果表明Sn掺杂ZnO纳米带为单相纤锌矿结构.X射线光电子能谱(XPS)表明样品中Sn的价态为4+.样品的室温光致发光谱(PL)在445.8nm处存在较强的蓝光发射峰,对其发光机制进行了分析.  相似文献   

11.
12.
Novel metallic Zn hexagonal hollow microprisms have been synthesized by a simple thermal evaporation technique using NH3 as a carrier gas under atmospheric pressure. As-prepared hollow microprisms were characterized using X-ray diffraction, energy dispersive X-ray spectroscopy, scanning electron microscopy and transmission electron microscopy. The hollow microprisms collected on silicon substrate are found to be 3-7 μm long with diameter in the range 900-950 nm. A vapour-solid (VS) process based growth mechanism has been proposed for the formation of hexagonal Zn microprisms grown along (0001) basal plane in [0001] direction. Photoluminescence (PL) emission spectrum of zinc microprisms at room temperature exhibited a very prominent peak at 384 nm owing to the radiative recombination of electrons in s, p conduction band near Fermi surface and the holes in the d bands generated by optical excitation.  相似文献   

13.
14.
《Optical Materials》2014,36(12):2618-2623
The uniform hollow spherical Sr2SiO4:Eu2+ green emitting phosphors have been successfully synthesized using hollow silica spheres as templates by an h-BN protective method. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) results directly confirmed the existence of the hollow spherical structure with a narrow size distribution and a shell thickness of 15–25 nm. The h-BN protective film, observed by high resolution TEM, plays an important role in the formation of the hollow spherical morphology and the improvement of photoluminescence properties. Comparing with the Sr2SiO4:Eu2+ micron-phosphor prepared by the traditional solid state reaction method, the hollow spherical phosphor with nano-sized grains exhibits stronger green emission under ultraviolet–blue light excitation. This could be attributed to the elimination of surface defects by the h-BN coating. This research gives an economic and convenient way to synthesize uniform spherical phosphors with high quantum efficiency.  相似文献   

15.
Several analytical models exist for determination of the Young’s modulus and coefficient of thermal expansion (CTE) of particulate composites. However, it is necessary to provide accurate material properties of the particles as input data to such analytical models in order to precisely predict the composite’s properties, particularly at high particle loading fractions. In fact, the constituent’s size scale often presents a technical challenge to accurately measure the particles’ properties such as Young’s modulus or CTE. Moreover, the in situ material properties of particles may not be the same as the corresponding bulk properties when the particles are embedded in a polymer matrix. To have a better understanding of the material properties and provide useful insight and design guidelines for particulate composites, the concept of “effective in situ constituent properties” and an indirect method were employed in this study. This approach allows for the indirect determination of the particle’s in situ material properties by combining the experimentally determined composite and matrix properties and finite element (FE) models for predicting the corresponding composite properties, then backing out the effective in situ particle properties. The proposed approach was demonstrated with micron-size SiO2 particle reinforced epoxy composites over a range of particle loading fractions up to 35 vol.% by indirectly determining both the effective Young’s modulus and the effective CTE of the particles. To the best of our knowledge, this study is the first published report on the indirect determination of both the Young’s modulus and the CTE of micron size particles in particulate composites. Similar results on Young’s modulus of micron-size SiO2 particles measured from nano-indentation testing are encouraging.  相似文献   

16.
Cd1-xZnxSe (x = 0, 0.5 and 1) thin films have been deposited onto glass substrates using thermal evaporation technique. The lattice constants, grain size, microstrain and dislocation density were studied by using X-ray diffraction. In addition the optical constants were calculated in the wavelength range 400-2500 nm. Transmittance and reflectance were used to calculate the absorption coefficient α and the optical band gap Eg. The linear relation of (αhυ)2 as a function of photon energy hυ for the thin films illustrated that the films exhibit a direct band gap, which increases with increasing Zn content. This increasing of optical band gap was interpreted in accordance to the increasing in the cohesive energy. Optical constants, such as refractive index n, optical conductivity σopt, complex dielectric constant, relaxation time τ and dissipation factor tanδ were determined. The optical dispersion parameters E0, Ed were determined according to Wemple and Di Domenico method.  相似文献   

17.
水浸腐蚀对SiO_2/Ag/SiO_2复合膜光学特性的影响   总被引:2,自引:0,他引:2  
用蒸镀法制备了SiO2 Ag SiO2 复合膜 ,探讨了水浸腐蚀和薄膜厚度对该复合膜光学特性的影响。试验结果表明 :适当增加复合膜中SiO2 膜层的厚度不但可以提高SiO2 Ag SiO2 复合膜可见光的透光率 ,而且可以相对有效地防止复合膜进一步被氧化 ,提高SiO2 Ag SiO2 复合膜的抗水浸腐蚀性能  相似文献   

18.
Single-crystalline Sb2S3 nanotubes have been successfully prepared by a simple hydrothermal method. It was found that ethylenediaminetetraacetic acid (EDTA) plays a key role in the formation of Sb2S3 nanotubes. Without EDTA, only irregular particles with a size of several micrometers were produced. The morphology and structure of the obtained Sb2S3 nanotubes were characterized by XRD, SEM, TEM, and EDS analysis in detail. UV–vis–NIR spectroscopy was further employed to estimate the band gap energy of the obtained products. The measurement of the optical properties revealed that the obtained nanotubes have a band gap of 1.55 eV. The obtained Sb2S3 nanotubes may find potential applications in photoelectronic and solar energy because the experimental band gap is close to the optimum value for photovoltaic conversion.  相似文献   

19.
M.F. Al-Kuhaili 《Vacuum》2008,82(6):623-629
Thin films of copper oxide were deposited by thermal evaporation of cuprous oxide (Cu2O) powder. The substrates were either unheated or heated to a temperature of 300 °C. The films were also annealed in air at a temperature of 500 °C for 3 h. The films were characterized by X-ray photoelectron spectroscopy, X-ray diffraction and UV-visible spectrophotometry. The effects of the substrate temperature and post-deposition annealing on the chemical, structural and optical properties of the films were investigated. As-deposited films on unheated substrates consisted of mixed cupric oxide (CuO) and Cu2O phases, with a higher concentration of the Cu2O phase. However, the films deposited on heated substrates and the annealed films were predominantly of the CuO phase.  相似文献   

20.
A semi-organic bisthiourea sodium fluoride (BTSF) is synthesized at ambient temperature and the single crystal of bisthiourea sodium fluoride is grown in slow evaporation technique using water as solvent. The cell parameters of the grown crystal are estimated from single crystal XRD analysis and also unambiguous assignments of fundamental modes of various molecular groups are made from the recorded FTIR and FT-Raman spectra. The thermal stability of the grown crystal is investigated using thermo-gravimetric analysis studies. Optical transmittance percentage of the grown crystal is measured from UV-VIS studies.  相似文献   

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